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By David R. Winfield

I would like to thank you for spending the time with me today to review the FLIR PathFindIR thermal imaging camera system: It is truly an innovative safety system that has the added benefit of offering increased efficiency Our company the Winsted Group, specializes in mobile video systems that are fully customizable to address standard and unique operational requirements in a variety of industries from heavy equipment cameras to police and military digital recording systems, high end video camera systems are a hallmark of Winsted?s product line. The use of thermal imaging camera systems to enhance mobile safety is a relatively new concept as it relates to their use in both transportation and heavy equipment operation. This technology, like so many before it, has been adopted for civilian use from its military roots. The identification of enemy combatants through their heat signature has given our troops a decisive edge in military operations in total darkness Likewise, the ability to discern people and objects that give off heat is a significant step forward in collision and accident avoidance. The PathFindIR camera system that I am demonstrating today is so advanced that it cannot be exported outside of continental North America without a US government approved export license I would like to commence my presentation with a short video clip that discusses the technology associated with the FLIR PathFindIR Thermal Imaging camera systems. The video demonstrates the operational effectiveness of thermal imaging camera systems installed on a vehicle operating on the roadway at night, of course there are definite parallels to use in a mining environment, primarily the fact that lighting is limited and the chance for vision limiting dust is ever present. We are, of course more concerned with personnel safety in our mines than encountering wildlife on the roadside. From the same perspective, the transport driver is just as concerned with encountering a stalled vehicle as our mine truck operators are with other mine traffic.

Feb 1, 2008

By Martin Plante, Denis Hamel, Marie-Pier Bédard, Jeff McLaughlin

"The results and methodology for the optimisation of the zinc flotation circuit at the Matagami Mill using the 6-Sigma methodology are shown in detail while only the base line and final results are presented for the copper circuit. As a result of the six sigma project, the zinc concentrate grade was improved by 2% and the zinc recovery by 3%, with reduced dosage of reagents while the copper concentrate was improved by 2.4%. The process variation in the zinc concentrate grade and recovery was also reduced by over 50%. The main factors contributing to the project success were identified to be improvement in the plant measurement systems, an internal benchmarking exercise and statistically designed laboratory and in plant tests to guide the process improvement. The annual value to Noranda resulting from this project has been estimated at approximately $5 million.INTRODUCTIONThe Matagami concentrator started ore processing from the new Bell- Allard deposit in July 1999. Concentrator performance (grade and recovery of zinc and copper concentrates) was highly variable and work was ongoing to fix the sources of variation. In the mean time, Noranda embarked on its 6-Sigma initiative across the company. The 6-Sigma DMAIC (Define, Measure, Analyse, Improve, Control) methodology was used in the two flotation circuits to reduce variation and improve performance. The statistical 6-Sigma methodology moves towards identifying and controlling critical process operating variables (the X' s) to achieve customerspecified performance (the Y's). The goal of the methodology is to describe a process in a numerical equation known as the transfer function, given as Y = f (XI, X2, X3.. .), where Y could be concentrate grade or recovery and examples of X's are reagent dosage, particle size, etc. With the transfer function, optimal operating conditions and control tolerances are established for the key X's to ensure the desired Y performance is obtained.Each phase of the 6-Sigma methodology is explained below with examples from the Matagami project."

