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By Y. Chunhua, L. Chunsheng, W. Sheng

"Countercurrent solvent extraction is the dominant industrial rare earth separation method. For the rare earth separation, with low separation factors and multiple components, designing and optimization plays an important role in reaching product quality and reducing separation plant costs. Based on the theory of countercurrent extraction, cost-efficient methods, such as third-outlet separation and hyperlinked extraction processing, have been introduced following computer simulation. The consumption and fixed investment of industrial practice are compared, by which advantages of the optimized rare earth separation process are indicated. INTRODUCTIONThe rare earths (RE) have outstanding optical, magnetic and electric properties in advanced material applications and have therefore received much international attention in recent years. Liquid-liquid extraction is the major industrial RE separation method and is widely used in the industry. Supported by the government and with collaboration from the institutions and enterprises, China has made great progress in RE separation, and has become the dominant supplier of separated RE products. Complicated by multiple elements and low separation factors, careful design of RE separation processes is vital for the quality and cost of production. The theory of separation is the key to basic of flowsheet design and industrial applications.BASIC SEPARATION PROCESS AND THEORYGeneral ProcessAcidic extractants such as P507, P204 and naphthenic acid, are the most popular extractants in modern RE separation industry. In the general separating process, the extractant is saponified with a base, then ion-exchanged with RE solutions, thereby to provide stable and high RE loading in the extractant to fulfill the requirement of production quantity and quality. The RE-loaded extractant is then countercurrently extracted and scrubbed with RE solutions and the RE element thereby is purified. After the countercurrent extraction process, the RE-loaded extractant is stripped with acid to obtain an aqueous RE product, and prepare the extractant for recycling (Xu, 1995)."

Jan 1, 2012

Discovery of an economic diamond deposit produces considerable wealth in terms of jobs, royalties, mining investment, and economic spinoffs for residents, including Aboriginal peoples. Diamond mines contribute to the GDP, increased personal income per person and reduced unemployment rates. Is it possible in Alberta?

May 1, 2008

By Adam Moore, Ryan Gillespie, Jarrett Quinn, Audrey Walters, Peter Radziszewski

"Vale Long Harbour Processing Plant (LHPP) was designed to process Voisey’s Bay nickel concentrate into finished nickel and associated copper and cobalt products. The plant includes a secondary grinding circuit comprising two Stirred Media Detritors (SMDs) operating in parallel. The ultrafine grinding circuit was designed to process concentrate at a rate of 33 t/h and produce a ground product (P80) of 20 µm to feed the leach circuits. Start-up of the grinding circuit at LHPP was undertaken in December 2014.The objective of this paper will be to describe the design, commissioning, start-up and performance of the secondary grinding circuit with a focus on the two Metso SMD-355-C mills. Following a brief overview of Vale’s LHPP and the SMD technology, the paper will review the design of the SMD secondary grinding circuit from lab tests through to scale-up performance prediction. This will be followed by the results of circuit commissioning outlining some of the issues raised and addressed after which SMD performance will be outlined. Specifically, the SMD circuit grinding performance will be examined since start-up which will include the effect of media size and wear on grinding. Furthermore, impeller wear will be examined by determining initial “shear volume” and worn “shear volume” as well as its effect on mill power and the means to maintain it. The paper closes with a discussion on grinding performance."

Jan 1, 2016

By L. W. Krahenbil

The programmable Logic Controller (PLC), at its present stage of evolution, is now considered as a mature control system. The PLC combines the solid-state reliability of hardwired logic and computer control systems with the simplicity of a relay ladder logic. Relay symbolic programming through a function-oriented keyboard provides a means which plant personnel can easily become accustomed to work with. In a large coal facility, it is shown that the control engineer can provide improved control flexibility with the advanced capabilities of the PLC.

Jan 1, 1979

By S. H. Schulz

100 YEARS AGO, on the first of August, 1877, the mining engineer Friedrich Koepe was granted the patent rights for a hoist driving ropes on the principle of friction. It was named after him: the Koepe hoist. On the occasion of this centenary, the main features of the Kcepe principle are described.

