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By H. Y. Cheng

A pulse column solvent extraction system was evaluated as an alternative to mixer-settlers for the separation and purification of rare earths. The column tested had an inside diameter of 44.5 mm and had 36 sieve plates with a free area of 25%. Pulsing was provided pneumatically using a solenoid valve controlled by a timer so that both pulse amplitude and frequency could be varied. Feed to the column was a mixed rare earth chloride solution containing 10 g RE L-1. The extractant was 5% Ionquest® 801 in Shellsol 2037 diluent. Hydraulic performance of the pulse column was excellent with no propensity towards stable emulsions or crud formation under normal operating conditions. The column was operated in organic-continuous mode with flow rates chosen so that yttrium and the heavy rare earths were extracted with high efficiency while the light rare earths were rejected. Yttrium extraction varied from 83 to 99.2%. Concentration profiles were measured in both the aqueous and organic phases, and, from this data, the height of a transfer unit (HTU), the mass transfer coefficient (Kxa) and the continuous-phase axial dispersion coefficient (Ey) were computed. The HTU ranged from 17-92 an which is within the range of values reported for other (non rare earth) pulse column systems.

Jan 1, 1992

By Kim Fagerlund

A novel apparatus for studying refractory infiltration and dissolution/degradation under a temperature gradient was developed. To supersede conventional isothermal refractory testing, a new temperature gradient technique, based on a crucible equipped with a cooling element, has been developed to provide practical information on the penetration and dissolution of refractory materials under cooled conditions. This technique was adopted and applied to several refractory-slag systems. Commercially available magnesia chrome refractory bricks against a copper-containing calcium ferrite type of slag were tested and compared using both a conventional crucible test and the new temperature gradient method. The experiments were conducted at 1300-1420°C under a controlled atmosphere of nitrogen or air. It was noticed that the type of porosity has a significant effect on infiltration of magnesia chrome refractories. Furthemore, the copper-containing calcium ferrite slag caused a severe slag attack and refractory failure in some cases, due to its fluidity and corrosive nature.

Jan 1, 2002

By S. F. Cheng

Among the many extraordinary features of the rare earths are their magnetic and magnetoelastic properties. The rare earths, e.g. Tb, Dy, Nd, Sm, are known worldwide for their large magnetocrystalline anisotropy and magnetization, which has led to the importance of magnetic rare earths as vital ingredients of modem permanent magnets. In this paper, we focus on the strain dependence of these giant effects which gives rise to huge magnetostrictions, magnetomechanical couplings, and ?E effects. Magnetostrictions greater than 10-3 have been measured at temperatures as high as 500 K. At low temperatures magnetostrictions reaches -1%. ?E effects - 10. No other solid state material has matched these values. A proper balance of magnetic anisotropy and magnetostriction, plus a proper choice of crystal axes lead to alloys which can switch large quantities of energy between the internal (magnetic) and external (mechanical) states with the application of small triggering magnetic fields. In addition to the traditional use of these materials in transduction, they are particularly valuable for smart systems where reliability and robustness are needed such as active structure stiffening and active vibration control.

Jan 1, 1997

A rotating-discelectrode system was used to evaluate the electrochemical behaviour of Eu(III) during its reduction in NaCl solutions. The solution pH and NaCl concentration have a great effect on the reduction kinetics. The thermodynamic modelling study also revealed that Eu(III) exists in various forms in NaCl solutions. At a low concentration of NaCl, the predominant species is the free Eu3+. Other Eu-chloro complexes become more predominant when the NaCl concentration increases.

Jan 1, 1992

By Florian Kongoli

The liquidus surface of multicomponent slags is an important parameter in various smelting and converting processes. It helps not only to optimize the slag, chemistry of current processes and their fluxing strategies, but also to determine the availability of new slags for more advanced technologies. In a series of our previous publications, the liquidus surface of some multicomponent iron oxide slags has been quantified at several constant oxygen potentials and the effect of the latter, ignored until that moment, was quantified along with the effect of some minor components. In this work, the liquidus surface of some iron oxide slags is quantified at constant CO2/CO ratios. This is a new convenient way for the quantitative description of the slag liquidus surface and the effect of several fluxes, especially in those processes such as slag solidification, where oxygen potential changes continuously. This type of diagram also describes more dynamically the effect of oxygen potential, clarifies the relation between CO2/CO ratio and oxygen potential in terms of the liquidus surface, which is not widely understood by metallurgist today, and reduces the gap between laboratory work and industrial experience.

