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By Ning Wang, Tengfei Guo, Wanyan Li, Hanjie Wen, Hannian Gu, Zehai Li

Red mud has been reported as a potential resource for lithium. To investigate the leaching behavior of lithium, a lithium-rich red mud was neutralized with hydrochloric or oxalic acid and then leached with acetic acid. When red mud was neutralized using dilute hydrochloric acid, about 58 to 60 percent of lithium was leached with 25 percent acetic acid at 95 °C for 60 min, while more than 95 percent of sodium and 85 percent of calcium were dissolved in the leachate solution. When oxalic acid was used to neutralize red mud prior to acetic acid leaching, lower lithium leaching efficiencies of about 42 to 47 percent were observed. Nevertheless, these leaching efficiencies of lithium were close to that of calcium and much higher than those of sodium under the same conditions. In this study, 25 percent (v/v) of acetic acid at 85 °C for 60 min was demonstrated to be the optimum conditions for lithium extraction from oxalic acid-neutralized red mud using acetic acid. The results are useful and of interest for lithium recovery and purification from red mud.

By III Kimball

Mining wastes have received individual attention under the Resource Conservation and Recovery Act (RCRA) since its inception, in recognition of the special characteristics that distinguish mining wastes from other solid wastes. The Environmental Protection Agency (EPA) has recognized that: - Mining wastes are generated in much larger volumes than other industrial wastes. Most material handled in mining is waste (over 99% in many cases) and not marketable product, whereas waste is a small portion of raw materials used in most industries. Consequently, controls used for hazardous wastes may be technically infeasible or economically impractical. - Nearly all mining waste is managed at the site of generation and is land-disposed. . - Mining wastes typically pose lower hazards than other industrial wastes. Mining operations are located predominantly in sparsely populated areas and in arid or semi-arid areas with little surface water runoff and deeper water tables.

Jan 1, 1990

By J. L. Watson

n the U.S., lead has been produced via blast furnace processing for over a century, and the slags from that pyro-metallurgical process have been accumulating on industrial sites over that extended period. Lead blast furnace slags typically contain both lead and zinc compounds in an iron-silicate matrix, and it appears highly likely that such materials will have to be processed in the near future to meet with EPA regulations. Thus it is appropriate to investigate possible processing routes to render the slags non-hazardous and simultaneously to recover metal values to partially off-set the inherent high cost of processing such materials. There are two major processing alternatives: one being pyrometallurgical and the other hydrometallurgical. The research reported here investigates leaching/solution purification/recovery processes for lead and presents experimental data for the treatment of lead blast furnace slags from S.E. Missouri. The results of the research suggest that both lead and zinc can be removed effectively from the slag, and that metallic lead can be recovered directly from the organic extractant utilized for solution purification.

Jan 1, 1995

By J. Lancaster

World demand of sulphur-in-all-forms (SAF), which in 1985 is estimated to total 57.5 million tonnes S equivalent, is expected to increase to 77.6 million tonnes S by the year 2000. Key factors are the evolution of sulphur demand in the USSR, China, and the developing countries notably India, Brazil, and the countries in North Africa and the Near East with vertically integrated phosphate industries. Brimstone will remain the dominant sulphurous raw material notwithstanding the progressive increase in the supply and use of sulphur in other forms resulting mainly from the enhanced recovery df pollution sulphur and the increased use of sulphur in pyrites in those countries with this sulphur resource. Sulphur demand for phosphate fertilizer manufacture is expected to have the main impact on world sulphur demand, but in contrast to the industrially advanced countries where non- fertilizer sulphur use is not expected to increase measurably, this demand sector is expected to be of some importance in those developing countries with dynamic economies and in the centrally planned economies of East Europe and the Far East.

Jan 1, 1986

By Bernie W. Martin, Paul MacLeod

The new St. Clair River International Tunnel Project presented unique challenges in planning, permitting and approval. The project straddles the border between the Province of Ontario and the State of Michigan necessitating the review of U.S. approval legislation that has not been used in 60 years. The preparation of an environmental impact report to satisfy the legislative requirements for the Federal laws of the U.S. and Canada as well as the Province of Ontario and the State of Michigan presented a daunting task. In all, over 200 external contacts were made in carrying out the environmental approvals and permitting work. The definition of the alternatives including the NULL option were documented along with the impacts and mitigation measures. A "Modified Delphi" technique, along with other methodologies, was used for alternative evaluation and selection. A formal and informal public consultation process was undertaken which involved over forty major presentations and external meetings. A unique alternative to the traditional design, tender, build contracting practice was adopted; The Negotiated Compressed Process (NCP).