Jan 1, 1977

By Parsons. Robert B.

"Starting this year, corporations that conduct business in Ontario face a new tax a corporate minimum tax. This tax is in addition to the myriad of other taxes that make up a corporation's total tax burden including federal and provincial capital 1oXJ!S, payroll tax and sales taxes. Mining companies with gross revenues in excess of $10 million or total assets exceeding $5 million may be liable for this new tax. IntroductionOn December 8, 1993, the Ontario government introduced legislation to implement the corporate minimum tax (CMT promised in its May, 1993 budget. There are very few differences between the final legislation and the budget proposals.The CMT is effective for taxation years commencing after 1993. Subject to certain specific exemptions (detailed below), the tax applies to all corporations liable for Ontario Corporate Income Tax that have either gross revenues in excess of $10 million or total assets in excess of $5 million. These measurements apply to the aggregate gross revenues and total assets for all corporations in an associated group and a corporate partner's share of partnership assets and revenues must be included in the determination.In essence, the CMT is an income tax that is based on financial statement profit instead of an income amount that is determined separately under a statute. Accordingly mining companies (including so called ""junior"" exploration companies), which traditionally sheltered their taxable income by claiming generous exploration and development deductions, could find that they have a CMT liability."

Jan 1, 1994

By G. F. Trainor

At the Canadian Natural Resources Limited (CNRL) Horizon Mine they use Wenco International Mining Systems Ltd (Wenco) Fleet Management System to monitor and control their production fleet with the goal of increasing operator productivity and safety, and raising dispatcher awareness and control. Amongst the broad productivity goals CNRL wanted to achieve with help from the system was a very specific need to blend ore at the truck level. CNRL uses 25m x 25m block geological model information to represent their complex ore body. Wenco's High Precision GPS application, BenchManager provides precise graphical actual-vs-design operator feedback and system integration. Together the two companies advanced the BenchManager product to meet CNRL's needs by using live camera feeds to compare activity with data collection that ultimately lead to changes in the algorithm to include enhanced GPS indicators and the support of a GLONASS assisted solution generating distance and bearing information.

May 1, 2011

By J. A. Eisele, D. L. Pool

"The Bureau of Mines has developed a particle agglomeration technique to improve the flow of leaching solution through heaps of low-grade gold-silver ores which contain clays. Benchscale experiments and industrial practice have shown that the percolation rate of cyanide leaching solution is greatly enhanced by mixing the ore with Portland cement as a binder, moistening the mixture, mechanically tumbling to form agglomerates, and aging before heap building and leaching. A slight modification ofthe technique allows its application to precious-metal-bearing tailings, which cannot normally be treated by heap leaching because they are too fine. IntroductionMany low-grade gold and silver deposits and tailing materials from former mining operations in the western United States are potential sources for precious metals. These sources are too low grade or too small to support the capital cost of a conventional cyanidation plant but have stimulated the development of lowcost procedures, such as extraction of the precious metals by heap leaching with cyanide. The Bureau of Mines has investigated methods to improve the recovery ofgold and silver by heap leaching these low-grade materials.For heap leaching to be successful, the crushed and stacked ore must have good permeability so that uniform distribution of the cyanide leaching solution through the heaps can be achieved. Some of the most difficult gold and silver ores to treat by heap leaching are those containing excessive amounts of clays, or fines generated during crushing. Excessive amounts of slimes, generally minus 50-micrometre or 270-mesh Tyler sieve size particles, in the heap feed will slow the percolation of the leaching solution, cause channelling, or produce dormant or unleached areas within the heap, resulting in long leaching periods and low extractions. In extreme cases, the clays or slimes can seal the heap and cause the leaching solution to run off the sides of the heap rather than through it."

