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By J. -P. Lempainen, K. Haavanlammi, K. Valkama

The Outotec nickel matte chloride leaching process is especially suitable for small capacity standalone nickel refineries. The matte is leached with hydrochloric acid and oxygen in multiple steps in atmospheric OKTOP® reactors. Oxygen feed prevents reductive conditions and hydrogen formation in the leaching process. A sufficiently high acid concentration keeps the iron dissolved in the solution. The iron is removed after leaching by precipitation and the pregnant leach solution continues to metals recovery. The metals recovery from the chloride solution is done by solvent extractions, where ammonia is used for pH control. Copper and nickel are stripped from the organic phases into sulphate solutions. Metals can be recovered from the purified solution by conventional electrowinning. Other alternatives are precipitation or hydrogen reduction processes. The ammonium chloride in the solvent extraction raffinate is regenerated into ammonia. The calcium chloride solution from ammonia regeneration is routed to acid regeneration where sulphuric acid is added and ultra-pure gypsum is precipitated. The hydrochloric acid solution from this step is recycled back to leaching. The process yields good overall metal recoveries and expensive

Jan 1, 2014

The use of QemSCAN in providing mineralogical input to detailed ore and product characterization has proved of immense value in recent years. In this paper, a brief review of selected Cu-case studies is presented to demonstrate the versatility of automated, quantitative mineralogy by QemSCAN. This versatility ranges from measurement and analysis strategies through to data processing and presentation. As a rapid diagnostic service, it is common to find that only grain size, the degrees of liberation and/or ore mineral modal mineralogy are of interest. By contrast, the detail afforded by the simultaneous determination of both gangue and ore minerals can alert mineral engineers to fatal flaws and attributes deleterious to processing that are directly a function of silicate and other gangue mineralogy. Examples of the latter effects include the influence of micaceous minerals and acid consuming species, while the former include fluorine minerals, which can provide both processing and environmental challenges.

Jan 1, 2007

By E. S. Moore

"The Centre of the silver-producing section of the Gowganda area lies about 55 miles northwest of Cobalt, and the village of Gowganda is 71 miles by road from New Liskeard. The geological similarities of the Gowganda and Cobalt areas led prospectors westward from the rich Cobalt field, first to Elk Lake and then on to Gowganda, where mineralization was found in 1907. A year later many showings were found, and rich hand-picked ore was shipped. Most of the ore has come, however, from two mines, both of which are still operating; the Miller Lake-O'Brien, which was purchased by Siscoe Metals of Ontario Ltd. in 1945, and the Castle-Trethewey. The annual production of these two mines runs over one and one-half million ounces of silver and considerable cobalt. The total production of the camp has reached about 32,000,000 ounces of silver and a large amount of cobalt, the total not recorded.General GeologyThe general geology of Gowganda is in many respects much like that of Cobalt. There are areas of Keewatin basic and acid Javas mixed with tuffs and basic intrusions. These rocks are deformed and partly altered to schists, and have been intruded by some Haileyburian basic and ultra-basic rocks and by Algoman granite. These were followed by a large number of porphyritic Matachewan quartz diabase dykes. After a period of extensive erosion the Huronian sediments were deposited on a pene-planed surface over all the older rocks; these sediments include large quantities of conglomerate (partly tillite), quartzite, and greywacke. The Keweenawan rocks include the Nipissing quartz diabase sill, later quartz diabase dykes, and one long olivine diabase dyke, the latest Precambrian rock. The area has been extensively glaciated.Structural FeaturesThere has been little folding in the area since the Algoman batholiths were intruded, and the Huronian sediments lie nearly flat, with dips of 10, 15, or rarely 25 degrees. The Matachewan dykes show a remarkably uniform, nearly north strike, indicative of east-west tension when they were intruded. On the other hand, the dykes later than the sill strike nearly east, tangentially to the northeasterly and northwesterly strikes of the Miller Lake basin."

