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By L. Cong, C. Liu, N. Zhang, W. Cao, C. Zhou, X. Fan

"The modes of occurrence of arsenic and the effects of low-intensity leaching-flotation on arsenic removal from coal slime from the Tanggongta Plant, Inner Mongolia, China were investigated. The coal slime was examined using hydride generation inductively coupled plasma optical emission spectrometry and X-ray diffraction to obtain the content of elements and the major minerals. The modes of occurrence of arsenic in minerals were determined using selective leaching, float-and-sink analysis, and polarized light microscopy. The results indicate that pyrite is the dominant carrier of arsenic in the coal slime, which predominantly exists in association with clay. Significant proportion of the arsenic is removed by a low-intensity leaching-flotation process, consistent with the data from selective leaching and flotation of gangue. The results show that low intensity leaching-alkali washing-flotation is more efficient than direct flotation and low-intensity leaching-flotation.IntroductionUnderstanding the occurrence of arsenic in coal and its removal is significant in optimizing coal utilization, because arsenic in the environment is viewed as a potentially toxic trace element (Finkelman, Belkin, and Zhang, 1999; Hall, 2002; Smith et al., 1992; Smedley et al., 2003; Zheng et al., 1999). Many studies on the modes of occurrence and concentration trends of arsenic in different coal and washing products have been performed (Diehl, Goldhaber, and Hatch, 2004; Kolker et al., 2000; Quick and Irons, 2002; Wang et al., 2006; Fan et al., 2016). Trace elements are usually preferentially associated with certain minerals and the form that these minerals take will influence the efficiency of removal during cleaning (Quick and Irons, 2002). Arsenic is mainly associated with minerals such as pyrite, carbonate, and silicate (Demir et al., 1998; Diehl, Goldhaber, and Hatch, 2004; Zhou et al., 2014). The existence of organically bound arsenic was also confirmed using X-ray absorption (Kolker et al., 2000). However, inorganic arsenic is the principal source of pollution because of its leachability and high concentration compared with organic arsenic (Fujino et al., 2004; Gao, Lu, and Wang, 2010; Jiang et al., 2008; Kolker et al., 2000)."

Jan 1, 2017

The key functions of project evaluation are to assess potential profitability and to develop an effective operational design. For mining projects, design aspects include mining methodology, ore treatment methodology and production rates. All of these characteristics impact on project economics and overall value. Resource models, which form the ultimate basis of project evaluation, typically consist of tonnes above cut-off, grade above cut-off and the spatial distribution (connectivity) of tonnes/grade above cut-off, for one or more variables. Dilution, ore loss and metallurgical recovery are all modifying factors applied to the resource model during evaluation and determination of profitability. A key issue is: how is the value determined? In addition to traditional combination of in situ tonnes/grade, the following merit serious consideration: the concentration of deleterious elements, throughput rates, mining/processing costs and - importantly - metallurgical recovery. Geometallurgy is an emerging field targeted at integrating these issues by identifying either direct measures or proxies for throughput (hardness, grindability), recovery (liberation, mineral shape/texture, etc) and concentrate quality from easily collected macro-, meso- and microscopic data. These 'geometallurgical variables' drive project costs and revenues in a fundamental way. For geometallurgical characterisation to have a real impact on business design, it must enable improved mine planning. When creating spatial estimates for such variables, it is preferable to find proxies that can be measured as close to the intact rock mass as possible. However, spatial estimation of proxies for geometallurgical properties and responses is complex and requires special consideration. Unlike grades, both proxies and absolute measures of geometallurgical variables are not necessarily linear or additive and therefore require very careful geostatistical consideration. In some cases, models must predict extreme values of geometallurgical attributes rather than averages. Incorrect characterisation of metallurgical recovery/throughput can (and has) led to misspecification of the scale of projects, and thus can be seriously value destructive. Aspects of geometallurgy have long been important in iron, bauxite, manganese and coal deposits and are increasingly on the radar for base and precious metal miners. However, as more metallurgically complex deposits are developed and mining of large-scale, low-grade deposits becomes more commonplace, the importance of characterising the metallurgical response in order to generate properly optimised projects will rapidly increase. It is possible that in many `traditional' (ie grades and tonnes) reserve models, the variables that drive the project are missing!

