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By R. K. Amankwah, E. K. Asiam

Changes in the thermal-oxidation behavior and other properties of gold-bearing waste activated carbon when milled in both a ball mill and a vibratory mill were investigated. It was found that significant changes occurred in the oxidation temperature of the vibration-milled waste carbon as a result of increases in surface area and mechano-chemical activation. The mechano-chemical action brought about modifications in the crystal structure of the waste carbon. As a result, the vibration-milled sample was completely oxidized at a temperature of 450°C. Thus, the study established that vibration milling is a better way of lowering the temperature of oxidation of the waste carbon. Furthermore, the gold was found to be concentrated in the ash and, when leached with cyanide for 20 hrs, the gold recoveries from a sample having a head grade of 2 kg/t was 99.5% for the vibration-milled sample and 82% for the ball-milled sample. The lower gold recovery for the ball-milled sample was attributed to sintering of the ash, which was caused by the higher temperature required for its oxidation.

Jan 1, 1997

By John Jonkman

Many companies in the mining and minerals processing industry are finding themselves in the transition stage from the Industrial Age to the Information Age and are trying to become prepared for the Knowledge Age. To remain competitive in the decades ahead, they are faced with integrating the enterprise through the use of computers and networks. This paper discusses some common human and organizational barriers to enter- prise integration. It proposes how to develop the organizational and human' networks to match the capabilities of the technical networks which are being' implemented. Ten practical considerations are then presented for consideration in the executive suite in addressing the human side of implementing the computer integrated enterprise.

Jan 1, 1989

By Thomas M. Tharp, Mark A. Travers

A new method is presented for precracking three-point bending specimens for fracture toughness testing. A notched specimen of rectangular cross section is placed on a flat loading platen, with paper between specimen and platen. The specimen is loaded from above through a roller placed directly over the crack. The thin, high compliance joint between specimen and platen causes a distributed load on the bottom of the specimen. This results in bending at the cracked section and crack initiation at the notch tip. Since the joint is thin, its stiffness increases rapidly with deflection and crack propagation in the specimen generally remains stable and controllable. Fracture toughness KIC in a sandstone directly overlying the No. V coal was measured to be 0.27 MPa m 1/2. Even for cracks 1 cm long this value of KIC results in substantially lower effective tensile strength (modulus of rupture) in roof beams than is expected from intact rock strength.

Jan 1, 1986

By E. M. J. A. Pallone, F. N. Cunha, W. S. Resende, R. M. Stoll, R. C. Bradt

Utilization of the magnesium aluminate spinel in refractor' applications is briefly reviewed. The synthesis of a magnesia aluminate spinet aggregate from natural raw materials is considered in terms of the crystal chemistry of the spinet structure and expected impurities. Principles for the formation of this spinet refractory aggregate from different natural raw materials are presented. The basic concepts were then applied to the reaction of a bauxitic clay with a natural magnesite. This combination of raw materials has the potential to produce a low-cost refractor' aggregate that is a composite of spinel and forsterite. Experimental results are reported to produce a spinel refractor.' aggregate containing a small amount of forsterite. It possesses low apparent porosity and high bulk density suitable for industrial refractor' applications, including steelmaking, aluminum and copper foundries and cement production.

Jan 1, 2002

By Leonhard Schmid

INTRODUCTION In the region of Zurich several of the Swiss Interstate Highways meet and have to be linked to form a continuous network. The subalpine glacial topography with hills, ridges and lakes requires the construction of many tunnels (Figure 1). The Milchbuck Tunnel forms part of the inner arterial highway system of the city of Zurich. It passes underneath the ridge separating the Limmat and Glatt valleys. In its final configuration the tunnel will consist of two parallel three-lane tunnels (Figure 2). For the time being only one tunnel is constructed. This tunnel will be operated with two outbound (climbing) lanes and a single inbound (descending) lane (Figure 3). The owner, the Canton of Zurich, awarded the contract for the construction to a joint venture with the following three contractors: Locher & Cie AG (leader), Prader AG, A. Brunner's Erben, all located in Zurich. The actual freezing was performed by subcontractor Philipp Holzmann AG, Mannheim, West Germany. Electrowatt Engineering Services Ltd, Zurich, was design engineer and performed the construction supervision.