Jan 1, 2001

"The ventilation-related risks from mines with elemental sulphur include dust explosions, spontaneous combustion with emission of heat and toxic sulphur dioxide or hydrogen sulphide gases, reactions with nitrates, corrosion, acid water, and pyrophoric reactions with naked iron or other metals. Elemental sulphur will form explosive mixtures in air at lower dust concentrations and at lower ignition temperatures than coal or sulphide dusts. Potential controls include primary ventilation circuit design, control of dust deposition and static discharges, enclosing steel surfaces, inert stone dusting, FRAS ducting, humidifying the air, alternate stench gas, self-contained self-rescuers with goggles, careful siting of underground infrastructure, controls on explosives formulations and procedures, mining method selection, controls on surface temperatures and protection of equipment, careful materials selection for ventilation seals and changes to worker clothing and training.INTRODUCTIONSulphur (“Brimstone” in biblical times) is one of the world’s most important industrial feedstocks and is used in a wide range of chemical processes and industries. Until the early 20th Century, most of the world’s production of sulphur came from ‘conventional’ underground mines in Sicily (Demetra produzioni, 2006; Bellia, 2006). This was a hazardous activity. The Frasch solution mining process replaced traditional underground mining of sulphur until the late 20th Century. Most of the world’s production of elemental sulphur is now as a by-product from sour gas produced in petroleum refineries and natural gas installations (Anon, 1993). As such, there is considerable experience in understanding and managing the hazards of elemental sulphur in chemical plants and surface transport.Whilst rare, underground mines with high elemental sulphur contents (as a gangue mineral) create an unusual range of mine design and operational issues, including many ventilation-related ones. The key hazards from elemental sulphur include: primary and secondary elemental sulphur dust explosions, fires and burning (with emission of heat and sulphur dioxide or hydrogen sulphide gas), reactions with nitrates used in explosives, corrosion of steel and other metals, generation of acid water (especially at higher water temperatures), and pyrophoric reactions with naked iron (e.g., ground support, ladderways or underground fixed plant) or other metals including silver and copper (e.g., used in electrical components and equipment)."

Jan 1, 2019

By R. R. Klimpel

"SYNOPSISA discussion of the importance of flotation rate in the analysis of mineral flotation is presented. In particular, the highly interactive nature of the flotation ""system"" is emphasized where there are components of chemistry, equipment, and operating conditions simultaneously involved. It is further shown that: 1) flotation rate must be measured in order to economically optimize the performance of an industrial flotation circuit, 2) that consistent patterns exist in both flotation rate and equilibrium recovery when changing various settings of the system components, 3) that knowledge of these patterns is necessary in order to avoid making system changes that are either self-compensating or dramatically re-enforcing in some particular aspect of performance, and 4) the rate related role of the chemistry component (e.g.frothers and collectors) is often much bigger than is sometimes realized (especially in a negative sense involving overdosing of reagents). INTRODUCTIONFroth flotation is widely usedl-6 in mineral beneficiation processes as a method for separating different types of finely divided solids present in a liquid (usually aqueous) suspension. The approach is based on the contacting of solids with upward moving air bubbles in an agitated vessel where the solids are exposed to chemicals (collectors) which create a condition favoring the attachment of a certain portion of the solids to the air bubbles. This selected portion is then removed in a froth stabilized by chemicals (frothers) and subsequently recovered from the flotation vessel. Depending on the settings of the various components of the flotation ""system"" (see Figure 1) it is possible to achieve a wide range of flotation performance."

Jan 1, 1984

By L. Dorador

"In block caving projects, the rock mass fragmentation process plays a controlling role in the design and success of the operation. Poorly understood, however, is the secondary fragmentation that occurs as blocks of caved ore move through the draw column and interact with one another. The initial size of these blocks can be considerable, as can their strength and stiffness as the presence of non-persistent joints and veining will be variable. Intuitively, more planes of weakness within the blocks should facilitate early fragmentation, but this assumption could depend on additional factors such as contact type between adjacent blocks and loads imposed through varying heights of the draw column. This paper reports the findings from a laboratory investigation examining the role of block strength and planes of weakness on secondary fragmentation. Testing was carried out on small-scale concrete cubes of uniform size, with and without embedded planes of weakness. The results obtained demonstrate the significance of veining and other planes of weakness on secondary fragmentation under one-dimensional compression, and allow for the development and constraint of empirical guidelines.INTRODUCTIONThe fragmentation process during block caving involves the initial (primary) fragmentation of rock in the cave back through stress-induced fracturing, release and fall of individual blocks onto the broken ore muck pile. This is followed by secondary fragmentation involving splitting and rounding of blocks as they move downwards through the draw column towards the draw point. The degree of secondary fragmentation achieved involves many variables related to the mechanical properties of the rock blocks as well as different operational factors. With respect to the block properties, the presence of planes of weakness in the form of veining and non-persistent joints is a topic of special interest given the significant influence it potentially has on the overall fragmentation process. However, the inherent heterogeneity and variable size of individual blocks generated from the cave back makes it difficult to develop any empirical relationships relating secondary fragmentation to compressive loading based on insitu observations and mine data. More preferable would be to keep constant block parameters, such as shape (aspect ratio and angularity) and size, through controlled laboratory testing. This work presents an efficient technique to fabricate concrete cubes in order to keep constant different block properties. These are then tested under one-dimensional compressive loading. The objective of these tests is to emulate a tight packing condition of single blocks such as that which would occur when the air gap between the cave back and broken ore in the draw column is small. When the air gap is small, detached blocks are unable to fall and rotate but instead maintain a very tidy arrangement with minimal voids left between adjacent blocks."

