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By K C. Corin, C T. O’Connor

In recent years it has been shown that the concept of using partial molar excess Gibbs energy (G̅ex) to explain the behaviour of collectors in the recovery of minerals can be usefully applied to explain flotation performance. Fundamentally this is because hydrophobicity of a mineral particle on which a collector is adsorbed may be strongly related to the fact that the alkyl chain associated with the collector behaves in the same way as any hydrocarbon would in an aqueous medium. This hydrocarbon-water system represents a classical non-ideal mixture, and such mixtures are quantified thermodynamically by determining the activity coefficient of the hydrocarbon moiety of the collector and hence its G̅ex in the mixture. It has been shown that G̅ex is a more rigorous indicator of the contributions of various alkyl groups of a collector than HLB (Corin and O’Connor, 2014) and was also able to explain aspects of froth behaviour (Harris and O’Connor, 2017) and hydrophobicity (O’Connor, 2021). The present paper is aimed at extending the above concepts in two different ways. Firstly, a study is undertaken of a range of results previously reported in which various reagents containing different alkyl groups were analysed in terms of their effect on contact angle and their performance as flotation reagents in terms of recovery. These results sustain the previous observations that there is a robust positive relationship between hydrophobicity as indicated by flotation recovery and contact angle and G̅ex of the alkyl group associated with the collector. Secondly, on the basis of the observation that increases in G̅ex are indicative of increases in the hydrophobicity of the mineral particle-collector aggregate, a study was undertaken to examine the effect of ions typical of electrolytes in water as well as the effect of the presence of alcohols and of pH on G̅ex of the collector alkyl group. In the former two instances the absence of any correlation between G̅ex and recoveries supported the proposition of the respective authors of these studies that the major effect of these electrolytes and added alcohols may be on particle–bubble attachment rather than on the hydrophobicity of the mineral/collector in the aqueous system. On the other hand, the effect of pH on G̅ex correlated reasonably well with changes reported in the literature on the effect of pH on recovery and contact angle.

Aug 24, 2022

By Harada M, Katsuta S

In order to shorten the time taken to com- plete shield tunnel excavation work, reduce labor costs and to improve safety, an automatic assembly robot system for the segments used has been developed. It was developed in the three years from 1982 until 1984. An experimental assembly system for concrete segments (outer diameter:.3.55m) has been thoroughly tested to confirm that these segments can be fed and assembled automatically (Fig. 1, 2). This report outlines the robot which will be put into practical use in the near future. The robot senses the position of already assem- bled segments by means of position sensors, controls the position and the attitude of the segment to be assembled to allow bolt hole positioning, and completes the automatic assembly of a se;nent by automatically tighten- ing bolts. The six segments which make up one ring can be automatically assembled in about 25 minutes.

Jan 1, 1987

By W Baguley

Attritioning has been a method of improving mineral extraction for over 60 years, however it is only recently that an understanding of the mechanism employed and the improvement in efficiency that have been achieved.The paper will discuss these improvements and how to overcome the problems that have been raised. At present there is a dearth of information on the correct design and operation of these machines.The paper will address these issues as well as fluid on the Zeta potential, micro shear, retention residence time and pilot plant operation.A study on the hydrodynamics of attritioner operation has been identified and will be discussed.Surface chemistry, clean lines of attrition material and the treatment of fines significant advances in the understanding of attritioning highlighted.CITATION:Baguley, W, 2013. Attrition scrubbers, in Proceedings MetPlant 2013 , pp 229-246 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

By Hawkins L. V, Seedsman K

A combined reflection seismic and magnetic survey off the south coast of New South Wales has revealed six distinct reflection horizons within the Lower Triassic- Upper Permian sequence, and has enabled the upper part of the Illawarra Coal Measures to be mapped in considerable detail. Large magnetic anomalies in the eastern half of the survey area appear to originate in the Gerringong Volcanic Sequence which forms the magnetic basement in this survey. Small residual anomalies in the western half of the area can be correlated with small scale faulting and folding in the uppert part of the Illawarra Coal Measures, as revealed by the seismic reflection survey. A synclinal axis striking at approximately 55¦ has been mapped near the western margin of the survey area, and areas of faulting and folding have been outlined by com- bined analysis of seismic and magnetic results.

