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By Liu Liu

In the recent 10 years the rapid development of Chinese steel industry has attracted the attention of the world. The technological progress of converter steelmaking has played an important role in this process. First of all, slag splashing has been extensively adopted by Chinese steel companies in various sizes of converters from largest to smallest ones, and even including those using special hot metal containing V and Ti. Remarkable metallurgical results have been achieved. Up to now the average converter campaign life has reached nearly 10,000 heats, and the longest exceeds 30,000 heats in three melt shops. Based on this process, the long-life combined-blowing converter steelmaking technology has been developed. Slag splashing has been used to form a gas permeable "slag mushroom" on the top of bottom nozzles to protect the nozzles. In order to keep the effective bottom blowing, furnace bottom thickness control technique has been developed to prevent the furnace bottom growth. It makes the service life of bottom nozzle the same as the converter campaign life (average 10,000 heats and longest > 30,000 heats). The complete combined blowing was ensured through out the furnace campaign. Concentration product [C][0] is in the range of 0.0023 ~ 0.0030%, the T.Fe in the slag is lowered by 4 ~ 6%, and the [0] in steel is decreased by 100 ~ 250 ppm.

Jan 1, 2004

By P. Tolvanen, A. Jalili

"When hard times strike in the mining cycle, sites tighten their belts and focus on lowering their unit costs. Lower unit costs can be achieved by reducing expenditure, increasing production, or by a combination of both. Faced with these requirements, site personnel must turn to areas where they can focus their effort for maximum return. For many sites, both in Canada and overseas, focusing on improving flotation cell maintenance is one of the areas where gains can be made for minimum outlay. Due to resource limitations and/or lack of equipment understanding, maintenance on many sites is only conducted on a reactive basis, once equipment fails. This paper will promote the idea that mineral processors should become more familiar with their equipment so they can ensure that the plant’s ability to produce is not compromised. By better understanding the flotation equipment and ensuring the critical components are maintained, it should be possible to unlock value in an operation. Flotation equipment inspections will be discussed in detail, including key items to look for during these inspections. Potential approaches for predicting wear and change-out time for flotation equipment components will be also demonstrated. An example of one approach used at a South African nickel site will be given.INTRODUCTIONWith metal prices decreasing and operating costs rising, concentrator operators are looking for ways to improve their bottom line. Lower unit costs can be achieved by reducing expenditure, increasing production, or by a combination of both. To meet the expectation of shareholders, mineral processors must turn to areas where they can get the best return for their efforts. One area where there is a large opportunity for improvement is in the maintenance of flotation equipment.On many mine sites, both domestically and around the world, it is quite common to see the philosophy applied of repairing equipment only once it has failed. Though some sites have advanced enterprise management systems and monitoring programs, in the authors’ experience, the decision on flotation equipment maintenance is rarely made on a proactive basis. Two common trends that are evident in the mining industry are that operations are under pressure to keep the plant producing, and maintenance managers generally have very strict budget targets to meet. In addition to these factors, few sites have a good understanding of the financial implications of running with worn or broken flotation equipment. Knights, Jullian and Jofre (2006) summarize this situation well, stating that the lack of correlation between some commonly used maintenance performance measures and key business drivers can lead to maintenance being seen only as a cost center (that needs to be reduced) rather than a tool for productivity improvement."

Jan 1, 2015

By Rolf A. Knopp

This paper discusses how design differences in FLP diesel equipment in underground coal mines came about. "Design standards" tend to create differences between countries while fostering uniformity among products of competing manufacturers. "Performance requirements," on the other hand, tend to eliminate differences between countries while encouraging competitive development of better products. Examples of regulations from the U.S., Canada. Great Britain. Australia. South Africa, etc., are used to illustrate differences in the design and certification of diesel equipment for underground coal mines.

