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By Shuai-Jun Li, Xia-Ting Feng, Xian-Jie Hao

"The anisotropy of rock is of great importance to the rock engineering. To investigate the anisotropic character of slate, the rock samples of slate under different confining pressures and bedding plane angles was conducted on the MTS. The results indicated that the relationship between bedding plane angle and elasticity modulus, friction angle, cohesion and strength was shown as U pattern. The minimum value of them is located from 30°to 45°.In addition, the elasticity modulus and Poisson's ratio increase with the increasing confining pressure. The slate behaves brittle failure both in the uniaxial and triaxial compression. The failure pattern of uniaxial compression is generally tension failure, and triaxial test usually shows shear failure. The failure angle decrease with the increasing of confining pressure.INTRODUCTIONThe anisotropy of rock is that loading in different orientations the rock has different mechanical properties. The anisotropic property of rock is always an important problem in rock engineering (Hoek E. & Brown E. T., 1980). J. C. Jaeger (1960) first presented that transverse strength criterion for sliding fracture on joint surface. Later he revised rock parameters to anisotropy empirically for isotropic Mohr- Coulomb criterion. His main idea is revising cohesion according to loading direction (J. C. Jaeger, 1971). Then, many scholars study a lot on transverse strength criterion. E. Z. Lajtai (1969) considered the influence of connecting rate in all directions in joint groups for shear strength in intact rock; R. Mclamore and K. E. Gray (1967) referenced the theory of J. C. Jaeger. They not only revised cohesion also revised friction coefficient. Y. M. Tien (2000, 2001) made further study on the influence of connecting rate in joint group to transverse strength. R. Nova (1980) studied on the variation of strength when rock specimens in triaxial pressure and complex stress paths. O. Cazacu(1998) put forwards a new anisotropic strength criterion for analyzing rock strength. S. Pietruszczak(2000) introduced fabric tensor for characterizing inner seismic structure and he built an anisotropic strength criterion containing the invariants of stress tensor and seismic fabric tensor."

Jan 1, 2015

By C. W. Eggert

This paper gives an account of the E.V.O.P. tests made at the Copper Rand mill of the Patino Mining Corporation in Chibougamau, Quebec. The runs were made to acquire an understanding of the method. A description of events, along with conclusions, observations and opinions, is out-lined.

Jan 1, 1967

By K. Maruyama, T. Nagasaka, R. d. Chairaksa-Fujimoto, T. Miki

Electric arc furnace dust or EAF dust is considered as a hazardous waste but contains a significant amount of economically attractive non-ferrous metals especially zinc as zinc ferrite (ZnFe2O4) and zincite (ZnO). The hydrometallurgical process is one alternative choice because it has the advantage of low energy consumption. The leaching of ZnO from the dust is very easy. However, the complex major zinc compound in EAF dust is ZnFe2O4, which is very stable and insoluble in alkaline or acidic media under delicate conditions, and causes the low zinc recovery yield by hydrometallurgical process. Moreover, halogens and heavy metals in the dust are also problematic. In order to develop a new effective EAF dust treatment process, the authors have proposed "CaO addition process" as pre-dust treatment to transform all of ZnFe2O4 in the EAF dust to ZnO and Ca2Fe2O5. In this study, the selective zinc leaching from the CaO treated EAF dust with NaOH and NH4Cl solutions was carried out. The effect of temperature, reaction time and solute concentration were systematically investigated. All of zinc in CaO treated EAF dust was successfully leached into both solutions.

Jan 1, 2014

By Washington Luiz Mafra

Every year the conventional direct reduction processes ? Midrex and HYL III ? increased their market share in the world steel production, even though they are only economically feasible in countries where natural gas is available at competitive prices. In this context, the new Midrex projects are based on large reactors (Megamod - 1.5 to 1.8 Mt/y of DRI), reduction temperatures of the metallic burden up to 850oC, with bustle gas temperatures between 960oC e 1050oC. Thus, the requirements of metallic burden performance, as well as the evaluating methods, usually based on ISO standards, need to be reviewed. It is well known that the standards usually applied to quality evaluation do not reflect the performance of metallic burden inside the reactors. This paper describes the different methods of evaluating the disintegration under reduction of DR pellets based on ISO 11257 standard. This is the most important method used by pellet producers and customers for evaluating DR feedstocks. The different methodologies tested to evaluate the disintegration under reduction had varying results, evidencing the relevance of the method and the quality of the pellet. Nevertheless, validating the method in an industrial reactor is still fundamental.