Jan 1, 2002

By Peng Peng, Ouo Cheng, Guodong Lai, Lijuan Chu, Zebiao Zhang

"The pressure acid leaching residue of zinc concentrate contains a large quantity of sulfur. The present study attempts to leach sulfur using a mixture of ammonium sulfide and water solution at 25°C. Effects of three leaching variables: ammonium sulfide concentration, leaching time, liquid/solid ratio on the sulfur leaching rate were investigated. The process conditions were optimized using response surface methodology based on the central composite design. From the analysis of variance (ANOVA), the significant factors on response were identified. The optimum conditions for leaching elemental sulfur from pressure acid leaching residue of zinc concentrate were obtained using an ammonium sulfide concentration of 2.5 mol/L, leaching liquid-solid ratio of 6.5:1 and leaching time of 7 min. Under the optimum experimental conditions, a maximum of 98.50% of total sulfur was extracted. The experimental results obtained agreed satisfactorily with the model predictions, with a correlation coefficient (R2) of 0.99.IntroductionSulfur is widely used in agriculture, medicine, rubber, building materials, gunpowder, wine and sugar, and other fields [1]. Currently the world sulfur production is 40Mt, out of which more than 90% is recovered from industrial processes, and 10% is natural [2], This highlights the importance of sulfur recovery. As the pressure leaching technologies [3] continue to mature and are increasingly applied to refining, a large quantity of high-sulfur residue is produced [4-5]. It is desirable to recover sulfur from this residue, so that it is economically advantageous, and reduces environmental pollution [6]."

Jan 1, 2012

By Virgil Optasanu, Yvon Lacroute, Eric Lesniewska, Tony Montessin, Pauline Vitry, Eric Bourillot, Cédric Plassard

A general challenge in metallic components is the need for materials research to improve the service lifetime of the structural tanks or tubes subjected to harsh environments or the storage medium for the products. One major problem is the formation of lightest chemical elements bubbles or different chemical association, which can have a significant impact on the mechanical properties and structural stability of materials. The high migration mobility of these light chemical elements in solids presents a challenge for experimental characterization. Here, we present work relating to an original non-destructive, with high spatial resolution, tomographic technique based on Scanning Microwave Microscopy (SMM), which is used to visualize in-depth chemical composition of solid solution of a light chemical element in a metal. The experiments showed the capacity of SMM to detect volume. Measurements realized at different frequencies give access to a tomographic study of the sample.

Jan 1, 2015

By Ruben Alvarado

The need to increase business competitiveness while complying with environmental requirements represent the great challenge that the Caletones smelter has decided to face in a new development project with a compromising and willing alliance with its workers. To date, the project is at the feasibility stage, with start up scheduled for the middle of the year 2002. The processing capacity of the Teniente Converters will be increased to levels up to 2400 tpd of chalcopyrite-based concentrates containing 30% Cu, by means of more intensive use of oxygen and improved stabilization of the overall operation. Productivity increses in the converting of white metal and the pyrometallurgical treatment of slag are also planned. As a result of related strategies, the productivity of the supporting facilities, included the capacitiy of the sulfuric acid plants, will be increased. An intensive and well-designed labor-upgrading scheme will allow the transformation of every worker into an expert in his working areas, thus becoming an active driving force in technology development. Mechanization, appropiate infrastructure, and complete process control and instrumentation will give to the skilled and motivated personnel the necessary tools in order to attain the highest potential ever reached with the Teniente technology. The necessary investment for this project based on the adding facilities to the existing plant is only a third of that required to reach the same objective for a greenfield plant, thus yielding a very high return on investment.