Jan 1, 1978

By S. k. Kim, H. B. Trinh, R. R. Srivastava

"Spent auto-catalyst is a promising secondary resource of platinum group metals (PGMs), which are being extensively used in automobiles catalytic converters to control the hazardous gaseous emissions (CO, NOx and hydrocarbons). Several pyro or hydrometallurgical routes has been employed to recover PGMs from such spent materials but there is no proper process for recovering the other constituents metals. Therefore, it causes the loss of other major constituents like, Al and Mg along with rare earth metal Ce. In the present study, we investigate the dissolution of Al and Mg using sodium hydroxide (NaOH) roasting followed by a sulfuric acid (H2SO4) leaching; thereby concentrating the PGMs and Ce in leached residues. The effect of roasting temperature, time and amount of NaOH were varied. Subsequently, the dissolution behavior of metals in H2SO4 as a function of acid concentration was investigated from the roasted samples. At an optimal condition for roasting at 600°C with 1:1 NaOH-to-catalyst ratio and 60 min duration, the maximum of Al and Mg were dissolved in 1 M H2SO4 solution at ambient temperature (~25°C). Thus obtained leached residues containing enriched PGMs and Ce content can be treated separately for the recovery of these high-value metals.INTRODUCTION Spent auto-catalyst has been considered as a potential resource for recovering the platinum group metals (PGMs) (Jha et al., 2013). The commonly used auto-catalyst is made of cordierite (2MgO.2Al2O3.5SiO2) in which the chloro complexes of PGMs are impregnated onto the surfaces of porous washcoat of alumina substrate (Aberasturi et al., 2011). The average concentration of PGMs in ore are 2-4 g/ton for Pt, 7-2 g/ton for Pd and 0.2-0.5 g/ton for Rh, whereas, an individual catalytic converter weighing about 1 - 2 kg contains on average 1.56 g Pt, 0.62 g Pd and 0.156 g Rh (Upadhyay et al., 2013). Moreover, recovery of PGMs from spent auto-catalyst offers other advantages like, simple process, low cost and less pollution, as compared to recovery from primary resources (Dong et al., 2015).Therefore, technologies to recover PGMs from spent auto-catalyst has become attractive in the recent past and their recycling contribution has been accounted for 35% Pt, 26% Pd and 36% Rh of the quantity consumed in the production of auto-catalysts (Johnson Matthey, 2016)."

Jan 1, 2017

By Rob Sloan, Simon Yu, Rob Robison, Mark Schmidt

"In 2000-2009, Highland Valley Copper (HVC) tested new generation 660 mm cyclones supplied by various manufacturers in an aim to replace existing first generation 762 mm cyclones without success. Due to plant infrastructure limitations, new generation larger (838 and 800 mm) cyclones were not feasible. In 2010, an approach of testing hybrid 800 mm diameter cyclones was initiated by HVC. The hybrid cyclone consists of an 800 mm cyclone upper head section and the use of existing 762 mm cyclone conical sections. Three hybrid 800 mm cyclones were engineered and fabricated, targeting a throughput of 850-950 mtph and were installed in the E line cyclone cluster. Since starting operation on September 20, 2011, three hybrid 800 mm cyclones have been running at combined throughput ranges of 750 to 1050 mtph. Based on plant Daily Met Reports, the test hybrid cyclones demonstrated a decrease in misplacement of coarse copper bearing material to the cyclone overflow and better cyclone efficiency when compared to the existing 762 mm cyclones at the same throughput. The hybrid 800 mm cyclones also demonstrated significantly higher capacity per unit when compared to the existing cyclones. Based on the improvement demonstrated in the full plant trials, HVC decided to install the new hybrid 800 mm cyclones in all five grinding lines starting in July, 2012. A more detailed discussion of the full plant trials and initial results of the first complete retrofit of E line will be presented. INTRODUCTIONHighland Valley Copper Partnership (HVC) is Canada’s largest base metals mine and one of the world’s largest producers of Cu-in-concentrate. The mine, located in the central interior of British Columbia, is owned (97.5% interest) and operated by Teck Resources Ltd. In 2011, HVC produced about 210 million lbs. of Cu and 8 million lbs. of Mo. HVC’s Mill Modernization Project (MOP), which was budgeted for $475 M, is currently under intensive construction and is scheduled for commissioning in Q1 2014. The following description was valid at the time of writing this paper.The operation has been expanded a number of times since the startup of the original Lornex mill in 1972. The plant started up with two 9.75 m (32 foot) diameter primary SAG mills. It was expanded in 1981 with the addition of a 10.36 m (34 foot) diameter SAG mill. In 1988, the Highmont concentrator grinding mills and flotation section were moved and attached to the Lornex mill site. This added two10.36 m (34 foot) diameter AG primary mills to the Highland mill. This brought the total number of primary mills to five referred to as Line A, B, C, D and E: three SAG mills (A, B and C) each with two ball mills in parallel and two AG mills (D and E) each with one ball mill. Each AG mill line is equipped with one short head pebble crusher. Ball mill circuits are classified using 8 clusters of ten Linatex 762 mm cyclones to reach a target P80 330 micron (equivalent 43% +100 mesh), before the cyclone overflow product advances to the bulk flotation circuit."