Jan 1, 1969

By Hungerford F

Long-hole drilling technology has rapidly advanced this decade beginning with rotary drilling/pump down camera surveying and culminating in down-hole motor drilling with cableless electronic surveying over the past two years. With the latter system, a high level of directional control is achievable in boreholes up to 1000m long. Past long-hole drilling across the industry has seen a mixture of success and failure. With these experiences, new and improved techniques and equipment have evolved. A number of long-hole drilling options are available as variations on the basic rotary and down-hole motor methods. They involve different levels of cost and equipment and vary in their suitability in different geological environments and definition of targets. Long-hole drilling is mainly target applied, either in defining geological structures in greater detail, or proving important mining areas such as longwall blocks, to be free of structures. Successful drilling hinges on a combination of drilling expertise, quality and appropriateness of equipment, understanding of geological conditions and good colliery support. Drilling expertise forms part of sound interpretation through keeping relevant records, understanding the reasons for changes in drilling conditions and implementing specific tests such as coring. The final interpretation builds upon all other available geological information. There is still scope for research into improved techniques and equipment. The use of long boreholes for geophysical surveys has high potential.

Jan 1, 1988

By James CH

For drainage sediment to be used as a successful sampling medium in reconnaissance geochemical surveys, the length of any dispersion train from a typical target must be great enough for it to be detected by a widely spaced sampling pattern, and must also be homogeneous enough to avoid it being missed by the unfortunate selection of a random low value sample. Elements which occur in stream sediments in the form of discrete heavy minerals present two special problems in this regard. Since the element is concentrated into a few particles, the medium is extremely heterogeneous, which makes representative sampling impossible unless very large samples are taken, while the high specific gravity of such grains leads to their being concentrated in traps along the stream bed. Several ways of overcoming these difficulties have been suggested. Among these the "schlich" test, in which heavy material obtained by panning is taken for analysis is among the most popular. However, the results of the present study indicate that while this method improves the nature of the patterns obtained, they are still far from satisfactory. Alternative methods of sample preparation, including the taking of light material for analysis, appear to provide better answers to the problem. In the area studied this approach eliminated most of the "noise" associated with the data obtained by other methods, as well as giving an extended dispersion pattern.

Jan 1, 1986

By Atalla YM

Steel rolling mill product finishing pro cesses gradually become or often already are unsuited for current production and marketing conditions. Indications are made as to what has been done to (i) rectify situations of this kind and, (ii) to reduce both product finishing time and costs. The principal features of two separate case studies are reviewed, these being (a) the finishing-end of B.H.P.'s Newcastle o.2 Merchant Mill and, (b) a mixed functions finishing yard and warehouses group (known as he Merchant Mills Loading Yard) which has been perating for a number of years. The areas in ach case are identified as a system while the arious functions, principal product streams nd processing equipment are respectively iden- ified as sub-systems and system elements. etails are given of the models used in each Sub-system dependency on the system as a le is traced by means of an information and ision analysis or by time studies and the sonableness of the system elements is deter- ed by computer programming or by simple com- ison methods. The-accumulated data is used derive improved mill finishing-end or Load Yard,functioning concepts according to pro- rules whilst at the same time considering

Jan 1, 1975

By Vidalinc, Raffoux

Longwall faces producing in the order of 20,000 tons per day of raw coal are presently running in the Houilleres du Bassin de Lorraine of Charbonnages de France. Production levels of twice that level pose some technical and economic problems of coal cutting, ventilation, coal and equipment transportation in the.face and from the face to the sur- face. The peak productions of the equipment in use today, the results of trials with new equipment, the utili- sation of forecasting models (some in the form of software), allow us to fo- resee feasable technical solutions to these problems. They will first be considered in the best possible context (thick- ness, dip, non gassy, soft coal, good strata, no faults). This will give. the necessary conditions to reach daily output'of that level. A sensitivity analysis of these- figures to the effective natural con- ditions will then be undertaken and the implication of such a project on health and safety (dust, climate ...) will be carefully considered. A concise technical and econo- mical approach will permit us to fore- cast the economical interferences of such production units and specially the consequences of sudden variations of the output (downtimes, failures, etc). From this investigation, goals for technological development and re- search areas will be outlined to be able to reach this production target in the XXIst century.