Jan 1, 1987

By Nabeel Khan

Annual oil production from the Canadian Oil Sands in Northern Alberta has been rising for several decades, and more ore and overburden are excavated each year from an increasing number of open pit mines. Overburden meeting certain specifications will be used to dam tailings and fill open pits, but the remaining material must be stored in overburden storage structures (OBSS). Well-designed overburden storage structures are more stable and cost less in the short- and long-term. The purpose of this paper is to explore OBSS designs that will be stable yet economical in the short- and long-term. The geological background of the site is briefly discussed, including the effect of each of the main geologic layers (recently deposited till and muskeg, Clearwater Formation clay shales, McMurray Formation oil sands, and the Devonian limestone) on the slope stability of the OBSS. Cost is considered in the analysis when balancing between minimizing costs (steeper slopes) and acceptable factors of safety (flatter slopes), all the while considering the financial consequences of failure. Potential failure planes are identified and probabilistic analysis is conducted on the critical failure surface. The variations in the factor of safety caused by varying pore water pressure, friction angle, and cohesion, are plotted and discussed.

Jun 1, 2012

By A. P. LeBis

This article attempts to relate the concept of utility to the risk involved when only a small number of projects (compared to their probability of occurrence) are accessible to a firm and to quantify utility when other financial and physical parameters are known.

Jan 1, 1978

By B. J. Cunliffe

"Filter cloth in the mining industry is an ambiguous title asthis suggests filter cloth use from underground ventilation to the refining processes. The time allowed for this paper would be better served in con-centrating on vacuum filters common to all mine mills and to offer some simple guide lines to the mill metallurgists in the choice of filter cloth for this type of filter.The requirement of the filter cloth is to separate solids from liquids under a vacuum head by forming a permeable layer of solids or cake, through which liquids can flow until the panel or disc sector leave the slurry tank and to continue to pass residual moisture from the cake formed during the cake drying cycle, and to discharge the cake on air-blow so that the cycle can be repeated.Whilst the mill metallurgist should not be expected to under¬stand all aspects of filter cloth manufacturer, it is however, advantageous for him to understand a little of the textile language associated with filter cloth for his own protection against ""trial-and-error"" methods, which are both time consuming and costly.If improvements are to be made over existing filter cloth in use an examination of the limiting factors of the cloth used should be made and the major causes for removal determined, e.g. cloth blinding, high moisture in cake, poor cake discharge on air blow, mechanical damage to cloth.As each of the limiting factors mentioned has a bearing on the choice of fibre used, the yarn type and weave of a suitable cloth, an under-standing of these points will assist the mill metallurgist in avoiding repetitive trials offering little degree of success."

Jan 1, 1971

By K R. Brentley

"Tshepong Mine, Harmony’s largest gold producing mine, is situated in the Free State portion of the Witwatersrand Basin, east of Odendaalsrus and north of Welkom, South Africa. The Basal reef is a narrow tabular conglomerate and is the main gold bearing ore body. The strata strikes mainly in a northsouth direction with an average dip of 22 degrees. Currently mining takes place at depths of between 1 690m and 2 150m below surface. The Basal reef unit consists of a conglomerate ranging between a few and 30cm in thickness. Some 80-90% of the gold occurs in the lower portion of the conglomerate. Directly above the conglomerate is a quartzite placer unit, the Basal quartzite, which is a clean, hard competent rock and varies in thickness between 50cm and 200cm. The Basal unit is overlain by the Khaki shale which can vary between 30cm and 500cm in width. It is weak and incompetent khaki coloured chloritic shale.A method of stoping, termed “undercut”, is practiced in order to remove the lower 15-20cm of the gold rich strata. The method entails removing this portion along with some 70-80cm of footwall host rock which is a strong competent quartzite. The hard competent quartzite overlying the conglomerate is left in-situ to form a competent hangingwall which can stabilize and prevent exposure of the weak Khakishale. This method of extraction was developed through trial and error and has been used reasonably successfully since its inception in the early 1960’s where the method was developed to extract the Basal reef at the Western Holdings Mines. Recently prospect drilling and a number of localised hangingwall failures indicated that the residual quartzite beam could be less than 60cm and in some instances as thin as 30cm in certain areas of the mine. The result of this is a less stable hangingwall which not only poses a safety risk to workers in these areas but also had the potential of locking up some 840 000 Tonnes of gold bearing ore. At the present gold price this amounts to revenue of approximately ZAR1.5 billion (U.S. $143 million).This paper discusses the method of “undercut stoping” and existing practices in place at Tshepong Mine. It also explores new initiatives such as the use of a simple freely-supported elastic beam solution to perform back analysis, on-site data capturing of beam thickness and support geometries in order to develop empirical design charts and numerical modelling to assist in the verification of the empirical design method."