Jan 1, 1981

By R. Mensah-Biney, M. T. Hepworth, K. J. Reid

The kinetics of gold-bromide loading onto activated carbon was investigated in a batch stirred reactor. Based on a second-order equation, the amount of gold adsorbed by the carbon was correlated with time. From a 30ºC solution containing 25 ppm Au and 0.8 g/L carbon, the rate constant for gold-bromide species onto activated carbon ranged from 0.27 x 10-3 to 1.2 x 10-3 (kg/t)-1 min-1. The equilibrium saturation capacity (Qe) was 36 ±3.0 kg/t from the same system. The rate of loading increased with increasing temperature and decreasing particle size, pH and solution gold concentration. The calculated activation energy (Ea) was 8.8 kcal/mole, significantly higher than those reported for physical adsorption. The equilibrium saturation capacity (Qe) increased with increasing concentration of gold in solution but was independent of other variables such as temperature, agitation speed, particle size and pH. These rate constants and equilibrium saturation capacity for the gold-bromide species are higher than those reported for the gold-cyanide systems.

Jan 1, 1998

By Satya Harpalani, Xue Zhao

This paper discusses the results of an experimental investigation to study the release of methane in coalbeds. Absolute porosity of coal samples was first determined experimentally. Following the porosity measurement, adsorption/ desorption tests were carried out to determine the gas content of coal and the rate at which it is released. Finally, micrographs were obtained using electron microscopy and the use of a physical model, developed to explain the gas flow behavior of coal, was justified. The results of this study indicated that the measured absolute porosity of the coal sample was between 5 an 6%. This was significantly lower than the porosity estimated by comparing the micrograph area occupied by the pores and the area of observation for several micrographs, suggesting that coal has a large number of pores with a very small volume. The micrographs also clearly indicated that coal has a large interconnected network of cleats and microfractures. The adsorption/desorption experiments showed a hysteresis between the adsorption and desorption isotherms. Also, the rate of desorption was found to be strongly dependent on the particle size of the specimen.

Jan 1, 1989

By A. E. Reisenauer, R. W. Nelson, G. W. Gee

A model assessment was made to evaluate contaminant transport to ground water from clay-lined and unlined tailings pits. The input hydrologic soil characteristics were measured on materials typical of those found at the Morton Ranch uranium mill site in central Wyoming. The assessment involved combined saturated and partially saturated flow and contaminant transport models for two-dimensional cross-sections typical of the proposed Morton Ranch burial pits. Specifically obtained from the models were contaminant flow paths, the advancing contaminant flow fronts for sorbed and non-sorbed constituents, and travel times of contaminants along flow paths. Such results enable evaluation of the environmental consequences for the alternative control methods.

Jan 1, 1980

By C. Maltesh, P. Somasundaran, G. A. Gruber

Anionic conditioning of phosphate ores prior to fatty acid flotation is a critical step that determines the selectivity, recovers and, hence, the economics of the process. However, the chemical mechanisms operating during this conditioning step are not very well established. In this work, a comprehensive surrey of plant practice was conducted. Then, adsorption on flotation feed and francolite were studied under simulated plant conditions. Different adsorption mechanisms were found to be dominant under laboratory and plant conditions. In plant water, there was sonic physisorption of oleic acid on phosphate flotation feed and francolite, in addition to chemisorption. However, in distilled water under laboratory conditions, only chemisorption was detected. Fuel oil reduces the residual oleic acid in solution after adsorption, which explains the beneficial role of extender in phosphate flotation. The dissolved species in solution arising from the flotation feed or plant processing water are shown to clearly play a major role in determining the adsorption of oleic- acid on the substrates. The study also specifically demonstrates that, for the results to be used commercially, it is important to conduct the tests under plant mixing conditions and with the same plant water chemistry.

Jan 1, 1997

By A. S. Trimble, J. C. Hower

The petrographic composition of sized coal produced through the progressive grinding of a Central Appalachian high-volatile bituminous coal blend was analyzed for multiple sets either by removing fine, -200-mesh, coal after each test iteration or by retaining the fine coal in progressive test fractions. With prolonged grinding, coarser fractions tend to become depleted in vitrinite and vitrinite-rich microl ithotypes, leading to progressively harder-to-grind coal remaining in the oversize, +200-mesh, fractions. The latter trend is shown both by the maceral and microlithotype composition of the coal and by the increased slope and fractal dimension of size frequency distribution, implying an increase in hardness and resistance to grinding of the oversize coal.

Jan 1, 2000

By B. J. Arnold, C. D. Harrison, R. A. Lohnes

More than 544 Mt (600 million st) of coal are handled annually for use by this country's coal fired power plants. Coal is transported in various ways: overland conveyors, railcars, trucks and barges. It can travel short distances or thousands of miles, picking up moisture, freezing or drying. When the coal is received at the power plant, environmental problems with fugitive dust and further handling problems can arise. To ensure that power plant availability is not jeopardized by coal handling problems, the Electric Power Research Institute's (EPRI) Coal Quality Development Center (CQDC) developed a research program aimed at addressing utility coal handling problems. The program has identified key areas, and is investigating the cost and cause of coal handling problems as well as the solutions to these problems. The ultimate goal of the program is to develop a "handleability index" that utilities can use in their coal specifications or hardware for a utility's sampling system to predict handleability and determine if a coal shipment should be accepted.