May 1, 2007

By R. Ghomashchi

Wear, fatigue and corrosion are the most widely encountered modes of failure in materials used in engineering applications, including aero-gas turbines. Although wear is distinctly classified as adhesive, abrasive, erosive, fretting and so on, there are usually more than one wear mechanism involved in the failure of components in service because there are many systems and materials variables active in materials wear that makes it more difficult to study. This is further complicated by the discrepancies between the results of laboratory tests and field data. The present investigation was set up to examine the wear characteristics of M50 and T1 high-speed steels at both room and elevated temperatures to draw a thorough understanding of the wear behavior of this class of high-speed steels. This article focuses on the mechanical and microstructural characterization of wear for T1 and M50 high-speed steels using a pin-on-disk wear machine.

Jan 1, 2005

By A. M. A. Mohamed, F. H. Samuel, S. Alkahtani

"This article was undertaken to investigate the effect of nickel and zirconium additions on the strength of 354 aluminum cast alloy. The cast alloys were given a solutionizing treatment followed by artificial aging at 190 ºC for 2 hr. High temperature tensile tests were conducted at various temperatures from 25ºC to 300ºC. Optical microscopy and scanning electron microscopy were used to study the microstructure of the samples. The results revealed that the intermetallics phases of (Al,Si)3(Zr,Ti), Al3CuNi and Al9NiFe are the main feature in the microstructures of alloys with Zr and Ni additions. The results also indicated that the tensile strength of alloy decreases with an increase in temperature. The combined addition of 0.2 wt% Zr and 0.2 wt% Ni leads to a 30% increase in the tensile properties at 300ºC compared to the base alloy.INTRODUCTIONThe task of improving the mechanical properties in an aluminum alloy at high temperatures should include the knowledge of several factors which are related principally to a decrease in the strength of the metal with increasing temperatures. This behavior is linked to the change or deterioration in the principal metallurgical parameters of the specific cast aluminum alloy during its performance at higher temperatures. Most of applications of Al-Si casting alloys are generally used at temperatures of no more than 230°C (Lee & Chen, 2002). This recommendation is made in view of the fact that, for certain applications such as those required by the automotive industry, these alloys must operate over a wide range of temperatures and stress conditions where temperatures are liable to rise even higher than 230ºC (Robson & Pragnell, 2003).Aluminum-silicon-copper-magnesium alloys such as the 354 alloys show a greater response to heat treatment as a result of the presence of both Mg and Cu. These alloy types display excellent strength and hardness VALUES (although at some sacrifice of ductility and corrosion resistance. These alloys are used for a wide range of applications, such as engine cooling fans, crankcases, high speed rotating parts, structural aerospace components, air compressor pistons, fuel pumps, compressor cases, timing gears, rocker arms, machine parts, and so forth (Cáceres, Svensson, & Taylor, 2003; Rurrxia, Rong-de, Yu-hua, Cherrxi, Xiao-feng, Heng-rong, & H. Zhuang-qi, 2004)."