Jan 1, 2007

By F. Diot, S. K. Tripathy, L. O. Filippov, I. Filippova

Among different pre-treatment methods, a high voltage electric pulse was recently developed and is gaining popularity due to multi-benefits such as pre-weakening along the grain boundaries, as well as size reduction to improve the liberation characteristics. In this paper, the pre-treatment using high voltage electric pulse of lithium-bearing granite ore was studied to understand the morphology through texture, as well as the friability of the particles. To understand the phenomena, SELFRAG, a laboratory facility used for generating high voltage electric pulse and key operating variables were varied. The role of applied voltage (94.5-195.5 kV), number pulse (3-87), and the frequency of pulse (1.3-4.7 Hz) was varied to understand the liberation characteristics as well as energy consumption. Characterisation tools such as optical, and electron microscopy were used to describe the pre-weakening phenomena through textural features. Further, the energy required to break the particle to finer sizes as well as friability were determined and described. Keywords: Pre-treatment, high voltage electric pulse, lithium, liberation, grinding

Jan 1, 2020

By N. Steven

Published parameters from the Mufulira copper in situ leach (ISL) in Zambia are used for order-of-magnitude flow-rate calculations for an envisaged gold ISL in back-filled Witwatersrand stopes. A successful leach operation requires that the porous medium, usually a sand, has a hydraulic conductivity in excess of 5 x10-7m/second (i.e. a permeability >50 millidarcies).Empirical evidence suggests that average linear velocities would be of the order of 60 m/day if the backfill has the grain size of a fine sand. The proposed gold lixiviant would probably be an alkaline or ammonium thiosulphate, not cyanide. The resultant sulphate-rich ground and drainage waters could probably be processed using existing purification techniques to produce gypsum and magnesium/calcium carbonate. Within the next 100 years it is inevitable that solution mining will find widespread application on the Witwatersrand, if not for gold extraction, then certainly for water remediation purposes.

Jan 1, 2009

By I. Zh. Bunin, M. V. Ryazantseva, V. A. Chanturiya

The paper proposes a new method for selective calciferous separation. The effect was achieved through the application of the combination of high-power electromagnetic pulses (HPEMP) and a specific reagent regime of the flotation. The combined application of HPEMP with the special reagent regime allowed for the improvement of the scheelite floatability: the recovery of CaWO4 rises from 41.2 % (untreated sample) to 58.5 (sample treated at 103 pulses). In contrast, the floatability of calcite decreases significantly: the recovery of calcite drops from 74.7% (untreated sample) to 41.1 % (sample treated at 103 pulses). The conditions were found for the selective separation of the minerals with very close flotation properties. Keywords: Calcite, scheelite, flotation, high-power electromagnetic pulses, DRIFT, XPS

