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By P. A. Olubambi

The leaching of zinc and copper from Nigerian bulk sulphide ore with sulphuric acid in the presence of hydrogen peroxide was studied. The aim of the study was to investigate the effectiveness of hydrogen peroxide as an oxidant for the sulphuric acid leaching of zinc and copper from a complex sulphide ore. Distribution of elementals within the various particle sizes was initially determined by ICP-OES and XRF to provide a basis for explaining the dissolution process. The effects of concentration of hydrogen peroxide, particle size, stirring speed, and leaching time at a constant temperature of 298K were studied. There were variations in elemental and mineralogical composition within the different sizes. The concentrations of zinc and copper reduced as particle size decreased while silica, sulphur, iron and lead contents increased. Dissolution results showed that the leaching rate of copper was lower than that of zinc. The highest recoveries of zinc and copper were obtained at a leaching time of 180 minutes, stirring speed of160 rpm, particle size of 75 µm and a concentration of 1M H2SO4/1MH2O2. It was observed that the leaching rate of zinc and copper increased with increasing hydrogen peroxide concentration. Increased stirring speed had a negative leaching effect as it promotes hydrogen peroxide decomposition. Keywords: Nigerian sulphide ore, zinc, copper, hydrometallurgy, sulphuric acid, hydrogen peroxide.

Jan 1, 2006

By C. S. Chenga

Sustainable development is currently an extremely relevant concept worldwide, especially in developing countries like South Africa. Mining and metals companies are also directly affected by the sustainable development agenda. The Mining Charter?s requirements as well as new legislation (Mineral and Petroleum Resources Development Act) expect, among others, for mines to support infrastructure and poverty eradication projects in the communities surrounding the mines. The aim of this paper is to, against the background of a qualitative study of mining communities in the North-West Province of South Africa, put forward some critical factors for the sustainability of social development projects in the mining sector.

Jan 1, 2006

By Maurice Bottiau

It is a quite challenging objective to aim at covering in one paper the most recent evolution in piling and deep foundations technologies. This report has to be understood within the limits of the session 2b. It will therefore concentrate on the technological evolution of deep foundation techniques, addressing design issues only when directly related to execution aspects. For the same reason, it will not address the related codes, as a separate session of this conference is specifically dedicated to this topic. Monitoring and deep excavations being covered in other sessions, they will only be addressed when clearly relevant. We will try to show, from a practical viewpoint what are the main changes and the most exciting or critical issues over the last years, as they appear from the topics addressed in the literature or in the papers published in this session of the conference. As the paper mostly intends to explain trends and critical topics, it cannot be exhaustive, neither can it give the full description of the case studies. The author invites the reader to read the full papers, for a more complete description. We have divided our report in three main topics: Piling, soil improvement and treatment and retaining walls. Anchors and tie-backs will not be treated, neither tunneling.

Jan 1, 2006

By Murat Baydogan

Effect of retrogression and reaging treatment on hardness and stress corrosion cracking resistance of 7075 aluminum alloy was investigated. As received 7075 alloys in T6 temper condition were retrogressed at 170, 220, 240 and 380°C for different durations between 15 s and 60 min. Subsequent reaging was made at the T6 aging condition. Treated materials exhibited higher hardness and better stress corrosion cracking resistance than T6 temper in a wide range of retrogression temperature and time. The highest hardness was obtained after retrogression at 170°C for 210 s followed by reaging, corresponding to 20% hardness improvement. Improvement in stress corrosion cracking resistance of the alloy by as much as 85% was also observed. In this paper, improvements in hardness and stress corrosion cracking resistance are discussed on the basis of the microstructural changes during retrogression and reaging treatment.

Jan 1, 2006

By Huang Zhiwei, Paul Skayman, Kevin Holley

In 1989 The First Brigade for Geology and Mineral Exploration of Qinghai Province discovered gold at Jinlonggou and Qinlongtan, Tanjianshan. Between 1992 and 2002 small scale mining was carried out at these sites using underground mining methods at Jinlonggou and an open pit at Qinlongtan. During 2003 and 2004 geotechnical investigations were carried out in support of a bankable feasibility study. An important objective of this investigation was to meet both internationally accepted standards and codes of practice, and also to satisfy the Chinese requirements. Extensive use of local experience was utilised. Where possible geological drilling information was incorporated into the assessment. Extensive geotechnical mapping of surface and underground exposures, and index testing to gain an appreciation of rock intact strength were used to characterise the sites. Rock mass classification (MRMR) was used to assess indicative overall slope angles and appropriate bench stack heights for the proposed pits at Jinlonggou and Qinlongtan. Measured discontinuity orientations were used in kinematic analysis to assess stability of possible pit slope geometry at a batter and overall scale to provide preliminary recommendations for the pit slope configuration. Numerical modelling was also carried out to improve the understanding of anticipated pit behaviour. Site investigation and preliminary geotechnical design details, that incorporate site specific conditions for the formation of open pits at Tanjianshan, are discussed in this paper.