Jan 1, 1993

By R. J. Cornelius

Gold with minor associated copper mineralization in the area of what is now the Bougainville porphyry copper deposit has been known since the 1920s and was probably known in German colonial times, pre- 19 14, although no records persist other than a reference by Stanley (1922) to copper specimens from Kieta that he saw in Rabaul. Stanley did not at the time believe that they came from Kieta. Gold was first discovered at Kupei by Jack Comb in 1929 and the Kieta Goldfield was proclaimed in May 1930. In December 1932, the Tapu Reward Claim at Moroni - the site of the Bougainville Copper concentrator, was pegged by C.W.M. Evans who prospected up river from the West Coast. The Pumkuna (Panguna) Reward Claim on the site of the subsequent porphyry copper deposit was granted in February 1934 to G.A. Myers. n May 193 1, the Kupei Reward Claim was transferred to Bou- gainville Gold Options NL and later reverted to Jack Comb and then the Bougainville Syndicate, as did the Pumkuna and Moroni claims. Most of the interested parties had come from the Edie Creek rush on the New Guinea mainland. In 1935, N.H. Fisher, the geologist in Rabaul for the New Guinea administration who later became director of the Australian Bureau of Mineral Resources in Canberra, reported on the three gold areas. Norm Fisher described the gold and copper mineralization and its habit in great detail and this report had a major influence on the events leading to the discovery in the 1960s. Gold production up to the Japanese invasion probably did not exceed $50,000 in value. Half a ton of copper-gold ore from Kupei was sent to O.T. Lempriere's in Sydney for assay in the early 1930s.

Jan 1, 1991

By George C. Trevorrow

It is a pleasure to appear on this program and discuss a subject which is of particular interest to me. In my regular duties as Safety Director of Bituminous Coal Operators' Association, I am called on by member companies to discuss matters affecting face ventilation. As a member of the Joint Industry Safety Committee, as I will later describe, I have a part in processing requests for the use of auxiliary fans for face ventilation. The use of auxiliary fans in bituminous coal mines for this purpose came into rather wide use in the late. '20's when conveyor mining was introduced. In this application, the equipment consisted of a chain conveyor with a face chain conveyor parallel to the face on which the coal was loaded by hand and, in turn, was discharged onto the room conveyor and thence to a loading point on the entry at the mouth of the room. Another method was to use a shaker conveyor with a duckbill which was maneuvered across the face of the room from which the coal was loaded and transported by the shaker to the loading point. In either case the equipment did not readily lend itself to driving crosscuts or breakthroughs with the result that rooms were driven to depths of 250 or 300 feet without adequate means of ventilating the face area with the main split of air. It was, therefore, necessary to use other means of ventilating this area as the rooms were being driven and during retreat work if pillars were extracted. Auxiliary fans of the blowing type were utilized for this purpose. They were of very small capacity using small diameter tubing. By the time the room was driven half way to its projected limit ventilation was very poor or practically nonexistent. To compound the problem the fan was usually set up at the mouth or neck of the room and in many cases the intake air to the fan was the return air from the room. It is small wonder, therefore, that there is on record 12 cases where auxiliary fans were given as the cause of explosions. In 9 of these occurrences, arcs or sparks from open-type motors or accessory equipment on these fans were given as the primary ignition source. They fell into such ill repute that in a number of cases they were blamed as the ignition source even though smoking was strongly suspected as the primary cause.