Jan 1, 2013

By L. Trytten, S. Bass, P. Nawrocki, J. Mercer

The Sherritt Fort Site nickel refinery and fertilizer plant has been operating continuously since 1954. The ammonia leach process uses ammonia and sulphuric acid, producing nickel and cobalt and an ammonium sulphate byproduct. One of the features of an ammonium sulphate based process is the aggressive nature of ammonium sulphate to concrete and structural steel. After six decades of operation, portions of the structural steel and concrete at the Sherritt facility have become degraded. Infrastructure replacement programs started in earnest more than a decade ago with pipe racks and electrical infrastructure, and have now progressed into building steel. Replacing and repairing this infrastructure within the tight constraints of an operating plant poses several difficult challenges. This paper will outline the approach taken to accomplish this difficult work, and discuss key learnings from the ongoing program.

Jan 1, 2015

By Adam Moore, Peter Radziszewski, Matt Gallimore

"Stirred mill technology dates back to 1928 where the idea to use “an agitator and spherical grinding media” was presented. In the context of the mining industry, interest in stirred milling technologies has grown over the last 20 years where the typical observation reported inDespite these developments, the tumbling mills are continuing to be used in fine and ultrafine grinding applications. The main reason for this, as communicated at the Canadian Mineral Processors roundtable discussion in 2013, is that the comfort level in understanding stirred milling technologies is not at the level of that of tumbling mills.At CMP 2014, one contribution was made to explore how mill design affects power and energy in a stirred mill. While the 2015 CMP paper explored the application of one scale-up methodology to the Gibraltar case. For the CMP 2016, the aim of this paper is to contribute to increasing the general comfort level with stirred milling technologies by developing a better understanding of the different scale-up methodologies used. This will be accomplished by first completing an overview of the scale-up models found in the literature followed by a review of the different testing and scale-up procedures. This review will be supported by a number of case studies found in the literature. The paper will close with a discussion on some of the challenges that these models and methodologies have and how future research might contribute to overcoming them.IntroductionStirred mill technology dates back to 1928 where the idea to use “an agitator and spherical grinding media” was presented (Stehr, 1988). The year 1948 saw the successful application of Du Pont’s “sand mill” for pigment grinding. Subsequent years have led to the development of different types of stirred mills spanning a number of industries that require fine and ultrafine grinding."

Jan 1, 2016

By SANDVIK WHITE

The mining industry produces approximately 4-7% of global greenhouse gas (GHG) emissions. It is fundamental for mining operations to take immediate sustainable action to actively contribute to an emissions-free future for the next generations. The mining industry has traditionally relied heavily on diesel technology and transitioning to more sustainable solutions requires change management to drive cultural acceptance and new product development. Sandvik was interested to find out the lifetime emissions of a single drill rig and to compare similar application diesel and BEV drill rigs with same use profile to each other. That led the calculation and pondering towards comparing different countries and mine sites as well

