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By Chikabumi Yamauchi

The comprehensive scientific development of conventional industrial technologies stimulates the creation of new ones in the next generation. Prof. Akira Yazawa has just accomplished such an important work in the non-ferrous pyrometallurgical field. The results of his successful research are immortal. The research group of the author has conducted since 1985 fundamental studies on the application of sodium carbonate slag to copper fire refining. In the present paper, a calculation method for the distribution ratios of impurity elements between sodium carbonate slag and molten copper will be shown. The specific treatment by sodium carbonate slag will also be presented as an effective way for reducing each impurity content in the molten copper to 0.1 mass ppm, which is the level required for the production of high purity copper. The thinking-out of this evaluation method gets a hint from the Equation (2) in the text which was proposed by Prof. Akira Yazawa.

Jan 1, 2003

By K Faure

At Sams Creek a gold-bearing, peralkaline granite pophyry dike intrudes Ordovician-Silurian metapelite and quartzite. These metasedimentary rocks have undergone three phases of folding: a first phase of recumbent folds (F1), a second phase (F2) of northerly-trending inclined folds with a prominent crenulation cleavage, and a third phase (F3) of steeply plunging folds. The granite porphyry dike has a thickness of up to 40 m and intrudes thin lamprophyre dikes along its contacts. Deflection of the crenulation cleavage around the granite dike, shearing within the dike and its sinuous outcrop pattern indicate that the granite dike has been deformed during F2 and F3. The granite has been hydrothermally altered, with a first stage of magnetite-ankerite alteration. This first stage is cut by a second stage of quartz-pyrite veins and a third stage of sulphide, quartz and ankerite veins, accompanied by pervasive silicification represented by quartz-perthite-albite-rutile¦pyrite-ankerite-sericite assemblages. Lamprophyre is altered to an ankerite-chlorite-sericite assemblage. The sulphide veins are composed of arsenopyrite + pyrite ¦ gold ¦ galena ¦ sphalerite ¦ chalcopyrite ¦ pyrrhotite. The altered granite and the veins have been deformed and recrystallised. The competent sulphide minerals pyrite and arsenopyrite are fractured and brecciated, with fractures locally filled by galena, a ductile sulphide mineral. Vein quartz shows local cataclastic and mortar textures and develops pressure shadows around arsenopyrite. Alteration and mineralisation are confined to the granite porphyry and adjacent lamprophyre. These features together with the style of veining and the sulphide mineralogy indicate that the mineralisation was formed from a magmatichydrothermal fluid that was sourced from the granite. Oxygen, carbon and sulphur isotope values of the vein minerals (quartz, ankerite and sulphides) are also consistent with a magmatic source.

Jan 1, 2003

By Gray Mullins

A post grouted drilled shaft foundation system was successfully used in place of the specified driven pile foundation system as a Value Engineering Cost Proposal (VECP) for the new PGA Boulevard Grade Separation Project. Pressure grouting the cohesionless sandy soils at the drilled shaft base significantly increased the end bearing capacity and stiffness allowing drilled shafts to be the more cost effective foundation system. The post grouted drilled shaft option also provided other benefits including reducing owners risk normally associated with pile driving vibrations and offered a high level of quality assurance for the drilled shafts. This paper discusses the implementation of post grouted drilled shafts from design to completion of construction. A design procedure for post grouted drilled shafts developed by the University of South Florida was used for initial VECP evaluation. Prior to construction, two instrumented test shafts were installed and load tested, one of which was post grouted. Therein, the design procedure was calibrated, tip elevations for production shafts were refined, drilled shaft construction and grouting procedures were demonstrated, and a grouting criteria was developed for the project.

