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By Nan Zhang, Gai-feng Xue, Shangchao Liu, Benquan Fu

"The high-magnetization microspheres of Fe3O4 encapsulated with S1O2 and T1O2 layers (Fe3O4@SiO2@TiO2) were prepared. The microspheres were characterized by transmission electron microscopy and scanning electron microscopy. These high-magnetization microspheres could be readily dispersed by shaking whereas they could be rapidly separated from the aqueous solution simply by applying an external magnetic field. The two shells of S1O2 and T1O2 protected the iron oxide well and the microspheres were stable in acid and base solutions. Therefore, they have a good potential for the enrichment of phosphopeptides or photocatalytic activity. They could also be used to remove metal ions from waste water.IntroductionSolid-phase extraction (SPE) is the most commonly used separation technique for its simplicity, consumption of small volumes of organic solvent, and the ability to achieve a higher enrichment factor. The quest for new adsorbents is an important factor in improving analytical sensitivity and precision in SPE techniques. To date, many novel adsorbents, such as nanometer-sized materials, carbon nanotubes, mesoporous materials and magnetic nanoparticles have been employed in SPE.Magnetic polymeric microspheres, an interesting advanced composite material, have received increasing attention in the past few decades because of their unique physical and chemical properties and their potential for use in applications in various fields [1]. Magnetic microspheres consisting of an iron oxide core and a silica shell have attracted particular attention for their unique magnetic response, low cytotoxicity, and chemically modifiable surface. The core-shell magnetic silica microspheres have shown great potential in the fields of biotechnology and biomedicine for applications such as cell labeling and separation, enzyme and protein separations, targeted drug delivery, and magnetic ferrofluids hyperthermia."

Jan 1, 2012

By A. L. Engel

This report is a compilation of results of brief preliminary tests on sulfide ores that contained gold and silver and, in some cases base metals. It is a companion paper to a recent similar report on oxide ores. Simple treatment methods employing the least possible equipment sometimes produce satisfactory results on marginal ores and in small-scale operations. Investigations of typical ores from newly discovered or recently explored mining districts have been made in continuation of a long-established part of the hydrometallurgical and ore-dressing program of the Reno station, Bureau of Mines. The purpose of such investigations is to encourage the search for and development of mineral resources and particularly to assist in the economical exploitation of low-grade and marginal ores as well as the conservation and recovery .of values in products that were discarded from former operations because of inability to treat them profitably. Several of these investigations have been limited to preliminary tests of samples from prospecting operations, whereas same involved samples of old dumps or tailings piles. The test work in these cases was not extensive enough to warrant publication as individual reports, but is of considerable interest inasmuch as it indicates the possibilities as well as the limitations of treating the respective materials. The samples were representative of the districts from which they wore obtained, so this information should be helpful in the future development of these districts.

Jan 1, 1951

By Stephen G. Mlot

The evaluation of mineral projects involves the identification, mitigation and management of significant uncertainty. Benchmarking is an essential and effective way of increasing confidence and reducing uncertainty associated with input parameters and assumptions. Comprehensive and detailed benchmarking will ensure ?best practice? technologies, methods and systems have been considered and that the appropriate practices can be identified and incorporated into the project. In conjunction with the involvement of experienced industry practitioners, benchmarking is best employed throughout project evaluation to enable early identification of ?errors?, producing more accurate and predictable outcomes. Considerable time and effort is required to gather data and information, which should be benchmarked by the project evaluation team. There is a history of mining projects underperforming, on production, on costs and on return to the investors. The quality of mine plans and feasibility studies, and the quality of the input data is being questioned in many ways. Benchmarking assists sound project evaluation practices, by providing a database of actual results, to validate project inputs and outcomes, ensuring they are realistic and achievable. Benchmarking also provides unbiased, statistical support as the basis for sound investment decision making and ensures well considered decisions are made resulting in a more efficient study process. The evaluation of the quality of projects which are the subject of transactions also benefits from the use of real data obtained from a benchmarking database. Vendors are quick to highlight the benefits of their projects, and conceal the flaws, inflating the value. Buyers will want to quantify the potential of a project through the due diligence process relying on actual results from benchmarking. For the reasons broadly outlined above, benchmarking should be considered as an essential component of effective Project Evaluation.