Jan 1, 2023

By F. Ford, J. Dong

"Laboratory and miniplant testwork was carried out to reject uranium from an Iron Oxide Copper Gold (IOCG) deposit that contains an average of 60-70 ppm uranium with high variability. The dominate copper bearing mineral is chalcopyrite with minor bornite and trace covellite. The main gangue minerals are iron-rich chlorite, quartz and magnetite. The main uranium-containing mineral is uraninite (UO2). Downstream processes require the maximum uranium level of no more than 80 ppm in final copper concentrate.Mineralogical examination reveals that uraninite particles are finely disseminated with grain size of less than a few microns in the deposit requiring fine regrind in order to liberate uraninite from chalcopyrite particles. A lab flowsheet was developed to include ultrafine regrind of the rougher concentrate to the particle size of 80% passing 11-13 µm with up to four stages of recleaning in flotation columns. Finer regrind to 80% passing 5-6 µm may continue to improve liberation but does not decrease uranium level in the final concentrate. In each of the successive recleaning stages by flotation column after fine regrind, uraninite is rejected into the column tailings, with the final copper gold concentrate containing less than 70 ppm uranium from a feed containing 83 ppm uranium. The conceptual flowsheet was further tested in an integrated, continuous miniplant showing average 94% copper recovery with average 74 ppm uranium. The uraninite particles that report to the final concentrate are either locked with chalcopyrite or entrained as liberated particles of less than 5 µm in size.IntroductionIron Oxide Copper Gold (IOCG) deposits are copper and gold ores hosted within a large body of iron oxide and are significant ore deposits for copper and gold (Williams, et al., 2005). These deposits can also contain economic levels of other metals such as uranium and rare earth elements. The known sizes of IOCG deposits range from 10 to 4,000 million tonnes with grade of 0.2-5% copper and 0.1-3 g/t gold. One of the greatest IOCG deposits is Olympic Dam in South Australia. It is the fourth largest copper deposit and the largest uranium deposit in the world. Gold and silver in the deposit also contribute significantly to the total revenue."

Jan 1, 2017

By E. W. Mountjoy

THE Exshaw formation is a thin but very persistent black shale unit generally well exposed along the easterly scarp faces of the fault blocks comprising tl1e front ranges of the Rocky mountains. It is over lain by the Mississippian Banff shales and silty shales and underlain by the massive Palliser Limestone formation of late Devonian age. The Exshaw continues eastward under the plains of Alberta and on into Saskatchewan, with little change until it reaches the surface of the Palaeozoic-Mesozoic unconformity. During the summer of 1953, the writer was working- with a field party under Dr. J. L. Usher in the front ranges of the Alberta Rocky mountains. This party, sent out by the Mobiloil Company, conducted a geological survey of Devonian rocks between the towns of Banff and Jasper. The writer helped to describe and map these Devonian rocks and obtained first-hand information concerning the Exshaw shale and its relationship to the underlying and overlying sediments. Additional information was obtained from reference material and from a number of geologists whom the writer has consulted. Grateful acknowledgment is offered to them, to the Mobiloil Company for releasing field information, and to F. W. Beales and W. P. Hancock who helped edit the original paper for publication. Information from areas north and smith of that studied and from bore holes on the prairies is referred to. Localities mentioned may be found in Figure 1.

Jan 1, 1956

By J. D. Clucas, N. Verbaan, T. Grammatikopoulos, D. B. Dreisinger, C. Forstner, M. Aghamirian

"Search Minerals is currently exploring the Port Hope Simpson (PHS) Rare Earth Element District in southeastern Labrador, Canada. The Foxtrot Rare Earth Element (REE) Project in the PHS District has a 43-101 resource estimate consisting of 3,410,000 tonnes of Indicated Mineral Resources and 5,850,000 tonnes of Inferred Mineral Resources. The indicated and inferred resources contain 1.07% and 0.98% total rare earth element oxide (including yttrium), respectively. The dysprosium and neodymium grades are particularly attractive at 218 ppm Dy2O3 and 1687 ppm Nd2O3 for the indicated resources and 208 ppm Dy2O3 and 1494 ppm Nd2O3 for the inferred resources. The mineralization remains open along strike and at depth and is only one of a number of attractive exploration targets in the Port Hope Simpson area. The REE minerals fergusonite and allanite are present. The ore can be beneficiated by gravity, magnetic separation and flotation to a recovery of +80% for the individual REE. Acid bake and water leaching may be used to extract REE into solution for subsequent purification and recovery. The extraction range for single stage leach tests were 91-96% for Nd, 84-87% for Tm and 92-94 % for Dy with modest acid consumptions. INTRODUCTIONSearch Minerals Inc. (Search) is exploring the 100% owned Port Hope - Simpson District in Labrador, Canada for rare earth elements (REE). This District is approximately 135 km by 12 km in size, and is highly prospective for heavy and light rare earth elements. A total of 11 REE prospects have been discovered in the District to date, including the Foxtrot. In addition, Search is exploring in the 100% owned Henley Harbour region and has joint ventures with Quest Rare Minerals in the Strange Lake region, and with Great Western Minerals Group in the Red Wine complex, all in Labrador. These exploration locations are illustrated in the Figure 1. The focus of this paper is the investigation of the mineralogy and processing of Foxtrot REE materials. The Foxtrot resource falls within the claims held by Search in the Port Hope Simpson REE District. The infrastructure available at Foxtrot is excellent with a deep water port, air strip and road and power infrastructure at Port Hope Simpson. Over $7 Million has been spent to date on exploration and development of the District. The Foxtrot has been explored using prospecting geochemical methods, geophysics (airborne and ground), channel sampling of surface outcrops, mapping and three phases of drilling (18,934 m total)."