Jan 1, 2020

By G. du T. Judeel

An investigation was carried out to determine whether a numerical model could be constructed that would produce results that realistically represent actual ground deformations in and around a vertical shaft. The ground deformation was brought about by the partial extraction of the shaft pillar. A special characteristic of the rock masses, affected by the shaft pillar extraction, was that the shaft was located in poor quality rock masses. After the extraction of a portion of the shaft pillar, excessive deformations occurred at the shaft/reef intersection. Therefore, a decision was taken to extract the entire shaft pillar protecting the shaft by a proposed waste-cut across the shaft. The effects of stress and displacement on the shaft were investigated by using inelastic numerical modelling in different stages. A calibrated numerical model was constructed producing modelled results comparable to the actual displacements along the shaft. Des recherches ont été poursuivies pour déterminer si on pouvait construire un modèle numérique qui donnerait des résultats représentant avec réalisme les déformations réelles du terrain à l’intérieur et autour d’un puits vertical. La déformation du terrain était entraînée par l’extraction partielle du massif de protection. Une caractéristique spéciale des masses rocheuses, affectées par l’extraction du massif de protection, était que le puits était situé dans des masses rocheuses de qualité inférieure. Après l’extraction d’une portion du massif de protection, des déformations excessives se sont produites à l’intersection du puits avec le filon. Par conséquent, la décision a été prise d’extraire le massif de protection en entier par une coupe de déblais à travers le puits. Les effets de contraintes et décalage furent étudiés en utilisant une modélisation numérique inélastique à des stages différents. Un modèle numérique calibré fut construit, donnant des résultats modelés comparables aux décalages réels le long du puits. Eine Untersuchung wurde durchgeführt um festzustellen, ob ein numerisches Modell konstruiert werden könnte, das Resultate produzieren würde, welche realistisch aktuelle Bodendeformationen in und um einen vertikale Schacht darstellen. Die Bodendeformation resultierte teilweise aus der Extraktion des Schachtpfeiler. Eine spezielle Eigenschaft der Gesteinsmassen, beeinflußt durch die Schachtpfeilerextraktion, war, daß der Schacht in Gesteinsmassen geringer Qualität situiert war. Nach der Extraktion eines Teils der Schachtpfeiler, traten übermäßige Deformationen am Schacht/Riff Kreuzungspunkt auf. Folglich wurde die Entscheidung getroffen, die gesamten Schachtpfosten zu extrahieren und den Schacht mittels eines geplanten Verlustschnittes quer zum Schacht zu schützen. Die Auswirkungen des Druckes und der Versetzung auf den Schacht wurden unter Anwendung unelastischer numerischer Modelle in unterschiedlichen Stadien untersucht. Ein kalibriertes numerisches Modell wurde konstruiert, welches berechenete Ergebnisse mit den tatsächlichen Versetzungen entlang des Schachtes vergleicht.

Jan 1, 2003

By B. Genc

Improving student success rates without compromising the quality of graduates is one of the biggest challenges expanding university programmes are facing in South Africa. By establishing a new Mine Design Laboratory (MDL) for higher learning in Mining Engineering, the School of Mining Engineering at the University of the Witwatersrand (Wits Mining) has achieved one of the important goals in its five-year strategic plan, i.e. to improve throughput in all years of study. Although the establishment of the laboratory has been a costly exercise, results so far have shown an improved success rate in most subjects taught in the facility. This paper outlines the design and equipment of the laboratory, the facilities incorporated, a comparison with the old laboratory, and the performance of students?all of which indicate how important it is to have proper facilities to improve the teaching of, and learning by, large classes. Through this initiative, Wits Mining has taken an important step that will contribute to addressing the skills shortages in the mining industry.

