Search Documents

"The adsorption of mixed cationic/anionic surfactants with different molar ratios onto quartz was investigated. The cationic surfactant used was dodecylamine bromide (DDA), and the anionic surfactant was sodium oleate (NaOL). The critical micelle concentration values for the individual surfactants and their corresponding mixtures were determined using a platinum plate. The adsorption mechanisms of mixed surfactants on quartz were studied using contact angle measurements, flotation tests and adsorption amount measurements. At alkaline condition, NaOL depresses DDA flotation of quartz without depressing the adsorption of DDA. The molar ratio of mixed surfactants is found to be a key factor in the orientation of alkyl chains and thereby the flotation response of quartz. A mixture of 1/2 or 1/3 DDA/NaOL forms on the surface of quartz when the concentration of NaOL is higher than that of DDA. The adsorption of the mixture decreases the wetting of quartz since the alkyl chains are in chaotically orientation with a conceivable number of head groups directing towards the solution phase. These results provide important insights into the adsorption of mixed surfactants onto quartz surface. INTRODUCTION Froth flotation is known as an effective method of separating mineral particles on the basis of their surface chemistry, specifically their hydrophobicity. [1]. The hydrophobic particles will attach to the bubbles and rise to the top of the containing vessel to form a froth that flows over the lip of the vessel. The hydrophilic particles remain in the liquid [2]. In the process, surfactant is often used as collectors for surface modification in order to change the wetting properties of mineral particles. The primary long chain alkyl ammonium salts are the most widely used as collectors for the flotation of oxide minerals, such as quartz, muscovite, hematite, phosphate and feldspar [3, 4]. Adsorption mechanism of alkyl ammonium salts on oxide minerals has been extensively analyzed [5, 6]. Generally, the ammonium salts are adsorbed through electrostatic interaction of the polar group of the molecules with the surface of these minerals [7]. Despite many obvious advantages of the ammonium salts in low temperature resistance and hard water resisting, however, their unavoidable drawbacks, such as high sensitivity and poor selectivity for slimes, relatively high cost, have limited their applications [8]. In recent years, mixed surfactants have drawn much attention due to their superior physicochemical and surface properties than single surfactants [1, 9-11]. They have been used in many industrial processes such as dispersion/flocculation, flotation, detergent, corrosion inhibition, cosmetics, foods, paints, chemical mechanical polishing, enhanced oil recovery, and nanolithography [12]. Most of the mixed surfactants have synergistic advantage in reduction of the surface tension and critical micelle concentration (CMC); therefore, they exhibit spurious properties, like excellent surface/interfacial activities, and are less expensive than single mixed surfactant systems [13, 14]."

Jan 1, 2016

By Dermot M. Winters, Brent T. Wahlquist, C. Y. Chen

The enactment of the Surface Mining Control and Reclamation Act (SMCRA) in August 1977 addressed subsidence resulting from underground mines, in addition to creating the requirements for reclamation of surface coal mines. Subsidence control regulations pursuant to SMCRA were initially promulgated in March 1979. Several revisions have since been made. In addition, due to court challenges some regulations have been remanded and others are still on appeal. In the meantime the Secretary has agreed to initiate rulemaking on some issues. It is yet to be determined how the prohibition of certain areas from surface coal mining operations under Section 522(e) of the Act applies to subsidence. This presentation discusses the status of the regulations and issues related to or affecting the subsidence regulations.

Jan 1, 1986

By G. A. Kordosky

LIX® 34 liquid ion exchange reagent, one of a totally new class of metal extractants, is discussed in terms of its properties. Specifically, these properties include improved selectivity for copper and greater recovery. Some comparisons to the well known General Mills' LIX® 64N have been made. Particular emphasis is given to treating solutions containing very low copper values and high impurity levels.