Jan 1, 1967

By Richard Campbell, Claire Pirona, MEHMET KIZIL, Ismet Canbulat, Stephen Giese, Ravindu Goonawardene, Edward Steed, Serkan Saydam

The Australian longwall mining industry spends millions of dollars per year on proactive and reactive ground consolidation applications across most of the operations currently in production. The design and effectiveness of the applications and products vary widely and are based predominantly on-site precedence or what were considered successful applications at other sites in similar situations. In the continual improve the effectiveness of how consolidation products are used and when by enhancing our knowledge of the mechanical properties of products used in underground coal applications and applying this increased understanding to geotechnical design. One of the current challenges to further developing more appropriate and accurate geotechnical design methods for consolidation activities is the lack of standardised materials testing and knowledge of rock mechanics data on in situ performance. The lack of industry standardisadesign of consolidation programs, with a reliance on experience-based guidance for rockmass consolidation design. consolidation products. The program was designed to provide the industry with a set of geomechanical property index tests and a data set that can be utilised by rock mechanics engineers as baseline information for product evaluation and engineering design. The laboratory work undertaken is critical to understanding the exact small-scale mechanical properties of these products and testing was carried out at Monash University for various states of curing of each product. Recognising that the speed at which a mixed product develops its desired properties to act as a support element in underground coal mines is critical to its serviceability. This paper presents the testing rationale proposed, the testing results, and a framework for how the data set can be used to improve the engineering basis for ground consolidation design, in terms of expected rockmass performance under various mining conditions and application parameters.

Jun 25, 2024

By R. E. Johnson, J. E. Dutrizac, B. R. Palmer

Silver sulphide (acanthite) and lead sulphide (galena) dissolve relatively rapidly in FeCl3 media with the formation of elemental sulphur and soluble silver and lead chlorides. Parabolic kinetics are observed, and the leaching rates are controlled by the outward diffusion of the AgCl and PbCl2 reaction products through the constantly thickening elemental sulphur layer formed on the sulphide. Hence, both leaching rates are strongly dependent on those variables which affect the solubility of AgCl or PbCl2 at the reaction interface. The rates therefore increase with increasing temperature and total chloride ion concentration, but decrease in the presence of elevated concentrations of AgCl or PbCl2. By contrast, neither sulphide is significantly attacked by ferric sulphate media, even at high Eh values. Although the reasons for the refractory behaviour of Ag2S in sulphate media remain unknown, the low rate of PbS attack is attributable to the passivating layer of PbSO4 and elemental sulphur formed on the surface of the galena.

Jan 1, 1993

By E. Craig Simmons

Uranium is an element incompatible with respect to the major rock-forming minerals crystallizing from granitic magma, entering in- stead trace minerals such as zircon. The relationship between the saturation limit (SL) for such a mineral and the bulk distribution coefficient (Do) for U is central to understanding the distribution of U and its availability to late- stage fluids which can form ore deposits directly, or labile U which can be remobilized later. Low SL values imply early crystallization of zircon, but in very small proportions, minimizing Do and maximizing the degree of enrichment of U in late-stage fluids. Thus, granitic rocks with low Zr contents (due to a low saturation limit for zircon) are most likely to evolve U- enriched differentiates; this will be reflected in a high U content of the zircons (but not necessarily high U abundances in whole-rocks). Thus, the ratio of the U content of zircon to the Zr content of the corresponding whole-rock is potentially a very useful parameter in identifying granitic rocks which are most likely to have U-enriched solutions associated with them. The granitic rocks associated with the U deposits of the Midnite Mine area, Washington, have geochemical characteristics which fit very well the model presented here. The rocks are very low in Zr (100 ppm) and contain zircons with extremely high U contents (3,000-4,000 ppm).

Jan 1, 1981

By Richard R. Radel, Jack Barry

Contract required excavating 2,000 If of 14' horseshoe tunnel in rock, a 95' deep work shaft on shore, and a 50' deep intake shaft located in the middle of the Niagara River just above Niagara Falls. Large quantities of H2S were encountered in the range of 20 PPM with ventilation. Peak levels of 40 PPM were recorded. The original designed ventilation system required only a volume of 10,000 CFM to meet OSHA requirements. The volume of air was increased to 50,000 CFM to dilute the H2S to al- low workmen to work and comply with OSHA H2S action levels. The second phase of the tunnel consisted of placing 72" ID X 20 foot long concrete reinforced pipe in the tunnel. When the tunnel was holed through and both shafts were open, a substantial amount of work was required to take place in the shafts which eliminated the possibility of placing a bulkhead to secure proper ventilation. The ventilation team designed a jet system airlock. The design of this system was to bring fresh air down the work shaft in two duct systems; one 30" diameter and one 24" diameter. Following the excellent work of Jan Wolski (7th Mine Ventilation Symposium chapter 58) our design incorporated nozzles located approximately 100' in by the work shaft. The velocity of the 24" diameter duct was 6,365 FPMD2.2 MPH. The velocity of the 30" diameter duct was 6,117 FPMl69.5 MPH. Both systems were on blow and being that air expands at 3112 degrees per side this high velocity of air expanded and created an air bulk head through which men and the large sections of concrete pipe could be passed without any delay or additional cost to the project.