Jan 1, 2012

By R. Kumar, A. K. Verma

"In this paper, an anisotropic shear behavior of rock joints is investigated under constant normal load condition (CNL). The natural rock joint roughness is transferred to artificial rock samples using room temperature vulcanizing (RTV) silicon rubber. Artificial cylindrical rock joint samples (90 mm diameter and 50 mm height) are made by mixture of cement, sand, and water in the ratio of 1:1.5:0.45 (by weight). Direct shear tests are conducted on these samples in twelve directions at 30º apart at four different normal stresses (250kPa, 500kPa, 1000kPa, and 1500kPa). Thus, 48 samples are tested in laboratory. Test results shows that the peak shear strength (?) of rock joints is anisotropic in nature due to change in morphological features in particular shearing direction. Joint roughness coefficient (JRC) is determined in each shearing direction by trial and error method using Barton’s model (1973). Further, cohesion ( c) and angle of friction ( ? )of joint surface in each direction is determined. Finally, a relationship between angle of friction ( ? ) and joint roughness coefficient (JRC) is developed. Experimental shear strength and Barton’s shear strength is compared and it is found that effect of anisotropic decreases with increasing normal stress. INTRODUCTIONRock mass is generally composed of discontinuity which refers collectively to joints, faults, bedding plane and folds etc. ISRM (1978) defined joint as a line of break of geological origin along which there is no visible displacement. Joint is three dimensional discontinuity which composed of two matched/mismatched surfaces. The presence of joints in rock mass plays an important role to define its overall shear strength, deformability behavior, in-situ stresses and hydro-geological properties. The shear strength of rock joints is important in the design of near surface/ deep geotechnical works (mining excavation, dam foundation, power plants, underground caverns, and slopes).In last 40 years, many constitutive models are developed to predict shear strength of rock joints under CNL conditions (Patton 1966; Landanyi and Archambault 1969; Barton 1973; Goodman 1976; Barton and Choubey 1977; Plesha 1987; Desai ad Fishman 1991; Amadei and Saeb 1992; Maksimovic 1992; Wibowo et al. 1993; Huang et al. 1993; Amadei et al. 1998; Indraratna 2000; Homand et al. 2001; Wang et. al. 2003; Samadhiya et. al. 2008; Asadollahi and Tonon 2010; Ghazvinian et al. 2012). These constitutive models have limitations to predict shear strength of rock joints in one direction. Till date, among all constitutive models, Barton (1973) model is widely used in practice due its simplicity. It includes parameters such as joint roughness and joint compressive strength (JCS) to quantify joint surfaces."

Jan 1, 2015

By D. Sharma, A. K. Singh, R. Singh, P. K. Mandal, M. Sarkar

"This paper deals with the stability investigations carried out at the XIVth seam of Jitpur colliery. The study was conducted to investigate the possible causes of roof cavity formation and face spalling at the middle slice face of block-3 longwall panel and to suggest remedial measures. The instrumentation and monitoring work was carried out in the panel over a period of nine months. On the basis of observations, it was found that if the maximum face span was reduced from the existing 4.8 m to 3.6 m, and if the face time schedule cycle was reduced from a maximum of 37 days to about 18 days, this problem could be eliminated. The recommendations of CMRI have been implemented in the middle slice face of block-4 panel with success. IntroductionModerate to steeply dipping, undisturbed seams of uniform thickness are worked by way of inclined slicing parallel to walls. In this method, the seams are treated as a combination of several moderately thick seams dipping parallel to roof and floor. Numerous variations of multislice mining have been used worldwide to get high coal recovery under local conditions of geology, subsidence control, proness to spontaneous combustion, statutes and economics. Multislice mining can proceed either downward descending from the roof or upward ascending from the floor. Ascending methods require backfill behind the working face to provide a base for the next slice. It is also adopted for surface protection against subsidence or mining under a massive roof. This paper presents a scientific study conducted in Jitpur colliery, IISCO where a 9 m thick seam is mined in three slices in ascending order with stowing."

Jan 1, 2002

By M. Piard

Fires and explosions are not likely to originate in clean gobs above pillar faces steadily driven through a solid panel in order to effect a complete extraction. As. to the storage which such a process implies where the market is intermittent, its cost will never equal that of abandoning large pillars in a fully developed property. Much less will that cost, thanks to the big sizes obtained, ever approach that of cleaning wet and dirty crushings robbed at great expense from small pillars exposed to many years of roof pressure. Even thick seams under bad roof may be fully extracted without the help of filling material. Fatal accidents from falls of roof owing to the great height of excavations, losses in coal, and the danger from fire, have compelled operators in South Staffordshire, England, to discontinue the stall-and-pillar system at one time supreme in the district, and to successfully adopt the following plan: A retreating' longwall is run along the top coal, as the first working; the bottom coal is taken in the same manner, after the fallen roof has become sufficiently consolidated to allow the mine to be reopened. A similar plan is suggested in this paper in order to deal with the outcropping and pitching seams found in the Kootenay measures.