Jan 1, 2006

By M. Hochenhofer

Due to economic aspects and environmental regulations recycling of slag and waste from ferroalloy production became a very important issue for the companies during the last years. The treatment of slag depends prior on the composition, especially on their content of valuable metals and impurities. The final aim should be a total re-use of these materials in the industry e.g. cement industry, pig-iron production etc.. Therefore, to reach the required physical and chemical properties for a further use, possibilities of a metallurgical treatment have been investigated. The conditioning of slag with a high V-, Mo- and P-content via reducing metal bath showed to be one alternative. To determine the optimal process parameters, practical investigations with different slag compositions and thermodynamic calculations were carried out.

Jan 1, 2006

Early strategic mine planning includes decisions over the organisation of work and workforce accommodation. These decisions involve significant commitments that affect not only employee quality of life but also the impacts and relationships with existing local communities. Strategies for workforce accommodation are characteristically community-based (either as purpose-built company towns or integrated within existing local communities) or commuter (fly-in, fly-out) mine camps. The quality of accommodation underpins the fulfilment, morale and motivation of employees. This is not only relevant to productivity and safety, but also to recruitment and retention, particularly with the current onset of a significant human resources crisis. In the event that communities exist in proximity to a proposed mine then the accommodation strategy selected can influence the value-adding potential for the sustainable development of such communities. This early planning is particularly challenging where mine locations are isolated and/or face significant economic, social and political adversity. This paper draws upon a case study review of five large mining projects implemented in three South American countries, selected to cover a range of scenarios and accommodation strategies. The review aims to advance our understanding of the complexity of the underlying planning issues. Each scenario considered the prevailing environmental, social, economic and political situation, together with the adopted accommodation strategy. The case study review aimed to identify lessons learned and to make recommendations for advancing mineworkersÆ accommodation planning practice.

Jan 1, 2006

By Emma Arakelova

An increase in concentration of a Zn-containing volatile complex for synthesis of ZnO films was investigated when processing their target by ultraviolet radiation emitted by mercury lamp. The experiments were carried out using a flow-type quartz reactor. ZnO tableted target was preliminarily irradiated during 2 to 7 hours. H2O2 (98%) vapor at 25Pa passed through the reactor with ZnO target at 373K. As substrate material, five subsequent quartz cylinders were used at 423K. The experiment lasts 4 hours. H2O2 decomposition on ZnO surface was accompanied by formation of a Zn-containing volatile complex which passed in gas phase and decomposed on the substrates with isolation of final ZnO. The concentration of the Zn-containing volatile complex (N) in gas phase increases with UV pre-irradiation time (t) (without irradiation N = 1.05 1011 particles/cm3; after t=2 hours, N = 5.19 1011 particles/cm3, after t=4 hours, N = 9.95 1011 particles/cm3; after t=7 hours, N = 1.86 1012 particles/cm3.

Jan 1, 2006

By Shane Baker

Cementation Foundations Skanska Ltd encountered many significant challenges in designing and constructing the foundations for the LNG (Liquefied Natural Gas) tanks and associated structures at the Isle of Grain, Kent, UK. With LNG cargo ship levels fixed by the adjacent English Channel, the platform could not exceed critical thickness in order to achieve final grade level, so a safe and efficient working platform for construction equipment on extremely poor alluvial soils was designed and installed. The detailed pile design also required particular analysis of the pile group behaviour and considered seismic load cases not usually associated with UK pile design. Continuous flight auger (CFA) piles were the chosen foundation solution and design was verified through preliminary and working pile tests both axially and horizontally. Contaminated land and existing foundations from a previous oil terminal meant that removal of spoil was extremely costly so specific measures were taken to minimise the off-site disposal. The management of a package of general Civil Engineering in addition to the piling scope, coupled with an unrelenting production program has forced a raising of the bar for this foundation technique.