Jan 1, 1949

By J. Visman

"SummaryThis paper is presented as part of a programme to show the steps taken by industry and others interested in supplying a solid fuel of constant quality to 'satisfy a consuming market. The paper deals with the general principles underlying quality control in coal preparation plants, namely, constant quality and close adherance to acceptance limits. It also describes how control of ash content is ""generally hampered by the problem of coal sampling .and the long duration of the ash analysis and how these difficulties may be overcome.Quality control can be effected in several ways. Thorough blending wll reduce variations appreciably, except those of long trend. The latter can be detected by automatic sampling and quick ash analysis. At present, under favourable conditions, a system of half-hourly ash determinations with an accuracy of 0.5 to 1.0 per cent can be realized, to the effect that trends with a 'wave length' of more than two hours cu be eliminated within the limits of accuracy of the ash figures. The general solution of the problem is a combination of blending, accurate sampling, quick ash determination, and statistical analysis of the pattern of ash distribution.The use of statistical methods of analysis, such as the t test and F test, is •discussed at some length in order to emphasize the importance of the correct evaluation of observational data if there is to be confidence in the validity of test results.General ConsiderationsCOAL, as a fuel, is too cheap for a long haul across the country. The limiting distance depends on the price of the local competitive fuels, and, as the price depends to a great extent on quality, so does quality, to the same extent, command the market."

Jan 1, 1952

By J. B. Edwards

"The case is presented for the use of simulators for the computer-based training (CBT) of mining plant operators and for introducing them to automatically controlled systems. As well as their use in the classroom, the role of simulators is examined for ""on-plant"" use in trouble-shooting, fault-finding and maintenance of automatic systems. Case studies are presented showing how specific simulators are becoming established or have potential in the areas of automated materials handling, machine testing, setup and guidance. The evolution of scientific simulations into simulators of widespread practical use is discussed and present-day limitations of computer speed and graphics are considered. Related areas of research for the Canadian Centre for Automation and Robotics in Mining (CCARM) are identified.IntroductionCCARM's Commitment to Simulator DevelopmentAs automation is progressively developed and exploited in mining operations, there arises an urgent need to educate and train staff responsible for its introduction and operation in our mines and for its maintenance. For this purpose , an essential ingredient of an automation program is the development of appropriate mining system simulators for use by a wide variety of personnel. The author has been fortunate to have been closely involved with the development of automatic control systems for a variety of mining machines and mining systems in the United Kingdom. A key ingredient of the research phase in each case has been the use of simulation techniques. As projects have moved toward their commissioning and exploitation phase, the simulations have evolved into simulators tailored for use by machine operators and maintenance personnel. Illustrative case studies are presented later. The researach of the newly constituted Canadian Centre for Automation and Robotics in Mining (CCARM) will likewise involve extensive simulation, and the development of simulators (from the scientific programs) for use at the mine by operators and technicians will be given high priority in the Centre's over-all work program."

Jan 1, 1990

By John Convey

This paper, a follow-up to an earlier study, gives the history of Canadian developments in mineral processing from 1921 to the fall of 1964. It deals extensively with comminution and flotation, and then goes on to cover the fields of gravity concentration, magnetic concentration, cyanidation, the processing of uranium ores, and instrumentation. Several outstanding examples of installations are given. The paper concludes with a discussion of present-day trends in mineral processing. Introduction T HE history of the developments in mineral processing in Canada from its earliest times to 1920 has already been published by one of the authors (1). The present paper is thus a logical follow-up to bring this history to date. From 1834 to 1920, mineral processing in Canada, as elsewhere in the world, was in its formative stage. This, however, prepared the ground for developments that have resulted in a mining empire from the Atlantic to the Pacific, a mining empire which could be said to be almost on par with that in the United States.

Jan 1, 1965

By J. W. Meier

Introduction The great importance of air warfare during World War II and the introduction of large-scale air transportation and airborne operations created an immediate demand for large quantities of high quality light alloy products. Before this war, the use of magnesium, the lightest structural metal, was barely in the development stage, and considerable research work was needed to overcome difficulties in improving its properties and to attain uniform quality in mass production of magnesium alloy products. The Canadian Bureau of Mines was frequently called upon, by various agencies of the Armed Forces and of the newly established war industries, to examine magnesium alloys that had failed in fabrication or in actual service, and to advise on proper alloys and fabrication methods to be used. Failures in magnesium alloy castings were connected mainly with lack of knowledge of proper founding and surface-protecting techniques. Most of the defects were due to microporosity and faulty heat treatment. To aid the foundry industry, small-scale investigations were started on the effect of various factors in the casting technique in order to improve the quality of the products. These investigations were made in co-operation with representatives of the Armed Forces and the Canadian magnesium industry. This work was later co-ordinated into a broad research programme on magnesium alloys, comprising problems on melting, refining, various casting methods, heat treatment, and testing of properties of standard and special alloys. This research programme? is still in force, and the present paper contains some results of the first series of investigations on magnesium casting alloys carried out at the Experimental Foundry of the Bureau of Mines.