Jan 1, 1988

By Massacci P

A review has been made of the studies focusing on methods for the description of grain -size distribution after breakage and, separa- tely, of the degree of liberation of the miner- al species making up the various grain-size classes of comminution products. The purpose of the study has been to de- velop an overall model of the phenomenon which, owing to the very effect of comminution, leads to the formation of grains that are generally of mixed composition. A calculation procedure has thus been de- veloped for the liberation function taken as the assessment of the distribution of mix com- ponents in the products obtained after a commi- nution process. The aim is to identify a func- tion which may, to a certain extent, simulate the variation of the grade-recovery function of an ore in relation to its degree of comminu- tion. The numerical model thus obtained has been tested out on results obtained experimentally.

Jan 1, 1986

My early experience with the coal industry was in the latter half of the 1970s, where attention to only ones own æaccidentsÆ and concentration on behaviour controls were impeding the introduction of effective engineering controls such as ROPS, FOPS, roof support and residual current devices. Lack of the broad picture of personal damage and of relevant veridical (true saying) knowledge and data had to be overcome to achieve progress in reducing fatalities. Thirty years on, it is again necessary to take stock. How good is our knowledge, our data, our information on which we make decisions. Despite Australian all industry 1992-93 data showing 80.5 per cent of costs came from occurrences which permanently altered peopleÆs lives, New South Wales is still the only state reporting permanent disabilities. In 1991 - 1992, the rate of permanent disability per 1000 wage and salary earners was two. In 2000 - 2001, it was over four û more than doubled. Also strongly motivating is the huge cost. Industry carried 25 per cent of the $34.3 billion costs for 2000 - 2001, up ten per cent of 82.8 billion if the costs of pain, suffering and early death are included.

Jan 1, 2005

By Bhattacharyya A. K

A major constraint on sustaining high rates of production in the collieries of the Southern Coalfield of New South Wales is the inability to develop panels fast enough to match the rates of extraction. This inability is particularly crippling in the case of retreat longwall mining and is due to nearly half the time in roadway drivage being spent on strata control operations such as roof support.Increased rates of roadway drivage and significantly improved roadway stability can be achieved by the application of yield pillars between parallel roadways. These pillars are designed to yield immediately upon formation and transfer the damaging roof loads away from the immediate vicinity of the roadways. Since the width of the yield pillar is the key to their successful application, it was determined through the Yield Pillar Experiment conducted by Kembla Coal and Coke Pty Ltd at West Cliff Colliery.Three experimental headings, each nominally 5.5 m wide and 2.8 m high, were driven to form two tapering pillars. The width of these pillars progressively decreased from 24 m to 3 m over a length of 154 m. The convergence between the roof and floor of the headings measured at various cross-sections corresponding to predetermined widths of the pillars are analysed in this paper to evaluate the stability of the tapering pillars at the different widths.The width of the yield pillar in a three heading development layout at West Cliff Colliery was determined to be 7.5 m.

Jan 1, 1995

By R G. Richards

Although most New Zealand coals are low in ash, there are situations where high ash coals could be won. Not all high ash coals can be upgraded by physical means, since the ash is either inherent in the coal or bound in such a way to make its physical removal either impractical or uneconomic. Nevertheless, the authors believe, the situations where high amounts of ash can be economically removed by physical means to make a saleable product are considerable.