Jan 1, 2006

By Harald Ludwig

In 2002, excavation support work commenced on the Capitol Visitor Center project located adjacent to the nation?s Capitol building in Washington, D.C. The outlying work (Slurry Wall Work at Main Site is not discussed) consisted of providing excavation support for a new truck tunnel approximately 1900 feet long up to 50 feet deep as well as support for the new underground auditorium and Library of Congress tunnel. The excavation support consisted of a combination of conventional drilled in soldier beams, lagging, tiebacks and braces; intricate underpinning inside the existing Capitol building; support of an existing Russell Tunnel; soil nailing and tiebacks underneath the existing Russell Tunnel; two temporary bridges; and a deep soil mixed wall with lateral support provided by braces. As part of an on-going research program, some of these braces were instrumented with strain gauges. The deep soil mixed wall was approximately 300 feet long and 65 feet deep on either side of the truck tunnel. Approximately 34,000 sf of deep soil mixed wall, 90,000 sf of conventional excavation support, 200 braces, and 320 tiebacks were installed. This paper describes the large scope and breadth of the project that required a variety of excavation support techniques. A few of the challenges in designing and installing the support of excavation are discussed. This paper also presents the results of the instrumentation program conducted on the deep soil mixed wall, which stood open for more than a year.

Jan 1, 2006

By Kurt RP Petersen, Hendriena van der Walt

With the decline in fine diamond production from the Argyle mine in Australia, there is a greater emphasis on efficiently treating the finer size fractions through a DMS circuit. Although it is generally well understood that smaller diameter cyclones are more appropriate for this application, practical results do not necessarily meet this expectation. In this paper the operational performance of particular sized cyclones throughout the group was compared. Based on the results there is evidence that under certain practical operating conditions, small cyclones are not necessarily best for fine size particle treatment, particularly given the production pressures faced by all mines. However, there seems to be considerable merit in using larger sized cyclones, which tend to exhibit less performance variability, irrespective of operation conditions.

Jan 1, 2006

By Martin van Staveren

In today's rapid changing construction world, the business pressures on piling and deep foundations reach sky-high levels. Ever increasing complexity of construction projects do severely contribute to these business pressures. Projects are often constructed in densely populated areas and located close to vulnerable buildings and infrastructure. The inherent uncertainty of ground conditions plays a dominating role in these foundation projects. Effective risk management is a key success factor for profitable and sustainable operations of piling and deep foundations. It starts with a fundamental requirement to be aware of risks. Next the different risk perspectives of all stakeholders in any foundation project have to be acknowledged. A simple and structured risk management approach is introduced, to demonstrate that effective risk management is not necessarily that complicated. A major element is the contractual allocation of risks, as a result from differing ground conditions. It is based on the so-called Geotechnical Baseline Report (GBR). The main objective of the GBR is to provide a clear contractual arrangement for the allocation of risks, arising from differing site conditions. The benefits of explicit risk management in general and contractual risk allocation in particular are illustrated with an example and experiences. The presented structured risk management approach, including contractual risk allocation, is still rather new. It proves to be promising for cost-effective risk control of piling and deep foundation projects, anywhere in the world.

Jan 1, 2006

By Tianjiao Luo

The electroless copper plating process for continuous carbon fiber using CuSO4?5H2O as the main salt and formaldehyde as reducing agent was experimentally studied, including the effects of pH values and concentration of chelating agents, stabilizing agents and reducing agent on the electroless plating process. The surface morphology and the composition of coating were investigated by means of Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDS), and deposited the coating thickness was measured by way of dissolution. The results indicated that the pretreatment of carbon fiber before plating was so important. This pretreatment could prevent the formation of the black cores, furthermore, it could form many active absorption cores with Ag as the center on the carbon fiber surface. Used the optimized parameters in this process, which led to a stable solution for plating, a homogeneous copper coating was conducted with the carbon fiber plated with favorable mechanical performance and high adhesion strength.

Jan 1, 2006

By S. Hamilton

Occurrences of boron-containing ores are relatively rare on a global basis. The first verifiable use of borax was in the 8th century by Arabian gold and silversmiths. Due to the rarity of the borate mineral occurrences, borates were originally traded at relatively high prices and were used for very specialized applications. Today, there are

Jan 1, 2006

By T. J. Nelson

Natural aggregates, primarily stone, sand and gravel, are recovered from widespread, naturally occurring mineral deposits and processed for use primarily in the construction industry. They are mined, crushed, sorted by size, and sold loose or in concrete products to build roads, houses, buildings and other structures. Smaller quantities are used in agriculture, cement manufacture, and chemical and metallurgical processes. The growth of cities, their buildings and the highways that connect them have created demand for enormous quantities of aggregates. Consumption has now reached 9 t (10 st) per person and continues to grow faster than population. The aggregates industry is the largest mining industry in the United States in terms of production by weight, by volume and by number of active operations. About 80 percent of the concrete pavement and more than 90 percent of the asphalt pavement is composed of aggregates.