Jan 1, 2012

By R. S. J. Toit

Discussion: T. L. Gibbs,* (Honorary Vice-President and Fellow): In terms of the Pneumoconiosis Compensation Act of 1962, a Pneumoconiosis Risk Committee was established whose function it is to estimate (by whatever means the committee deems fit) in respect of every controlled mine the pneumoconiosis risk to which persons employed in a dusty atmosphere at that mine are exposed. In estimating such risk the committee may estimate different risks in respect of individual mines or parts of mines or classes or groups of mines or occupations or localities at mines. The pneumoconiosis risk may be reviewed and re-estimated at any time. The Act provides further that the General Council for Pneumoconiosis Compensation shall apportion the levy imposed on owners of controlled mines on the basis of the pneumoconiosis risk determined by the risk committee and the numbers of persons employed in a dusty atmosphere. The task of the risk committee is a most responsible one and also a very difficult and complex one in view of the many different types of mines, rock formations, dust conditions, etc. Quite obviously, comparisons between mines cannot be made on dust concentrations alone as different mineral dusts have different toxicity or pneumoconiosis response factors. However, with its present knowledge, the risk committee is satisfied that the risk at mines, other than coal mines, is related to the mean quartz-equivalent dust concentration to which persons are exposed and the estimation of risks is based on this relationship. From the above, it will be clear that the work done by Dr du Toit on the problem of basing the current rate of levies to provide for pneumoconiosis compensation on the current dust hazard at mines has been of immense value to the risk committee. Up to now the risk committee has not been able to obtain complete and accurate information on the dust exposure of persons at all mines - and, in fact, it is doubtful whether it will be economic or practicable to obtain this in the foreseeable future - but reasonable assessments have been possible from routine dust sampling in some cases and from periodic comprehensive dust surveys in others. As a temporary measure the risks of some mines were estimated initially on a group basis relating to average dust conditions and the type of rock and mineral mined, but as more information became available, differentiation between individual mines became possible. It is the aim of the risk committee to eventually apply such a differentiation in all cases and to ensure that within the bounds of practicability each mine pays for its risk and for its risk only. In this connection, the relationship between the levies and the amounts actually paid out in compensation are examined regularly. In conclusion, I wish to add my congratulations to the author on his excellent paper. His findings will assist materially in the just administration of that very important piece of beneficial legislation, the Pneumoconiosis Compensation Act. G. K. Sluis Cremer MD (Visitor): Dr du Toit has made a valiant attempt to relate dust hazard and the rate of collecting funds for the purpose of paying compensation for Pneumoconiosis. In doing so he has had to make a number of assumptious, some of which touch on the medical aspects of pneumoconiosis. It is worth discussing whether these assumptions are justifiable. Pneumoconiosis is defined in our Pneumoconiosis Act as permanent disease of the cardio-respiratory organs which is caused by the inhalation of mineral dust. To a non-medical person this definition has probably a clear cut meaning. The doctors however have to deal with such conditions as silicosis and asbestosis where there is a well defined dose response relationship to the inhalation of quartz and asbestos respectively and on the other hand chronic bronchitis where the relationship to dust inhalation is poorly defined and where certainly no clear dose response relationship has emerged after many investigations in this country and overseas. Nevertheless since 1953 about half of our certifications for Pneumoconiosis are on the grounds of chronic bronchitis i.e. the X-rays show no evidence of silicosis, asbestosis or other relevant disease. This fact must affect Dr du Toit's computations. The next assumption we should examine is the manner in which toxicity factors have been allocated to the various mineral species. These allocations have in part been based on a restricted number of animal experiments carried out overseas but mostly in South Africa by Webster at the Pneumoconiosis Research Unit. To extrapolate the findings in a relatively small number of animal experiments to the expected reactious in man is a notoriously dangerous exercise. Furthermore the bracketing together of all silicates (except asbestos) and the insoluble metal oxides is entirely unacceptable. Talc (a hydrated silicate of magnesium) and muscovite mica (a silicate of aluminium and potassium) cause pneumoconiosis in their own right. On the other hand

Jan 3, 1970

It is well understood that to develop wagon wheels with higher abrasion resistance, fracture toughness, and fatigue resistance, steels with lower amounts of inclusions need to be used. Clean steels are produced with technologies that minimize the amount of inclusions in the microstructure. The demand for cleaner steels is high, and lowering of non-metallic oxide inclusions and controlling their morphology, composition, and size distribution is vital. Reduction of residual impurity elements such as sulphur, phosphorus, hydrogen, nitrogen, and trace elements is essential in the production of cleaner steel. Material cleanliness is vital for fatigue endurance, since oxide inclusions may act as stress concentrators and initiation points for fatigue cracks. To better understand the relationship between the cleanliness and toughness of the 34-inch cast wagon wheels, two samples of different levels of cleanliness were supplied for investigation. This paper presents the results of metallurgical analysis using scanning electron microscopy(SEM), energy-dispersive spectrometry (EDS), and mechanical tests for the pearlitic high-performance cast rail wagon wheel (identified as Class B) that are currently being used. The Charpy V-notch impact test results for the three samples from wagon wheels were compared. With the aid of SEM/EDS analysis system, non-metallic inclusions in these steels were detected, and it was possible to determine the position, size, shape, and composition of each particle. Alumina and manganese sulphide inclusions could be identified as the dominant inclusion types in the investigated samples. Fracture surface analysis of the Charpy specimen with high inclusions indicated that transgranular cleavage was the predominant fracture mode. Fractography of fracture surfaces of Charpy impact test samples also showed improvement of toughness properties on the clean sample.