Jan 1, 1948

By N. R. Thote, J. L. Porathur, C. P. Verma

Highwall mining is a highly mechanized coal mining method associated with several advantages, such as a very high production rate (approximately 3,000 t/d) and low production costs. There is no requirement for underground support, ventilation, or blasting. Production leads to added recovery, which is otherwise lost in the ultimate pit. The use of highwall mining can bridge the gap that exists between supply and demand in the energy sector. This paper presents a brief review of highwall mining technology, including current status, analysis tools, and design techniques. In addition, it identifies important parameters from the analysis of failure case studies.

Jan 1, 2014

By S. C. Tadolini, J. M. Goris, J. L. Gallagher

Cable supports offer several advantages over traditional secondary support methods by enhancing stress redistribution to pillars and gob areas, minimizing or eliminating timbers and cribs that reduce ventilation, eradicating material-handling injuries related to placement of crib supports, and providing a cost-effective alternative to secondary support. The U.S. Bureau of Mines (USBM), researching alternatives to traditional roof support methods, designed and installed high-strength cable supports to improve the stability of longwall gate road entries in a western U.S. coal mine. With the cooperation of industry, methods were developed to install and evaluate cable supports in a tailgate area using traditional resin cartridges. The cable-bolted areas successfully maintained roof support throughout the developed entries. Cable supports have replaced wood cribbing as secondary support in the bleeder entry system and have minimized or eliminated the use of cribbing in the longwall tailgate entries. This paper describes the theory, application, and advantages of cable supports and presents some mine measurements made to assess the cable performance during the retreat process of longwall mining.

Jan 1, 1999

By Arun Verma

Thermal energy storage offers a means of effecting significant costs savings and conservation of premium fuels. Na2SO4 has been found to be a good material for storing thermal energy in the medium-temperature range, mainly because of its dimorphic nature and high heat of transition. Basic data and development of the salt to a practically usable block are discussed.

Jan 1, 1978

By J. M. Hemstock, H. L. Ames

THESE forums have been held annually since they were introduced by Mr. L. E. Djingheuzian in 1957. The response of millmen to questionnaires such as the one this year is ample evidence of the interest these create. This year's topic is unlike those of past years since it is an attempt to understand a new concept of grinding rather than to improve the old. Before, we were thinking in terms of 2-5 cents improvement in grinding costs, now we will be discussing savings of 15-2 5 cents. As a background for this forum we will begin by summarizing the major controversial issues relating to grinding with steel, many of which will undoubtedly apply to pebble milling. Our •task to-day is to learn what has already been done in pebble milling and obtain a fair overall view of this method of grinding.

Jan 1, 1961

By Peter A. Hacquebard

Recent drilling programs have shown that the in-situ coal resources of Nova Scotia are very substantial. The grand totals of the measured, indicated and inferred categories amount to 232 m, 646m and 993 m tons, respectively. This vast quantity of coal occurs essentially in five main fields: Sydney, Mabou, Port Hood, Pictou and Springhill. The largest resources (84% of the total) occur in the submarine area of the Sydney coalfield. With a 65% recovery rate, there are at present 150m tons of proven, recoverable coal in Nova Scotia. At a predicted maximum annual production of 5 m tons, this amount equals a lifespan of 30 years. However, additional drilling, particularly in the Sydney offshore area, holds promise of increasing the recoverable reserve tonnage to at least 350 m tons. This figure may be compared with the 484 m tons production obtained during 191 years of mining (from 1785-1976). The geological appraisal of the remaining coal resources in the five fields mentioned is presented in three-dimensional diagrams, per individual seam and corresponding reserve area. In addition, the submarine extensions of the Sydney and Mabou coalfields are discussed in light of results obtained from off shore oil exploration wells. The terminology and standards of coal resource calculations are pointed out, and the phenomenon of seam splitting and its prediction from geological data is illustrated. The availability in Nova Scotia of either thermal or metallurgical coal is considered in relation to rank and sulphur content. This paper was presented in June 1977 at the 90th Annual Meeting of the Mining Society of Nova Scotia. The coal resource estimates, however, have been updated to include the results obtained with the offshore drilling in the Sydney Coalfield to November 1977.