Jan 1, 1930

By F. Habashi

Magnesium is the eighth most abundant element in the earth's crust, It occurs in nature in sea water, brines, and a number of minerals, Metallic magnesium was first isolated by Humphry Davy (1778-1829) in England in 1808 via electrolysis of anhydrous magnesium chloride with a mercury cathode, Antoine Bussy (1794-1882) in France extracted the metal in 1828 by reducing fused magnesium chloride with metallic po¬tassium vapour, The first industrial production of magnesium by electrolysis of molten carnallite began in 1886 in Hemelingen in Germany, In 1940 Lloyd M, Pidgeon (1903¬1999) in Canada pioneered the first industrial metallothermic magnesium extraction plant based on the reduction of dolomite with ferrosilicon under vacuum, Since then the magnesium industry developed further and a variety of processes are presently used.

Jan 1, 2006

By P. Nayak

"Comminution is an energy intensive and expensive process consuming approximately 40-50% of the total processing costs in a mining operation. This process poses an even greater challenge with gold ores due to their low elemental concentration and small particle size. Over 99.9% of the ore fed to the mill is waste which must be removed during the ore processing stage. Preconcentrating the Run of Mine (ROM) ore before feeding the mill will result in significant cost savings. In partnership with Sacré-Davey Engineering, Agnico Eagle Mines Limited identified this opportunity and is currently evaluating the implementation of sorting technology to preconcentrate the ore or upgrade the waste material at its operations. This paper will discuss the steps adopted by Agnico Eagle in the evaluation and installation of sorting technology at its operations. Since the Company has a large portfolio of operations, the first step in the project was to shortlist the operations that had the highest probability for successful application of the technology. Following this, the top three operations were selected for bench scale evaluation. The projects which showed the most economic potential were then considered for detailed evaluation and pilot plant installations. This paper provides an insight into the methodology followed by Agnico Eagle and Sacré-Davey in the evaluation of the technology.INTRODUCTION The benefits of ore sorting technology are being increasingly understood by the mining industry today. The application of ore sorting in gold mining is attractive due to the nature of the mineral distribution. The presence of high value minerals distributed in an extremely small mass of the ROM ore creates a tremendous opportunity for preconcentration with ore sorting. Since Agnico Eagle currently has a portfolio of eight operating mines and numerous development projects and exploration properties, the challenge was to identify the deposits which had the most favourable mineralogy and grade distribution for successful ore sorting. The success of ore sorting is mostly based on the minerals present in the deposit and the grade distribution. The minerals signify the amenability of the deposit for ore sorting and the kind of sensing technology to be used. On the other hand, the grade distribution demonstrates the amount of material that can be rejected without losing value. In order to understand a deposit’s characteristics, it is important to examine the sample’s behaviour with various sensors and then assay it to know its actual value. It is a common practice in the mining industry to document assay value of drill cores and/or material feeding in and out of the mill. However, those VALUES (are insufficient to understand the grade variability on a granular basis. To capture the ore variability in very high resolution and significantly improve the selectivity of the material feeding the mill, it is vital to assay the samples on a rock-by-rock basis, as this is the level of resolution which will be examined by the ore sorter during sorting. A careful and elaborate procedure was followed in evaluating the technology at Agnico Eagle’s operations which is discussed in this paper."