Jan 1, 1999

By Andre Thess, Oleg Zikanov

"Direct numerical simulation methods are applied to study the influence of a constant magnetic field on turbulent flows of liquid metals. The flow is assumed to be homogeneous and the problem is reduced to the classical case of the turbulent flow in a 3D box with periodic boundary conditions. The main subject of the study is the anisotropy developing in a liquid metal flow affected by constant magnetic field.To investigate the long-time evolution of initially isotropic flow the large-scale forcing is applied to maintain the flow energy at a statistically steady level. It is found that the flow evolution depend strongly on the magnetic interaction parameter (Stuart number). In the case of small Stuart number, the flow remains three-dimensional, turbulent, an approximately isotropic. At large Stuart number (strong magnetic field) the turbulence is suppressed rapidly and the flow becomes two-dimensional and laminar. Very interesting is the intermittent flow evolution at moderate Stuart number. Long periods of almost two-dimensional, laminar behavior are interrupted by strong turbulent three-dimensional bursts.The influence of a constant magnetic field on scalar transport properties of liquid metal turbulence is investigated using the simplified formulation of homogeneous flow driven by an imposed mean temperature gradient. Such a flow consists primarily of two turbulent antiparallel jets providing an effective mechanism for heat transfer. It is shown that the magnetic field parallel to the mean temperature gradient stabilizes the jets and, thus, enhances heat transfer considerably."

Jan 1, 1999

By Ilkka V. Kojo

This paper gives an overview of the primary copper smelting business during the years of flash Smelting in the light of various projects taking into account the sustainability of copper production. Also the future challenges of copper smelting are addressed with special emphasis on the environment. Flash Smelting connected with either Peirce-Smith converting or Flash Converting offers the most economical and environmentally friendly alternatives for the smelting of normal and lean copper concentrates. For rich copper concentrates the feasibility of Outokumpu Direct Blister Flash smelting is, understandably, beyond compare. When the total investment costs for building a smelter and acid plant are considered, it is clear that Flash Smelting is the more feasible option compared to bath smelting. Reduction of equipment and operating cost is further achieved by the LUREC-process developed by Outokumpu Technology for operating plants with SO2-contents up to 25 % by volume. As an example the Kennecott-Outokumpu Flash Converting Furnace (FCF) has been in operation at Kennecott Utah Copper for 10 years and has achieved excellent results both environmentally and production vice. The FCF treats the entire output of the Kennecott Flash Smelting Furnace and has excess converting capacity. Furnace life, initially projected at two to three years, is now projected to be more than 5 years. It is likely the life will be essentially the same as a well-operated Flash Smelting furnace.

Jan 1, 2006

By A. A. Bustos

Four Air Liquide Shrouded Injectors (ALSI ) were installed and operated for over one year in a Peirce-Smith converter at the Falconbridge nickel smelter in Falconbridge, Ontario, Canada. A shrouded injector consists of an inner pipe and an annulus, through which high oxygen enriched air and nitrogen flow, respectively The nitrogen cools the injector and protects the refractory in the vicinity of the injector tip, allowing for substantial increases in oxygen flow rates to the converting reactions. Several injector designs were tested to study the effect of changes in the cross-sectional area and changes in the entrance geometry of the annulus. An optimum design would minimize the injection pressure required for a given flow rate to achieve choked flow conditions at the tip of the injector. The operation of the ALSI was simple and did not require any special care or maintenance, either between blows or between converter cycles. In particular, the shrouded injectors did not require punching, as is the case with conventional tuyeres. In terms of refractory performance, the ALSI, operating at 30-40 % oxygen enrichment, were superior or equal to the conventional tuyeres, which operated at 21-23% oxygen. The results of the demonstration program led Falconbridge Limited to implement the ALSI technology on a commercial scale The paper presents the demonstration program results in terms of gas flow rates, accretion formation, punchless operation and refractory wear.

Jan 1, 1999

By P. C. Guillaume

Global plant modernizations or expansions cannot be considered in the same light as any other industrial investment project. Relationships between the partners, relationships and communications with the client, structure and organisation of the teamwork, schedule of the work, and a lot of other tasks and missions devoted to external contractors have to be defined considering one fundamental input: an operating plant. For an engineering company expert in processing, like UM Engineering, such a context requires a specific approach as well as specific procedures able to efficiently challenge the generated constraints. First of all, even if a detailed audit had been conducted at the beginning of the conceptual engineering phase, new elements will be discovered during the preparation and realization of the project, and must be continuously integrated. Consequently, a close proximity to the site is necessary. This is one reason why UM Engineering, most often, works in partnership with a local engineering company. The second important point for the client is that the operation must not be interrupted during the realization. In order to make that possible, UM Engineering has defined a specific project structure and organisation, integrating on a permanent basis the operators (the "users") in the project teams. This paper presents the way UM Engineering copes with this type of "multi-constraints" context with reference to the recent copper cellhouse modernization under realization for the CCR Refinery of Noranda Inc. in Canada.