Jan 1, 2003

By N. Kinoshita, Y. Inada

The authors have proposed and discussed storage of low temperature materials such as LNG, LPG and frozen food in rock caverns. In this case, as the rock mass around the caverns will receive effects of low temperature, it is necessary to consider the thermal behavior and the stability of caverns. In this study, strength and deformation characteristics obtained by the uniaxial tension test and the compression test at low temperatures were discussed. Using the results, temperature and stress distribution around caverns when LNG was stored, were analyzed. Then thermal behavior of the rock mass around caverns was discussed. Die Autoren haben Lagerung von Niedertemperatur-Materialien wie LNG, LPG und tiefgefrorenen Nahrungsmitteln in Felskavernen vorgeschlagen und diskutiert. Da in diesem Fall die Felsmasse um die Kavernen den Effekten der niedrigen Temperatur ausgesetzt ist, ist es erforderlich, das Thermalverhalten und die Stabilität der Kavernen zu berücksichtigen. In dieser Untersuchung wurden Stärke-und Deformationseigenschaften, die durch ein-axialen Spannungstest und Kompressionstest bei niedrigen Temperaturen erhalten wurden, diskutiert. Mit diesen Ergebnissen wurden Temperatur- und Stressverteilung um die Kavernen bei Lagerung von LNG analysiert. Dann wurde das Thermalverhalten der Felsmasse in der Umgebung der Kavernen diskutiert. Les auteurs proposent et discutent l'entreposage de matériaux à basse température, tels que le GNL, le GPL et des aliments congelés, dans des cavités rocheuses. Comme, dans ce cas, la masse rocheuse entourant la cavité subit les effets des basses températures, il est nécesaire d'étudier le comportement thermique et la stabilité des cavités. Dans cette étude, les auteurs discutent des caractéristiques de résistance et de déformation, obtenues par essai de tension uniaxial et essai de compression à basse température. En se servant des résultats, ils analysent la répartition de la température et des pressions autour des cavités, lors du stockage de GNL. Ils discutent ensuite le comportement thermique de la masse rocheuse autour des cavités.

Jan 1, 2003

By John Ralston, Stephen Grano, Yongjun Peng, Daniel Fornasiero

"A specially designed mill which allowed the control of pH throughout grinding was used to study the effect of rgrinding conditions on galena flotation and galena separation from pyrite. The various reactions occurring on the mineral surface were investigated by a range of techniques, including OH- addition to maintain the grinding pH, EDTA extraction, XPS and ToF-SIMS measurements.Galena flotation and galena separation from pyrite were strongly dependent on the metal oxidation species produced on galena and pyrite surfaces under different grinding conditions. Iron oxidation species depressed both galena and pyrite flotation, whilst lead oxidation species activated pyrite but had little effect on galena. Optimum galena flotation and galena selectivity against pyrite were achieved by selecting grinding conditions that enabled lead and iron oxidation production to be controlled."

Jan 1, 2003

By B. Moritz, W. Schubert, E. A. Button

ABSTRACT: Geological conditions associated with alpine environments in combination with high overburden in many tunnelling projects lead to squeezing behaviour. The main problems associated with such conditions include large deformations, overstressing of supports, and lack of face stability. In the past during Alpine tunnelling the problem of large displacements incompatible with rockbolt – shotcrete support systems have been solved by leaving gaps in the lining to accommodate excessive deformations. In the late nineties, yielding elements have been developed, which are integrated into the lining. The paper deals with the basic concept, the design and the application of that system, which has been successfully used in several Alpine tunnels. ZUSAMMENFASSUNG: Die geologischen Verhältnisse in den Alpen führen bei großer Überlagerung häufig zu starken Deformationen während des Baues von Tunneln. Die großen Verformungen führen in vielen Fällen zu einer Überbeanspruchung des Ausbaues und Problemen mit der Ortsbruststabilität. Früher ist man dem Problem der Unverträglichkeit des Ausbaues mit den hohen Dehnungen durch Freilassen von Deformationschlitzen im Spritzbeton begegnet. Vor etwa 10 Jahren wurden duktile Stahlelemente entwickelt, welche in die Spritzbetonschale integriert werden. Der Beitrag beschäftigt sich mit dem Konzept, der Planung und der Ausführung. RÉSUMÉ: Les conditions géologiques dans les Alpes conduisent fréquemment lors d'un grand recouvrement à des déformations fortes pendant la construction des tunnels. Les grandes déformations conduisent dans beaucoup de cas à une surtension du revêtement et à des problèmes avec la stabilité de front de taille. On a fait face plus tôt au problème de l'incompatibilité du revêtement avec les extensions élevées par libérer des rainures dans le béton projeté. Il y a environ 10 ans, des éléments sidérurgiques ductiles qui sont intégrés dans le béton projeté ont été développés. La contribution s'occupe de concept, de planification et de mise en oeuvre.