Jan 1, 2019

By M. Barati, K. Ebrahimi-Nasrabadi, P. W. Scott

"The conversion of cryptocrystalline magnesite to caustic magnesia was studied experimentally at temperatures of 400–1,200°C and for calcination times of up to 8 h. A differential thermal analysis– thermal gravimetric analysis showed that decomposition begins at temperatures as low as 340°C and is completed at 600°C. Specific surface area, iodine adsorption number, crystallite size, and loss on ignition were measured to characterize the product quality. It was found that high-quality caustic calcined magnesia can be produced in a narrow temperature (600–650°C) and time range (1–4 h).RÉSUMÉ La conversion de magnésite cryptocristalline en magnésie caustique a été étudiée de manière expérimentale à des températures de 400 à 1200 °C et pour des temps de calcination atteignant 8 heures. Une analyse thermique différentielle – analyse thermique gravimétrique montre que la décomposition commence à des températures aussi basses que 340 °C et qu’elle est complète à 600 °C. La surface spécifique, l’indice d’adsorption de l’iode, la taille des cristaux et la perte au feu ont été mesurés afin de caractériser la qualité du produit. Il a été trouvé qu’une magnésie caustique calcinée de grande qualité peut être produite dans un petit écart de température (600 à 650 °C) et dans une période de temps variant entre 1 et 4 heures."

Jan 1, 2015

By S. Perez

Core drilling is a fundamental process in the mineral exploration industry. As deep exploration in hard rocks is accelerated due to the depletion of near ground mineral resources, deep-drilling operations need to reduce their reliance in operators experience and begin to implement new technologies in order to increase efficiency and cost-effectiveness of the overall process. Currently, lack of real-time information on the bit/rock interaction is a major problem. Therefore the mechanism behind the acoustic emission, which is a proven technique for remote monitoring, generation in mechanical rock cutting must be understood in order to provide real time information about the rock. This paper aims to identify the influence of mineral composition of granitic rocks on the acoustic emission (AE) during rock abrasivity test with a single contact tool and to evaluate the feasibility of AE as a means to infer Cerchar Abrasivity Index (CAI). Single contact tool will provide precise and accurate description of the source of AE. To provide constant grooving speed Cerchar apparatus was modified to monitor AE during rock/tool interaction. Tests on the modified Cerchar apparatus are carried out under the static load of 70N and cutting speed of 1 mm/s. A Scanning Electron Microscope (SEM) is utilized to visualize the groove in the rock and to identify the mineral composition through Back-Scattered Electrons (BSE) reflected from the rock sample. Based on the microscope images, it was found that biotite shows a larger groove area and plate-like fractures accompanied with burst-type AE signal, whereas plagioclase and quartz, which are characterized by similar hardness and BSE brightness, possess shattered-like fractures and more continuous-type AE signals. In addition, a-value of the Gutenberg-Richter scale has been found to well correlate with Cerchar Abrasivity Index (CAI).

Jan 1, 2015

By Maurice Séguin

The primary aim of all ground geophysical work has been, of course, to locate orebodies. As with any geo-physical method, its success depends on a proper mastering of the types of surveys and equipment used and their application to the physical properties associated with the orebodies. The Schefferville deposits are iron ores subjected to enrichment by the process of leaching. Although some ore types are porous and low in demiity, most of the ore zones have had a net increase in density brought about by enrichment. In the course of their formation, the magnetic characteristics of the rocks have usually changed, as much of the magnetite was altered to relatively non-magnetic iron oxides and hydrous iron oxides. Ali drift-covered areas underlain with iron-formation are potential ore-producing areas. From these first two physical proper-ties and a determination of the thickness of the over-burden, a combined gravity-magnetic-seismic and/or resistivity survey allows for the detection and sorting out of iron-formation and potential ore zones from the country rocks. If the iron-formation possessed relatively uniform physical and chemical properties, the problem of locating areas underlain with ore, using geophysical methods, would be greatly simplified. Unfortunately, the iron-formation is a complex assemblage of rock types, each having different physical and chemical characteristics. In spite of this, qualitative and semi-quantitative correlation between the results of the surveys and the geology and structure of the area could be established. In addition, a semi-quantitative to quantitative correlation of the values of the residual gravity anomalies with the specific gravity, the iron content, the porosity factor, the dimensions of the under-lying orebodies and the values of the ground magnetic intensity above a reference lithologie unit, with the per cent weight Fe304 recovery and the susceptibility, led to the discovery of a direct-shipping iron ore deposit in the Schefferville mining district of Canada.

