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By Donka H. Andreeva

Gold catalysts based on different supports, titania, zirconia, ceria and mesoporous titania and zirconia, nonpromoted and promoted by vanadia in the reaction of complete benzene oxidation have been studied. XRD, HRTEM, TPR, Raman and ESR spectroscopy were applied for the characterization of the catalysts. The influence of gold on the reduction behavior, state and structure of vanadia on the surface was studied, as well as the role of supports nature on the properties and catalytic activity. A strong synergistic effect between gold and vanadia was observed for the all studied catalysts with an exception of the catalysts supported on mesoporous zirconia. In the last case the catalysts containing gold and gold-vanadia exhibit high and equal catalytic activity. The catalysts on ceria show highest and stable catalytic activity in the studied reaction among the all studied catalysts.

Oct 1, 2003

By D. O. Tansey

This paper will describe the mechanisms involved in delay blasting and how they are applied with the use of D.S.B. It will examine the control of potential damage resulting from detonations, and show how good fragmentation and efficient recovery of this material blasted can be achieved

Jan 1, 1979

By Bob Robinson

In 1990, the European Space Agency (ESA) initiated a technology transfer program to stimulate the wider use of technology developed by the European and Canadian space communities. This paper focuses on the method of technology transfer from the space industry to terrestrial industries, with a focus on the mining resource sector within a program called the Harsh Environments Initiative (HEI) created in 1997. Other resource sector applications include forestry and oil & gas. C-CORE in partnership with the Mining Innovation, Rehabilitation and Applied Research Corporation (MIRARCO) supported by ESA, Canadian Space Agency (CSA) and European R&D organizations conduct projects to promote and demonstrate the transfer of innovative technologies from space to non-space industries. Space programs have and continue to develop new knowledge for extra-terrestrial application, e.g., satellite earth observation, manned missions and unmanned planetary exploration. Many of which hold the potential for application on land and ocean. Currently, space technologies of interest to the mine sector range from robotics and image analysis to sensors, software and advanced materials. The HEI works to identify and apply these types of technologies in the areas of automated/tele-controlled mine operations and mine monitoring.

May 1, 2001

By W. Keith Buck

This paper defines the discipline of mineral economics. By example, it describes the application of the tools of economic analysis to mineral problems - to problems in the areas of: mineral resource analysis and forecasting, mineral industry activity from exploration to distribution and marketing, mineral commodity analysis, and mineral policy analysis and policy formulation - all in a regional, national or international context.

Jan 1, 1972

By M. V. Rowley, D. D. Warkentin

With high commodity prices, tightening operating budgets and increasing disposal costs, there is an increasing interest in processing municipal waste streams, such as the ash derived from combustion processes. This paper describes laboratory development work for a process to recover metal values from the finer fractions of these wastes. The work was initially aimed at recovery of copper and the removal of lead and other heavy metals from the ash residue, but results showed gold and silver recovery to be an important objective as well. The process uses gravity and flotation as the principal separation steps, with gold recovery occurring mainly in the flotation stage. The particle size range and chemistry of the ash presented numerous challenges to developing a suitable flotation method, but an effective flowsheet was developed by separating the ash into a fine fraction and a separate slime fraction, each with a unique flotation strategy. Specialized conditioning stages and careful reagent selection have resulted in effective gold and silver recovery from a range of ash types and sources. The work has resulted in a patent being issued for a process based on this novel approach to the treatment of combustion wastes.