Jan 1, 2015

By Paul Guliov

Potash dominates the industrial mineral scene in Saskatchewan accounting for 44% of total provincial mineral production in 1981. More than 7 million tonnes of potash have been produced annualy in recent years; ten underground mines are presently (1983) active. Sodium sulphate and cement are also important mineral products. Construction aggregates, clay products, bentonite, salt, peat moss and sulphur complete the list of industrial mineral products.

Jan 1, 1984

By S. C. Radopoulou

Pavement condition assessment is an indispensable constituent in maintaining roadway infrastructure. Current practices for pavement condition assessment are labor intensive which introduce subjectivity in pavement rating and are time consuming. Automated methods rely on full 3D reconstruction of the pavement surface which introduces high equipment and computation costs. This paper presents a methodology for detection of patch type distresses in asphalt pavement images. This method uses filtering and histogram equalization for clearing and enhancing the image accordingly. It continues by applying the morphological process of closing, along with some rules based on the characteristics of a patch when captured in an image, to finally detect the area it occupies. Criteria for area, length, and width of a patch as seen in an image are taken into account to decide whether a probable patch is actually a patch. The method has been implemented in C#. The preliminary experiments demonstrate it produces promising recognition results

Aug 1, 2013

By Matthew Scott

Introduction The refining of precipitate is the final stage of all the processes involved in gold mining and cyanide milling, by which the precious metal is at last obtained in a concentrated form, which can be accurately valued and marketed. Possibly one ought to say, conveniently shipped, for accuracy in valuation depends in many instances on a toughening treatment given the bars as received at the Mint so as to obtain a homogeneous metal that lends itself to representative sampling; which, of course, entails a surcharge on the regular Mint charges for the extra work necessarily undertaken. There are several methods of refining zinc-gold precipitate, each with its advocates; the method employed depending not always on the quality of the bullion produced but on the local exigencies of the case in point. These methods are more or less detailed in various textbooks and it is not the purpose of this paper to discuss them, but to confine ourselves to the specific case as stated in the title of the paper. At the outset, it behooves the writer to express his thanks to Mr. Brigham, the General Manager of the Hollinger Mines, for the kindly consideration and encouragement given in developing this process. This will be better understood when one considers the immense values involved, tending towards conservatism in practice, and making one chary of radical innovations. This process has been in satisfactory operation now for about two and-a half years, during which time over twenty-five million dollars value in fine gold has been produced, so that it may be reasonably held that the process is successful.

Jan 1, 1931

The SART (sulfidisation, acidification, recycle, and thickening) process is an effective way to separate copper and cyanide from each other in the waste stream of gold processing plants using cyanidation. Factorial experimentation has been conducted to create models of copper recovery, cyanide recovery, acid addition, and oxidation I reduction potential during SART. Economic analysis of the resultant models showed that SART is best operated with a sulfide to copper molar ratio of around 0.56, a pH of 4, and a minimised cyanide to copper molar ratio. The experiments also showed that thickening time may have drastic impacts on SART performance.