Jan 1, 2015

By S. R. McCutcheon, D. R. Lentz, W. S. Downey

"Abstract - The Little Falls member of the Nepisiguit Falls Formation is situated in the northern part of the Brunswick Belt of the Bathurst Mining Camp and has been interpreted as the distal equivalent of proximal tuffaceous rocks that host the stratiform Brunswick No. 12 and No. 6 Pb-Zn massive sulfide deposits. It comprises fine-grained, greenish-gray tuffaceous sandstone in the lower part, and coarse-grained, crystal-rich tuffaceous sandstone in the upper part. Petrographic evidence suggests that these rocks have a turbiditic origin. The Little Falls member is underlain by the Vallée Lourdes member, mainly composed of relatively shallow-water calcareous rocks, and is conformably overlain by Mn-rich sedimentary rocks, mainly red argillites that host the Tetagouche Falls Mn-(Fe) deposit. All these rocks are considered to belong to the Nepisiguit Falls Formation, part of the Ordovician Tetagouche Group. Whole-rock geochemical data from the fine-grained tuffaceous sandstone and coarse-grained tuffaceous sandstone indicate that the two units of the Little Falls member are distinct. Zr and TiO2 contents, and total rare earth element (REE) values are higher in the coarse-grained unit (average Zr/TiO2 = 0.040, average SREE = 247 ppm, n = 6) than in the fine-grained unit (average Zr/TiO2 = 0.048, average SREE = 158 ppm, n = 17), which can be attributed to the variation in crystal content between the two units. Both units are HREE-enriched and have elevated La/Yb relative to the typical Nepisiguit Falls Formation. Overall, the geochemical data combined with evidence from the bounding units suggest that the Little Falls member was deposited in relatively shallow water, possibly in a near-arc environment. The relationship of volcanic facies within the Nepisiguit Falls Formation and the geochemistry of these facies indicate strongly that fine grained, reworked tuffaceous rocks, regardless of whether they are the distal equivalents of proximal tuffaceous rocks, are not associated with the major ore-bearing horizons of the Bathurst Mining Camp. Sommaire - Le Membre de Little Falls de la Formation de Nepisiguit Falls se retrouve dans la partie nord de la Ceinture Brunswick du Camp Minier de Bathurst ou elle a été interprétée comme l’équivalent distal des roches tuffacées proximales hôtes des gisements de sulfures massifs de Pb-Zn stratiformes Brunswick No.12 et No.6. Il consiste en grès tuffacé à grains fins gris verdâtre dans sa partie inférieure et en grès tuffacé à grains grossiers riche en cristaux dans sa partie supérieure. Les données pétrographiques suggèrent que ces roches ont été déposées par des courants de turbidité. Le Membre de Little Falls repose sur le Membre de Vallée Lourdes, lequel consiste principalement en roches calcareuses déposées en eau relativement peu profonde; il est de plus recouvert en concordance par des roches sédimentaires manganifères, lesquelles consistent principalement en argilites rouges hôtes du gisement de Mn-(Fe) de Tetagouche Falls. Toutes ces roches appartiennent à la Formation de Nepisiguit Falls, laquelle fait partie du Groupe de Tetagouche, d’âge Ordovicien. Les données lithogéochimiques des grès tuffacés à grains fins et à grains grossiers indiquent que ces deux unités du Membre de Little Falls sont distinctes. Les teneurs en Zr et en TiO2, ainsi que la teneur totale en Éléments des Terres Rares (ÉTR) sont plus élevées dans l’unité à grains grossiers (Zr/TiO2 moyen = 0.040, SREE moyen = 247 ppm, n = 6) que dans l’unité à grains fins (Zr/TiO2 moyen = 0.048, SREE moyen = 158 ppm, n = 17), ce qui pourrait s’expliquer par la variation de la quantité de cristaux dans chacune de ces deux unités. Chacune de ces deux unités présente un enrichissement en ÉTRL ainsi qu’un rapport La/Yb relativement plus grand que ce qui est typiquement observé dans la Formation de Nepisiguit Falls. Les données géochimiques considérées conjointement à l’information provenant des unités adjacentes suggèrent que le Me"