Jan 1, 2003

By ?. ?. Zimin, B. A. Kutlin, X. Baddamsuren

"The ore features of Mongolian fluorspar deposits are shown in the paper. The possibilities of the technological of ore processing on the Bor-Undur combine scheme improvement are analyzed there. Some recommendations are done for scheme development: spare output technologies, the usage large-sized ore separation, flotation by columnar flotation cells, leaching and concentrate agglomeration.New evaluation and usage of mineral sources approach was developed for Mongolian fluoride ores. The conception allows using maximally available mineral resources for getting of metallurgical and acid fluoride concentrates while mining and technological processes: mining (as well as quarrying) -storing, blending-crushing, grinding-combined processing methods-metallurgical using preparation It has been established mining and processing technological schemes should include:• spare blasting technologies providing minimum effect on fluorite crystals which follows ore selective excavation;• large-sized ore separation methods resulted in maximum recovery for these operations in respect to metallurgical fluorite concentrates;• grinding and flotation regimes providing high-quality flotation concentrates getting for their usein chemical industry;• fluorite concentrates agglomeration technologies for providing ability of their use in metallurgical and cement industriesThe results of industrial usage of jugging machines, columnar and pneumomechanical flotation machines for fluospar dressing.The technological approaches implementation in “Bor-Undur” plant maintenance within 1993-2002 years leaded to:• change plant status from just flotation one to gravitational-flotation characterized by technological process stages which are traditional for metallurgical industry and plant capacity increase from 400 to 600 thousand tones of treatment ore as well as concentrate production increase from 120 to 150-170 thousand tones including 120-140 thousand tones of acid grade concentrates with 97% CaF2 ."

Jan 1, 2003

By D. G. Krige

For the purpose of determining confidence limits for ore grade estimates, an extensive simulated data base was used, which included 1728 ore blocks with ‘actual’ grades and the corresponding estimates based on ordinary and simple kriging. The practical results show that conditional unbiasedness is essential and that acceptable confidence limits can then be set using Normal theory for the simulated error distribution based on the logarithms of the ratios of ‘actuals’/estimates with a variance related to the kriging variance. The mean of the data used to prepare the variogram and the estimated block grade are to be used properly in this approach. A practical analysis was also done of the actual point and block data from a very large mined out Carbon Leader area. The distributions of the actual grades for two levels of block sizes with different levels of variability were fitted using three models, ie. 2-. 3- and compound-lognormal. The trends of tonnages, grades and relative profits for a range of pay limits, as well as the usual tonnage-grade curves, show a practical insensitivity for the choice between the three lognormal models considered.