Jan 1, 1979

Underground mine ventilation is now com monly simulated on a digital computer. Such a programme, incorporating natural ventilation has been modified by others to account for methane emission and elevated local tempera- tures. At Wollongong University, the pro- gramme was further developed and extensive interactive graphics incorporated such that any view of the three dimensional mine could be viewed, and superimposed upon that view are areas where a nominated parameter has exceeded a particular value - generally at a nominated time after a particular event and usually a fire/explosion of one type or another. A further programme was developed such that up to 20 'times' could be examined at a particu- lar location after say, a fuel rich fire at some other place in the mine. The output from this programme includes a plot of methane 1, smoke 1, temperature, pressure and air flow versus time - a most useful graphic to observe the limits of safe attendance in a particular Airway.

Jan 1, 1983

By J Levett, O Rondon, I Glacken

Reporting Codes are not prescriptive on methodologies to report or classify Mineral Resource Estimation results, but the assessment of risk and uncertainty is required, and is likely to be increasingly important in future Code updates. The 2012 JORC Code indicates that relative confidence in tonnage-grade estimations should be considered for classification, and that there should be a discussion of relative accuracy and confidence levels in the Mineral Resource Estimate. These considerations are also relevant to the drill hole spacing required for various classification categories, along with other geological and data quality criteria. This paper summarises the theory, principles and current practice of various drill hole spacing analysis techniques for both achieving a desired level of resource categorisation and for optimising grade control or resource drill-out costs. The authors provide practitioners with a guide in their use to assess uncertainty and relative accuracy, as illustrated by a number of case studies. While all drill hole spacing studies rely on the assumption of consistency of the continuity model from current to future drilling, the range of methods available provide much more objective outcomes than previously adopted ‘rules-of-thumb’.

May 24, 2023

The importance of proper planning, preparation, and execution of a steady state sampling campaign for metallurgical plant assessment must not be underestimated. Careful planning can increase the amount and reliability of information from an optimum number of samples and fully utilize available plant data. It requires specification of the data required, determination of run duration sampling frequency, the selection, modification and testing of sample points and cutters, as well as organisation and briefing of plant and sampling personnel. Preparation immediately prior to sampling, the conduct of the sampling campaign itself and procedures to handle the collected samples and information are discussed. Cutter design, fabrication and use are described in detail, and typical sampling situations, for ball mills, classifiers, pipes, launders, flotation cells and thickeners are considered individually. Measurement of pulp flow rate can often resolve difficult mass balance problems, and discussion of convenient techniques is included.

Jan 1, 1976

Most compact bucket wheel excavators in use are in the small to medium range. Large compact bucket wheel excavators compete directly with con- ventional longer boom excavators which have operational advantages over the large compact. There are, however, situations where the large com- pact excavator is viable. In the development of these large compacts there are a number of technical features to be addressed. In addition the SECV now propose to expand the concept to a large compact bucket wheel excavator with a bridge and loading unit for their Loy Yang Open Cut.

Jan 1, 1989

By Y-B Kang, W-Y Cha, Y-M Cho

Molten slag used in the secondary refining process (RH process) for the production of Ultra-Low C (ULC) steel is typically composed of CaO-Al2O3-MgOsat.-FetO with minor constituents. FetO in the RH slag is the main source of reoxidation of the molten ULC steel in the ladle by 2Al + 3(FetO) = (Al2O3) + 3Fe, thereby serving as the source of the alumina inclusions. On the other hand, FetO also enhances the fluidity of the slag, thereby increasing inclusion absorption capacity. Optimum slag chemistry design is therefore required to produce clear ULC steel. The reoxidation kinetics was investigated in the present study by employing high-temperature experiments and developing the reaction rate model. Initial compositions of slag ((% CaO)0/(% Al2O3)0 and (% FetO)0)) and reaction temperature were varied and change of [% Al] in the molten steel was measured. The rate-controlling step was analysed. It was found that the rate-controlling step in some cases changed during the reoxidation: from a mass transport of Al in the molten steel to a mixed transport including Al2O3 in the molten slag. The experimental data validated the reaction rate model based on the elucidated reaction mechanism and FactSage thermodynamic database. The model suggested that high (% CaO)0/(% Al2O3)0 suppresses the reoxidation only when (% FetO)0 is low (5 or lower in the present study).