Jan 1, 1976

By D. Parks, A. Miller, M. McNinch, R. Jacksha, H. Nickerson

Each year hundreds of mine workers are involved in machinery-related accidents. Many of these accidents involve inadequate or improper use of lockout/tagout (LOTO) procedures. To mitigate the occurrence of these accidents, new safety methods are needed to monitor access to hazardous areas around operating machinery, improve documentation/monitoring of maintenance that requires shutdown of the machinery, and prevent unexpected startup or movement during machine maintenance activities. The National Institute for Occupational Safety and Health (NIOSH) is currently researching the application of Internet of Things (IoT) technologies to provide intelligent machine monitoring as part of a comprehensive LOTO program. This paper introduces NIOSH’s implementation of an IoT-based intelligent machine monitoring system to improve safety during operation and maintenance at a concrete batch plant. INTRODUCTION Of the hundreds of machinery-related accidents occurring every year in the mining industry, incidents involving stationary machinery at surface mines continue to be amongst the most frequent [1]. A National Institute for Occupational Safety and Health (NIOSH) study showed that the majority of fatal accidents involving stationary machinery at surface mines occurred at sand and gravel (38%) and stone (26%) operations. Of these accidents, entanglement in conveyor components were the most common cause of fatal accidents (48%) [2]. The same study stated that one-third of these accidents involved improper lockout/tagout (LOTO) procedures as a contributing factor. The U.S. Mine Safety and Health Administration (MSHA) acknowledged this problem, stating in a recent request for information (RFI) [3]: “Since 2007, there have been 17 fatalities related to working near or around belt conveyors, of which 76 percent were related to miners becoming entangled in belt drives, belt rollers, and discharge points. Factors that contribute to entanglement hazards include inadequate or missing guards, inadequate or an insufficient number of crossovers in strategic locations, and/or inappropriate lock out/tag out procedures. Systems that can sense a miner's presence in hazardous locations; ensure that machine guards are properly secured in place; and/or ensure machines are properly locked out and tagged out during maintenance would reduce fatalities [3].” In response to this problem, NIOSH’s Spokane Mining Research Division (SMRD) is exploring the potential application of Internet of Things (IoT) technologies to provide cost-effective intelligent machine monitoring systems for improved worker safety [4, 5]. SMRD partnered with Central Pre-mix CRH Company (Central Pre-mix) to develop and install a proof-of-concept wireless IoT solution to monitor machinery and conveyors during operation and maintenance. The primary goals of the system were to provide real-time monitoring of access points and facilitate the planning and execution of LOTO procedures

Jan 1, 2019

By Christopher J. Bise

The potential of the coal reserves in the western United States for meeting future energy needs has been recognized for quite some time. However, two of the major constraints which have tended to limit the development of these reserves which can only be deep-mined are the great thicknesses of the coal seams encountered and their high pitch. Although new mining methods may need to be developed to recover these reserves, at least in the short- term the industry has to incorporate presently available equipment which were not originally designed for thick-seam mining. The purpose of this paper is to present an analysis of the various equipment that are in use today and their possible application to thick-seam mining. The paper also addresses the various ground control and safety considerations that are unique to thick-seam extraction.

Jan 1, 1981

By Yassine Lahmadi, Edoardo Trivellato, Christian Chereau, Bénédicte Robert

Within the framework of the adaptation of the South-East European Technicentre (Technicentre Sud-Est Européen TSEE), SNCF Voyageurs appointed Pini with the project management mission (MOE) for the design and construction monitoring of a road tunnel. This investment has a dual function: during the site transformation phase, it facilitates the work logistics (and shorten traffic flows); and in the operating phase, it is intended to ease all movements on the site over the long term. This is a limited-length gallery (50 meters) to be performed in conventional excavation below Poniatowski Avenue (Paris 12e). The excavation, crossing the entire width of the boulevard, constitutes a major challenge, given the very low coverage (less than 5.5 m), and the surrounding main infrastructures. The same project mis- sion includes the design of the tunnel accesses, via reinforced-concrete frame structures. The targeted design questions several aspects of its execution framework, and particularly, continuous operation must be guaranteed to the neighboring networks during the works. The installation of an umbrella- pipe all along the excavation profile, the progression in divided sub-sections, and the implementation of a complex monitoring system are hence key elements for limiting and controlling any deformation. An exhaustive 3D finite element modelling was performed, taking into account the detailed phasing of construction (pre-support, excavation in divided section, preliminary support and definitive lining), to dimen- sion the structures, and, overall, to analyze the impacts on the neighboring structures and facilities. During the execution phase (planned for mid-2024), monitoring activities with back-analyses as close as possible to the works are planned.