Jan 1, 2011

By P. Tukkaraja, K. Katzenstein

"Block caving is one of the most economical and efficient underground mining methods and has gained popularity around the world especially for extracting low grade and massive ore bodies. However, during the extraction of ore from the draw bells, gases trapped inside the cave could emit into the working areas; hence, ventilation plays a key role in operating block cave mines successfully where gas emission is a concern. To design an effective ventilation system for a block caving mine, given the dynamic nature of the caving process, it is necessary to develop airflow characteristic curves (P-Q) for a given cave. This study uses a 1:100 scale physical model with an exhaust fan system, and a Computational Fluid Dynamics model of a block cave to investigate the airflow behavior through the cave filled with broken rock material. From this study, it was observed that the cave airflow resistance increases with the decrease in cave porosity and the particle size.INTRODUCTIONThe block cave mining method is gaining popularity owing to its low cost and high productivity. This study considered a case where this bulk mining method is used for the extraction of an orebody that contains uranium mineralization. During the extraction of broken ore from the draw bells, radioactive gases trapped in the cave zone could be released into the production drifts and could create unsafe working conditions in the mine. Mine ventilation systems play an important role in regulating the migration of radon in working areas. One of the strategies to control radon migration in a block cave mine is to exert negative pressure on the cave zone by using an exhaust fan above the cave zone. In order to select an appropriate exhaust fan system, it is necessary to study the airflow resistance of the cave zone (Loring & Nelson, 2006).Extraction of broken ore via drawpoints creates a void volume inside the cave called the air gap. Air gaps with larger heights can lead to air blasts in a block cave mine should the cave collapse. Besides that, the air gap can also lead to decrease in ventilation system efficiency due to recirculation of air flow and associated shock losses. Air gap height can also have a profound effect on the variation of cave airflow resistance (Erogul et al., 2015, 2017). The knowledge of cave airflow resistance is also important for predicting the intensity of an air blast. Cave airflow resistance is a function of cave properties such as broken rock size, air gap, and porosity inside the cave zone (Baysal et al., 2017). Initially, a scaled experimental model with a forcing system was developed to investigate the airflow behavior through the cave, however, this model couldn’t provide an observable change in the airflow resistance when the cave properties were changed (cave porosity, and airgap) This was attributed to the difficulties associated with forcing system in terms of achieving lower porosity values with the available material (lightweight shipping boxes) for simulating broken rock inside the cave zones, and controlling air leakage from the model (Ajitha et al., 2018)."

Jan 1, 2019

By Gheorghe Marin, Franco Chiesa, David Levasseur, Bernard Duchesne

Over the past 20 years, pressure die casting has evolved to a point where structural parts can now be produced by this process. This has been made possible by the development of vacuum die casting and by the development of die-castable, low iron content alloys. This resulted in the production of low porosity, weldable die-cast parts on which heat treatment may be applied. In the present paper, the influence porosities on the tensile properties of as-cast A360 tensile test bars was evaluated. This was done by casting 24 clusters, comprising three 6mm diameter test bars each, in a 280T cold chamber pressure die casting machine after a steady dynamic equilibrium had been reached. Modeling of filling allowed to explain the differences in porosity observed in the 3 samples of a same cluster while the results of solidification modeling were related to the microstructure. Tensile samples were radiographed on a real time X-cube apparatus and separated into 2 lots: samples where no porosity defect were visible and samples with visible defects. By measuring the tensile properties of the 2 lots it was possible to quantify the drop in tensile properties brought about by porosity, which is the most common defect observed in pressure die-cast parts.

Jan 1, 2015

By M. G. Stamatakis, C. Zagouroglou, C. Helvaci, J. Kanaris

"Abstract -Borate minerals, such as colemanite, ulexite and borax, have been reported in Tertiary continental basins of West Anatolia, Turkey, and Samos Island, Greece.Tuffaceous rocks interbedded with the borates are rich in authigenic silicate minerals such as zeolites, potassium feldspar and opal-CT, all of which have a genetic association with the borates. Chemical analyses of the tuffaceous rocks show variation in major elements due to the varying percentage of carbonaceous, detrital, and volcanic derived material.The volcanic activity in the vicinity of each particular lacustrine basin created ion-rich fluids from which a series of borates were precipitated under arid climate. Additionally, the saline-alkaline character of these fluids was responsible for the diagenesis of the silicic glass of the tuffaceous rocks, altering them to silicates and silica polymorphs."