Jan 1, 1999

By S. D. Prosser

The earliest record of slag in the world was the discovery of the remains of a copper blast furnace in Southern Israel, which has been carbon dated at 3500BC, nearly 6,000 years ago. Slag in Australia is a much more recent phenonenum with the first iron blast furnace commencing operations in 1848. The early days of metal smelting in Australia were marked with many company failures due to a variety of reasons. This paper traces the progress of metal and slag production from those early days up to the present times

Jan 1, 1994

By A. K. Kyllo

The use of Composite Furnace Module cooling systems has been shown to give improved refractory performance in a number of above bath locations in WMC flash furnaces. To test the behaviour of modules in contact with a melt, a set of instrumented modules have been installed in the reaction shaft of a. nickel flash furnace. The location was chosen to provide a suitably harsh environment to ensure rigorous testing, while still allowing relatively easy access for module installation. The modules were continuously monitored to provide information on the module performance, as well as the temperature in the shaft itself. The shaft temperature showed significant transient behaviour, which resulted in heat fluxes through the modules ranging from 10 to 92 kW m-2. The modules were capable of handling the highest heat flux with no risk of the coolant boiling. This paper details the design and operation of the modules over a period of seven weeks.

Jan 1, 1999

By I. Kim, J. C. Choi, W. D. Cho

"The effect of yttrium addition on the oxidation behavior of Fe3Al intermetallic compound was investigated in the range of temperature 800 to 1100 °C in 0.2 atm 02 in terms of oxidation rate and oxide adhesion. The oxidation rate of alloys, Fe-14.3 wt% Al and Fe-14.1 wt% Al-0.3 wt% Y, was nearly identical and the parabolic rate constant calculated as a function of temperature is Kp=5128 exp[-39506(cal/mol)/RT] mg2/cm4 hr.Rapid cooling and ultrasonic stress tests were carried out to test adhesion of scale formed on the alloys. While the oxide layer formed on the Fe-Al alloy without Y was found to be fragile and detached easily during the tests, the oxide layer formed on the Fe-Al alloy containing Y was protective, dense, and adhesive. The following two mechanisms were proposed to explain the adhesion improvement of Ah03 formed on the Fe3Al containing yttrium : (1) the addition of yttrium decrease generation of growth stress in alumina scale because the preferential diffusion of yttrium through grain boundary in alumina scale prevent internal oxidation of Al, one of main causes of growth stress, and (2) the second phase formed on the oxide scales prevents crack propagation through the scales, leading to better mechanical stability of the oxide scales.IntroductionIron aluminides have attracted the attention of many researchers as a candidate for use at high temperature because of their excellent oxidation resistance due to the formation of protective alumina scale. In order to resist aggressive environments at elevated temperatures, oxide scale formed on iron-uluminum alloy must satisfy the following three requirements : (1) thermodynamic stability (2) slow growth rate (3) adherence on substrate. According to Wallwork and Hed [l], the most suitable alloys for high temperature application are Fe, Ni, and Co alloys with the protection of Si02, Cr203, and Ah03 scales. While chromium oxide can vaporize as Cr03 above 1000 °C and silicon oxide may form low melting silicate [2,3], Alz03 has a high melting point and is the most stable among the three oxides thermodynamically [6]. In this respect, iron aluminides forming alumina seem to be most suitable for use at high temperature. However, alumina scale formed on the iron aluminum alloys tends to be easily spalled during oxidation due to the combination of growth stress and thermal stress."