Jan 1, 2006

By G. Tairova, M. Murchie, B. Esford, E. Lam

"The objective of this project is to investigate methods to lower the sulphate concentrations in the mill effluent. Currently, the concentration of sulphate in mill effluent is approximately 2 g/L. The high concentration of sulphate ion in the effluent has the potential to become a regulatory issue. The target sulphate concentration in mill effluent for this work was less than 500 mg/L. The pilot studies, using sulphate precipitation, were carried out at the mill. The results of the sulphate precipitation pilot study, using calcium hydroxide and sodium aluminate, indicated that:• The sulphate concentrations in effluent could be reduced to less than 500 mg/L.• The concentrations of most other elements of concern, such as selenium, arsenic, cobalt, nickel and vanadium, were also reduced.INTRODUCTIONHistorically, the concentration of sulphate, SO4 2-, in water has not generally been subject to regulation. However, with the increasing global consumption of water, stricter regulations on sulphate quantity may be imposed. Sulphate is a concern in process waters as it forms scale on process equipment and leads to operational problems. High sulphate concentrations may result in adverse health effects. The taste theshhold for the most sulphate salts in drinking water ranges from 250 to 500 mg/L.A literature search and review to identify methods to reduce sulphate concentration in the mill effluent was carried out. A number of methods were selected and tested in the lab. The experimental results indicated that the precipitation methods, using calcium hydroxide and aluminum compounds, barium compounds, as well as the ion exchange and the membrane methods, were effective for the removal of sulphate to below the required limits. Some other elements, such as vanadium, nickel, cobalt, selenium and molybdenum, were also removed.The process, using calcium hydroxide and aluminum compound for sulphate precipitation, similar to the Cost Effective Sulphate Removal (CESR), also known as “Walhalla” process, described in the Montana Tech report (“Demonstration Of Sulfate Removal” 1999), was selected for further consideration [1]. In the CESR process, the water is treated with lime for precipitation of gypsum, followed by the reaction with a proprietary aluminum compound for removal of a residual sulphate. The final pH adjustment is carried out using carbon dioxide. Results of a preliminary cost estimate indicated that the removal of sulphate using calcium hydroxide and aluminum compound was the preferred method of treatment, considering its low cost, availability of chemicals and minimal changes to the existing plant circuit."

Jan 1, 2012

By K. Mayhew, A. Lossin, H. Salomon-de-Friedberg

"The proportion of arsenic-bearing copper concentrates that supply the copper industry is on the increase. The current strategy of miners and smelters to blend feeds to reduce average arsenic levels is rapidly becoming unsustainable as more concentrates with even higher arsenic levels enter the marketplace. In addition, the capability of smelters to manage increasing arsenic levels to more stringent and restrictive environmental standards is limited by available process technologies.CESL Cu-As Technology is a viable technical and economic alternative to traditional smelting. It offers the advantage of simultaneous leaching and precipitation of the arsenic in a single processing step while achieving high copper extractions. The process has been piloted in six separate, fully-integrated pilot campaigns for feeds ranging from ~1% to 12% arsenic in concentration. This paper will focus on the behaviour of arsenic in CESL’s leaching/precipitation step and operational factors that influence it, and on the chemical and physical characteristics of the subsequent iron-arsenic residue that represents today’s best available technology from a long-term sustainable (capital/operating costs, metal recovery, safety, environmental) perspective.The examples provided will demonstrate copper extractions approaching 99% and arsenic deportment to residue of 99%. Instantaneous settling rates of the residue were measured at 15+ m/hr. Data from subsequent short and long-term stability testing of the residue confidently support the view that the scorodite-bearing residues from the process will be stable and provide an acceptable arsenic management practice. The technology offers increased revenue and environmental certainty for miners, smelters & refiners to support the development of metallurgically challenged copper-arsenic deposits. Furthermore, results will be presented demonstrating the technology’s ability to successfully incorporate hazardous arsenic containing smelter by-products such as dust into the process feed and simultaneously extract copper value while fixing the arsenic in a stable residue."