Jan 1, 1993

By H. D. B. Wilson

"IntroductionRECENT ADVANCES in geo-chemistry and in •our knowledge •of crystal structure provide a key which enables us to create a systematic picture of the genesis of many ore deposits. This genetic scheme may be used with confidence in assessing certain types of orebodies and may be of some aid in actual exploration, since it affords a rational explanation of the dependence of the composition •of the ore minerals on that of the rock type in which they occur with which they -are •associated. For purposes of the present paper, .the elements chosen are •chromium, vanadium, iron, and titanium. The oxides of all these metals occur in deposits of similar or related type, and it is proposed to show that, for each, the composition of the •ore mineral is related to •the composition of the enclosing :rock, and that one of the principal factors controlling the composition of the ore is the ionic size of its constituent elements.Geochemical PrinciplesThe crystals of the rock-forming silicates and of the magmatic oxide minerals are essentially ionic types. This means that they are composed •of oppositely charged ions such as Mg²+ and 0²-, which are held together by electrostatic attraction. The ions of each element are spherical, with characteristic size known as the ionic radius. Crystals are built up by the packing of these spheres in the most stable arrangement compatible with the size and the size and valence of the ions• involved.Many of the principles governing the formation of ionic crystals are •simple ,and logical."

Jan 1, 1953

By Raymond Dallaire

The Humphrey's spiral is a static gravity separation device which cannot be adjusted to match short-term variations that occur in the feed. Any disturbance in the feed grade, per cent solids or flow rate affects substantially the recovery and grade of concentrate. Such variations must be minimized in order to maintain the desired rate of production and quality of the product for which the installation has been designed. A study has been performed in which the foregoing assertions were quantified. The feed grade, per cent solids, flow rate and particle size were varied independently. Ore from Carol Lake, Nfld., was used throughout the experiments. This consisted of specular hematite and magnetite in a silica gangue.

Jan 1, 1978

By A. R. Barnes, N. O. Lotter

Recoverable economic copper sulphide minerals such as chalcopyrite, bornite, chalcocite and covellite often occur together in varying proportions in the major copper-bearing ores, and have individual flotation requirements and characteristics. Pyrite also occurs in these ores to varying extents as the sulphide gangue, and is problematic because of its natural tendency to float quickly and easily. In a bulk sulphide float, selectivity against pyrite is desirable, particularly if it does not host other paymetals such as gold or silver. At the same time it is a requirement to float all of the copper sulphides despite their electrochemical differences. The electrochemistry and semiconductor properties of these minerals are reviewed, together with implications for flotation with and without collector addition. Mixed collector systems for the improved flotation of these sulphides are proposed as a solution. The use of xanthate and dithiophosphate in the collector suite allows the co-existence of dixanthogen and free dithiophosphate radical because the latter has a higher redox potential requirement than xanthate to oxidise to the dithiolate. Because some of these minerals require dixanthogen, and others, free thiolate, to generate surface hydrophobicity, a bulk flotation of all the species becomes possible in the overlapping area of Eh and pH between the two dithiolate equilibrium lines on the Pourbaix diagram. The arsenic-signature copper minerals are added to the study, since many copper operations encounter arsenic as a penalty element in the saleable concentrate. It is shown that the addition of arsenic to the copper and iron sulphides alters the semiconductor and electrochemistry properties, and in turn, its flotation characteristics. The degree of mineral association and liberation between these minerals can be a complicating factor due to textural associations, and should also be considered in the process as a next step.

