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By S. Subramanian, K. A. Natarajan, D. N. Sathyanarayana

FTIR spectroscopy is used to study the ad¬sorption of an oxidized starch on hematite, corundum, and quart: substrates. The difference spectrum of the adsorbed starch on hematite indicates surface reactions involving -CH2OH and -COH groups and shows striking similarities with that of the ferric-starch system, suggesting chemical interaction between the iron of hematite and the starch adsorbate. The IR spectra of starch adsorbed on corundum and quart: show no evidence of chemical interaction, although hydrogen bonding is apparent. The extent of adsorption of starch on hematite. corundum, and quartz decreases along the series. The evidence for chemical interaction of starch with hematite is further obtained by the X-ray photoelectron spectra of starch adsorbed on hematite, showing noticeable decrease in peak positions of O(Is) and C(Is) of free starch. The Mössbauer spectrum of hematite with stanch adsorbed on it complements these findings.

Jan 1, 1990

By Jerry Demchuk, Allan Flemming, Stephan Day

Luscar Ltd. is currently developing open pit mining plans for the Telkwa Coal Project. Most waste rock is predicted to be non-acid generating but a proportion (less than 20%) is potentially acid generating. The waste management plan includes in-pit and ex-pit disposal of blended and till-capped waste rock, segregation and in-pit encapsulation of strongly potentially acid generating materials, and in-pit underwater disposal of coarse and fine tailings. The paper will present the steps used to design the waste management plan including the development of geochemical design criteria using various tests and theoretical and practical knowledge of waste behaviour.

Jan 1, 2000

By R. F. Holub, E. Franco, T. B. Borak, K. J. Schiager

INTRODUCTION According to a recent analysis by Schiager et al.(1981), inhalation of radon daughters continues to contribute the largest risk from exposure to radioactive materials in underground uranium mines. The American National Standards Institute (1973) has published a concensus standard for radiation protection in uranium mines. According to this standard, a monitoring system for radon daughters must be capable of measuring the annual accumulated exposure in working level months within an uncertainty interval of 50% at the 95% confidence level. To satisfy this criterion, uranium mining companies in the USA have adopted a procedure consisting of single or periodic measurements of the air concentration of radon daughters. All of the measurement methods sample a known volume of air through a filter. After a specified delay interval, the filter is analyzed for radioactivity. The exposure rate from total airborne potential alpha energy in units of working level (WL) is estimated from the measured activity on the filter. For control purposes, this measurement establishes whether or not a work area is safe for occupancy by miners. For routine dosimetry, the concentration estimated from the grab sample is assigned to the appropriate work area. It is then assumed that the concentration of radon progeny is equal to the average of the two measurements at the beginning and end of the specified interval. Meanwhile, the work locations and exposure times of each miner are recorded on the daily time card and verified by the shift supervisor. Most cards provide space for 15-minute time intervals. The exposure in working-level hours (WL-hr) for each shift is obtained by summing the time spent in a given location multiplied by the exposure rate (WL) assigned to that location.The exposure of an individual miner to radon progeny is summarized on a weekly basis and commonly reviewed each month. These values are then accumulated in units of working level- months (WLM) during the calendar year. EVALUATION TECHNIQUE AND RESULTS The evaluation of grab sampling methods for monitoring exposure to radon progeny is presented in two sections. The first section examines each method individually according to accuracy, precision, and uncertainties attributed to human errors. The second section includes an analysis of procedures which are common to all measurement methods. The ultimate goal is to determine whether a specific measurement method, or grab sampling in general, can fulfill the criterion that the annual accumulated exposure of each miner be known to within ± 50% at the 95% confidence level. In addition it is essential that the above criterion be satisfied at an acceptable cost to the mining company. The results of each testing procedure are presented in terms of the contribution of the relative uncertainty in the estimates of cumulative WLM. Each of these are then combined to form a figure of merit for the complete monitoring system. The method of combining statistical uncertainties and interpretation of the results is subject to some debate. However, since all of the tested parameters enter into the final computation of WLM multiplicatively, we have used the commonly accepted procedure of combining the squares of the relative uncertainties. We have also assumed that each of the uncertainties is derived from independent random variables and the covariance of any two variables is zero. A description of each grab sampling measuring method is given in Table 1. Also included is the equation used to compute WL from the measured quantities. Accuracy (U A) Our definition of accuracy is based on the uncertainty inherent in any method which attempts to estimate potential alpha energy without unambiguously determining the concentration of the three unknown radioisotopes, RaA, RaB and RaC. (For simplicity, the RaC and RaC' nuclides are referred to in combination as RaC.) The inherent uncertainty strongly depends on the mixture of these three components at the time of measurement.