Jan 1, 1998

By Norman L. Kotraba

Zia Metallurgical Processes, Inc. has developed and patented a steelmaking process capable of converting iron bearing metallurgical wastes into high quality steel products. The process utilizes a proprietary design rotary hearth furnace to convert iron bearing wastes, pelletized with coal, or other forms of carbon, into direct reduced iron (DRI). This DRI is fed, hot, from the rotary hearth furnace into a Zia All Purpose Vessel (ZAV) where it is smelted and refined into high quality steel. A specially designed turret with three independent arms, each supporting a separate ZAV, comprises the heart of the meltshop. No overhead cranes are required to transport molten metal from the smelting/refining operation to the ladle metallurgy station to the caster to an inspection station and back to the smelting/refining point. The molten steel is contained in the ZAV throughout the operations eliminating the possibility of steel con¬tamination by non-metallic inclusions occasioned by the exposure to ambient air during metal transfer into ladles. The result is the creation of very clean steel that can be alloyed to produce virtually any desired grade from stainless steel to common structural steel.

Jan 1, 1994

By Xiao Y. Yan

A fused salt electrochemical process was investigated for the synthesis of non-oxide ceramic powders directly from metal oxides, boric oxide, and carbon powders by electro-deoxidation. Sintered pellets of the mixed powders were designed to act as a composite cathode in the electrolytic cell. Electrolysis was carried out in molten CaCl2-NaCl eutectic at 3.1 V and at 600-900 ºC under argon. The favoured cathodic reaction was the removal of the oxygen from the oxides to produce metal atoms that reacted with either the reduced boron atoms, forming a metal boride, or the carbon initially present in the sintered pellets to produce a metal carbide. The technical viability of the process was demonstrated by the electro-deoxidation of sintered pellets of TiO2/B2O3 and TiO2/C to produce TiB2 and TiC, respectively. Compared to existing carbothermic reduction process, this new electrochemical process may be less energy intensive and may lead to lower production costs. I

Jan 1, 2008

By Melissa L. Trapani

The removal of molten products from metallurgical furnaces is one of the most hazardous and labour intensive processes in a non-ferrous smelter. The proximity of operators to the molten metal and slag during tapping and the oxygen lancing that facilitates the flow have led to many reported injuries on tapping floors. In most cases, tapholes are opened and closed periodically leading to extreme thermal cycling in the tapping assembly. As a consequence, refractory wear rates are high and unpredictable in the taphole. This paper provides a review of the current state of taphole development, and gives a methodology that is now being applied to gain a better understanding of the taphole region to allow design improvements.

Jan 1, 2002

By F. Sakurai

The enlarged Mitsubishi process in Naoshima has been in steady operation since. May 1991. However, the sulfuric acid plants have been in operation for more than 30 years. The acid plants were modernized between 1999 and 2001 by renewing some of main equipment such as the drying tower and gas heat exchangers, and introducing new technology. At the same time, as an electric energy saving measure, the electric power consumption in the sulfuric acid plant was vastly improved by decreasing the volume of gas treated the installation of low temperature activity catalyst in the 1st pass of the converter and optimization of main gas blower runner. Furthermore, last year, the oxygen plant was replaced and enlarged, and anode production increased from 240,000 to 280,000 tonnes per year with an associated increase of sulfuric acid from 550,000 to 660,000 tonnes per year. This paper describes these recent improvements in the acid plant at Naoshima smelter.

Jan 1, 2002

By Sundarrajm Suresh, Hrushikesh G. Pimpalgaonkar, Thiyagarajan Paramadayalan

In this paper, a model of a fuel cell system has been proposed to account for the membrane physics at the micro level which is coupled with the macroscopic flow and mass transport phenomena occurring in a single channel of a Polymer Electrode Membrane Fuel Cell (PEMFC) system. We have developed a novel approach to model the catalyst layer electrochemical processes in a Membrane Electrode Assembly (MEA) and coupled it with mass transport and fluid flow calculations at the channel level using STAR-CD commercial software. The predicted values of the cell voltage from this micro-macro model are validated with experimental data available in the literature. A sensitivity analysis has been carried out to study the effect of the design and operating parameters such as catalyst loading and initial temperature on the overall performance of the PEMFC. The results indicate that the cell voltage increases at higher platinum catalyst loading and is also independent of the choice of initial cell temperature.

Jan 1, 2012