Jan 1, 2016

By J. Esson, R. A. D. Pattrick, M. K. Nimfopoulos, D. A. Polya, K. M. Michailidis

"Abstract-Economic Mn-oxide ore deposits of commercial grade occur in the Rhodope massif near Kato Nevrokopi in the Drama region, Northern Greece. The Mn-oxide mineralization has developed by weathering of continental hypogene rhodochrosite-sulphide veins. The vein mineralization is confined by tectonic shear zones between marble and metapelites, extending laterally into the marble as tabular, pod or lenticular oreshoots (up to 50 m ?? 20 m ?? 5-10 m). Supergene oxidation of the hypogene mineralization led to the formation of in-situ residual Mn-oxide ore deposits, and secondary infills of Mn-oxide ore in embryonic and well developed karst cavities.Whole rock geochemical profiles across mineralized zones confirm the role of thrusts and faults as solution passageways and stress the importance of these structures in the development of hydrothermal and supergene mineralization at Kato Nevrokopi. Three zones are recognized in the insitu supergene veins: (A) a stable zone of oxidation, where immobile elements form (or substitute in) stable oxide mineral phases, and mobile elements are leached; (B) a transitional (active) zone in which element behavior is strongly influenced by seasonal fluctuations of the groundwater table and variations in pH-Eh conditions; and (C) a zone of permanent flooding, where variations in pH-Eh conditions are minimal. Zone (B) is considered as the source zone for the karst cavity mineralization. During weathering, meteoric waters, which were CO2-rich (PCO2 ~10-3.8 to 10-1.4) and oxygenated (fO2 ~10-17 for malachite), percolated downward within the veins, causing breakdown and dissolution of sulfides and marble, and oxidation of rhodochrosite to Mn-oxides. Karst cavity formation was favored by the high permeability along thrust zones. Dissolved Mn2+ was transported into karst cavities in reduced meteoric waters at the beginning of weathering (pH~4-5), and as Mn(HCO3)2 in slightly alkaline groundwaters during advanced weathering (pH~6-8). Mn4+-oxide precipitation took place by fO2 increase in ground waters, or pH increase by continuous hydrolysis and carbonate dissolution. In the well developed karst setting, some mobility of elements occurred during and after karst ore formation in the order Na>K>Mg>Sr>Mn>As>Zn>Ba>Al>Fe>Cu>Cd>Pb."

Jan 1, 1997

By Jose R. Hernandez-Aguilar

"Three models to predict the effect of bubble size (Db) on metallurgical response were tested in a pilot-scale flotation column at Teck Highland Valley Copper mine. The column was fed with slurry collected from the Cu/Mo separation circuit. The first model was the one developed by Gorain et al. (1997), which assumes that the collection zone rate constant (kc) is inversely proportional to Db. The second model was the one proposed by Hernandez-Aguilar et al. (2010), which considers kc as an inverse square function of Db. The third model was the one developed by Yoon and Luttrell (1989) which provides expressions to describe the efficiency of particle collection (E) based on first principles. The results showed a significant bias between experimental and predicted data using the model of Gorain et al. (1997), possibly reflecting the model’s inability to explain the impact of bubble size, bubble rise velocity and flow regime on E. The model of Hernandez-Aguilar et al. (2010) well described the experimental evidence. The model of Yoon and Luttrell gave accurate and unbiased predictions. However, Yoon and Luttrell’s approach calls for a criterion to determine whether the flow regime is potential or intermediate, a subject that requires more fundamental research.INTRODUCTIONParticle collection, i.e., bubble-particle collision followed by attachment, is the basis of flotation. In a quiescent environment (such as the one observed in a column, or away from the impeller in a mechanical cell), a collision event can take place as long as the “degree of turbulence” caused by the rising bubble does not prevent particle and bubble to flow in close proximity. Upon collision, the particle slides on the bubble surface for a period of time. If the particle is hydrophobic, attachment occurs when the “sliding time” is longer than the “induction time”, which is the time required to thin and rupture the intervening liquid (usually water) film forming a three-phase contact angle. While the induction time is largely influenced by the degree of hydrophobicity of the particle, the degree of turbulence is governed by the bubble size. Generally, direct control of bubble size is not exercised by most mineral processing practitioners, in spite of its obvious importance. Studies to model the effect of bubble size on particle collection using fundamental approaches have been conducted (e.g., Anfruns and Kitchener, 1977; Webber and Paddock, 1983; Yoon and Luttrell, 1989; Dai et al., 1999). However, these models have been validated under highly idealized laboratory conditions (micro-scale experiments using single minerals and uni-sized bubbles), far from resembling those existing in practical industrial applications. Fundamental studies to interpret the effect of bubble size on particle collection in industrial environments are largely absent in the literature. Partly because of this lack of practical knowledge, many mineral processing practitioners perceive laboratory “bubble size” studies to be valuable academic exercises, but not something that can be directly applied to daily production issues."