Jan 1, 1979

By Matthew R. Ward

This paper aims to describe the reasons and methods to extend enterprise networks into underground mines. Currently mines use a number of communication networks for telephones, PLCs, two-way VHF radio and computer networking. Each system can have different wiring, protocols, converters and interfaces all which require expansion and maintenance. The convergence of voice, video and data using Ethernet and TCP/IP has the very real benefit of one ?wire? for underground networks. Now that the majority of underground equipment can communicate using TCP/IP, network convergence can offer reduced network expansion and maintenance costs. Cost savings are good, but the truly exciting aspect of network convergence using Ethernet is the low-cost, high speed wireless networking now available . These wireless networks offer an opportunity to facilitate mining automation even on a small budget. How would mine operators change they way they operate if they could gather vehicle location and data in real time? What about controlling equipment remotely? The list of applications is long and includes traffic control, dispatching, real-time ore blending, tele-operation, automated production reporting, vehicle health monitoring, elimination of paper forms and immediate network access for surveyors and geologists. An ideal converged network for underground mining would be robust, inexpensive, easy to expand, enable fast and secure connections while keeping voice communication performance equivalent or better than what is now provided by VHF radio

Apr 1, 2005

By N. Romani, R. Provost

"Commissioning of a circulating dry scrubber plant was recently completed at an existing facility, in order to treat the sulphur dioxide off-gas emitted from rotary kilns. Proper planning of the different commissioning stages and staffing an integrated team are the most important factors required for a successful plant start-up. A strong operational readiness plan must be in place as early as the start of construction in order to ensure a smooth transition from commissioning to operations. Plant performance can meet or exceed performance criteria within the required timeframe if the proper group dynamic and good communication is established between construction, commissioning and operations teams.INTRODUCTIONCommissioning of a circulating dry scrubber (CDS) plant was recently completed at an existing facility in Quebec, Canada. The CDS plant treats the sulphur dioxide off-gas emitted from rotary kilns in order to meet increasingly stringent environmental requirements. This installation enables the existing facility to reduce their sulphur emissions by over 90%.The CDS ProcessA general overview of the CDS process is presented in Figure 1 below. The combined, de-dusted off-gas from multiple kilns is sent to the CDS, which acts as an entrained fluid bed, where the gas is contacted with a water mist, re-circulated solids and hydrated lime. The SO2 from the gas stream and the available calcium hydroxide (Ca(OH)2) from the hydrated lime dissolve in the water and react to ultimately form calcium sulphites and gypsum. The solid residue (referred to as CDS residue), is the primary byproductof the process.Fresh hydrated lime and CDS residue is captured by the dust collection system and is re-circulated to the CDS via a fluidised transport system. Clean off-gas passes through the dust-collection system and is then sent to the atmosphere by a single exhaust fan.The CDS residue purged from the system is combined with the dust collected from the kiln offgas system and this mixture is wetted in the already exiting agglomeration system, to minimize dust generation during handling, and then sent to disposal."

Jan 1, 2016

By C. L. Emery, A. V. Corlett

"The stress equilibrium is disturbed in a body of rock by a mine opening and is restored by a redistribution of the stresses around the opening. The pattern of the redistribution of unilateral stress around an opening has been established by mathematical analysis and photoelastic measurements. The pattern for multilateral stress is found by superimposition of unilateral fields. The mathematical analysts do not use the elastic moduli as parameters and they are not significant in photoelastic work. The medium is isotropic. The concept of unilateral stress from vertical loading and the classical pattern of its stress distribution around openings does not explain commonly observed failures around the perimeters of mine openings. They show evidence of compression where tension is postulated.When it is recognized that few minerals and perhaps no rocks are Hooke Solids, most rocks must be St. Venant Solids. The components have varying degrees of elasticity and viscosity. The assembly will be-have elastically to rupture under shock loading, but when loaded short of rupture will adjust viscously to equilibrium. Similarly, the highly elastic components may initiate rupture before equilibrium can be established when stress is instantaneously relieved. Polycrystalline adjustments may produce permanent deformation. The mechanics of consolidation, especially in sedimentary deposits, ac-quire a stress component normal to the direction of compaction which can exceed that of the loading. It is one source of prestress. There are others. The principles of prestress design are based on the normal beam reactions, modified by a built-in compression in the lower chord. When the beam is loaded to design limits, the lower chord retains some compression and the whole beam depth is effective in compression. Some of the . common evidences of failure in compression over a mine opening can be duplicated in a prestressed experimental model.When the triaxial stress pattern is recognized and suitable measuring techniques are devised, mine design can be done on a rational basis."