Aug 1, 2013

By F F. Pitard

Observation from attending many conferences around the world reveals that many people are constantly shifting from the word ‘error’ to the word ‘uncertainty’ without a clear vision of what the subtle difference is. The same applies to a large swath of the scientific literature, in which these two concepts are unfortunately often used synonymously, which is a scientific flaw of the first order. In practice, as demonstrated in the Theory of Sampling (TOS), there are both sampling errors and sampling uncertainties. Sampling errors can easily be preventively minimised, while sampling uncertainty for a preselected sampling protocol is inevitable. P M Gy’s work, supported by G Matheron’s critical reviews, demonstrates beyond any possible doubt that sampling uncertainty cannot be achieved if sampling errors are not preventively minimised by applying very stringent rules that are too often ignored by sampling practitioners. A clarification, in line with the TOS, is presented to mitigate the confusion created by circles favouring the use of uncertainty versus the use of the word error. Both words are very different in nature and scope and they are both necessary in their due place and time.CITATION:Pitard, F F, 2017. From errors to uncertainty – a clarification for proper use by the Theory of Sampling, in Proceedings Eighth World Conference on Sampling and Blending , pp 355–358 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

The status of utilization of copper ore resources, and the application and development of biohydrometallury technology in the world is reviewed. Based on the characterization of Zambia?s copper resources, biohydrometallurgy technology is shown to be a practical approach to extract and utilize the enormous low grade copper resource, such as ore tailings and low grade copper ore in this country. Through the cooperation of CSU, China and MMMD, Zambia, ?CNMC-CSU Demonstration Base of Biohydrometallurgy Technology in Zambia? was launched and several biohydrometallurgy plants are being constructed. This indicates that the biohdyrometallurgy technology would be applied soon in Zambia and in the whole Africa. Biohydrometallurgy technology stands as an efficient alternative to the traditional pyrometallurgy process and it can be the key to unlock mineral resources value. Keywords: biohydrometallurgy, low grade copper ore, Zambia, Central South University

Sep 1, 2012

By R. W. Jenkins, O. J. Neslage

The need for mechanized drilling to decrease mining costs has resulted in the development of the jumbo from column-and-bar drill carriages to hydraulically controlled jib jumbos. Resultant savings from use of improved jumbos have been high enough usually to retire the machinery investment within a year. The jib jumbo unit has been applied successfully to development and preparation programs and flat-bedded stopes, and an even wider field is forecast for its use.

Jan 1, 1950

By Ian Misich

A research programme has been undertaken to evaluate and predict the effect of total extraction of coal by underground methods on the superimposed strata, aquifer systems and ground surface in the Collie Basin. Western Australia. The research work has integrated comprehensive field monitoring of surface and subsurface subsidence with empirical, analytical and physical modelling in an effort to develop an effective predictive tool which can be used in all mining scenarios. Early results indicate that although each method has certain limitations, this approach has enabled the researchers to develop a very good understanding of the subsidence mechanisms from the mine panel through to the surface in the weak, water saturated sediments in the Collie Basin. Given that both subsurface and surface subsidence characteristics have tied in well, greater confidence can be held for predictions made by representative models.

Jan 1, 1993

The Cadia mine is shifting from the open pit operation to the Cadia East underground block cave. The resulting increase in milled tonnes and the decrease in fines production through shifting to block caving require an increase of over 25% in installed power. This expansion is being accomplished via the installation of up-front crushing and HPGR milling of the ore, with the SAG mill receiving a secondary crushed feed. This design, criteria and rationale for selection is presented. Over the coming years, the mine will further expand capacity. The target is to accomplish this with minimal addition of installed power or use of fresh water. This presents a challenge that epitomizes the future constraints on our resource dependent and intensive industry. The approach and proposed options to this longer-term expansion are also presented.

Jan 1, 2012

By Eric S. Weiss, Deno M. Pappas, Timothy M. Barton

During the past few years, the Pittsburgh Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) has been evaluating developments in sealant support systems from a ground control perspective. The proper selection and use of a sealant material can significantly enhance ground control which may result in a decrease in worker related injuries due to ground falls. The purpose of this paper is threefold: to briefly review the current state-of-the-art technology in shotcrete and membrane developments, to evaluate the preliminary findings of a long-term underground study of various types of sealant materials, and to examine installation practices that are critical for an effective sealant material. The underground study utilizes NIOSH’s Lake Lynn Laboratory Experimental Mine to evaluate the long-term performance of several types of shotcrete and membrane materials. Sealant performance to date have been evaluated on a regular basis over a two year period. Although the study is still ongoing, critical mining practices were identified that may seriously effect the bond of the sealant materials to the mine roof and rib; most notably, the importance of scaling and thorough cleaning of the rib prior to application. Also, results froman extensive series of Schmidt Hammer tests found that the shotcrete increased in strength by 70% during the humid summer months.

By A. de Meyer

Zincor experienced significant losses of metallic zinc to dross during the melting of zinc cathode plates. In this study five factors affecting the formation of dross are identified from literature. Dross from both the plant and that produced in the laboratory is characterized using XRD. An empirical model, based on laboratory-scale investigations, was developed to quantify the effect these factors on their own or in combination with each other has on the amount of zinc loss to dross. The predictive capability of the model is evaluated based on the laboratory-scale investigations. Predictions are made on the effects that heat treating the cathode plates prior to melting, increasing the cathode plate thickness, washing and drying prior to melting, and loading the furnace in a controlled manner have on the amount of zinc loss to dross. Keywords: Zinc, dross, optimize, smelter, yield, losses, empirical, model, XRD.