Jan 1, 2013

By J. C. M. De Souza

The Samarco pipeline, the longest in the world for iron ore slurry transportation, started operation in 1977 to transport concentrate from the Germano facilities, in the state of Minas Gerais, to the pelletizing plant, located 396 km away, in the state of Espirito Santo, on the south-east coast of Brazil. Designed for a nominal capacity of 12 million tons per year, the pipeline reached 15.5 million/year due to operational improvement and, in late 2005, it was resized to transport 16.5 million tons per year, with the installation of a booster station. In order to ensure the accurate performance of the system, a pipeline cleaning programme was carried out and, since it has been29 years from the operation start-up, precise knowledge of the pipe condition would be fundamental to guarantee the success of the project. The cleaning programme demonstrated the potential of operational gains from this initiative, and its effect on the corrosion control and future measures, which should be permanently adopted to maintain the improved capacity. The intelligent pig runs provided essential data used to establish a pipeline integrity programme that allowed Samarco to develop a pipe repair plan based on the severity and significance of the features and to implement a future pipe replacement plan.

Jan 1, 2007

By Monica M. Cole

The Empress nickel/copper deposit west of Gatooma in Rhodesia occurs within gabbro and amphibolite, disposed at the contact of a granodiorite stock (Barebottom Hill) and the surrounding greenstones of the Archaen Bulawayan System. The orebody has a pipelike form and a poor surface expression due to plantation of the area by Miocene (Africa) and later Victoria Falls erosion cycles. Barebottom Hill represents a monadnock remnant in the geomorphological surfaces while traces of the once larger Empress orebody have been removed. Limitations in soil geochemistry necessitated both studies of the vegetation ecology and the biogeochemistry of the area, both of which were anomalous. The use of geobotany was found to be restricted but biogeochemistry offers a most effective prospecting tool and was found to define the sub-outcrop of the ore-body more precisely than soil geochemistry since these methods reflect and differentiate anomalies emanating from bedrock mineralisation and those due to surface phenomena.

By H. L. Zimba

Flotation involves the selective levitation of mineral and its transfer from cell to launder. The flotation rate is the rate of this transfer. It may be defined by the slope of a recovery-time curve for any cell in a bank or at any time in a batch operation. The objective in flotation rate study is an equation expressing the rate in terms of some measurable property of the pulp. This can be either the concentration of floatable mineral in weight per unit volume or a relative concentration, which will be a function of the recovery. A rate equation for an actual flotation pulp will contain at least two constants, both to be determined from the collected data. The data used in this paper were collected from bench-scale flotation tests on Konkola primary mill cyclone overflow at various pulp densities and pre-flotation thickener underflow at a pulp density of 35% solids by weight.

Jan 1, 2009

By Oaitse Medupe

The feed to the BCL concentrator is made of the ore from Phikwe No3 shaft, Selebi shaft and Selebi North shaft. The receiving bin of the concentrator has daily throughput of 7869mt live capacity of ore with feed grade from underground operation of 0.70%Ni, 0.75% Cu and 0.05% Co. The valuable minerals in the ore are Pentlandite, Chalcopyrite. Cobalt is present mainly in the solid solution in pentlandite. The common non-sulphides minerals are Amphibolites, quartz, micas, and Feldspar while pyrite and pyrrhotite are the major gangue sulphides. Pyrrhotite contains between 0.1% and 1% Ni in solid solution. From the mineralogical investigation, it was found that approximately 65% of the pentlandite in the ore occurs as exsolutions in the pyrrhotite and the grain sizes ranges from 8 to 38µm. about 25% of the nickel bearing pentlandite is medium grained and subhedral. This kind of pentlandite occurs along the cracks of pyrrhotite or as inclusions in pyrrhotite. The rest of pentlandite present is disseminated in the gangue matrix. Because of the fine occurrence of pentlandite, fine grinding was conducted in order to improve the recovery as well as the concentrate quality. A series of subsequent flotation test were performed in order to evaluate grinds of 35, 40, 45, 50, 60 and 80% passing 75µm. It was observed that ? The mass pull increased together with increasing fineness of grind ? Similar nickel recoveries were obtained at 35 and 40% passing 75µm but from 50% and 60% the grind was seen to adversely affect the nickel recovery. At 80% passing 75µm the recovery increased by small amount. ? Flotation kinetics showed higher initial nickel recoveries but these did not translate into higher final recoveries. ? Grinding finer than 80% passing 75µm yield very high grades of the concentrate in the first minute of the flotation test, and the grade is dramatically reduced in the fifth minute of the test. It was concluded that the current grind of approximately 48% passing 75µm is close to the optimum and no significant benefit were found to be associated with finer primary grinds. The inconsistence of the grade and recovery as well as the pentlandite losses will be discussed. Keywords: Pentlandite, Nickel losses, Grain size, Flotation