Jan 1, 2011

By B. E. Shaw

This paper describes the use of the Free Piston Valve, and a simple hoist brake control system, which has been developed over the last two years, greatly improving the performance of low-pressure brake engines. The basic control system is outlined, with sections devoted to emergency trips and differential braking, and the application of the system to deep shaft hoisting is discussed.

Jan 1, 1966

By R. P. Chapman

The geochemical interpretation of results of statistical analysis of published multi-element stream sediment data from southwest and northern New Brunswick is presented. Element concentrations in southwest New Brunswick are low and comparable to element concentrations in background areas in northern New Brunswick. Deposits of copper and nickel are indicated in southwest New Brunswick. Anomalous element concentrations occur in several areas in northern New Brunswick and the elements most commonly associated with these anomalies are Cu, Pb, Zn, As and Ag; and also Mo, Wand Sb. Bedrock geology greatly influences element concentrations and may cause false anomalies. Manganese has a pronounced effect on the dispersion patterns of Co and also Zn, Mo, Pb, As, Ba and Ni. Nickel and Cr are strongly sympathetically related and this association is independent of bedrock type.

Jan 1, 1977

By J. Esson, R. A. D. Pattrick, M. K. Nimfopoulos, D. A. Polya, K. M. Michailidis

"Economic Mn-oxide ore deposits of commercial grade occur in the Rhodope massif near Kato Nevrokopi in the Drama region, Northern Greece. The Mn-oxide mineralization has developed by weathering of continental hypogene rhodochrosite-sulphide veins. The vein mineralization is con-?ned by tectonic shear zones between marble and metapelites, extending laterally into the marble astabular, pod or lenticular oreshoots (up to 50 m x 20 m x 5-10 m). Supergene oxidation of the hypogene mineralization led to the formation of in-situ residual Mn-oxide ore deposits, and secondary infills of Mn-oxide ore in embryonic and well developed karst cavities.Whole rock geochemical pro?les across mineralized zones con?rm the role of thrusts and faults as solution passageways and stress the importance of these structures in the development of hydrothermal and supergene mineralization at Kato Nevrokopi. Three zones are recognized in the in-situ supergene veins: (A) a stable zone of oxidation, where immobile elements form (or substitute in) stable oxide mineral phases, and mobile elements are leached; (B) a transitional (active) zone in which element behavior is strongly in?uenced by seasonal ?uctuations of the groundwater table and variations in pH-Eh conditions; and (C) a zone of permanent ?ooding, where variations in pH-Eh conditions are minimal. Zone (B) is considered as the source zone for the karst cavity mineralization. During weathering, meteoric waters, which were CO2-rich (PCO2~10-3.8 to 10-1.4) and oxygenated (fO2~10-17 for malachite), percolated downward within the veins, causing breakdown and dissolution of sul?des and marble, and oxidation of rhodochrosite to Mn-oxides. Karst cavity formation was favored by the high permeability along thrust zones. Dissolved Mn2+was transportedinto karst cavities in reduced meteoric waters at the beginning of weathering (pH~4-5), and as Mn(HCO3)2in slightly alkaline groundwaters during advanced weathering (pH~6-8). Mn4+-oxide precipitation took place by fO2increase in ground waters, or pH increase by continuous hydrolysis and carbonate dissolution. In the well developed karst setting, some mobility of elements occurred during and after karst ore formation in the order Na>K>Mg>Sr>Mn>As>Zn>Ba>Al>Fe>Cu>Cd>Pb."

Jan 1, 1997