Jan 1, 2016

By G. Barr

"The Polymetallic Twin Metals Project deposits in Northern Minnesota are being developed by Twin Metals Minnesota. Amongst the flowsheet alternatives being examined at a prefeasibility study level is one involving flotation of a bulk concentrate followed by high temperature autoclaving of the concentrate using the PlatsolTM Process to solubilize all the valuable metals in the concentrate (Cu, Ni, Pt, Pd and Au). Autoclave operating conditions have been established in which recoveries of all the pay metals are in the 92 to 99% range, and the autoclave residence time has been reduced to an hour. The stability of the precious metals in solution after autoclaving has been assessed, as well as the impact of internally recycling process liquors to the feed to the autoclave.INTRODUCTIONPlatinum group metals (PGMs; platinum, palladium, rhodium, ruthenium, iridium and osmium) are traditionally recovered from their ores by production of a high-grade concentrate by flotation and/or gravity concentration followed by smelting of the concentrate. Concentrates are smelted to remove nonsulphide minerals and converted to remove iron and sulphur. The resulting high PGM grade matte is processed hydrometallurgically to leach the base metals, leaving a residue with a very high grade (20-40%) PGM concentrate for final refining to individual PGMs. Due to the complexity of this process and its high capital cost, this process can only be applied economically to high grade PGM ores. Lower grade PGM concentrates might be accepted as copper and nickel concentrates but may not yield attractive payment terms for the PGMs. The mineralized Duluth Gabbro region of Minnesota hosts several low grade base and PGM deposits and Twin Metals Minnesota is working to develop the Twin Metals Project deposits. Earlier studies at both pre-feasibility and feasibility level, by other mining companies, have failed to yield an economically viable project based on the traditional process. It is possible to produce a saleable copper concentrate from these ores, but economic recovery of nickel and PGMs into saleable concentrates proved elusive.In the late 1990’s and early 2000’s the Platsol™ process was developed at SGS in Lakefield, Ontario (at the time Lakefield Research Limited) for the NorthMet deposit (also within the Duluth Gabbro) owned by PolyMet Mining. The process developed was a high temperature chloride-assisted pressure oxidation process capable of dissolving simultaneously the base metals (Cu, Ni, Co, Zn), gold and the PGMs."

Jan 1, 2012

By H. A. Hamza

An experimental study of the settling characteristics of a washery effluent originating as tailings from a froth flotation circuit was undertaken by using a systematic approach to select the most appropriate flocculant(s) under predetermined conditions. Selection and evaluation procedures which greatly reduce the effort required to select flocculants are described. The results show that, although different flocculants display superiority at different ranges of dosage. Separan MG 700 (Dow) is the most suitable on absolute economic grounds. Flocculant evaluation is based on a Cost Performance Index (CPI) which expresses the cost of flocculant (¢/ton) required to produce a unit settling rate (in./hr). From experiments carried out with a number of flocculant aid and flocculant combinations, it was concluded that the use of flocculant aids can be economically justified only if the settling rates required are higher than those obtainable at the optimum flocculant dosage. Otherwise, the value of the flocculant aid appears to be limited largely to the reduction of supernatant turbidity.