Jun 23, 2024

By P. W. Conrad, C. Todd, N. West, R. Kramer

"Surface subsidence caused by both underground room-and-pillar mining operations and solution mining operations have each been studied separately, but never combined. In 2008, FMC Minerals began using solution mining at its Westvaco Mine as a secondary extraction method in an area that had been previously mined using the room-and-pillar mining method. Mining regulations require that subsidence associated with underground mining activities be monitored and measured annually. Researchers at Montana Tech were able to develop a relationship between measured surface mine subsidence and solution mining that can be used at the Westvaco Mine to estimate the production of trona from solution mining operations. PROJECT BACKGROUND FMC Minerals (FMC) has increased the production of trona from its Westvaco Mine near Green River, Wyoming, using solution mining as a secondary extraction method in an area previously mined using the room-and-pillar method. The area of interest was mined until 2001 with the use of a borer miner at a depth of approximately 1,600 feet. Currently, FMC determines the amount of trona produced using its solution mining operations by measuring the dissolved solids pumped from the mine. This approach, however, does not account for the location from which the trona was removed. The location from which the trona was removed and the size of the cavern created by the solution mining operations is important to FMC’s mine planning. FMC believed that with proper investigation of the subsidence at the Westvaco test site, a correlation might be found that would allow for the use of surface subsidence measurements to estimate the amount and location of trona production from the solution mining activities. The primary goal of this project, conducted by Montana Tech, was to find a relationship between the measured subsidence and the solution mining activities. The project attempted to model the relationship between the measured subsidence and the solution cavern using Salt_Subsid, an existing subsidence software package from the Solution Mining Research Institute (SMRI), to determine the program’s usefulness for locating and developing the cavern created by solution mining activities. The project also attempted to develop an equation that could be used to predict solution trona production based on measured subsidence. The data used in this study were collected over a seven year period, 2008 through 2014."

Jan 1, 2016

By Ramon LaRusso, Frank Wheby, Richard Acker

Field investigations and office studies were used to develop criteria and cost parameters related to the geologic aspects of the proposed project. These results were employed in optimization of layouts and comparison of alternative schemes, leading to selection of the recommended program. Study of project features included the development of subsurface shafts, tunnels, and mined storage areas, and the utilization of existing surface quarries. These project features were proposed for construction within the bedrock units underlying Chicago. Principal geologic considerations included bedrock structure, stratigraphic sequence of units, rock competence and uniformity, and requirements for aquifer protection. All geologic factors were interrelated with other project considerations such as surface hydrology, hydraulics, and urban setting. Data for analyses was acquired through an exploration program conducted intermittently between 1967 and 1971, in addition to that already available through numerous explorations and well constructions in the project area. The exploration program included seismic surveying, core drilling, geophysical borehole logging, and water pressure testing of boreholes, and water well drilling and testing. Extensive laboratory tests were conducted on core samples. The data formed the basis of studies enabling the formulation of preliminary design and siting criteria resulting in construction cost evaluation.

Jan 1, 1997

Newmont has been producing gold from the Carlin Trend for over 45 years. Naturally the focus, scale and complexity of the operations have changed considerably over this time. Newmont discovered and developed the Carlin Main ore body which is located about 32 km (20 miles) north of Carlin Nevada. The property was developed as a one mine one gold mill treatment plant operation which produced about 6,200 kg (200,000 Troy ounces) of dorè gold bars per year. The initial mine, mill and gold refining facilities were relatively small in comparison to today?s standards. The milling circuit used the Merrill-Crowe zinc precipitation process to recover dissolved gold and prepare a concentrated precious metal ?precipitate? to be melted into a dorè bar for sale.

Jan 1, 2012

By Leping Liu, Sachin Urade, Li-Ting Chen, Pengbo Chu

This study aims to provide industrial perspectives on the current U.S. metal mining engineering education and areas for improvement. An online survey was designed to seek opinions from the U.S. mining industry. Findings indicated a shortage of qualified graduates from the current U.S. metal mining engineering education system. The qualifications that need to be improved include engineering sciences underlying mining methods, mining design experience, mining feasibility study, the connection between theory and practice, and understanding of the overall mining operation. The survey also identified future desired qualifications, such as the ability to acquire and apply new knowledge as needed and sufficient field experience. Respondents recommended enhancing collaborations between industry and academia.