Jan 1, 1968

By I. Yarita

Magnesium alloys have the lowest density among the metals in practical use, and have properties such high specific strength, electromagnetic interference shielding and good vibration damping. Thus, there are many applications of these materials in automotive and electric parts. However, there is a little use of the products of metal forming of these materials because of poor plastic deformability in the normal temperature range and their high cost of production. To expand the range of application of products manufactured by metal forming, rolling technology for producing thin sheets having good mechanical and surface qualities is required. In this study, hot-rolled Mg-alloy sheets are experimentally rolled with or without lubrication in the temperature range from 293 K to 523 K. Rolling force, plastic deformability and surface quality are investigated, and the grain structures and their uniformity are observed. The effect of friction between the roll and the deforming material on the uniformity of the grain structure is discussed. Moreover, rolled materials are annealed and their mechanical properties are investigated by the tensile test and compared with those of as-rolled materials. The effects of the rolling conditions on the mechanical properties are discussed.

Jan 1, 2006

By J. Fox, K. Kocsis

"Planning for sustainable cooling potential requires protected space to successfully maintain chilled propylene glycol in storage until needed. Stored propylene glycol should be judiciously cared for, safely kept from the ill effects of heat, in order to remain useful for bulk air cooling. Minimizing the chilled temperature of the propylene glycol reservoir tanks means that atmospheric conditions will be monitored closely during the chilling phase. Storage facilities would maintain restricted airflow while minimizing possibilities for heat transfer during the storage phase. Sustainable cooling systems could reduce or eliminate the need for mechanical cooling if installed with favorable conditions. Storing the cooling potential from the winter months is what this new design is all about.INTRODUCTIONIn most subsurface, bulk air-cooling methods, the main source of potential cooling energy comes from cold-water applications. This paper investigates the practical use of harvested, chilled propylene glycol as the source of cooling potential. Propylene glycol is chosen as the cooling storage liquid refrigerant since its chemical make-up is intrinsically safe to fresh water supplies and will not harm underground workers should a leak occur in the closed cooling circuit. Harvesting the cold of winter is a meaningless endeavor without proper thermal planning for the storage of the cooling potential in cold refrigerant.PROPYLENE GLYCOL STORAGE RESERVOIRA new design for a closed refrigerant bulk air cooling system employing propylene glycol as the refrigerant is presented as the main design topic of this paper. Given that a deep and hot mine will need to be considered safe and productive, a cost-effective cooling system is desired in order for the mining operation to be considered sustainable. For underground mines at northern latitudes, cooling applied to fresh air is only required 3 to 4 months of the year. During winter, ambient atmospheric conditions can be harnessed and stored for use at a later time.The basis of this sustainable design uses very cold ambient air that is circulated around galvanized steel refrigerant reservoir tanks. The propylene glycol reservoir tanks are arranged in a concrete walled pit, or tank farm, excavated in bedrock. During the coldest months, the tank farm will be exposed to the open air. As the seasons change the tank farm will be covered with insulation to maintain the maximum cooling potential for use during the warmest months of the year."