Jan 1, 2017

"Air Products approached LAC Minerals in 1987 to initiate trials with pure oxygen in the leach circuit at several LAC facilities in Canada. This paper gives an overview of oxygen use and covers specific operating data from the Doyon and Terrains Aurifères mills near Val D'Or in northwestern Quebec. LAC also uses oxygen at the Macassa mill in Kirkland Lake, Ontario.In addition to the LAC facilities, oxygen is currently in use for test purposes at the Holt McDermott mine in Kirkland Lake, Ontario and the Camflo mine near Val D'Or.There are two requirements for oxygen in the cyanide leach mill. Firstly, oxygen is required in the familiar gold dissolution reaction as follows:(1) 4 AU (s) + 8 NaCN (aq) + 02 (aq)+ 2H 20(aq) - 4NaAu(CN) 2(aq)+ 4Na OH(aq)Of the reagents on the left side of the equation, the availability of gold is fixed by the ore in question. Obviously, water is available in excess, 1eaving cyanide and oxygen as the limiting constituents in the process. Most mills operate with an excess of cyanide, which is fairly closely monitored. Dissolved oxygen levels, however, are not normally watched very closely and find their own level based on the temperature, the availability of compressed air and the ability of the ore to consume oxygen.Typical D.O. levels are in the 3-8 ppm range, however levels less than 1 ppm are not uncommon for refractory ores.With pure oxygen, dissolved oxygen levels as high as 30 ppm can be achieved. (Figure #1). This greatly accelerates the kinetics of the leach reaction and may also shift the reaction further towards completion thus increasing gold dissolution slightly."

Jan 1, 1990

By J. P. Van Cruyningen, M. J. Puro

"A 2400 acre extension to the existing Tailings Area is under development at Inco's Copper Cliff Milling operations.The new area is being developed in stages as production levels dictate thus minimizing immediate capital expenditures while permitting disposal operations to proceed as further site work progresses.The first stage of the new storage site will be fully operational by early 1987 and will include a 400 acre site specific to the storage of Pyrrhotite rejected from milling circuits. The Pyrrhotite site is located in the centre of the Tailings area and is designed for water cover throughout much of its projected life.The new development incorporates perimeter dams designed to operate with low phreatic levels for maximum structural stability. Acid seepage water is collected behind secondary impermeable dams for return to the Tailings Pond.Tailings are deposited by up-stream methods permitting segregation of coarse fractions for use in future lifts of the perimeter dams."

Jan 1, 1987

By Ursula M. Franklin

Old iron nails are one of the most common objects which entice the general public to ask questions about the history of metallurgy. There is a lot of history in old nails - history of the manufacturing industry, and social and economic history. Nails, therefore, are fine teaching tools; whether students have to acquire metallurgical skills or explore the structure and properties of wrought iron, whether they want to look into the history of inventions and the development of machinery, studying nails tells a story better than any teacher or any book. I have used this approach often and the following note is based on several student projects, particularly the work of Carmina Herrero and Vicky Marchant. Nails, those essential metallic fasteners, have long been with us. Their size, shape and design is basically a compromise between the makers' ability to control and manipulate material and the demands of the intended application. There were copper and bronze nails in antiquity, but in this paper I want to deal only with iron nails. In Rome, iron nails were common, and Cleere carried out the fine metallographic investigations on a large stock of nails recovered from a Roman fort site in Scotland. Those nails were hand forged; sorting them at the site on the basis of length, shape of head and shape of shank (in cross section) indicated that there seemed to have been some nail standardization. It appears that the Roman smiths used a series of heading dies starting with a 1/s-in. size. Each successive size increased by approximately 1/16-in. The metallographic inspection of the microstructures of the nails showed that the smaller nails were made in the one operation; i.e. both the tapering and the formation were accomplished on the heated rod without reheating. However, in the case of the larger nails, the nail had to be reheated for the tapering after the head had been forged. Most nails were tapered on all four sides of the shank and the shanks were square in cross section; only one group had rounded shanks. Most heads were flat disks, but in one group the heads were pyramids and another group had conic heads. Figure 1 shows the procedure used to produce the pyramidal heads. Obviously, Roman nail making was sophisticated and each nail design was meant for a particular use.

Jan 1, 1999

By P. G. Lazenby

This paper describes the latest instrumentation improvements in the INPUT Airborne E.M. System, particularly the new electronic signal-processing techniques. Several anomaly examples illustrating these techniques are shown.