Jan 1, 1997

By E Mutaz, M Bahaaddini, D J. Williams, M Serati

The contribution of the mining industry to the global economy has reached (and gone beyond) $1,800 billion in recent years that necessitates (more than before) the need to ensure workability, viability, health, and safety of mine sites and workers to meet the ever-increasing global demand for mineral resources. Amongst the many challenges facing the excavation industries, rockburst and spalling failures in deep mines in hard and brittle rock formations are yet happening that are still deemed as unsolved problems. During unconfined compressive testing of brittle rocks, microcracks initiate at approximately 0.3–0.5 of the peak strength (which is commonly known as the Crack Initiation stress level) mainly in the direction of the major principal stress, then grow unstably and coalesce to form macro fractures at approximately 0.7–0.8 of the peak load at a so-called Crack Damage stress threshold. From a stress-strain perspective, the crack damage stress threshold () is associated with the reversal point of the volumetric strain, which is also proved to be strongly affected by the intermediate principal stress. This paper extends the previous studies on the impact of true triaxial loading conditions on the CD stress level in high porosity rocks, and introduce a new Crack Mode-Changing Stress (CMCS) defined as the minimum principal stress required to change rock fracturing from splitting to a sliding failure mode. A large number of experiments on sandstone specimens were carried out at different true triaxial loading conditions and the effect of principal stresses on the CI and CD as well as CMCS were studied. The results show that not only the intermediate principal stress, but also the minor principal stress can significantly affect the CD and CMCS thresholds.

Apr 26, 2022

By HONGWEI YANG, Lili Zhang

Copper slag is mainly used in cutting tools, abrasives, asphalt pavement, road construction, and in the production of concrete as an alternative to sand and cement [1]. As a renewable resource, only about 15-20 percent of the slag is used for these applications, and the dumping or disposal of surplus unused slag results in waste of a certain amount of usable metal in the feedstock [2]. In this work, the oxidation behavior of copper smelting slag under nonisothermal condition is studied using data obtained by the thermogravimetric (TG) method, and the kinetics parameters and reaction mechanism of oxidation are determined. It provides a theoretical basis for the comprehensive recovery of iron resources in slag and the selection of reasonable slag-making conditions.

Oct 1, 2022

Evver since it first displayed an autonomous mining truck at the 1996 MinExpo show in Las Vegas, NV, Caterpillar has been building the blocks to a fully autonomous mine. In May, the company unveiled another block in that progression, the new Cat MineStar System that it says is ?the industry?s broadest, most comprehensively integrated miner operations and mobile equipment management system.? The full system is comprised of five capability sets ? Fleet, Terrain, Detect, Health and Command ? to help operators define the size and scope of their management system based on the needs of their mining operations. Michael Murphy, technology and autonomy manager for Cat Global Mining, explained that the customers were not ready for an autonomous mining truck in 1996, but that many customers wanted the building blocks to eventually get to autonomous mining. After 15 years of work, Murphy said the building blocks have come together in the form of the Cat MineStar System.

Jan 1, 2011

By R. J. Sweigard

Three case studies were undertaken to investigate the role of land use potential evaluation in reclamation planning and to determine the impact of regional differences on the evaluation process. The three surface mines studied were representative of operations in the Appalachian, Interior, and Northern Great Plains provinces. The scope of the investigations included a survey of regional characteristics, a detailed investigation of the mining operations and site conditions, and an assessment of local land use planning activities in the area of the mine. Special attention was given to key factors that presently determine the use of reclaimed land. Also, for each case study, the postmining land use potential was evaluated using site planning principles. Specifically, the environmental, economic, and social impacts of several potential postmining land use plans were considered.