Jan 1, 2012

By R. Harris

The vacuum thermal route for magnesium production today accounts for roughly 80% of the global production of magnesium despite significant investment in the competing electrolytic technologies, This is up from 30% of the global production 10 years ago and is all the more significant because global magnesium production has more than doubled in the same time, A review of the sophisticated anhydrous magnesium chloride production technologies provides some explanation for this sea change in technology usage, However, an examination of the economic factors provides compelling reasons, The present review outlines some of the salient strengths and weaknesses of the competing technologies, It also offers suggestion as to where future R and D and economic effort needs to be vested to improve the sustainability of the world magnesium market in terms of its value and impact.

Jan 1, 2006

By Hung-Ming Chen

This paper presents a Cloud-based system framework for providing a web-based building information model (BIM) service. Cloud computing technologies were used to develop a BIM data center, which can handle the big data of massive BIMs using multiple servers in a distributed manner. In addition, the system allows multiple users to access the BIM data center online to submit and review BIMs concurrently. In this study, the advanced technologies/tools of web development and Cloud computing were applied and incorporated to develop a prototype system, named CloudBIM. On the client side, this study applied WebGL and HTML5 in the web-based interface development to achieve the 3D display of BIMs and the dynamic interaction with viewers through browsers. Users can access the services of CloudBIM by using PCs, laptops and tablets anytime anywhere to view the 3D model via browsers, which support WebGL. On the server side, this study used Apache Hadoop, an open-sourced distributed file system based on Google?s technologies, to establish a BIM data center. The Hadoop Distributed File System (HDFS) can utilize multiple servers to provide mass storage spaces in a distributed manner. Based on the use of Apache HBase, which provides Bigtable-like structured storage for HDFS, this study proposes database schema for storing the information from massive BIMs in two bigtables, named Object table and Property table respectively. In addition, Hadoop MapReduce, a Hadoop component for the parallel processing of large data sets, is utilized for model data acquisition by parsing the IFC files of uploaded models in parallel.

Aug 1, 2013

By W. Leblanc, J. Phalen

This paper tells the story of a serious mine fire on a mechanized longwall face in a submarine coal mine at Glace Bay, Nova Scotia. The story gives, in chronological order, a technical account of the steps taken to investigate, fight and contain the fire. The time during which the events took place spans from June 19 to November 7, 1975.

Jan 1, 1976

By F. Charette

The paper reviews recent investigations of the impact of corrosion on the performance of both plain and coated Swellex rock bolts. It addresses the problems associated with estimating and predicting corrosion rates of friction bolts, and based on field data it suggests an empirical relationship to predict corrosion rates. A review of the necessary qualities for a protective coating leads to recent experience with coated Swellex bolts that suggest that they can contribute to extending the useful life of Swellex bolts in potentially corrosive environments.