Jan 1, 1973

By R. Mulligan

"The Cordilleran tin belt extends from the Seward Peninsula in westernmost Alaska to Mexico. Throughout the Canadian section, tin occurrences are mainly confined to a belt along the northeastern fringe of the Western Cordilleran sub-region; the boundary of this sub-region with the Eastern Cordilleran sub-region is most simply defined as the practical eastern limit of granitic and metamorphic rocks. The stratified rocks underlying this restricted belt are mainly late Precambrian and early Paleozoic miogeosynclinal sedimentary rocks, which are more or less metamorphosed but otherwise are generally equivalent to the less severely deformed rocks underlying the Eastern Cordilleran sub-region. They contrast with Late Paleozoic - Mesozoic eugeosynclinal volcanic-sedimentary assemblages farther west, but the granitic intrusions throughout are mainly of Late Mesozoic age. Thus, narrowly defined, the tin belt largely coincides with a lead-zinc-silver metallogenic province, whereas copper deposits characterize the eugeosynclinal regions to the west. In addition to the tin occurrences, which include the Sullivan lead-zinc-silver mine, Canada's only significant producer, the belt contains all the beryllium, most of the tungsten and many Iithophile-type molybdenum occurrences. Several types of occurrences of each metal are represented. Lithium occurrences in the Canadian Cordillera are notably rare, and these few are insignificant."

Jan 1, 1971

By H. Salomon-de-Friedberg

The amount of pyrite in copper concentrates fed to the CESL Process can vary appreciably. The fraction of pyrite that oxidizes influences both capital and operating costs and is therefore an important variable. The present paper explores operating conditions that influence the extent of pyrite oxidation and the probable overall reaction chemistry under CESL conditions.

Jan 1, 2014

By Edward P. Barrett

Iron ore, when subjected to reducing gases at a temperature suitable for reduction of the oxide but not high enough to melt the ore or metal formed, is converted into metallic iron. The product, being the original piece of iron oxide minus its oxygen, is sponge-like in appearance when viewed under a magnifying glass, and hence is called 'sponge iron. Sponge iron was probably the form in which some of the first iron was recovered from the ores. As early as the eighth century the Catlan forge developed into a low shaft furnace known as the high bloomary, in which iron was produced in the form of a pasty mass. These furnaces were increased in height, and with increased temperatures came the production of liquid cast-iron, at first undesirable because of lack of knowledge of methods for working it. In 1340 the first true blast-furnace was built iri Belgium. Some castings were made, but the greater part of the iron was converted into wroughtiron blooms by a crude puddling process. Charcoal was the universal fuel until the latter part of the seventeenth century, when coke was first used in England. Larger scale developments of methods of refining pig-iron followed. In I 885 Bessemer built his first converter in England, and within a few years the Siemen' s regenerative open-hearth furnace was developed, also in England, to produce steel. Then followed the enormous expansion in the metallurgy of iron. The idea of a direct process for the production of iron and steel has persisted during all of this time.

