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By W. S. McDonald

PRACTICALLY all dusts derived from organic matter are explosive and instances are recorded of explosions-some of them extremely violent-having occurred in grain elevators and flour mills. While a discussion of the explosibility of dusts in general, doubtless, would be of more than academic value, it will be of greater interest, on this occasion, to consider various phases of the problems connected with the hazards arising from coal dust. Extensive and valuable research has been carried out during the past few decades on the subject of coal-dust explosions and a great part of this work has been concerned with the preventive effect of stone or other incombustible dusts. Four men have been outstanding in this very substantial achievement. The first is Dr. W. Galloway, who succeeded in demonstrating by experiments that one pound of coal dust mixed with 150 cu. ft. of air formed an explosive mixture. The next is Sir W. Garforth, who proved that stone dust is an effective preventive for coal-dust explosion. The third is G. Haon, and last but not least, L. G. Hill, both of whom laboured incessantly to produce a suitable stone-dust and a satisfactory method of application. Today, mining men all over the world are satisfied and convinced that stone dust, if properly applied, will prove effective in greatly minimizing, if not completely preventing, explosions of coal dust, as has been demonstrated in experimental mines, as well as in actual explosions, in practically every coal mining industry.

Jan 1, 1938

By Jr. Fackler

The ionization potentials of gaseous Group 11elements are similar, with Au(0) being 1.5 eV greater than the next highest member of the group, Cu(0). The ionization potentials are all very much greater than the alkali metals, making these ?coinage? elements rather unreactive to chemical oxidation. Ionization from the first oxidation state shows a different pattern, with Ag(I) being the most difficult of the Group 11 ions to lose an electron. Gold(I) is noble and only normally oxidized in the presence of strongly coordinating ligands such as thiols or cyanide. Gold(I) compounds are 2-, 3- and 4- coordinate, with 3-coordinate species generally showing visible photoluminescence under UV excitation. Dinuclear Au(I) compounds with strongly coordinating S or C ligands can be oxidized to form isolable metal-metal bonded Au(II) compounds which are often readily isolable. Many have been structurally characterized. T he ease with which electrons are lost from closed shell dinuclear sp ecies (with anti-bonding M-M interactions) increases when metalmetal bonded compounds are formed. T his observation was made by our group with oxidative-addition studies of dinuclear gold(I) ylide complexes. It was superbly demonstrated recently by Cotton?s group who reported the isolation and characterization of a dinuclear closed shell transition metal species which is more readily oxidized than cesium. Trinuclear Au(I) pyrazolates, TR(pz), carb eniates, TR(carb), and benzylimidazolates, TR(bz), are well known and undergo electron loss through oxidative addition forming Au(I,III) mixed valence species and ultimately trinuclear Au(III) species. Au(II) species are absent from isolation in these oxidations. These carbeniates and benzylimidazolates also are excellent bases for metals ions such as Tl(I) and Ag(I). The acidic, neutral trinuclear compound [Hg(C6F4)3]3 also interacts with these bases. We have also shown that the neutral organic pi acids C6F6 and TCNQ form stacked pi-acid pi-base products with the trinuclear Au(I) compounds. In this paper, the structure of the octafluoronaphthalene acid-base product will be described. It displays a feature not observed previously in that the product is photoluminescent with a bright yellow emission. The 3.5 ms lifetime is very long and reminiscent of the long lifetimes observed by Balch for the stacked methyl,methoxy Au(carb). The electrochemical oxidation of tetragold(I) clusters, [Au4(form)4] have been studied in 0.1 M Bu4NPF6/CH2Cl2 at Pt working electrode at different scan rates. Three waves are obtained at 0.75, 0.95, and 1.09 V vs Ag/AgCl at scan rate 500 mV/s. The potential of the three reversible waves is independent of the scan rate in the range 50 mV/s to 3 V/s. The current at the third wave is larger than those at the first two waves. These tetranuclear species app ear to be effec tive catalyst precursors for the oxidation in air of CO. Introduction. The electronic structural relationships of the coinage elements and the alkali metals are similar in the sense that each have a [closed shell]ns1 configuration, yet their ionization energies (Table) and chemistries are clearly vastly different. The Group 11coinage elements have an underlying nd10 level immediately below the ns1 level. Unlike the alkali elements, ionization leaves the filled d electron shell the next accessible for further ionization. The coinage elements are all relatively ?noble?, much less reactive to environm ental conditions than the alkali metals. With the coinage elements, oxidation becomes very much dependent upon the types of ligand s availab le to bo nd to the ionized state.

Oct 1, 2003

By WM. G. Heeley

This paper will describe the experience gained and explain the deductions made from the phenomenon of the great squeeze which occurred at Brule Mines. The first indication of the commencement of the squeeze was the breaking of posts on the high-side rib of the slope. At first we thought this was due to a lateral pressure only, and we renewed the broken posts with new ones, the result being that the new posts also were soon broken. A noticeable bending and breaking of the collars occurred, with a corresponding reduction in the height of the haulage slope. These symptoms were also evident on the counter above the slope, indicating that the trouble was of an exceptional nature. In the meantime, we had concentrated a large force of repair men, renewing broken timbers and brushing the roof and floor, but in spite of all our efforts we could not overtake the damage being done. Our next problem was to find the cause of this trouble. We were in a new basin of coal (No. 2) which had only been opened a few months, as we had worked the previous four years in another basin (No. 3) where no such trouble as this had ever been encountered. Naturally our first thought concerned the adequacy of the size of the pillars. We had worked in the No. 3 south basin for the previous four years. without any such experience, with 60-feet pillars between slope and counters; whereas we had established 100-foot pillars in the No. 2 south basin between the slopes and counters with an 80-foot pillar between counter and first line of cross-cuts, and 100-foot pillars between the breasts.