Jan 1, 1983

By James E. McNulty

The planning and development of new coal mines is requiring the increased use of geologic, geologic engineering and hydrogeologic investigations. This is caused in part by the fact that new mines must deal with less favorable conditions than existing mines as well as higher costs of development and in part by the dictates of regulatory authority. High costs of new mines require greater reliability of geologic assessment using best available geotechnical and geophysical methods and technology. Although the increased cost of additional subsurface data is significant, the more important factor may be the impact on project lead time.

Jan 1, 1981

By J. Wesley Atkins

In considering the importance of lease management and administration, I have decided to approach the topic, Lease Default and Eviction: Action or Reaction, as a three phase presentation dealing with mineral lease administration and management, past, present and future. Though the title may border on the dramatic, it illustrates the real consequences of alternative approaches to property management viewed from my experience in the evaluation, development and implementation of a number of such systems and services in my current position as president of Talco Group Corporation. First, though, let's take a moment and set the stage by giving a few actual examples of why a pragmatic approach is needed in this particular area.

Jan 1, 1983

By PATRICK R. TAYLOR, NICHOLAS BELLUSCI, D. ERIK SPILLER, VICTOR BRAMAN

Most of the world’s production of natural soda ash comes from the mining and processing of trona found near Green River, WY. The processing of trona ores to ultimately yield a high-quality dense soda ash product and reject the insoluble gangue species, primarily in the form of oil shale, is water and energy intensive. It is speculated, however, that the glass-manufacturing industry, which is the largest consumer of soda ash, may be able to use product of a lower grade and consistent level of the insoluble constituents. Thus, the viability of using sensor-based sorting to produce a beneficiated trona stream that would be fed to calcination was investigated. The study encompassed the preparation of a run-of-mine (ROM) Green River ore sample; selection of specimens sized 25 to 75 mm; imaging of the specimens by sensors based on X-ray transmission (XRT), color and laser-induced fluorescence (LIF); insolubles analysis of the specimens; and a bench-scale sorting test. Results of the study established that a correlation between the color of the individual ore particles and their insoluble content exists, and that a surface-detection-based sensor, particularly LIF, is apparently more suitable than XRT to produce a beneficiated trona stream. The bench-scale sorting test demonstrated that a 65 percent separation efficiency and a 70 percent recovery of trona could be achieved.

Feb 1, 2023

By Allan M. Hale

The central Florida phosphate industry is not a recent development. The first phosphate mining occurred in approximately 1888 (1). Many of the original mining companies were "wildcat" operations operated with rapid phosphate extraction as the sole purpose and no long-term commitment to development. Many of the early pioneers were ill-equipped to mine phosphate at either a practical or economical level; as a result many of these early companies "folded" after only a brief period of operation. However, as these early companies went out of business, several large companies developed, expanded their mining territories bought up the folding companies and by 1903 (little more than 10 years after the first mines were started), approximately 37 of the original 60 mines were control- led by three major companies (1). In the early period, mining reclamation was nonexistent. The mined out areas were left to revegetate and reclaim "naturally" over the period of many years. Reclamation practices were only started relatively recently and the various reclamation techniques developed and used in the past have continued to be employed with varying degrees of success through the present time. The reclamation techniques used in the past and currently include land and lakes restoration, sand tailing reclamation, slime ponds reclamation and overburden fill.

Jan 1, 1980

By Liuhuai Ding

Background of Ocean Mining Research Inspired by the 1970?s deep seabed mining activities of other nations, China started ocean mining research work within the framework of the International Law of the Sea Treaty (UNCLOS) and the subsequent establishment of the International Seabed Authority in the 1990?s. This work has been carried out mainly with the cooperation of the Changsha Research Institute of Mining And Metallurgy. We have been committed to this work to fulfill our responsibilities and obligations as a Pioneer investor under UNCLOS and also to support the much needed development of deep-sea technology in China. Exciting recent advances by Nautilus Minerals in the development of seafloor massive sulfide deposit exploitation has led us to a new perspective of ocean mining and some re-evaluation of ocean mining economics. This has provided us with an opportunity to support more efforts in ocean mining research. We will not delay the development of our ocean mining system and corresponding technology, although commercial mining in the deep-sea area may not occur for many years.

Jan 1, 2008