Jan 1, 1959

By N. Aslin, G. Heferen, H. DeWaal

"Mount Isa Mines (MIM) acquired a reputation for the successful application of R&D to develop break-through technologies for the mining industry starting in the 1978’s through until the early 2000’s. The ISAPROCESSTM tank-house technology has been licensed to copper refineries throughout the world, and a significant per cent of the world’s copper is refined using this technology. Since development in the late 1980’s more than 20 ISASMELTTM copper and lead smelting furnaces are now installed in countries around the world. Jameson Cell flotation technology developed jointly by Mount Isa Mines and Professor Graeme Jameson is widely used in the Australian coal mining industry and increasingly in the base-metal and gold industry. The IsaMillTM’s developed at Mount Isa and McArthur River made it possible to develop the McArthur River and George Fisher orebodies and has been successfully implemented into base metal fine grinding applications around the world. The most recent commercialised innovation is the atmospheric leach Albion ProcessTM with its supersonic HyperSpargeTM gas sparger, is being adopted as a solution to the increasing complexity of orebodies. MIM’s contribution to the industry was significant given the size and the remote location of its operations with Townsville Copper Refineries more than 1350 km and Mount Isa 1800 km from the nearest state capital of Brisbane. This paper will briefly discuss the development of each of these technologies and why MIM – now owned by Glencore - was so successful innovating and developing such technologies over a period of nearly 40 years.INTRODUCTION Mount Isa is located in the Gulf Country region of Queensland about 1800 kilometers North West of Brisbane (see Figure 1). It came into existence because of the world class mineral deposits found in the area. In 1923 the orebody containing lead, zinc and silver was discovered by the miner John Campbell Miles. Mount Isa Mines Limited (MIM) was founded in 1924 to develop the minerals discovered by Miles, but production did not begin until May 1931. It paid its first dividend in 1947 after 16 years of troubled production. In 1954 the 1100 copper orebody was discovered and with rapidly rising reserves during the 1950’s and 1960’s led to the construction of new concentrators to treat lead/zinc/silver ores in 1966 (#2 concentrator) and copper ore’s in 1973 (#4 concentrator). The difficult nature of the Mount Isa lead-zinc orebodies has meant that the company had always needed to be at the forefront of mining technology. In the 1970’s through to the 1990’s, it became a world leader in developing new mining techniques and processing technologies as a response to declining metal prices and rising costs. Mount Isa has been smelting copper since 1953 and lead since the early 1930’s. Copper Refining at Mount Isa’s fully owned subsidiary of Copper Refineries Proprietary Limited (CRL) had commenced operations in 1959."

Jan 1, 2018

By Karl J. C. Harries

"7.1. INTRODUCTIONThis chapter addresses the joint venture and examines a number of general concepts of the joint venture relationship. Chapter 8 looks at some specific concepts related to the provisions of a joint venture agreement, which are equally applicable to a shareholders’ agreement or other contractual relationship. The term “joint venture” is used because the author is a common law solicitor (a matter of convenience for which apologies are offered to civil law readers), but it should be noted that, in many aspects, the legal structure of an entity is irrelevant. It is the relationship of the parties, be they venturers or shareholders, that is important, and the areas of concern are surprisingly similar (except for terminology).The details of the joint venture relationship and agreement could fill several books. Accordingly, this chapter and the next focus on selected topics that appear to have caused problems or confusion or to be the basis for disputes. And remember that, although the following discussion is in the context of a joint venture, many of the comments apply, either directly or indirectly, to virtually any common undertaking and the agreement defining it.For interest’s sake, this chapter starts with a summary of some of the earlier types of agreements and arrangements that have evolved into the joint venture agreement of today in Canada, the philosophy of their format, and the reasons for their demise.7.2. EVOLUTION OF THE CANADIAN JOINT VENTUREThe Early DaysMuch of the opening up of Canada’s north is due to exploration for and development of mines. The early discoverers were relatively free to roam and explore at will and, if they were fortunate enough to find something, they dealt with the appropriate government to acquire exploitation rights. The early interests lay in gold or silver. Workings were small, usually worked by the owner alone or with only a couple of helpers to extract the native gold or silver. If the owner wanted to move on, he could sell his property outright and use his stake to look elsewhere.As logging and mining camps were opened, the development of better roads and railways made access easier. Entrepreneurs saw the opportunity to make money by assembling large parcels of land and working them as a single operation. In order to do this, some owners who were not ready to sell out had to be convinced to do so through more attractive offers"