Jan 1, 2003

By A. Fahimifar, H. Soroush

Abstract: Triaxial tests were conducted on the schist specimens with various anisotropic angles under confining pressures of 0, 7 and 15 MPa, and axial stress-axial strains, were measured and plotted for various conditions. The results obtained reveal the effects of schistose on the strength and deformability of the rock very clearly. Peak strength of the specimens for 00 and 900 schistose orientations are nearly the same. Modulus of elasticity of this rock varies with anisotropic angle. For 0 orientation modulus of elasticity increases to a maximum. Confining pressure increases the peak strength and improves the rock deformability. However, this effect is not the same for various orientations, and there are no similar trends for each anisotropy direction. Analysis of the results shows that consideration of a linear failure criterion such as Mohr-Coulomb is appropriate for the prediction of rock behaviour up to 10 MPa, rather than a non-linear one. The analysis also reveals that the friction angle and cohesion are affected by the anisotropy orientation, and this effect is more important for the cohesion than the friction angles. Resume: Les esseys triaxiales sur les echantillon d un roch schist avec les differents angles non-isotrop sous les tension lateral zero et sept et qoinze mega pascal (mpa) est fait et les covtraite et allongment unitaire sont mesure et leur curues est destine sous different condition les resultats obtenues montre les effets du schistosite sur le resistance et le ductilite vissiblement. Le resistance final sur les echantilions pour les angles o degre et 90 degree est equivalent. Le modoule d elasticite de ce roch sera difere par a port de l angle de stratification. Pour l angle o degree le valeur de modoule est le maximum. le pousse lateral augmenterai le resitance final, et sera amilterai le toleran le de ductilite. Mais cette effet bn est pas unigue pour les different stratification, et pour les diferents directions no– isotrop it n y a pas le meme solution. L analyse des resulitats montre que le criterre de ruin comme mohr–colomb est moderate pour le pousse lateral jusq av lo mega pascal , et ce n est pas neccesaire d utiliser de criterre no–linear . Cette analyse aussi montre que l angle de frottement et cohsion est en relation de la direction no–isotrop, et cette effet est olus important pour le cohsion par a port de l angle de frottement . Abriß : Dreiachsige Prüfung wurde auf den schist Exemplaren mit verschiedenen anisotropic Winkeln unter Bestätigen von Drücken von 0.7 und 15 MPa geleitet, und axiale Spannung axiale Spannungen, wurden gemessen und für verschiedene Bedingungen wurde geplant. Die Ergebnisse haben die Wirkungen von schisocity auf der Kraft und dem deformability des Felsen sehr deutlich erhalten offenbart. Maximale Kraft der Exemplare für 0° und 90 sind° schistos Orientierungen beinahe das gleiche. Modulus der Elastizität von diesem Felsen ändert sich mit anisotropic Winkel. Für 0° vermehrt Orientierung modulus der Elastizität zu einem Maximum. Einschränkender Druck vermehrt die maximale Kraft und verbessert den Felsen deformability. Aber ist diese Wirkung nicht das gleiche für verschiedene Orientierungen, und es gibt keine ähnlichen Tendenzen für jede anisotropic Richtung. Analyse der Ergebnisse zeigt jener Überlegung Kriterium eines linearen Ausfalls wie zum Beispiel Mohr Coulomb passend für die Voraussage von Felsen Verhalten bis zu 10 MPa, anstatt eines nicht linear ist. Die Analyse offenbart auch, daß der Reibung Winkel und Bindekraft werden beeinflußt von der anisotropic Orientierung, und diese Wirkung wichtiger für die Bindekraft ist, als der Reibung Winkel

Jan 1, 2003

By Kenneth Rigsby

Black Mountain Resources' Highlands Mine No. I is a full extraction room and pillar operation located in Harlan County, Kentucky. Black Mountain extracts the 0.9 to 1.1 meter (36- to 42-inch) thick Owl Scam that is situated 60 to 70 meters (200 to 235 ft) above the longwall panels of the abandoned Arch No. 37 Mine, in the 3.4 meter (I I ft) thick Harlan Scam. In the areas where full extraction has taken place, the overburden above the Owl Seam ranges from 60 to 430 meters (200 to 1,400 ft). A short room and pillar panel was developed above an extracted longwall panel to test the selected pillar size, to evaluate support systems, and to verify the shape of the subsidence profile over the recovery end of the depleted longwall panel. It is over the recovery end that Highlands Mine No. I would access the Owl Seam reserves that exist above the No. 37 Mine. Black Mountain selected pillars sizes to be employed above the longwalls based on the ability to fully extract a pillar employing extended cuts. After a mechanical testing program was completed and mine behavior and top disturbance were observed in the test panel, John T. Boyd Company (BOYD) verified pillar stability and designed support systems. BOYD previously designed No. 37 Mine's gate pillars and studied subsidence and gob formation over its longwall panels; this effort aided the analysis of overburden movement and pillar integrity at Highlands Mine No. 1.