Jan 1, 2007

By H. A. D. Kirsten

Mining-induced seismicity is usually evaluated in terms of continuum elastic analyses, and is quantified in terms of energy release rate as state parameter and excess shear stress along particular features on which failure may be induced. Although both of these quantities are representative measures of potential seismic activity, elastic analyses do not enable the associated stresses and displacements in the rock in which failure occurs to be evaluated reliably. The paper compares the effect of depth, span, support stf1Jhess, field stress ratio, and discontinuity strength on mining induced seismicity determined from elastic analyses and from analyses in which discontinuities in the rock are allowed to fall. It is, accordingly, shown that the incidence and magnitudes of potential seismic events and the net excess shear as representative state parameter cannot be determined reliably from elastic analyses that do not account for the failure of ubiquitous discontinuities. The magnitudes of seismic events in rock in which ubiquitous discontinuities are allowed to fail are very considerably overestimated in elastic analyses. The extent of the seismic source region and the associated seismicity do not increase with depth, which, together with the improved containment of the concomitant rockburst damage by backfill is reassuring for mining at greater depth in future. For conventional support, the magnitude of potential seismicity increases for an increase in span in elastic rock, but remains unaffected in non-elastic rock. For backfill, the magnitude of potential sesmicity decreases substantially in elastic and non-elastic rock for an increase in span. Increases infield stress ratio very significantly reduce potential seismicity irrespective if the type if analysis, but effect the distribution if potential seismic events very differently in elastic and non-elastic rock.

Jan 1, 1994

The aspect ratio (mill diameter/mill length) of autogenous and semi autogenous mills varies widely and can be as high as three or as low as 0.5. The literature on the subject of what effect aspect ratio has on grinding mill performance or energy efficiency is almost non-existent. However, at the design stage of many grinding circuits the subject is often vigorously debated amongst metallurgists. In this paper the performance characteristics of mills with different aspect ratios are examined to determine whether process performance characteristics are a function of aspect ratio and whether high aspect ratio mills are any more or less energy efficient than low aspect ratio units. Data from both pilot and full-scale mills are used for this purpose in open and closed circuit configurations.

Jan 1, 2007

By F. H. Deist, H. D. Small, J. D. Austin, L. F. Duvel

The development and application of a computer system to aid in the planning of production in mines by F. H. DEIST, L. F. DUVEL, J. D. AUSTIN, and H. D. SMALL Published in the Journal, December 1972. Discussion by J. W. WILSON and R. W. HAZELL Although the Mine Planning Simulation Programme was originally developed as an aid to coal-mine planning, its extreme flexibility has enabled us to simulate gold-mine planning with equal facility. The initial application of the Mine Planning Simulation Model was in a small area of a large Free State gold mine where the primary aim was to assess the applicability of the programme to the gold-mining situation.