Jan 1, 2003

By D. J. McCulla

Mineral development and utilization affect the health of the economy and the pattern of long-term development throughout Canada. There are many diverse opinions on the contribution of minerals to the economy, but there is a dearth of adequate quantitative information. This paper discusses some recent research and provides some new information.

Jan 1, 1977

By A. O. Sfriso

"Numerical modelling is becoming universal in rock engineering practice. Most applications focus on the prediction of failure loads of 2D problems, where the numerical models are useful extensions to analytical methods and experience-based design criteria. For 3D problems and problems where the assessment of serviceability indicators – displacements, ground-structure response, etc. – are of importance, the selection of the constitutive models themselves and the implications of the selection of material parameters may have a very heavy impact on the reliability of the model outcome and its predictive capability.This paper overviews basic common aspects of constitutive equations used in practical rock engineering and summarizes some challenges that are frequently observed when reviewing numerical models performed for routine problems in rock engineering. INTRODUCTIONNumerical methodsFrom a philosophical perspective models, either analytical or numerical, are idealizations of a perceived reality. For us engineers, models are just tools we use to guide our judgement and understanding of the problem in hand. When dealing with problems in rock engineering, we resort to a wide range of techniques:1. Closed form solutions like confinement-convergence methods for circular tunnels: these methods satisfy equilibrium and compatibility requirements at the cost of a crude simplification of the material behavior and geometry;2. Limit analysis methods, like bearing capacity formulas: lower bound methods satisfy equilibrium but sacrifice compatibility, and upper bound methods do the opposite. Material behavior must be simple, geometry admits limited freedom;3. Limit equilibrium methods, like method of slices for slope stability: they satisfy restricted forms of equilibrium, do not satisfy compatibility requirements, require simple material behavior but have a much greater flexibility on geometry;4. Numerical methods, where a mesh is employed to discretize the problem geometry: when properly formulated, these methods satisfy equilibrium and compatibility requirements and give reasonable approximations to the behavior of very complex geometries and construction sequences. Very little restrictions remain on geometry and material behavior, but the cost of calibrating the material parameters can be very high."

Jan 1, 2015

By D. A. Livingstone

Abstract Golden Manitou Mines, Limited, nine miles east of the town of Val d'Or in northwestern Quebec, are presently milling, at the rate of 1,000 tons daily, a relatively complex 3.11-phide ore and producing, in decreasing order of value, zinc, silver, gold, lead, and copper. The products are a zinc concentrate, a silver-lead-copper concentrate, and a silver-gold precipitate from cyanidation. Although several independent pre-production metallurgical investigations into the treatment of the ore were carried out, current practice is different from any of the recommended methods and, while still leaving room for improvement, is considerably more effective than earlier performance. Flow-sheet developments from the commencement of operations in 1942 are dealt with briefly, showing the reasons for making numerous changes, the shortcomings of the various schemes tried, and, finally, covering data pertinent to present-day practice. From the recovery standpoint, silver has presented the greatest difficulty. The writer's association with the Company coincided with the start of production. Characteristics of the Ore The predominant metallic minerals present in the ore, in decreasing order of their abundance, are: pyrite, sphalerite, galena and chalcopyrite, with lesser amounts of argentiferous tennantite-tetrahedrite, arsenopyrite, covellite, bornite, and chalcocite. The sphalerite is mostly light in colour, sometimes colourless, and practically free from combined iron. Some of the sphalerite is very closely associated with minor amounts of pyrite, chalcopyrite, and galena. Pyrie is abundantly disseminated as medium to fine grains; more rarely it is massive and contains occasional grains of sphalerite, galena, and chalcopyrite.

Jan 1, 1952