Jan 1, 2006

By S. E. Phillipson

During the course of evaluations by the Mine Safety and Health Administration’s Roof Control Division, the controls on ground instability were investigated at surface and underground limestone mines throughout the eastern and southern United States. Structural geologic features, including joints and faults, were identified by basic geologic mapping as primary controls on highwall and back instability in surface and underground limestone mines. By comparing the spatial orientation of discontinuities and internal angle of friction with the orientation of highwalls on a stereonet, the potential for sliding, toppling, and raveling failures was evaluated in a semi-quantitative fashion. Structural geologic mapping identified faults and joints, which dismembered the back and were associated with ground instability, in underground mines. This paper documents the importance of recognizing structural geologic controls on ground stability in limestone mines, advocates basic geologic mapping as a critical component of ground control programs at surface and underground limestone mines, and provides examples of simple stability evaluations using the stereonet method.

Jan 1, 2006

By Tariq B. Hamid

Deep excavation is commonly associated with construction of different deep below-grade structural elements (e.g., basement walls and slabs, tunnels, retaining walls, tanks, utilities, etc.) Deep Excavation Retaining Systems (DERS) are required when open cuts with safe slopes are not possible. Careful analysis, design, and planning of the DERS are required to provide safe below-grade construction and secure nearby structures from damaging effects that may result from the deep excavation. Selection and design of temporary or permanent DERS (e.g., soldier pile and lagging, sheet piling walls, secant pile walls, tie backs, etc.) can have significant impact on time, cost, and performance. In order to design DERS using conventional methods, it is necessary to obtain shear strength parameters, angle of internal friction (ø), and cohesion (c), of retained soils. Residual shear strength parameters (ø'res, c'res) obtained from drained direct shear tests and triaxial tests on saturated samples have been commonly used in practice for the analysis and design of DERS. However, there are cases where ground water table remains at or below the base of excavation during the design lifetime of DERS. In such cases, the soil above the ground water table is in an unsaturated state. Therefore, it is important to account for the unsaturated conditions of soils in order to optimize the design of DERS. This paper is focused on implementing the basic concepts of unsaturated soils mechanics including matric suction and soils-water characteristic curve (SWCC) to estimate design shear strength parameters of unsaturated soils (i.e., ø°, c', and ø') for the design of a cantilever sheet pile walls, a typical case of study of the DERS. The results of this study indicate that the determination of unsaturated soil strength shear strength parameters is simple. In addition, using unsaturated soil mechanics theories has an outstanding impact on the design of retaining systems.

Jan 1, 2006

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from theUniversity of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

By Paul Downing

Identity Theft Outline • What Are MY Chances??? • Types Of Thefts • Sources Of Theft Info • Stolen Identity vs. Background Checks • Information/Data Safeguards • Corporate Data Handling • Reclaiming Your Identity • Monitoring Your Identity

Jan 1, 2006

By Zia Zafir

Design of the deep foundations for the loads imposed by lateral spread include the estimate of the pressure applied by the liquefied material as well as amount of anticipated displacement. In the absence of a non-liquefiable cover over a liquefiable layer, it is possible to design the foundation system just for the additional pressure applied by the flow slides. On the other hand, if a non-liquefiable layer exists above the liquefied zone, the foundation should be designed for anticipated movements. To completely account for liquefaction and/or lateral spread and their interaction with the deep foundation system, a coupled soil-structure interaction (SSI) analysis should be performed. However, a complete SSI analysis may not be feasible for most of the projects. This paper will present recent advances in analysis techniques and simplified methods to design deep foundations for liquefaction and lateral spreading. In addition, a case history of the Rancho California Bridge in southern California located within 1 km of the active Elsinore fault will be presented. One of the bridge abutments is underlain by potentially liquefiable layers. The pressure applied by the liquefiable layer was estimated to be greater than the shear capacity of the 36-inch CIDH piles designed for the abutment. However, with limited ground improvement and more careful analyses incorporating structural effects of CIDH piles, resulting design and construction resulted in a factor of safety greater than 1 against slope failure. The recommended approach was generally consistent with the recently published, and AASHTO sponsored, NCHRP 12-49 project regarding seismic design guidelines for new bridges and the effects of seismic displacements against bridge foundations.

Jan 1, 2006