Jan 1, 1981

The sixth annual conference of the Mineral Economics and Management Society (MEMS) was held Feb. 27 through March 1 in Boulder, CO. This year's event was attended by more than 100 academic, industrial, government and other professionals interested in mineral economics and materials management. With about 250 members worldwide, this not-for-profit society seeks to promote scientific and economic analysis of current relevant issues. This year's program was sponsored by Alcan, Bateman Engineering, Cyprus Amax Minerals, J.P Morgan, Knight Piesold LLC and Newmont Gold. The conference's technical program consisted of six sessions. These included "Financial tools for a changing world," "Access to minerals," "Comparing North and South America," "Environmental issues in today's world" and "Transporting minerals." The program was concluded with a panel discussion titled "National minerals policies in Asia." In addition, a student papers session was held, in which students were given the opportunity to compete for a $1,000 award. The following is a brief review of the technical pro¬gram.

Jan 1, 1997

By S. G. McDowell

Automation techniques are used during the design stage of continuous miners to decrease the time required and ensure the accuracy of the design. This is followed by automated manufacturing processes to reduce manufacturing time and improve the quality and consistency of parts. Combined, the result is a more reliable machine that can provide ongoing production capability. With the use of automation to enhance operator effectiveness and monitor machine condition, the productivity of machines is also improved. Productivity of continuous miners doubled over a 10-year span (Fig. 1). Although this article focuses on the continuous miner, it should be recognized that production increases of the continuous miner would not be realized without increased capabilities throughout the rest of the mining system. There are several aspects of automation that have played a role in providing increased continuous miner productivity. Though some are considered indirect, they still had significant influence on the overall result. Basically, productivity increases are obtained by cutting, loading and transporting the coal at a maximum rate. In addition, these tasks must be consistent, with minimal downtime. Therefore, the miner had to improve in operational capability and reliability. Automation techniques used during machine design, manufacturing and operation have all played significant roles in achieving higher productivity.

Jan 1, 1991

By Richard D. Christie, K. Jay Pillai

In the past, it was not unusual for coal preparation plants to discard fine run-of-mine coal. This practice has changed due to increasing quantities of fine material, improvements in beneficiation methods, and the need to recover revenue from these fines. It is in this context that the coal industry has increasingly been turning to froth flotation for fine coal beneficiation. Reagent schemes have been developed to promote coal flotation and to treat the resulting refuse material. While reagent technology has improved, however, most plants rely on manual control of reagent dosing and circuit operation. This often results in misuse of reagents, loss of coal recovery, and consequent loss of revenue. Fine coal circuit operations can be dramatically improved through automation. Intelligent process control systems are now in use which are capable of optimizing reagent usage, maximizing coal recovery, and minimizing chemical costs associated with refuse handling. This paper describes a type of control system currently used in preparation plants, and provides data and information on the significant improvements such systems can produce.

Jan 1, 1994

By Peter A. Burger

The Greenvale Orebody comprises a series of contiguous lateriteprofiles developed terrace-like during the Cainozoic over a serpentinized harzburgite intrusive emplaced within Proterozoic schists. Each terrace displays individual characteristics of metal distribution. Topographically higher (older) profiles have been partially eroded and metal concentrations reworked. Within the laterite profile, metals have been concentrated or depleted according to their relative solubilities. At tropical temperatures, acidic meteoric waters have progressively depleted the ultrabasic parent rock of Si and Mg, leaving A1 and Fe to form a surface duricrust. Ni, Co, Mn and Cr have accumulated in the lower and middle levels of the weathering mantle. Only Ni and Co have accumulated to exploitable grades. Lateritization has evidently proceeded over a considerable portion of the Cainozoic and may be still continuing.