Jan 1, 2003

By D. Grabowski, Z. Pokryszka

ABSTRACT: Some residential areas of the iron basin of Lorraine (in the North-East of France) are affected by noxious gas emissions (under oxygenated, carbon dioxide loaded and radon loaded gas mixtures). Site investigations showed that the gas flow was mainly due to natural thermal air circulation between old mines and the external atmosphere. The main hazards associated with this flow of gas and its potential accumulation in confined volumes within buildings are asphyxiation and intoxication. A further study is in progress in order to better understand the origin of the gas generation within the old iron mine workings. Following the first hypothesis, the carbon dioxide emission is mainly due to the specific hydro-geo-chemical process associating the pyrite oxidation with the acid dissolution of carbonates. KEY-WORDS : gas, emission, mine, flow, pyrite. ZUSAMMENFASSUNG: Einige Wohngebiete der Eisenmulde Lothringen (im Nordöst Frankreich) werden von Ausgasung gesundsheitsschädlichen sauerstoffarmen Mischungen, die mit Kohlendioxid und Radon beladen sind, betroffen. Untersuchungen am Ort haben gezeigt, wie diese Gasstroemung von natürlichem thermischen Luftumlauf zwischen den alten Bergwerken und der externen Atmosphäre ausgelöst wird. Erstickung und Vergiftung sind die wichtigste Risiken, die mit dieser Gasströmung und ihrer möglichen Speicherung in begrenzten Lokalen zusammenhängen. Eine weitere Untersuchung wird durchgefuehrt so dass man die Herkunft der Gaserzeugung in den alten Grubenräume besser versteht. Der ersten Hypothese folgend, Ausgasung von Kohlensäure liegt vor allem an dem hydro-geo-chemischen Prozess, der Pyritrösten mit der säuren Auflösung von Karbonate verbindet SCHLÜSSELWÖRTER: Gas, Ausgasung, Bergwerk, Strömung, Pyrit RESUME: Certaines agglomérations du bassin ferrifère lorrain (au Nord-Est de la France) sont affectées par des émanations de mélanges gazeux sous-oxygénés et chargés en certains gaz nocifs (dioxyde de carbone, radon…). Les investigations effectuées in situ ont montré que les écoulements gazeux à l’origine de ces émanations sont liées au phénomène de tirage naturel entre les anciens travaux miniers et la surface. Les principaux risques engendrés par ces émanations de gaz et son accumulation possible dans des endroits confinés sont l’asphyxie et l’intoxication. Une étude est en cours afin d’expliquer l’origine de la modification de l’air au sein des vieux travaux miniers. Les émissions de dioxyde de carbone seraient dues à des processus hydro-geo-chimiques associant l’oxydation de la pyrite et la dissolution de carbonates. MOTS CLES: gaz, émanation, mine, écoulement, pyrite.

Jan 1, 2003

By M. K. Eryadin, I. Yildirim, R. Asmatulu

Novel dewatering aids were tested on various coal samples from the U.S. and Canada in laboratory and pilot-scale filtration experiments. The reagents substantially improved the dewatering kinetics and reduced the cake moistures. The cake moistures were typically reduced from 20-30% by weight to 8-14% range in vacuum filtration. When the reagents were used in conjunction with a pressure filter, higher degrees of moisture reductions were achieved. In the present work, the novel dewatering aids were tested using different types of pilot-scale vacuum filters. The results were consistent with those obtained in laboratory experiments.

Jan 1, 2003

The use of scrapers in mining and earthmoving operations is not new, in fact they are one of the earliest methods of bulk earthmoving. A single machine which can load, haul, and dump material with a minimum of ancilliary support is a highly productive and cost-efficient method of earthmoving. In recent times scrapers have been unpopular due to perceived problems and operational limitations, but the last couple of years have seen a resurgence in the use of scrapers in the Bowen Basin as a primary prestripping tool. The main operational limitation of scrapers is the economic operating range. maximum productivity and lowest cost per bcm is achieved on short leads, as the lead distance increases the cost per bcm quickly reaches and then overtakes that of an truck-excavator fleet. The geometry of a ætraditionalÆ coal mine does not readily allow short leads for prestrip fleets due to the nature of dragline stripping operations. The strip arrangement means that material has to be taken around the end of the pit, meaning a longer haul distance than the actual point-to-point distance between load and dump. This can be alleviated by using pit bridges, however these can cause spoil problems for draglines if not properly planned and have been avoided by many mines. Due to the economic haul distance limitation of scrapers, truck-excavator fleets have become the normal method utilised. Currently more geologically complex mines are opening up, which do not allow traditional down-dip strip mining to occur. Cross-dip mining methods allow for short leads between prestrip loading and dumping areas, hence scrapers and bulk doze are realistic alternatives to a truck-excavator fleet in the prestrip environment. Keeping the lead distance to a minimum a fleet of 657Æs can move material at a very low cost. The other main operational limitation of scrapers is the type of material that can be economically excavated. Hard material can lead to damage to the bowl, free-flowing sand will not readily stay in the bowl leading to reduced load factors. Ripping the material with a dozer prior to excavating can lead to improved loading time, and greatly reduced GET consumption. When considering scrapers for prestrip operations a number of things must be considered: is the lead distance within the economic haul distance? should twin power (push-pull) or single power (dozer pushed) scrapers be used? do I need to rip, what should I rip with? what ancilliary support is required? is there another system already available on-site which is currently under utilised? This paper considers the parameters under which large twin power scrapers are the most effective way of undertaking prestrip operations.