Oct 1, 2023

By Jose F. T. Agapito

The mining engineer must be able to predict the structural behavior of the rock around underground openings so that he can answer questions relating to safety and economics. With the present status of rock mechanics knowledge, exact predictions cannot be attained and approximate idealizations are made. As a first approximation, structural design makes use of theory, laboratory testing of rock properties, and available experience from excavations in similar rock formations. However, realistic design can usually be obtained only after in-situ observations and measurements are made. After all the information is collected, judgement and experience play a most important role in the final formulation of the design. This paper describes part of a geotechnical program which was instrumental in obtaining information for the design of large oil shale pillars. The work was carried out during 1971 and 1972 in the experimental mine of the Colony Development Operation. Colony is an oil shale venture formed between Atlantic Richfield Company, Operator, The Oil Shale Corporation, Cleveland-Cliffs Iron Company, and Sohio Petroleum Company to conduct research and development in mining and retorting of oil shale, The property is located in the southern edge of the Piceance Creek Basin in northwestern Colorado, approximately 250 miles west of Denver (Figure 1) . Mining was conducted by the room-and-pillar method in a 60-ft high portion of the Green River Formation at a depth of 600 to 850 ft, Pillar dimensions are approximately 60 ft by 60 ft. The mine site is in the eastern face of the canyon containing the Middle Fork of Parachute Creek, The distance from the mine to the side of the mountain varies from 500 to 1,200 ft, and its height above the stream floor is approximately 700 ft.

Jan 1, 1974

By P. Schilizzi

The increased impact of mining subsidence in the U.S. coalfields and the recent regulatory constraints legislated by government and state agencies have provoked an intense research effort on this topic by government agencies, coal companies and academic institutions. Subsidence and horizontal strain predictions are a basic requirement if subsidence and its associated effects are to be controlled and contained within acceptable environmental levels. As a result, several such prediction techniques have been proposed or are currently under development to assist coal operators in minimizing the detrimental effects of these surface deformations. VPI&SU has been actively involved in this research effort in the past few years, with particular emphasis on the Appalachian coalfield. During the initial stages of this research a large number of subsidence case studies were collected from the literature, the coal industry and government agencies. In total, data from 32 longwall panels and 60 room and pillar panels were collected. This data bank was used to determine relationships between the basic mining and subsidence parameters, in order to allow the evaluation of the various prediction methods for the Appalachian coal region. Based on this data two subsidence prediction techniques, one based on profile functions and the other on influence functions have been developed. Profile function methods provide a tool for a fast calculation of subsidence on a line across a mine panel. Influence function methods, on the other hand, allow for a more detailed calculation of ground movements, in any mode and at any depth, on a grid or at any specific point. The limitations of the data of the collected case studies, i.e. accuracy of surveys, frequency of monitoring, lack of horizontal movement measurements, etc, led VPI&SU to the initiation of a detailed subsidence and strain monitoring program above a number of active mines, located in three major coal producing counties of Virginia. The aim of this program was to enhance the data base with accurate and complete measurements of surface movements and to allow, therefore, the refinement of the prediction techniques. This paper presents this monitoring program, discusses in detail the results obtained from three specific case studies and provides recommendations for the implementation of the field data in the general prediction methods.

Jan 1, 1986

By Brendan Demich, Linda L. Chasko, Brendan Macdonald, Timothy J. Orr, Jessie J. Mechling, Cassandra Hoebbel, Jason Navoyski, William Helfrich, Jessica Cohen, Paul E. Schmidt, Jennica L. Bellanca

The National Institute for Occupational Safety and Health (NIOSH) in partnership with the Mine Safety and Health Administration (MSHA) developed VR Mine Rescue Training (VR-MRT). It is a training platform that allows mine rescue team members to explore virtual emergency scenarios collaboratively. Team members use a head-mounted display to visualize and interact together with equipment, hazards, and dynamic ventilation. All player actions are recorded and displayed for debriefing. Researchers at NIOSH demonstrated the training platform at various mine rescue competitions, including the International Mine Rescue Competition, and collected feedback. Participants’ responses were overwhelmingly positive. This paper describes the development of the software platform and the results of the usability surveys and interviews.