Jan 1, 1979

By G. E. S. Valadão

This paper is concerned with studying the dewatering behavior of three samples of iron ore products. The objective is to improve the industrial filtration performance by taking into account the laboratory results. Mineral samples came from the Iron Ore Quadrangle in the state of Minas Gerais, Brazil. These samples represent products from the industrial processing of hematitic ores. The samples have almost the same chemical and mineralogical compositions, but they have different size distributions and different specific surface areas. The filtration tests were performed using a modified Büchner funnel apparatus. The results indicate that size distribution and specific surface area have significant influences on dewatering behavior. For Sample 1, the addition of flocculant and/or surfactant was not essential to improving filtration performance. For Sample 3, the cake porosity and the cake thickness were influenced by the addition of the flocculant. On the other hand, the simultaneous addition of flocculant/surfactant decreased the cake formation time and reduced the cake moisture. For Samples 2 and 3, it was also observed that the industrial operation could be improved by taking into account these laboratory results. Key words: Dewatering, Iron ore, Hematite, Filtration, Flocculation, Surfactant

Jan 1, 2003

By J. M. Scharer, Bruce E. Halbert, Lysane Bouduc, Douglas B. Chambers, Jennifer L. Kirkaldy, Carol M. Pettit

Io contrast to acid mine drainage (AMD), neutral mine drainage (NMD) has not yet received widespread attention. Metal and sulphate concentrations can be elevated and of concern in neutral drainage from waste rock and tailings. In the present paper, metal release in high ionic strength mine drainage at neutral pH is evaluated at several mine sites. Specific factors including oxidation rates, buffering capacity, and hydrology are also addressed and their effect on the production of contaminated NMD from mine wastes is evaluated. Case studies are presented involving current seepage water quality and predictive geochemical modelling to illustrate the possible time frame and magnitude of the contamination.

Jan 1, 2000

By J. J. Moore, I. Iwasaki, L. A. Lindeke

Correlation of scale-up from small-scale batch laboratory mills to large-diameter industrial mills was established by performing two series of laboratory and pilot plant grinding tests using a magnetic taconite ore and a siliceous sulfide ore. In one series, controlled batch grinding tests in 203-, 508-, and 914-mm (8-, 20-, and 36-in.) diameter mills were carried out followed by a second series involving continuous grinding tests using 305-mm (12-in.) and then 1067-mm (42-in.) diameter pilot plant ball mills in open circuits. The effects of ball diameter on wear and of mill diameter on grinding power and ball wear are illustrated.

Jan 1, 1988

By S. K. Mishra, S. B. Kanungo, D. Biswal

An attempt was made to beneficiate low-grade, high-phosphorus manganese ores of the Garividi-Garbham region of Andhra Pradesh, India, by using wet high-intensity magnetic separation (WHIMS). The distribution behavior of both mass and chemical constituents in different size fractions of a typical highly weathered ore sample was studied to obtain information about the liberation characteristics of various chemical constituents. Magnetic separation indicated that in the +208-µm size fractions, P and acid insolubles were concentrated in the magnetic fractions. However, in the -208-µm size fractions, P and acid insolubles were concentrated in the nonmagnetic fraction because of a lower recovery of the magnetic fraction. Variations in field intensity between 1.3 and 1.75 T had little effect on the recovery and the grade of concentrate. The results also demonstrated that phosphorus was associated with all three major constituent phases, namely, oxides of Mn and Fe and aluminosilicate gangue minerals.

Jan 1, 2000

By S. Kelebek, S. O. Fekete

The flotation process developed at Falconbridge laboratories utilizes sulphur dioxide and diethylenetriamine (DETA) reagent combination in the depression of pyrrhotite to allow its separation from pentlandite and chalcopyrite. DETA by itself has failed to produce flotation selectivity with samples from plant and pilot plant streams which showed relatively high redox potentials. However, DETA was found to function effectively on laboratory-generated samples under certain conditions. The results of poor depression are in keeping with thermodynamic calculations which indicate that in the presence of sufficient xanthate and DETA, the formation of ferric dihydroxy xanthate and dixanthogen is possible under oxidizing conditions. The use of sulphur dioxide alone has also resulted in a rather poor depression of pyrrhotite. However, the combined use of these reagents has resulted in an efficient and consistent separation of pyrhotite from pentlandite and chalcopyrite. Various aspects of this selective flotation system are presented along with a discussion on possible operating mechanisms.