Jan 1, 2003

By Elena L. Chanturiya, Vladimir A. Bocharov, Roman A. Amosov

"In many volcanogenic base metal deposits of Russia the gold is closely associated with copper sulphides and pyrite. The recovery of gold associated with pyrite is especially difficult problem.Investigations of gold chemical state and mineral forms in copper-zinc sulphide ores of Gay and Barsuchiy Log deposits in the Urals have been made using EPMA, optic image-analysis, XRA, SEM, thermo-electrical force measurements and selective gold leaching experiments.Two gold varieties are determined: 1) free native gold particles (from 5 µm up to 0,25-1,0 mm), which can be liberated after grinding of ore up to 0,074 µm and named “free gold”; 2)”invisible” gold, including finely disseminated native gold and chemically bound gold. The second variety can’t be disclosed during grinding. Free gold can be recovered by gravitation and flotation while the processing behaviour of “invisible” gold is determined by properties of gold-bearing sulphides: pyrite and chalcopyrite. According to results of diagnostic leaching experiments in ores of deposits mentioned above the part by weight of free gold reaches 70%, the part by weight of the ”invisible” gold is up to 20%. About 10% of gold is enclosed in quartz and acid-soluble minerals.Theoretically (taking into account gold distribution data) it’s may anticipate gold recovery by gravitation up to 60%. However after grinding up to 50-60% of class –0,074 mm only about 40% of gold passes into oversize product including 30% of free gold and 8% of ”invisible” one. It can be recovered by gravitation. Remaining free gold and ”invisible” gold can be extracted by flotation – 25% in total. Inevitable gold losses in tailings may reach 8-10%."

Jan 1, 2003

By Adrian Moore, John Wilson, Alan Richards, Emad Gad

Project C9040 – ‘Structure Response to Blast Vibration’, funded by the Australian Coal Association Research Program (ACARP), involved the investigation of the structural response from blast vibration of three houses of brick veneer construction subject to a wide range of ground vibration levels. This paper summarises the findings of a house subject to vibration levels up to 220 mm/s (8.7 in/s). Damage attributable to blast vibration was not observed until vibration levels exceeded 70 mm/s (2.8 in/s).

Jan 1, 2003

By Frank Cappuccitti, Stephen Chryssoulis, Stamen Dimov

Surface organic microanalysis of platinum (Pt) and palladium (Pd) minerals by TOF MS1 is an attractive complement and potential alternative to conventional collector screening methods. Its attractiveness lies on its ability to focus on individual Pt and Pd mineral particulates, therefore providing a more targeted approach. The only requirement is knowledge of the occurrence (mineral composition, grain size and association) of Pt/Pd in the feed sample. This newly developed technique can detect, and identify collectors and quantitate loadings on individual Pt/Pd mineral particulates at plant concentration levels. Using this technology, collector loadings were measured on Pt and Pd metal plates and on PtS2 and PdS particulates which had been exposed together to aqueous solutions of different collectors. Thus, data were obtained on collector selectivity, the effect of sulphur; and of depressants, the latter in combination with TOF-LIMS2 results. Staged rougher tests on North American and UG-2 ores linked Pt/Pd flotation kinetics with collector loadings and ultimately grade/recovery.