Jan 1, 1993

By Stefan Zanon, Ty Faechner, Clayton V. Deutsch

Secondary data are important in geostatistical simulation of continuous variables. Geophysical data and geological trends are used for modeling porosity and permeability. Multiple mineral grades must often be modeled for mining applications. Sequential Gaussian simulation (SGS) is often used because of its relative simplicity and robustness. The two most common approaches to integrate secondary data in Gaussian simulation are with (1) locally varying mean, or (2) collocated cokriging. A significant problem with both of these techniques is variance inflation, that is, the variance of the resulting simulated values is too high because of an inappropriate decision of stationarity or an artifact of choosing a single secondary data in presence of many. We introduce a self-healing procedure for dynamic correction of this problem. The dynamic correction is different for the locally varying mean approach and for collocated cokriging since there are different reasons why each of these methods causes variance inflation. The reasons for variance inflation are discussed and the self-healing is applied to a number of data sets.

Jan 1, 2002

By M. J. McPherson, P. Mousset-Jones, G. Danko

Ventilation and refrigeration fortune climate modification contributes significantly to the operating costs of a deep hot mine. Mine climate simulation programs can he used to minimize the impact of these costs. There are several computer codes available to assist in this work. Whichever simulation program is used, it is the mine ventilation engineer who must supply the input data. This paper raises and answers the following question, namely, what accuracy is required of the basic input parameters, in order for a certain precision to he obtained in the predicted air temperatures? In the first part of the paper a new approach is described to estimate the dry and wet bulb temperature of the airflow, either in a dry or wet roadway. The calculation procedure allows an arbitrary temperature change with time, using Duhamel's superposition solution. Matrix-vector representation is applied to simplify the computational structure. In the second part of the paper the sensitivities of the dry and wet bulb air temperatures are analyzed, to the changes of the rock thernrophysical properties, the heat transfer coefficient, and the wetness factor.

Jan 1, 1987

By Charles L. Karr

Grinding is a necessary component in the processing of a number of minerals, and improvements in this area could provide substantial cost savings for the minerals industry. Optimizing the process of grinding, however, is a difficult task because there are multiple objectives; i.e., several aspects of the process are important including the fineness of the ground product, the energy consumed in the process, and the viscosity characteristics of the final slurry. Genetic algorithms (GAs) are search algorithms based on the mechanics of natural genetics and have been proven capable of solving multiple objective optimization problems. These robust search techniques are able to rapidly locate near-optimum solutions across a broad spectrum of very difficult optimization problems. In this paper, two varieties of GA are used to optimize a grinding process as it is described by a computer model: (1) a simple genetic algorithm (SGA) and (2) a micro genetic algorithm (MGA). The performance of these techniques is compared to the performance of a more conventional search technique, a simplex algorithm. Results indicate that the GAs are efficient, versatile, quite capable of improving the grinding process, and easily incorporated into the toolbox of today's process engineer.

Jan 1, 1993

By Bruce Kennedy, Dan Nilsson

Mining means drilling and blasting in order to break down the rock, loading and transport, and often also crushing the ore down to a suitable size. These operations can be done in open pits or in underground mines, and also, to a lesser extent, in marine mining. The same operations are also used in various types of construction, i.e., for roads, water power stations, etc. Before beginning a detailed economic analysis of the factors which enter into deciding whether to mine by open-pit or underground mining, and at what point a change should be made from open-pit to underground mining, or vice versa, it is of interest to consider some general factors.

Jan 1, 1982

By E. Topuz, M. J. McPherson, I. M. Konduri

The research is carried out to investigate the flow mechanics and effectiveness of face ventilation using induction fans, as an effort to provide a more efficient alternative to conventional auxiliary duct or brattice ventilation systems. The induction effects and plume longevity of fluid jets are being studied with the help of a plexi-glass model, using water as the fluid medium and creating a system that is dynamically similar to the flow in mine headings. This scaled model represents a typical 1.5m x 6m x 25m heading connecting to a crosscut. Reynolds Number criteria are used to obtain dynamic similarity of the flow in the designed model to simulate real mining conditions. The role of various parameters such as nozzle position in three dimensions, airway roughness, nozzle geometry, and flow rate in the jet are studied. During the laboratory tests, flow visualization techniques, coupled with still and video photography, were employed to identify the flow patterns. The results indicate that in typical coal mine headings, jet fans can produce effective face ventilation for distance up to 30 meters.