Jan 1, 1995

By Prasad Kummarapurugu, Maija Teijonsalo, Sirkka-Liisa Jamsa-Jounela

There has been a significant progress in the use of mathematical modeling and simulation in the minerals industry in the last decade. Process models have moved from academic world to important industrial tools. This paper reviews the status of mineral processing simulators and recent progress in simulator development and applications is discussed. The simulation for process design and optimisation is now an established technique, as evidenced by its increasing use of practising engineers through commercially available simulator software. The paper presents a systematic approach to the process study procedure for the control system development, clarified by practical case examples calculated by SimCon - a novel steady-state simulator for mineral processes. Examples of the application of SimCon in drawing flowsheets, calculating mass balances and making simulations for grinding and flotation processes are presented. At the end of the paper, the state-of-the-art and the future of computer-aided pro- cess study at mineral processing plants is discussed. Keywords: Simulators, modelling, object oriented programming, computer aided control system design

Jan 1, 1996

By Weston Bourret

The need for wartime supplies of uranium for the Manhattan Project prompted a 1944 study of uranium in South Africa. Uraninite had been reported by R.A. Cooper in 1923 in a Witwatersrand heavy- mineral concentrate, and the search for uranium, therefore, included the district's 30 operating mills. The method of investigation was simple: take bulk concentrate samples from the Wifley tables and determine their mineralogy. Samples were taken on a daily basis, although weekly composites also were taken of some mills. In 1944, most mills had simple gravity circuits and produced (I) a gravity concentrate, and (2) an all-slime [-75 pm (-200 mesh)] product. The tonnage throughput was known, and from that, head assays could be calculated. Concentrate samples were sent to the United States for chemical analyses. A Geiger counter set up in a Johannesburg hotel room provided preliminary data. The early data showed uraninite to be widespread. Microscopic, mineragraphic, and siezing tests were all under- taken in Johannesburg. Ultimately, tests led to a high grade (+90%) uraninite concentrate. Platinum and other heavies were the impurities. In seven months, the investigations had reached the stage where it was possible to forecast an annual production of 5.4 to 7.3 kt (6,000 to 8,000 st) of U3O8. The estimate is still realistic. Additional details are found in Bourret (1981).

Jan 1, 1991

By Richard V. Beck, Donald R. East, Jeremy P. Haile

In view of the increasing use of heap leach operations in the mining industry and the critically important performance of the leach pad liner in both the economic and environmental aspects of the design, it has become essential that the designer fully understand the factors affecting the performance of the liner. Minimizing the loss of pregnant solution through the leach pad liner is obviously of paramount importance to the economic efficiency and environmental compliance of the heap leach operation. Losses through the liner are a function of the hydraulic conductivity of the liner material and the hydraulic gradient across the liner. This applies to both natural and synthetic materials. The hydraulic gradient across the liner is a function of the build-up of solution above the liner, which in turn is determined by the permeability of the heap material, the slope of the liner, the drainage path length and the leachate infiltration rate. A relationship incorporating each of these parameters and their effect on the hydraulic head acting on the liner has been developed in terms of the Dupuit criterion, assuming one- dimensional flow with vertical accretion.

Jan 1, 1987

By R. Poulin, A. Lamontagne, N. Tassé

This paper presents the results of a laboratory investigation aiming to verify the concept of co-mingling of waste rock with layers of compacted tailings. Overall, co-mingling is expected to delay the onset and reduce the magnitude of acid mine drainage (AMD) production in waste rock. To denionstrate the efficiency of the method proposed, five different column tests have been set-up. Columns were fed with deionized water at the top and drainage waters were collected and analyzed. Bacteria counts were done on the tailings and waste rock after the column tests. Permeability in saturated conditions and capillary parameters were measured for the tailings. The results obtained show that the co-mingling method would be effective in mitigating AMD by maintaining nearly water-saturated conditions in compacted tailings, thus reducing oxygen supply in waste rock by preventing thermal air convection and minimizing oxygen advection and diffusion.