Jan 1, 2010

By George R. Ingham

This paper is one of a buries being prepared by the Bureau of Mines on mining methods and costs at various mines in the United States, and is a description of the mining practice at Ajo, Ariz., where the New Cornelia Branch of the Phelps Dodge Corporation mines copper ore from an open pit, and operates a concentrator for the treatment of the ore thus mined. ACKNOWLEDGMENTS The authors wish to express their appreciation to M. Curley, manager of the New Cornelia Branch of the Phelps Dodge Corporation, for his review of this paper and permission to publish it. They also wish to acknowledge the assistance given by W. C. Lawson, assistant engineer, in the preparation of the paper.

Jan 1, 1932

By J. J. Dowd

1. The Pittsburgh bed is the most important bed in Ohio County, and virtually the entire production of coal in the county comes from this bed. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 tons per acre-foot of-coal in place, are estimated at 365 million short tons as of January 1, 1954. Of this total, 356 million short tons is in beds 28 inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics are too meager to make an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1955

Removal of Arsenic in Fluorite Ore by Simultaneous Grinding-Leaching with NaHS Generally speaking, a high-grade fluorite ore is converted into hydrogen fluoride (HF), which is essential for the semiconductor manufacturing. With the continuous depletion of resources, novel technologies for processing low-grade fluorite ores are urgently needed, in order to lower the arsenic concentration to less than 100 mg/kg. In this study, a low-grade fluorite ore was upgraded by removing arsenic, which is difficult to remove by conventional method. The mechano-chemical leaching of fluorite ore (i.e. the sample was ground in presence of NaHS, using a beads mill) was carried out to investigate the removal of arsenic from the low-grade fluorite. Experimental results showed that the arsenic concentration was reduced to 73.2 mg/kg.

Sep 13, 2010

By P. Share

As part of JAGUARS (JApanese-German Underground Acoustic emission Research in South Africa), high-resolution tiltmeters were installed during 2007 at Mponeng gold mine, South Africa, in an attempt to study and understand the risks posed by in-mine seismic events and to subsequently use the knowledge gained to mitigate these risks. In December 2007, an M2.2 event occurred at Mponeng and was detected by the tiltmeters installed. The tilt expected for the M2.2 event is modelled through the use of numerical and analytical tools and utilizing, as input parameters, characteristics of the event such as the rupture area, the amount of slip, elastic properties of the rock, the state of stress before the event occurred, and frictional parameters of the rupture. The calculated tilt values are correlated and compared with the recorded data, and are found to be of the same order. Certain input parameters, such as the initial rupture point, are further constrained by varying them, during modelling, until the calculated and observed tilt values are approximately equal. From modelling, it can be concluded that the rupture point had to be closer to the location of the tiltmeters. In addition, possible locations acting as source areas for the observed aftertilt are determined. Further modelling still needs to be done to quantify the effects of the tunnel close to the tiltmeters and plastic deformation of the rock mass. Keywords high-resolution tilt data, Mponeng gold mine, M 2.2 seismic event, analytical modeling, numerical modeling, rupture plane.

Oct 1, 2013

By Thierry Bernard, Guy Gagnon

Blasting at very close proximity to urban areas is typically a situation where both local communities and mining stakeholders get nervous. The context becomes logically even more tensed when the blasting operations have to be performed above an old underground mine. When mitigating subsidence risks requires firing the largest possible shots, the nuisance control (flyrock, vibration, and noise) required by local and national regulations, contrarily urge for being more conservative.

Jan 1, 2014

By O. Worku, J. H. Masliyah, Z. A. Zhou

ABSTRACT The viscosity of concentrated kaolinite or illite clay in aqueous suspensions was measured in the presence and absence of a small amount of montmorillonite (<1 wt%). To avoid solids settling and to increase the sensitivity of the suspension viscosity measurements, solids concentrations higher than 38 wt% were used. The pH of the suspensions and the concentration of calcium and bicarbonate ions were found to significantly impact the viscosity of the clay suspensions. The results showed a significant increase in the viscosity of kaolinite suspensions with the addition of as low as 0.25 wt% of montmorillonite on a solids weight basis. In addition to illustrating the role of water chemistry in modifying slurry rheological properties, our study demonstrated that viscosity measurement could be a simple, yet sensitive technique for determining the content of smectite clays, such as montmorillonite, in a complex mix of various types of clay.