Jan 1, 2003

By Thomas Barkley

Recent developments in hardware and software have made accurate measurement of Underground Face (Development) Drilling a reality. New and compact laser profiling equipment makes it possible to measure drilled material left on the face as well as the actual tracks of the holes drilled in the rounds. Utilization of these available technologies makes it possible to correctly define the drilling accuracy and the blasting pull. Through the use of actual face round measurements, I will show the level of definition and amount of information that can be collected.

Jan 1, 2003

Based on experimental and computer simulation results from our group, we report a systematic, atomic level analysis of carbon dissolution from carbonaceous materials in molten iron. Experimental results on graphite/Fe-C-S system were obtained using carbon dissolution studies, XRD and FESEM investigations and were supplemented with Monte Carlo simulations. Three basic mechanisms, namely carbon atom dissociation rate, interfacial phenomena and mass transfer in the melt were found to be responsible for the overall dissolution process. While mass transfer in the melt is governed by the concentration gradients, melt composition and temperature; impurities present in ash play a significant role in the interfacial phenomena. For less ordered forms of carbonaceous materials, carbon atom dissociation rate depends strongly on the degree of long-range order and is an important rate controlling mechanism in the overall dissolution process. A systematic comparison of dissolution rates for a variety of coal-chars, natural and synthetic graphites has been carried out in an attempt to identify rate-controlling mechanisms. The structure of the carbonaceous material appears to be an important underlying factor in the carbon dissolution process.

Jan 1, 2003

By J. D. Miller, C. L. Lin

The appropriate software and hardware necessary to adapt an X-ray CT analyzer for the determination of coal washability was developed and successfully tested for well-characterized samples under laboratory conditions. Evaluation of the CT-based analyzer under simulated on-line conditions is also presented to verify the on-line capabilities of the newly developed X-ray CT analyzer for the control of coarse coal cleaning circuits. The investigation shows that the data obtained from CT washability analyses compare favorably with experimental sink float data. Further, image frequency was considered to evaluate the CT-Based coal washability analyzer for simulated on-line conditions. Specifically, the number of observations (image spacing) needed for accurate sampling and the total time required to perform the calculations for a representative data set were determined. Key words: Coal washability, Computer simulation, X-ray CT analysis

Jan 1, 2003

By Carin Laubscher, Francis W. Petersen, Jaap P. Smit

"Waste streams, such as acid mine drainage, are often characterised by low pH values and high concentrations of heavy metals, dissolved solids, calcium and sulphates. Although lime remediation effectively removes most of the heavy metals as hydroxides, it is less effective at lowering levels of sulphates. Various methods of removing sulphates from effluents exist, such as precipitation with lime, precipitation with barium salts, co-precipitation with calcium carbonate, reverse osmosis, and ion exchange. Mintek developed a chemical precipitation (SAVMIN) process to treat acid mine drainage, which entails the addition of lime to precipitate the metal hydroxides, and the subsequent formation (precipitation) of calcium sulphoaluminate or ettringite. The key to the viability of the new technology lies in the correct use, regeneration and recycling of Al(OH)3 used to precipitate the ettringite. The water produced by this process is suitable for disposal to watercourses or for agricultural, domestic or industrial consumption. No brines are produced as the salts are converted to solid hydroxides, gypsum and calcium carbonate.The SAVMIN process has been tested successfully during several laboratory scale operations, and during two pilot plant operations at Stilfontein Goldmine for Anglogold and Navigation Plant, Witbank for Anglocoal. During the pilot plant campaign at Navigation Plant, metal and mineral precipitation was achieved with lime addition. The sulphate concentration in the water was reduced from 2136 mg/L to an average value of 102 mg/L and the calcium concentration was reduced from 727 mg/L to an average value of 70mg/L.The SAVMIN process generates a number of different waste streams including metal hydroxide sludge from neutralisation, gypsum sludge from the gypsum crystallisation steps, and calcite sludge from carbonation. The metal hydroxide sludge is composed of Mg, Ca, Mn and Fe hydroxide, and could be disposed of on a slimes dam. Gypsum sludge was greater than 99% CaSO4.2H2O. This gypsum could be used for dump or road capping, underground backfilling, production of wallboard and cement. The calcite sludge is pure CaCO3, which is recycled back to the neutralisation stage."

Jan 1, 2003