May 1, 2004

By C S. Stevens

This paper describes the problems encountered and the steps taken to solve them in milling an ore containing relatively large amounts of pyrrhotite. A complex and greatly lengthened flotation circuit was required to recover the pyrrhotite. A very low pH had to be maintained in the cyanide circuit in order to get good recovery of the gold and maintain reasonable cyanide recovery. Introduction D ELNITE Mines Ltd., a gold mine situated about 5 miles by road south and east of the town of Timmins, Ontario, is serviced by two shafts. No. 2 shaft extends from surface to the 2875-ft. level, and No. 3 shaft, an internal winze, extends from the 2875-to the 5275-ft. level. No. 2 shaft was stopped at the 2875-ft. level because of a heavy band of chloritic schist which necessitated a drive to the north for 1000 feet, where No. 3 shaft was sunk. The latter bottomed in the schist at the 5275-ft. level. From the 2500 to the 2875-ft. level in No. 2 shaft, the ore was

Jan 1, 1965

By F. Bruey, T. Bruce, D. R. Nagaraj, W. Thomas, P. Riccio, E. Guitard

"AEROPHINE® 3418A Promoter is a flotation collector that has been an industry standard in the Canadian mineral processing industry since its first commercial use at the Kidd Creek concentrator in 1980. Its wide range of applications in sulphide mineral flotation has made it successful, specifically in the processing of complex sulphide ores which contain copper, lead, zinc, and silver or any combination of these elements for selective separation.AEROPHINE® 3418A Promoter is a unique, phosphine-based collector originally developed for the flotation of copper sulphide minerals and activated zinc minerals. It is now recognized for its selectivity for complex, polymetallic sulphide ores and porphyry copper ores. In addition, AEROPHINE® 3418A Promoter is highly selective for copper, lead, activated zinc, nickel and precious metals. AEROPHINE® 3418A Promoter exhibits strength yet, selectivity against iron sulphides (pyrite, pyrrhotite, marcasite, and arsenopyrite), non-activated sphalerite, and many minerals which contain penalty elements.This paper outlines a brief history of the product’s development, its historical use in Canada and several potential innovative mineral processing applications with the use of the chemistry. Three Canadian case studies will be presented on various ore types including: a Cu-Au ore, a Cu-Zn ore, and Cu-Pb-Zn ore. A plant production update will also be given on the future supply of AEROPHINE® 3418A Promoter.INTRODUCTIONCytec Industries Inc. operates a phosphine derivatives plant in Niagara Falls, Ontario, that manufactures various products for their speciality chemicals division. The products from this site are based on phosphine (PH3) chemistry and are used in a variety of markets including electronics, agriculture, LED lighting, water treatment, metal extraction, and mineral processing. One of the major products is the phosphine-based sulphide mineral collector, AEROPHINE® 3418A Promoter.AEROPHINE® 3418A Promoter (Figure 1) was originally developed for the flotation of copper and activated zinc minerals (Thomas, 2010).."

Jan 1, 2015

By V. Sheikhzadeh, M. Saghaeian, R. Hejazi, P. Ghobadi

Design and selection of equipment for a grinding circuit strongly depends on the mill function, ore properties and requirements of the down-stream circuit. Primary mills usually work in open circuit and size distribution of product would be controlled in the final steps using a classifier like cyclone. Although HPGRs are mostly utilized as pre-grinding mills, it is preferred to utilize them in a closed circuit due to their specific mechanism of comminution. Unique mechanical design of HPGR and its completely different crushing process than tumbling mills needs precise consideration on its circuit design. In this paper, we investigate the impact of different parameters on design of pre-grinding HPGR circuit and selection of the proper classifier. Our study focuses on iron ore properties (e.g. moisture, particle size distribution of feed and product, compatibility and de-agglomerability). We also investigated various options of HPGR circuit according the classifier efficiency and influences on down-stream processes. The optimum operating parameters of HPGR (working pressure, speed and level of hopper) for the selected circuit were also determined based on pilot and industrial data. Our pilot and industrial tests and observations revealed that HPGR should be arranged in closed circuit because of the edge effect, as a negative factor of non-uniform distribution of pressure force along the roller width and presence of non-crushed particles in the mill product. Wet vibratory screen could be the optimum option for screening of its discharge. Fine part of the wet screen discharge could be delivered to the concentration stage without over-grinding in ball mill using a hydrocyclone working in a reverse closed circuit mode. Moreover, our pilot and industrial tests during design and operation of ten HPGRs in various iron ore processing plants proved that higher pressure and lower roller speed in a fixed level of material inside the hopper could give the desired product size distribution.