Jan 1, 2012

By V. Miguel-Silva, B. C. Afonseca

Drill-hole spacing analysis (DHSA) and optimization are becoming commonplace for uncertainty assessment and management in the mining industry. However, there is no standardized DHSA workflow, and the outputs of certain methodologies are not interchangeable. We group available simulation-based DHSA methods according to their accounted uncertainty into (i) raw uncertainty, assessed by drawing realizations from synthetic data-sets with the drilling spacings to be tested; and (ii) model uncertainty, in which these synthetic data-sets are used to assess the variation between the estimated model and the (unknown) actual value. DHSA workflows available in the literature ignore the differences between both types of uncertainty. Commonly, the DHSA algorithm is chosen without a detailed analysis of its uncertainty output, which may lead to misleading results and suboptimal decisions. While available solutions are based only on assessing raw or model uncertainty, the proposed approach simultaneously analyses both and their relationship for models at different stages of the mine. The integrated analysis results deliver more information to support decision-making than available methods. Principles, practical considerations, and discussions of the advantages of the proposed integrated analysis are presented. The approach is applied to a real gold deposit to illustrate its use.

Jun 2, 2022

By Wen Tao Liu, Tong Tian, Fu Sheng Niu, Xiu Man Liang

In order to address the difficulty of accurate segmentation of froth images of different sizes, a method of froth image segmentation based on highlight correction and parameter adaptation is proposed. First, a machine vision system on a single-cell flotation machine is built to collect froth images. Homomorphic filtering is used to improve the uneven brightness and shadow of the images. Fuzzy c-means (FCM) clustering is then utilized to classify similar highlights that belong to the same froth. After Otsu threshold segmentation, a parameter-adaptive morphological operation is used to extract the marker points and edge bands and correct the froth edges in the original image. Finally, the modified image is filtered by morphological reconstruction, and the highlight mark is used as the local minimum point for watershed segmentation. Three sizes of froth images are segmented in comparative experiments. The results show that the proposed method is suitable for the segmentation of froth images of different sizes. The position of the extracted segmentation line is close to reality, with average over-segmentation and under-segmentation rates for froth images of 2.6% and 6.8%, respectively. The froth image segmentation performance is stronger than that of the other methods examined.

By W. W. Culver

The paper explores the substance, circumstances and significance of the Whelpley and Storer Copper Process. The 1866 Whelpley and Storer patent specified a process combining mechanical and chemical engineering. The process called for a down-drafting shaft furnace with a horizontal flue connected at the bottom of the shaft. Powdered sulphide ore was roasted in the shaft and then sent forward fully oxidized to a bath of sulphuric acid and/or calcium chloride. The “water furnace” was developed in Boston, at a time when the city was home to most Michigan copper mining companies. The process was field-tested at Quebec’s Harvey Hill copper mine. In 1865 James Douglas, Jr. took over management of the Harvey Hill mine with the challenge of saving the family investment. He needed a way to make money from low-grade sulphides. Through his relationship with chemist T. Sterry Hunt, Douglas learned of a possible way ahead using the process developed by Whelpley and Storer. The paper confirms the centrality of publications, meetings, and networking in the advancement of metallurgy. The process is of interest historically, as much as anything, because it is one of the pillars of James Douglas’ distinguished career in copper. INTRODUCTION At the 1866 meeting of the American Association for the Advancement of Science (AAAS) in Buffalo, New York, T. Sterry Hunt (1826–1892) read a paper “On the Metallurgical System of Messrs. Whelpley and Storer.” The paper is part of a chain of events that constitute the foundation of James Douglas’ (1837–1918) success in the copper mining industry. To understand the career of Douglas over the early years of modern copper mining, we must necessarily start with Whelpley and Storer. Going back to Hunt’s paper, he concluded his remarks by asserting that the Whelpley and Storer Process was “capable of such wide and varied application, that it is probably destined to have a very important influence on the industry of the world” (Hunt, 1867a). He reached this conclusion reasoning that the process had overcome a critical metallurgical hurdle (Hunt, 1867a). Hunt, a geo-chemist in modern terms, recalled that the chemist of those years easily separated copper from “sulphuretted” ores by converting it to a soluble salt from which pure metal was precipitated by “an equivalent of iron.” The problem was to “…apply this principle in the working of copper ores on a great scale...” (Hunt, 1867a). Hunt noted that this very problem had “…engaged the attention of many metallurgists, and has given rise to various processes for obtaining copper by the moist way, many of which are nearly or quite perfect in their operation, but are lacking in practicability and cheapness” (Hunt, 1867a). Hunt thought Whelpley and Storer had overcome the low-grade sulphide hurdle with a commercially viable engineering breakthrough. Yet in the history of copper metallurgy, the process is missing. What happened?

Jan 1, 2019

Preparation of MgO Nano-Particles with Magnesite

Sep 13, 2010