Jun 25, 2023

By Kenneth S. Johnson

Oklahoma is the only; state in the nation that is currently producing iodine. The iodine is extracted from iodine-rich natural brines being pumped from deep wells drilled into Pennsylvanian sandstones in the Anadarko basin of northwestern Oklahoma. Woodward Iodine Corp., started in 1977, was the first plant in the United States built for iodine recovery since the 1930s. At present, three companies are operating four iodine-producing facilities in northwestern Oklahoma. The combined production of these facilities, 1,321,000 kg in 1997, is about 26% of the U.S. annual consumption. Iodine is present in concentrations ranging from less than 100 ppm (parts per million) to as much as 1,560 ppm in brines in various Paleozoic strata in the subsurface of northwestern Oklahoma; these concentrations are exceptionally high, and are well above those of any other known brines in the world. Strata with the highest iodine content in the area (Mississippian limestones) have low permeabilities, and thus would yield only small amounts of brine. On the other hand, the lower Morrow sandstones (Lower Pennsylvanian) have a relatively high permeability and are capable of yielding large quantities of brine that average 300-350 ppm iodine. The Morrow brine reservoir was deposited in shallow-water-marine and intertidal-shelf environments and now is buried 6,000-10,000 ft below the land surface. Production is localized to Morrow channel deposits confined to an Early Pennsylvanian paleovalley that is 1-2 mi wide, is about 70 mi long, and is referred to informally as the "Woodward trench." All three companies are producing iodine-rich brines from Morrow sandstones in three different parts of the Woodward paleovalley, and one of the companies also is extracting iodine from oil-field brines coming from several petroleum reservoirs near Dover, about 80 mi east of Woodward. The basic extraction method employed by Woodward Iodine Corp. was used in Louisiana and California operations in the late 1920s. This method is commonly called the air-stripping process. Lower Morrow brine containing dissolved sodium iodide is pumped to the plant through a series of pipelines, where by-product natural gas is separated and processed. The brine is then acidified and subsequently oxidized with chlorine to convert the iodide to iodine. The iodine is air stripped and reabsorbed with sulfur dioxide and water, converting it to hydriodic acid, or process liquor. The process liquor is then processed, using chlorine once again, to crystallize the iodine as a solid. This is then melted and frozen to form a solid product, which is packaged in 110-lb (50-kg) drums and shipped to end users throughout the world.

Jan 1, 1999

By Stuart Lister

"When MacLean Engineering chairman and founder Don MacLean got the first question from a minesite about the possibility of addressing ventilation limits through incremental fleet electrification, he was intrigued. It was back in 2015, and the MacLean scissor bolter was already diesel-electric (jumbo trailing cable), so it made sense to him that if they could engineer a battery drive system for the unit’s tramming cycle, they would have the inaugural electric vehicle (EV) MacLean unit.At that time, there were not any entirely diesel-free hard rock mines in existence on the planet, and that remains the case to this day — although the Borden project in northern Ontario is progressing toward that goal (see page 33). This meant there was essentially zero market demand for battery electric vehicles as well as a complete lack of battery technology to address the battery electrification of heavy haulage. Heavy haulage is the part of a typical mine’s mobile fleet with the largest footprint when it comes to diesel particulate emissions, greenhouse gases and wasted energy in the form of heat.Three years later — the wave of battery electrification that is currently picking up speed across the mining industry promises to hit full swing by the early 2020s when a slew of new build, diesel-free mines will start construction. But this movement toward emissions-free mobile fleets is not a completely new phenomenon. Instead, it is an updating of mining technology from a previous generation. What is going on now is the re-electrification of mining. Up until the 1960s, early generations of battery technology (lead acid) and electric locomotive systems were the norm for material and ore haulage in Canada and elsewhere.The thought of a coming paradigm change in mining was particularly pertinent to Don MacLean back in 2015, as he had been part of the era that ushered in the first generation of rubber-tire diesel equipment, when he was a divisional foreman with Inco in Sudbury in the 1970s. He was part of the operating team that was tasked to build a rail loop on one extraction level of the mine. At that time, events on the ground overtook the project, as diesel-powered mobile equipment became a viable option. Once the first diesel scoop was introduced at Creighton #3 shaft, it was clear what the power, haulage capacity and mobility could do for operations and that era of electric rail haulage underground was effectively over."