Jan 1, 1979

By Francis Breton, Lei Pan, Kun Liu

"Effects of Fe, Cu and Mg minor alloying elements on creep properties of 8xxx aluminum conductor alloys were investigated by conducting compressive creep tests at 100 ºC under a constant load of 69 MPa. The microstructural evolution was studied using an optical microscope and electron backscatter diffraction technique. The creep properties were characterized by the primary creep strain in the first stage and the minimum creep rate in the second stage of creep deformation. Results showed that additions of all three minor alloying elements (Fe, Cu and Mg) demonstrated a beneficial effect on the creep resistance but individual alloying elements exhibited different impacts on creep properties. The additions of Fe and Mg showed a strong impact on both the primary creep strain and minimum creep rate, while the Cu addition displayed a favorable effect on the primary creep strain but no impact on the minimum creep rate. Microstructure observation revealed that with increasing Fe contents, the volume fraction of fine intermetallic dispersoids gradually increased while the subgrain size and misorientation angle became smaller, providing strong barriers to the dislocation and grain boundary movements. The addition of Cu moderately reduced the subgrain size and misorientation angle and in combination of solid solution strengthening it promoted the retardation of the creep deformation during the primary stage.INTRODUCTIONThe 8xxx aluminum conductor alloys offer significant advantages such as low density, high conductivity to weight ratio and low price over copper conductors and become an attractive candidate in electrical engineering and building wiring (McQueen, Chia, & Starke, 1986; Birol, 2009; Engler, Laptyeva, & Wang, 2013). The mass resistivity of aluminum conductors is one-half of copper conductors. Thus, only one-half the weight of aluminum is required for equivalent capacities. Therefore, this unique property coupled with a relatively low price of aluminum offers significant economic advantage to develop aluminum conductor alloys for electrical applications in the electrical wire industry."

Jan 1, 2016

By Ana Adé

The use of gold compounds in homogeneous catalysed organic reactions has been undervalued for many years due to the preconceived opinion that gold is an expensive and extremely chemically inert metal. However, recent reports have changed this assessment and gold salts in small amounts are known to display high catalytic activity.[1] Thus, it has been reported recently that anhydrous AuCl3 catalyses the formation of C-C and C-O bonds (usually mediated by hydrochloric and other protonic and Lewis acids).[2] Some examples include Michael type additions, selective cross cycloisomerisation/dimerisation of propargyl or allenyl ketones, benzannulation between o-alkynylbenzaldehides and alkynes or cyclisation of alkenyl furans. It is noteworthy that some of these reactions[2a] can be also catalysed by silver salts but with much lower yields. The 1,3-dipolar cycloaddition of nitrones to alkenes is a powerful synthetic method that has found numerous applications in the synthesis of a variety of carbon frameworks.[3] Several laboratories have focused on the development of Lewis acidic reagents to modulate the selectivity of the reaction.[4] Despite the extensive study performed, there are not many examples in which a metallic complex catalyses the dipolar cycloaddition. Most of these reactions require the presence of a metallic complex and nitrone in a 1:1 molar ratio. Recently, we have carried out stoichiometric reactions of the N-benzil-C(2-pyridil)nitrone, 1, with different dipolarophiles in the presence of zinc and silver compounds.[5] Apart from an increase of the reaction rate and the selective formation of one of the possible isomers, we have shown the formation of zinc and silver-nitrone complexes during the reaction, which behave as the intermediates in the cycloaddition process. As suggested by the results obtained with silver complexes, we decided to test gold derivatives (in the oxidation states of I and III). Interestingly, we have found that they can be used not only as stoichiometric reagents but they can also mediate these cycloadditions in catalytic amounts (5 to 10 mol % respect to the nitrone). Here we present the results on the 1,3-dipolar cycloaddition reaction of the N-benzil-C(2-pyridil)nitrone (2-PyBN), 1, and methylacrilate, 2, (Eq. 1) catalysed by gold(III) derivatives.

Oct 1, 2003

By J. L. Gartshore

PRACTICALLY all of Quebec's chrysotile asbestos production derives from twelve mining and milling operations located in the "Eastern Townships" area of the province. The annual output of these twelve operations exceeds one million tons of chrysotile asbestos, valued at over one hundred million dollars, and is shipped to manufacturers spread over all six continental areas of the world. A total of approximately twenty million ton of asbestos ore yearly, or about seventy-five thousand tons a day, is mined. Individually, the operations vary in size from about two thousand tons to thirty thousand tons per day. Removal of waste rock and overburden to develop these ore tonnages varies greatly from one mine to another, but would probably average out at about a one to one ratio.

Jan 1, 1962