Jan 1, 1995

By Kerby Glass, Glenn A. Gruber

Mr. C. A. Hollingsworth introduced commercial column flotation to the Florida Phosphate Industry in 1976, with a six feet diameter prototype cell at the Tenoroc Mine. More than two-dozen column cells have been installed in phosphate beneficiation plants since then. The increased interest in column cells for phosphate flotation, and their potential use in new plant construction, prompted the Florida Institute of Phosphate Research to fund programs to investigate various aspects of column flotation. This report describes a test program, conducted by JACOBS at CF Industries Hardee Complex II, as part of a comprehensive research program awarded to the University of Florida by the Florida Institute of Phosphate Research. The 1.5 feet diameter test column was operated with plant process water and plant reagentized flotation feed. Several variables considered for column cells design and operation were tested. Feed specific capacity, air superficial velocity, and the length to diameter ratio of the column were the variables that influenced phosphate recovery. Concentrate phosphate grade was influenced by concentrate superficial velocity and feed specific capacity.

Jan 1, 2002

By Ryan Lindmark, Guoxing Gu, Zhenghe Xu, Jacob H. Masllyah

Induction time is often referred to the time required to form a stable three-phase contact between a gas bubble and a flat or droplet surface in a liquid medium. It can be used to quantify the attachment process in aflotation system. Various techniques have been developed to measure this important parameter. Due to its importance in flotation systems and other processes, significant advances in refining the induction time measurement techniques have recently been made. This paper summarizes these recent advances and describes a novel method developed to monitor bubble attachment to a pendant bitumen drop or bitumen-coated flat surface. This visualization-based method offers a higher sensitivity and accuracy than the previously developed apparatuses in the induction time measurement. As an example, the induction time for oxygen bubble-bitumen attachment was measured at a fixed bubble size as a function of temperature in two different aqueous solutions. The results showed that higher process temperature is favorable for oxygen bubble-bitumen attachment and hence bitumen flotation. Addition of calcium to the aqueous solution slightly decreased induction time.

Jan 1, 2005

By M. A. Marticorena, R. Stratton-Crawley, C. I. Basilio

Diethylenetriamine (DETA) is a selective depressant for nickeliferous pyrrhotite during pentlandite flotation. Laboratory flotation tests conducted on ore and process samples showed that pyrrhotite rejection is greatly improved by small additions of DETA; however, the effectiveness of this depressant is most noticeable when the mineral sample is oxidized. LIMS and XPS analyses conducted on flotation products and pyrrhotite specimens showed that the difficulty in pyrrhotite rejection arises from inadvertent activation of the mineral by heavy metal ions, such as Ni2+, cu2+ and Ag+, that are present in the process water. In the presence of DETA, however, the mineral is deactivated under oxidizing conditions. The deactivation mechanism may involve oxidation of the activation products, which are likely in the form of heavy metal sulfides, followed by solubilization by DETA. FTIR spectra of pyrrhotite electrodes contacted with DETA showed no trace of the reagent on the surface, substantiating the view that its role is one of complexing agent that enhances the dissolution of activation products under oxidizing conditions. FTIR spectra of pyrrhotite contacted with amyl xanthate solutions showed that both dixanthogen and iron xanthate are formed on the surface, the latter becoming more predominant at higher potentials. In the presence of DETA, however, only a small amount of xanthate is adsorbed on the mineral at potentials (Eh) approximately 200 mV higher than the case without DETA.

Jan 1, 1995

By R. Karl Zipf, Z. T. Bieniawski

Based on the premise that understanding the fundamental mechanics of fine fragment formation in coal will lead to reducing coal dust problems in mines, a thorough study of the mechanics of crack propagation in coal was undertaken. Two approaches were considered in an attempt to understand and quantify the fracture process as it relates to fine fragment formation. In one approach, theoretical models are used which describe the size of the fracture process zone which may relate to the amount of structural damage and fine fragment formation on the new crack surface. The other approach is based on the relationship between crack tip stress intensity and new surface appearance for mixed mode crack propagation. Preliminary observations with a scanning electron microscope support the premise that fine fragment formation is related to fracture surface appearance and fracture initiation conditions. An experimental program designed to supply the input parameters for these approaches is presently underway. The experimentation features mixed mode fracture toughness testing, using a special mixed mode testing rig, and fracture velocity measurements with a crack propagation gage. The interpretation of this data via the approaches discussed will provide further under- standing of the mechanics of fine fragment formation in coal.

Jan 1, 1986