Jan 10, 2018

By J. Noll, A. Miller, J. Volkwein, C. Pritchard

Hecla Limited, Magee Scientific and the U.S. National Institute for Occupational Safety and Health (NIOSH) combined efforts to evaluate an in situ air filtration system for use in an underground mine environment. The purpose of the collaboration was to determine the efficacy of such a technology for reducing the concentration of airborne diesel particulate matter (DPM), with the aim of improving air quality in underground hardrock mines. A secondary goal was to evaluate the use of an aethalometer as a means of real-time measurement of black carbon as a surrogate for DPM. The evaluation included measuring the DPM-capture efficiency of the filter when it was preloaded with dust. Toward this end, rock dust was introduced at the filter inlet to create a dust layer on the filter surface, with the intent of providing improved capture of the much smaller DPM particles. The filtration efficiency for DPM was assessed by comparing measurements of DPM taken at the inlet and outlet of the system, using both realtime and time-weighted-average approaches. The real-time measurements were performed with a Model AE33 aethalometer, and filter samples analyzed by the NIOSH 5040 method were used to assess the effects of the system on time-weighted-average concentrations of total carbon. Results showed a reduction in DPM concentrations in the range of 82 to 89 percent. While the calculated efficiencies based on the two different measurement methods were similar, the DPM levels reported by the aethalometer were higher, possibly due to differences in the performance of the size selectors used for the two methods: impactors versus cyclones. More research is required to develop a robust correlation between the two methods to support the use of the aethalometer in future mining applications. The advantages of the aethalometer are that it can measure and record DPM levels for weeks at a time and can be directly connected to a mine monitoring system, potentially at multiple locations. Ideally, such data can be used to initiate the startup of the filtration system should DPM concentrations reach an action level. This work demonstrated that in situ filtration systems, modified to collect DPM and coupled with real-time monitoring, show promise in reducing DPM concentrations in the mine environment.

Mar 1, 2017

By E. Cho

Illinois No. 6 coals of IBC 101 and IBC 112 were treated in solution with sodium hypochlorite to remove their sulfur contents, especially organic sulfur. The lab experiments were conducted in two steps of leaching at room temperature and hydrolysis at 90oC. The removal of organic sulfur from IBC 101 was by 37.8% while that from IBC 112 was only 13.7% under their respective optimum conditions. This large difference in organic sulfur removal is considered to be due to difference in concentration of surface total acid group, 3.14 vs. 0.88 mmol/g of coal.

Jan 1, 2007

By David A. Campbell

There has been a long history of ironmaking on the North East coast of England centered around the River Tees. The industry developed here because of the availability of good coking coals to the North in Co. Durham, and the discovery in 1851 of ironstone in the nearby Cleveland Hills, South of the .River. Cleveland ironstone is relatively poor in quality, with an iron content not exceeding h% and high proportion of sulphur and phosphorous. The iron exists in chemical association with alumina and silica, and physical beneficiation processes involve a serious loss in iron unless the upgrading is limited, when the economics of the process become doubtful. Over the years, richer foreign ores have replaced the local ironstone, and the last operating mine was closed in 1964.

Jan 1, 1982

By A. Karami

It is well established that an ordered sequencing of charge initiations in a blast pattern is an important design consideration that affects blasting performance. Delay times must be chosen such that damage to the rock mass is controlled. The accuracy of delay detonators is also of major concern. A large scatter could lead to an incorrect blast sequencing that would lead to damage to the rock mass causing increased over-break, degraded fragmentation, increased fly-rock and poor vibration control. In this study, the effect of using accurate delay detonators on the explosive energy generated is investigated. For this purpose, power spectral density of the blast vibration for delayed shots are calculated and compared with the case where holes are shot at the same time (no delay). At the end the results are presented and discussed.

Jan 1, 2000

By VIVEK KUMAR HIMANSHU, PK SINGH, AK MISHRA, MP ROY, RAVI SHANKAR

Underground blasting has many challenges. The primary aim of blast designers is to optimize drilling and blasting parameters to deal with the associated challenges. Optimizing these parameters is currently based on various rules of thumb, which have many site-specific limitations. Accordingly, computation of these parameters using empirical rock fragmentation predictors can be useful for blast designers. This paper presents the results of work on burden-spacing determination by back-calculation from the empirical Kuz-Ram model for underground stope ring blasting.