Jun 19, 2024

Brief summary of results obtained by a French-Japanese cooperative study on the bottom of trenches around Japan. The geophysical prospection, multi beam echo sounding and direct observation with submersible dives of the trench bottom clarified the details of the subduction of oceanic plates. It may be noted, among many new facts found: 1. The subduction and geologic structure resulted from the process is different according to the nature of subducting oceanic plate, and the geology of the land behind the trench. Thus the Nankai trough characterized by the developpement of accretionary prisms is contrasted to that of the Japan Trench where the basement rocks are exposed on the land side cliff of the trench wall. 2. The compressional tectonic situation prevailing in the trench bottom provokes the venting, along the fissures on the bottom, of water contained in sediments. Hydrocarbons contained in the sediments are comming out with water and give nutrients for bacteria. Clams, tube warms, sea slugs and shrimps are taking these bacteria as their food and biological communities with exceptionally dense population for the deep sea of more than 3000 meters in depth are formed on the field of accretionary prism and wall of the land side cliff. 3. An intense compressional tectonic field resulted from the subduction is inducing the transition from the subduction of oceanic plate to the collision of a part of the plate to the continental plate.

Jan 1, 1987

By Abishev D. N, Balakirev V. F, Davydov G. I

The problem of recovery of cobalt products from poorly oxidised nickel ores (Kempirsaisk deposit) and pyrite concentrates with a low content of cobalt (Sokolovsk-Sarbaisky deposit) has not been solved to the present time in Kazakstan. The balance reserves of nickel ore of the Kempirsaisky deposit make up more than 35 million tons with a nickel content of 1.13 per cent and cobalt content of 0.05 per cent; besides there are 110 millions tons of out-balance ores (Anon, 1995). In a tailing dump of Sokolovsk-Sarbaisk Mining and Productional Association more than 320 million tons of tailings of wet magnetic separation have accumulated, which contain 7.2 per cent of sulphur, 0.022 per cent of cobalt, 0.012 per cent of nickel, 0.094 per cent of copper, 0.079 per cent of zinc, 16.45 per cent of iron, and from which a high quality pyrite concentrate car) he separated through flotation, containing 48 - 50 per cent of sulphur, 44.15 per cent of iron, 0.141 per cent of cobalt, 0.07 per cent of nickel, and 0.10 per cent of copper. The well-known technological flow charts for cobalt and nickel recovery from the tailings of sulphide-magnetite ores dressing (to give pyrite concentrate) and from oxidised nickel ores, are not profitable at the existing prices for metals, but are not worthless and require significant capital investments for the realisation of their value. The flow chart `sulphate roasting - leaching - solution processing' is used widely for combined processing of cobalt-containing pyrite ores and concentrates.

Jan 1, 1996

Flotation science and technology are related to three major sub- processes which are organized in a hierarchical structure as shown in Fig. 1. The basic sub-process is the chemical process which affects the attachment of air bubbles to mineral particles. In particular, the chem- ical process is related with the adsorption of surface active sub- stances at the gas-liquid, liquid- solid, and gas-liquid-solid inter- faces. This field has been most intensively explored in flotation research. The second domain in flotation research is concerned with the mineral particle to air bubble attachment sub- process in the system. This sub- process represents the dynamics of particle and bubble encounter where the contact angle and the induction time, determined by the surface chem- istry of the system, are among the most significant parameters. This sub-process can be referred to as the micro-process as against the third sub-process, or the macro-process, which corresponds to the integral behaviour of the system. Two other sub-processes are integrated into the macro-process in which they may not reveal themselves explicitly in the details. The third sub-process does not entail surface-chemical or physi- cal events any more, but it represents them all inclusively. To represent this sub-process we use mathematical equations, called models. Only in some simple or simplified cases can the models be solved exactly to find out the behaviour of the flotation system in which we are interested. Digital

Jan 1, 1984