Jan 1, 2019

By H. L. Cameron

General Statement In July, 1948, experimental aerial photography o shallow water zones on Northumberland strait was carried out by the Nova Scotia Research Foundation. This work was designed to test the feasibility of aerial photography for coastal surveys o various types, including seaweed and bottom detail surveys. In the course of the work at Lismore, undersea faulting was noted visually and was later clearly apparent in the photographs. In order to prove beyond doubt that the lineations photographed are actually faults, a ground check was made, and terrestrial stereoscopic photographs were obtained of these features where they intersect the shore line. There can be no doubt of their nature, and the type of faulting is probably thrusting due to compressive forces. This is indicated by the successive right- and left-hand displacements on intersecting faults. The age of the fracturing is post Lower-Pennsylvanian (Lismore) and is correlated with similar compression faulting in western Cape Breton. As far as can be ascertained, this is the first time that subsea faulting has been photographed, though it is quite possible that similar structures have been observed elsewhere. Location and Area Lismore is on Northumberland strait, approximately thirty-five miles east of Pictou (see index map, Figure 1). The area mapped from aerial photographs (Figure 2) is a strip approximately two miles long by a quarter of a mile wide. Figure 3 shows a stereo-pair of the aerial photographs used to construct this map. The terrestrial stereoscopic photographs (Figure 4) show one of the faults.

Jan 1, 1949

By G. B. Harris

A new process for the recovery of copper and associated base metals from a polymetallic massive sulphide ore is described. The massive sulphide contains copper and especially nickel sulphide in a mineralogical form which negates both good recovery and high grades in concentrates using conventional flotation methods. Flotation concentrate processing and smelting from this ore is therefore probably not an economically viable option. Utilising the properties of high concentration chloride brines, a flow sheet has been developed and tested whereby the recovery of all of the metals and some of the power requirements for the plant itself can be derived from the ore. The new process overcomes the less-amenable-to-flotation ore characteristics, and provides the opportunity of economic processing in remote locations where the dependency on fossil fuels is both a logistical and an economic concern. The Ferguson Lake deposit of Starfield Resources in Nunavut, Canada, is the subject of this paper, which focuses on the leaching and copper recovery unit operations of the proposed flow sheet.

Jan 1, 2007

By Erwin L. Zodrow

THE AUTHORS welcome this timely opportunity to comment o n a paper by MacLean and Merner (" Room-and- Pillar Mining at the Prince Mine of the Cape Breton Development Corporation " , ClM Bulletin , June 1978, pp. 59-62) concerning the rock falls and their relation to "a change in the strata". First, however, it is proper to express our gratitude to the Cape Breton Development Corporation, and in particular to A. R. MacLean, for making it possible for us at the College of Cape Breton to start two new collections. The first of these is a fossil plant reference collection from the Sydney Coalfield, Cape Breton (Upper Carboniferous period) , and the second is a documentation of the role o f pyrite in the formation of hydrated sulphates (samples from No. 26 Colliery, 1-B Mine, and the Prince Mine at Point Aconi). Conditions of sedimentation in the deltaic-type basin of the Upper Carboniferous time in the Point Aconi area were such that on the (coal) swamp, now represented by the Stubbart (or Hub) seam , (a) clays of varying thickness and extent were deposited , (b) biogenetic sulphur was introduced and (c) flora were buried. These are essentially the culprit s that make rock falls possible and at the same time predictable over large areas (in the present mine). The clays lithified to become shale, and biogenetic sulphur combined with iron to become pyrite (marcasite?), which exists as nodules and in fine-grained layers.

Jan 1, 1978

By F. Baerhold

Recycling of hydrochloric acid from the pickling of mild steel using pyrohydrolysis is a state-of-the-art technology. Recent developments have focused on the production of a high value iron oxide by-product, where the chemical purity and physical properties are the main issues. New processing routes, especially for TiO2 and Ni production, use leaching operations with hydrochloric acid. The feasibility of those processes depends on the availability of an economic and reliable process for the recovery of the acid. Depending on the level and type of impurities and the required specification of the by-product, pyrohydrolysis in a fluid bed or in a spray roast reactor can be the ideal solution. In stainless steel annealing and pickling lines, a mixture of nitric and hydrofluoric acids is used to remove the scale from the surface after heat treatment. Nitrate emissions from the pickling and the rinsing processes have to be avoided because of more stringent environmental regulations. An annealing and pickling line that is totally wastewater-free was developed, where not only the nitric/hydrofluoric acid but also the rinse water, is completely recycled. New developments to increase the HNO3-recovery rate and to obtain a metal oxide by-product that is easier to recycle are presented.

Jan 1, 2006