Jan 12, 1972

By J. O. Roux

The Impala Platinum Limited Base Metals Refinery in Springs, South Africa, refines convertor matte containing base metals and PGM?s (platinum group metals) using a hydrometallurgical process. In addition to a PGM-rich concentrate that is further refined, the Base Metals Refinery produces nickel (in powder or briquette form), copper cathodes and cobalt powder. Five leaching stages are utilized to remove the base metals and impurities from the PGM concentrate. The project described in this paper involves a radical redesign of the second stage leach autoclave with the aim of reducing maintenance costs and downtime, increasing throughput and ensuring a safer working environment. The second stage leach process at the Base Metals Refinery, produces a PGM-rich residue through the extraction of copper and any remaining base metals from the first stage leach solid residue material. Leaching is performed in an autoclave operating at a pressure of 600 kPaG and a temperature of 140°C to 150°C. Concentrated H2SO4 is added to the feed to produce a solution with a free acid content between 10 and 30 g/L and a pH of less than 2. Oxygen is passed into the 1st and 2nd compartments of the autoclave. As a result of the aggressive, highly oxidizing conditions within the autoclave, the original design utilized a heavy wall carbon steel shell with lead lining and two layers of acid bricks. The bricks acted as a wear resistant material and ensured a low surface temperature at the skin of the lead lining, whereas the lead lining acted as a corrosion barrier to protect the steel shell. These brick lined autoclaves were heavy, maintenance intensive and prone to catastrophic failure. A radical autoclave redesign was needed to reduce the high costs of manufacturing, installation and operation. Finite element modelling was used to optimize the design and various high alloy materials were investigated for the application. Based on extensive test work, the carbon steel shell was replaced with duplex SAF 2205 stainless steel in the new design. The use of this highly corrosion resistant material, eliminates the need for the lead and brick linings and reduces the wall thickness requirements substantially, resulting in an increase in the available volume for the same external shell dimensions. The vessel is welded in circular sections to form an elongated, impermeable, cylindrical body, with several agitator nozzles and compartments. The first new duplex stainless steel unit has been in continuous operation for more than 24 months and its performance has exceeded the highest expectations. The design was so successful that a patent has been registered. The major benefits of the new stainless steel design include increased throughput, improved performance, less downtime and a safer working environment. Lead has been eliminated and replaced with a more environmentally safe material, and the total lifespan of the vessel has been extended. In addition, the autoclave project has made significant developments in advancing the field of welding and optimizing the integrity of welding quality standards in South Africa.

Jan 1, 2009

1. Mintek reports The folowing reports are available from Mintek, Private Bag X3015, Randburg, 2125 South Africa. They are available at R25 (plus R3,25 GST) per copy to South African addressees, and US$25 per copy (including airmail postage) to addressees elsewhere. Report M91D A mineralogical investigation of samples from the Renosterkop tin prospect near Upington, by M.J. Southwood. First issued Jul. 1983, reissued May 1989. 16 pp. Report M256D The upgrading of Mamatwan manganese ores heavy-medium separation, by P. W. Overbeek. First issued Apr. 1986, reissued May 1989. Report M299D A mineralogical investigation of samples from the Eenzaamheid cobalt-molybdenum deposit, by C.D. de Nooy. First issued Jan. 1987; reissued May 1989. Report M301D The evaluation of manganese metal powder by automatic image analysis, by E.J. Oosthuyzen. First issued Feb. 1987, reissued May 1989. 13 pp. Report M311D Mineralogical and beneficiation studies of ore from Lutzputz, by R.N. Guest and C.T. Logan. First issued Mar. 1987, reissued May 1989. 13 pp. Report M314D The beneficiation of a sample of magnesium ca/crete, by L. Jonker. First issued Apr. 1987, reissued May 1989. 13pp. Report M369 The determination, by flow-injection analysis, of thiocyanate, by E.A. Jones and M-J. Hennings. Jun. 1989. 7pp. Report M389 A spectrophotometric method for the determination of zinc by flow-injection analysis, by D.E. Barnes and RA. Jones. Jul. 1989. 15 pp.2. Recent publications Pumps-principles and practice. Available from K. Myles & Associates CC, P .0. Box 2212, Northclif 2115. :200pp. R99 including GST. Standard handbook of hazardous waste treatment and disposal, edited by H.M. Freeman. Bergano Book Co., P .0. Box 190, Fairfield, CT 06430, USA. 1120 pp. US$130.Quality control handbook, by J. Juran and F. Gryna Jr. Bergano Book Co. (address as above). 4th 00. 1536pp. US$125.Refractories in the manufacture and transport of pig iron. Verlag Schmid GMBH, P.O. Box 6609, 7800 Freiburg, West Germany. DM 100. The user-computer interface in process control, byW.E. Gilmore, D.I. Gertman, and H.S. Blackman. London, Harcourt Brace Jovanovich Ltd, 1989. " 312pp. $29.Aluminum alloys-contemporary research and applications, edited by A.K. Vasudevan and R.D. Doherty. London, Harcourt Brace Jovanovich Ltd, 1989. " 676 pp. " £90.3. TMS publications issued recently The folowing publications are available from The Minerals, Metals & Materials Society, 420 Commonwealth Drive, Warendale, PA 15086, USA (Telephone: (412) 776-9000, Telex: 9103809397, Fax: 4127763770). Advances in magnesium alloys and composites, by H. Paris and W.H. Hunt (eds.). 145 pp. $65. Arsenic metallurgy-fundamentals and applications, by R. Reddy (ed.). 515 pp. $104. Casting of near net shape products, by Y. Sahai (ed.). 7oopp. $155.Continuous casting of non-ferous metals and alloys, by H.D. Merchant, D.E. Tyler, and E.H. Chia (eds.). 360 pp. $90.Dislocations and interfaces in semiconductors, by K. Rajan, D. Ast, and J. Narayan (eds.). 210pp. $75.