Jan 1, 1925

By J. Nesset, F. Rosenblum, P. Spira

"Sulphide concentrates may exhibit self-heating to various degrees during storage or shipping, the worst cases presenting a serious hazard from fire and SO2 emission. Based on measurements of heating rates on a wide variety of concentrate samples in a special apparatus, combined with field experience, a methodology has been developed which allows concentrates to be rated for their heating potential. This has proven to be very useful in practice, for example, in deciding on the need to take preventive measures. Oxidation under ambient conditions in the presence of moisture initiates heating locally within a stockpile. In the case of highly active materials, such as those that contain abundant pyrrhotite, heating may progress through three stages to temperatures well above 5000C. However, most concentrates show little or no propensity to selfheat. Heating rates were used to estimate values of the heat output, or self-heating capacity (in joules per gram), which sustains the process at each stage. Thermal data from differential scanning calorimetry are also reported. Variables which affect self-heating are discussed and an actual case of heating control on a stockpile by covering is described. A simple apparatus which can be used to simulate stockpiling conditions has been tested successfully and is proposed as a convenient test system.INTRODUCTIONPrevious publications from this laboratory on the evaluation of self-heating in sulphides dealt with tailings backfill (Rosenblum et al. 1982) and waste rock (Rosenblum and Spira 1995). Sulphide concentrates may likewise exhibit self-heating in storage or during shipping. In a comprehensive but dated review, Kirshenbaum (1 968) pointed out the conflicting nature of information on means of controlling the problem, particularly with regard to the application of water and ventilation. Modelling by Simpson (1 97 1) of autogenous heating in stockpiled zinclead concentrate and associated field measurements by Wright et al. (1972) showed that the supply of oxygen by wind and the shape of the piles were the major factors in the development of hot spots. Simpson did not attempt to explain the complex mechanism of self-heating, simply ascribing its onset to oxidation. Pearse (1 980) investigated a potential method of testing for selfheating which consisted of (i) reaction with hydrogen peroxide and (ii) differential thermal anal sis, to characterize the response of concentrates at both ambient and temperatures above 100 C. He found the method sensitive enough to identify the need for careful handling but not to predict ignition. He recommended compacting concentrates and covering stockpiles with plastic sheeting to prevent ingress of air. All these workers recognized the key role played by oxygen and moisture in triggering self-heating."

Jan 1, 2001

By R. P. Zahn

The need for quantitative mineralogical data to characterize ore types before they are processed is becoming increasingly necessary. Mineralogical data (modal abundances, grain size, liberation/locking characteristics, mineral textures and associations) can provide invaluable information to facilitate the identification of metallurgical issues that may arise during processing of a particular ore. This paper will discuss the use of QEMSCAN analysis in conjunction with bench scale flotation test work to determine metallurgical characteristics for several ore types that will be fed to the Morenci concentrator upon commencement.

Jan 1, 2007

By Oy Leuangthong

Red Dog mine is the world's largest Zn producer. The deposit consists of sulphide ore zones in sedimentary exhalative (sedex) deposits, and is characterized by the presence of multiple metals and multiple ore types. The objective of the case study is to characterize seven different minerals, Zn, Pb, Fe, Ba, sPb, Ag and TOC, within eight different rock types. Geostatistical models were constructed for each variable within the eight rock types, and subsequently assembled to give 40 realizations for six 25ft benches. The stepwise conditional transformation was used to account for the complex multivariate relations. In addition to reproducing the input data, histogram and variogram, the resulting models also respect multivariate relations locally and globally. This paper documents the methodology to construct these models. A thorough validation procedure was implemented. Comparisons with blasthole data show that the conditional simulations and the long-term models agree in expected value. The main advantages of the conditional simulations are (1) the explicit accounting of multivariate relations between the data in model construction, and (2) the ability to quantify variability and uncertainty at any scale. A small exercise comparing the profit from a kriged and a simulated model is also examined. Results show that the simulation approach showed a 3% increase in profit, relative to the conventional estimation approach.

May 1, 2004

By W. F. MacIsaac

"The large low-grade Copper Mountain deposit is located in the northern portion of the Gaspé Cooper Mines property. It is approximately 1 mile north of the Needle Mountain deposit. The orebody outlined to date lies in the top 1,000 feet of the Grande Greve formation. Chalcopyrite occurs in association with pyrite and quartz in small veinlets and numerous fractures. The deposit is immediately adjacent and parallel to a quartz-feldspar dyke and may be associated with a nearby porphyry stock. Stratigraphy, alteration and structure appear to have played an important role in ore deposition."