Jan 1, 2000

By J. Hanna, I. Anazia

Selective fatty acid flotation of carbonate gangue from sedimentary apatites was achieved under acidic pHs without a specific apatite depressant and without conditioning the pulp with the collector. Concentrates (35% to 38% P2O5, 0.8% to 1% MgO) with high recoveries (80% to 85%) were produced from Indian and Chinese dolomitic ores. The calcareous and/or dolomitic-siliceous phosphate ores of South Florida and Utah required two flotation stages: one for carbonate removal, as mentioned above, and the other for phosphate recovery from siliceous gangue. Preliminary tests on the South Florida ore gave concentrates analyzing 29% P2O5 and 0.8% MgO, with a P2O5 recovery of 76%. A concentrate obtained from the western US phosphate ore from Utah assayed 30% P2O5 and about 1% MgO, with a P2O5 recovery of 89%.

Jan 1, 1988

By M. G. Ayat

Engineers in the field of coal preparation are continually striving to increase the efficiency of various circuits used in preparation plants. Undoubtedly, one of the important factors concerning the processing efficiency of a coal preparation plant is improved analyses and control of the processing equipment. The necessary link between the performance criteria of a circuit may be provided through on-line determination of various parameters. Currently, there are a certain number of on-line instruments developed for measurement of ash content of coal (Watt and Sowerby, 1983; Kawatra, 1976; Fauth et al., 1984; Lyman and Chester, 1980), moisture content (Hall et al., 1969), and sulfur content (Stewart et al., 1974). In the case of coal separatory units, these parameters are often directly related to the quality of the product. In other words, the extent of misplacement of refuse in the product, or vice versa, would indicate the performance characteristics of any particular coal washing equipment. Partition curves are therefore established to predict the performance of coal cleaning operations. Conventional sampling and testing is currently the major tool with which partition curves are produced and the performance efficiency of the operation is assessed. While conventional analysis techniques are accurate, they are slow and time-consuming.

Jan 1, 1987

By Lynn I. Kelley

Industrial-mineral production contributes on the order of CDN$1.5 billion per year to the economy of Saskatchewan, Canada. Potash is the primary industrial mineral produced in the province, followed by aggregate, sodium sulphate, salt, potassium sulphate, peat, clays, silica sand, calcium-chloride brine, and "clinker." Potentially economic deposits of kaolin, diamond, and building stone are under evaluation. All of the major deposits of commodities discussed here are located south of lat 56°30'N. Most of the locations are presented on Figure 1 POTASH Saskatchewan supplies approximately 30% of the world's demand for potash. Eight conventional underground mines and two solution mines produced an all-time high of more than 13 million metric tonnes of potash (KC1) (8 million tonnes K2O equivalent) in 1997, valued at over CDN$1.4 billion. All of the mines exploit the middle Devonian Prairie Evaporite. The four potash-bearing members of the Prairie Evaporite underlie much of southern Saskatchewan and extend southward into North Dakota and Montana and east- ward into Manitoba (Fig. 2). Halite and anhydrite separate the potassic members. The evaporite beds locally are interrupted by solution structures (anomalous ground). Some of the structures may be related to deep-seated tectonic features.

Jan 1, 1999

By Ing Newton Amegbey, Joseph Afari Idun

Ashanti Goldfields Corporation (Gh) Ltd., the leading gold mining operation in Ghana is embarking on a major rehabilitation and expansion programme to increase gold production. A new southern ventilation district was targeted for this programme, and the ventilation system was to be reviewed in order to cope with increased production. The southern ventilation district was previously ventilated by booster fans. This arrangement was however, inadequate to solve the problem of the need to reduce smoke clearance time of the production areas, and to generally improve the underground ventilation conditions. Fan maintenance costs increased with the number of fans installed in the booster fan arrangement, and the fact that the fans were installed underground made maintenance difficult and took longer time. It became necessary to consider the installation of a new main fan on the surface. This paper gives an overview of the ventilation systems of the southern ventilation district of the mine before and after the new main fan was installed. The field tests carried out on the fan to ensure that it complied with supplier's specifications are described, and the new system analysed to see it's effectiveness.

Jan 1, 1993