Jan 1, 1989

By A. F. Lee

Dr E. C. Hanekom (Visitor): Two years ago we used the bubble pick-up technique as developed at Anglo American Corporation for screening candidate flotation agents prepared in our laboratories. It was obviously necessary to know to what extent the technique gave reproducible results and a statistical evaluation of the test method was made using a mineral sample provided by Anglo American Corporation. A bubble of 2.0 mm diameter was used and the measuring graticule was divided into squares (units) with sides of 5.0 mm at 25 X magnification. The mineral granules had diameters from 53 to 74 mm. The bubble was loaded by depressing it against a layer of mineral grains to give an arbitrary but constant compression of 0.4-0.5 mm. It was rolled five times through 2 mm horizontal displacement. The bubble was then lifted, its load compacted by gently stirring and the projected area measured in squares (units) on the grid. Each substance was tested at 5 ppm concentration in distilled water at five points in the pH range 3-6. With these standardized conditions of operation the reproducibility of the test was studied. Four materials were tested and at each pH value the procedure of forming a bubble, picking up granules and counting the units was repeated ten times. From these results the standard deviation for a single count at any pH value was calculated for each material (Table 1. The coefficient of variation of approximately 3 per cent was relatively low and it was decided that further refinements in the counting procedure would be of doubtful benefit with the present apparatus. Similar experiments were carried out with 12 sample materials. In this case the bubble formation and pick-up were repeated four times at each pH value, the mean value was calculated for each set of four observations and final pick-up values for the materials were obtained by selecting the highest mean count. Each test was completely repeated a number of times as indicated in Table 2 and the standard deviation calculated. The results allowed the selection of the more promising materials and the rejection of poor performers at the 95 per cent confidence level. All tests were carried out by one operator. Some evidence was obtained that the method is sensitive to operator bias. In conclusion it can be said that from all the results analyzed it would appear that once operation conditions are fixed (viz operator, pH control) the precision of the method is adequate. The author wishes to thank Messrs African Explosives and Chemical Industries Limited for permission to publish these data. G. S. Stander and C. J. Kooij (Visitors): We must congratulate Mr Lee for this most interesting and useful development of the pick-up experimental method. It certainly provides research workers with an instrument which makes flotation more of a science and less of an art. We visited Mr Lee at his laboratory where he gave us a demonstration of the bubble pick-up instrument and technique as developed and improved by him.

Jan 12, 1969

By B. Kweto, W. Legodi, C. van Buuren, R. F. Sandenbergh

Biooxidation, and especially the BIOX® process, is a viable, economical and environmentally attractive process to liberate gold hosted in refractory sulfides by oxidatively leaching the sulfides as soluble sulfates. The moderate to high cyanide consumption during the subsequent cyanidiation of the washed biooxidation residue is probably caused by the retention on the solids of labile sulfur species formed during the multi-electron oxidation process of sulfide to sulfate. In this work the nature and mode of transport of the cyanicides in the products from the mesophile BIOX® process, as well as that of the combined mesophile and thermophile bioxidation process, were considered and strategies to reduce cyanide consumption evaluated. It was found that labile sulfur species were the major cyanide consumers in the mesophile biooxidation product, forming predominantly thiocyanate during cyanidation. The transfer of labile sulfur species was only marginally decreased by more intensive and thorough washing of the biooxidation products with warm and hot water, intense stirring and warm caustic leaching. A major reduction in cyanide consumption was however achieved by using a combined mesophile and thermophile biooxidation process. Keywords: Biooxidation, refractory sulfide gold ores, cyanide consumption

Jan 1, 2020