Jan 1, 1969

"3.1. IntroductionAmong the six platinum-group elements (POE), four have identical cubic symmetry, two identical hexagonal symmetry (Table 3.1). Despite crystallographic differences, there is a clear relationship expressed in the chemistries of the POE: they tend to be mutually soluble in one another and can frequently substitute for one another in compounds with other elements. This chapter consolidates the data on phase relations of the POE and the compounds they form with elements selected for their known or potentially important mineralogical significance- As, Bi, Cu, Fe, Hg, In, Ni, Pb, S, Sb, Se, Sn and Te-together with selected data for the occurrence of POE in certain elements such as Au and Ag, and compounds such as FeS. Resources used to compile the data are those available from the chemical, mineralogical and metallurgical literature. First each element is discussed, with composition limits of solid solutions drawn from binary phase diagrams. Single element data are followed by a discussion of the relevant binary systems and a tabulation of data for binary compounds found in those systems (Table 3.2). Tables and diagrams for the ternary and quaternary systems for which information is available follow, and finally the very limited information on the solubility of POE in mineralogically important elements and compounds is presented.The chemical, mineralogical and metallurgical literature on the unary and binary systems is extensive and widely scattered in many languages and publications; fortunately, most of the data needed to compile this chapter can be found in reliable compendia. The most useful and most recent of these works is by Moffatt (1979), because it provides a ready index to all material relating to binary systems listed in previous compendia; furthermore, the Moffatt compendium will reportably be kept up to date by annual supplements."

Jan 1, 1979

By Poul Hansen

"In mid-I986, a world-class mining enterprise was created in British Columbia, bringing together the copper mining operations of Lornex Mining Corporation and Cominco into a new entity, Highland Valley Copper. This paper will focus on the background and rationalef or the formation of this partnership, the resulting operating changes and the productivity and cost benefits expected.IntroductionSince the deterioration of the world copper industry in 1981, the future of the Lomex and Cominco mines in the Highland Valley of British Columbia looked increasingly precarious. Despite the expansion of the Lomex mill complex in 1981 to one of the world's most cost-efficient copper and molybdenum concentrators, persistent low metal prices had made the remainder of the ore in the Lomex orebody marginally economic and had significantly foreshortened the expected life of the operation.Cominco had acquired the Bethlehem Copper assets in order to consolidate its ownership of the Valley orebody, and was feeding the Bethlehem concentrator with ore from the Valley orebody. In spite of the high grade and free-milling character of the Valley ore, profitability of the Cominco operation was severely restricted because of the limited capacity of the Bethlehem concentrator and its location high on the hillside above the orebody."

Jan 1, 1987

By J. S. Edwards

The ISASMELT? process is recognized worldwide as a modem, flexible, environmentally-friendly and low capital cost smelting technology. Due to the inherent simplicity, and the advanced process control that has been developed, personnel become competent within weeks of being introduced to the ISASMELT? technology. This compares with the years required to become proficient with alternative technologies. Copper smelters in Australia, USA, India, China, Peru and Zambia have installed ISASMELT? technology under licence from Xstrata Technology. In the secondary copper business, plants in Belgium and Germany are processing copper and/or lead materials in ISASMELT? furnaces in a two stage process. In a single furnace smelting is followed by converting. Both plants have exceeded design capacities and are continuously improving their performance. The next evolutionary step for the technology is the implementation of the continuous copper converting process on a commercial scale. The present work describes the design status of the continuous converting process - ISACONVERT?.

Jan 1, 2007

By J. R. Giegerich

THE problem of dust control in metal mines has, of late years, received considerable attention. In 1932, a detailed study of dust conditions at the Sullivan mine was undertaken and, while there are no actual data available regarding conditions prior to that date, there has unquestionably been a great improvement as a result of the investigation and of the preventive methods adopted. In attacking the problem, three main factors were considered: first, and most important, how to prevent dust from being formed; second, how to depress or collect it if formed; and third-if unable to accomplish these-what precautionary measures must be adopted to prevent inhalation of this dust. Seven distinct methods of dust control are now practised at the Sullivan. Six of these are employed underground; they are tabulated below in the order of their relative importance. The seventh method is used in the crushing plants on the surface. (1) Improved ventilation (2) General use of water sprays and atomizers (3) Curtailment of secondary blasting during shift hours ( 4) 100 percent wet drilling-primary and secondary (5) Wearing of protective equipment (6) Change from carbide to electric lamps (7) Installation of dust collectors

Jan 1, 1936