Jan 1, 2016

By G. M. Brownell

Introduction The Flin Flon mine is located on the boundary line between the provinces of Manitoba and Saskatchewan at a point about four hundred miles northwest of Winnipeg. A branch of the Canadian National railway provides the town of Flin Flon with direct transportation facilities. The property was staked in 1914 and, after a considerable amount of exploration; the Hudson Bay Mining & Smelting Company was organized and brought the property into production in November, 1930 (1). Mining is carried on by open pit and underground methods at the rate of about 4,400 tons per day. Production for the year 1934 was: 99,334 ounces of gold; 1,335,319 ounces of silver; 37,486,054~pounds of copper; and 49,427,280 pounds of zinc; in addition to small amounts of cadmium and selenium. The Flin Flon deposit is one of the largest low-grade ore deposits in Canada with complete hydro-electric and metallurgical plants for the production of blister copper and electrolytic zinc. Previous Work The development of the Flin Flon mine into one of the major mining operations in Canada has created a need for a more detailed geological study of the area. Practically all of the information published to date concerns the general surface features. It is the purpose of this paper to deal more specifically with the ore-body and its relationship to the enclosing rock as revealed by studies made possible through recent underground development. The earliest published report on the area is by E. L. Bruce (2), who made a reconnaissance geological investigation of the region for the Geo-logical Survey of Canada in 1914 and established the main. petrological units. Several years later the area immediately around Flm Flon was mapped in greater detail by F. J. Alcock (3). In the summer of 1934, the area of Missi sediments to the north and east of the mine was studied by J. W. Ambrose. His report has not yet appeared in print but his findings are of importance.

Jan 1, 1935

By G. J. Kipouros, W. Judge

"The prevalent metal extraction processes for most reactive metals are fused salt electrolysis and metallothermic reduction. The feed material for both of these processes is the anhydrous chloride of the metal under consideration. Dehydration of the feed material is then a critical step in the production of most reactive metals and requires rigorous thermodynamic analysis. Thermodynamic data for most of the reactive metal chloride hydrates have not been measured. Improper dehydration of the metal chloride may lead to a prohibitive amount of hydroxychloride, oxychloride, and oxide. To prevent hydrolysis a certain pressure of hydrogen chloride is required. An estimation and prediction model is presented for the vapour pressures of reactive metal chloride hydrates in an attempt to deduce the conditions necessary for dehydration to proceed without hydrolysis. Thermodynamic data including heat capacities, standard entropies, and standard enthalpies are estimated/predicted for all conceivable intermediate hydrate compounds. Estimations are based on published data as well as trends proven in similar systems. The thermodynamic estimations and predictions are presented for the magnesium, neodymium, praseodymium, and dysprosium chloride hydrates. INTRODUCTIONThe high reactivity of metals such as the alkalis, alkaline earths, and lanthanides prevents their reduction by traditional pyro- or hydrometallurgy. In their elemental form, these metals are raw materials in the manufacture of intermediate products such as alloys and electronic components. Currently the only two viable metal production methods are fused salt electrolysis and metallothermic reduction. Various feed materials have been proposed for these processes. Using the chloride of the metal as a feed material offers advantages in separation and purity of the final product, as well as lower energy input. Chlorides, however, are hygroscopic and must be dehydrated before use. Improper dehydration will lead to a prohibitive amount of oxychloride which will lower efficiencies and contaminate the final product.Optimum conditions for proper dehydration of MgCl2•6H2O to produce pure MgCl2 without hydrolysis have been calculated from existent thermodynamic data and have been reported previously (Kipouros, 1987; 2001). Calculations were also performed for the case of production of pure anhydrous NdCl3 from NdCl3•6H2O (Roy, 1997)] and the mechanism of dehydration was elucidated. Some thermodynamic studies on the dehydration of chlorides of the rare earths have also been conducted (Sundstrom, 1997; Hong, 1997; Aschcroft, 1968; Haeseler, 1965; Ukraintseya, 1989)."

Jan 1, 2012