Jan 1, 1924

By J. Mosher, G. Banini, J. Hollow, A. Villanueva

Prior to installation of High Pressure Grinding Rolls (HPGR) at PT Freeport Indonesia (PT-FI) a series of laboratory tests were carried out to determine the design parameters and also determine key performance indicators (KPIs) for the industrial unit. The design parameters derived from the lab test work were then scaled up to estimate the industrial capacity of the HPGRs to be installed. These parameters include specific power draw, specific throughput, and specific force, rolls speed, product size distribution and wear rate of the rolls. This paper compares the performance of the scale-up procedure against the installed industrial size HPGR. Overall, the specific throughput of the industrial size HPGR is higher by a minimum of 30% compared to the expected scale-up value. As a result of the high specific throughput, the specific power draw and grind sizes are below the scale-up expectations in the commercial application. The impact of these factors also contribute to a lower than expected wear rate on the industrial rolls. Installed rolls achieved a service life in excess of 18,500 hours relative to the target of 6,850 hours predicted from the laboratory testing.

Jan 1, 2012

By R. Heikkilä

In this paper the utilisation of building information models (BIM) and construction automation on building sites is discussed. A lot of research has been carried out to develop new applications for using BIM to assist construction site planning, different operations and logistics. The methods of production control and management on site utilize BIM together with machine control and navigation systems. In Finland machine control systems and the automation of construction equipment is widely used in infrastructure construction. Recently similar methods have been introduced also in building construction. This paper describes some latest Finnish examples where BIM-software is used for the planning, execution and control of building construction operations. University of Oulu has studied methods and technologies to capitalize BIM-models. The research has been mainly in infrastructure construction but the activities have recently been extended to building construction. In this paper a BIM-based tower crane operation and control system is discussed as a case study. The aim of this study was to highlight the potential areas were automation can increase the crane productivity and improve site operations and logistics. The construction site managers and tower crane operators interviewed in this study were experienced in using BIM-models on site.

Aug 1, 2013

By Georgy A. Cherkashov, Andrey V. Efimov, Yury S. Borodaev, Nadezhda N. Mozgova, Sergey G. Krasnov, Tamara V. Stepanova, Alexander M. Ashadze

"Abstract - A horizontal mineralogical-geochemical ore zonation with a southeast to northwest trending succession of Cu and Fe (Zn) main zones has been discovered in the Logatchev hydrothermal field (14°45??N Mid-Atlantic Ridge). The major minerals are pyrite, chalcopyrite, bornite, isocubanite, digenite and chalcocite. Zn-sulfide, marcasite and covellite are less abundant. Rare minerals are native copper, zincian copper and cobalt pentlandite (first found in oceanic massive sulfides), Cu and Cu-Co-bearing Fe-disulfides. Two groups of the main sulfide assemblages with different copper contents are recognized: Group I comprises assemblages with primary sulfides (isocubanite, chalcopyrite, pyrite and Zn-sulfide; Cu up to 35 wt% in Cu-bearing minerals); Group II contains assemblages with secondary Cu-rich sulfides (bornite, digenite, chalcocite; Cu ~60 wt%) as well as rare minerals (cobalt pentlandite, native copper and zincian copper). The assemblages of Group I formed at a temperature of about 300°C; the sulfur fugacity (log fs2 atm) at 300°C is probably 9.9. Relations between minerals of this group are contradictory, attributed to non-equilibrium environments, and no unified sequence of crystallization of minerals has been determined. Minerals of Group II replace, rim or cross the assemblages of Group I. Group II minerals crystallized in a distinct sequence (cobalt pentlandite-bornite-digenite- chalcocite-native copper), with increasing copper content from the start to the end of the depositional sequence. This may correspond to pH from 7 to 8 near Eh = -0.2 at 250°C. Minerals of this group were generally formed under hypergene alteration processes. Compositions of ore minerals were studied by means of electron microprobe analysis (EMPA) (150 analyses). Narrow composition fields were revealed in all main sulfides, which comprised known experimental data. ZnS contains 6.0 to 28.0 mol.% FeS, which is close to data known for other hydrothermal massive sulfides from the Mid-Atlantic Ridge (MAR). A common admixture in ZnS is Cu (0.16 to 1.32 wt%). Rare grains of unusual anisotropic Fe-disulfides, (Fe0.95Cu0.05)S2 and Cu(Fe,Co)9S20, were found among the ore minerals."

Jan 1, 1999

By G. Yan

The gas diffusion layer (GDL) is one of the most critical components of the proton exchange membrane fuel cell (PEMFC) in achieving good performance. The GDL serves as a current collector, transport media for fuel and oxidant to the catalyst layers, a support for the catalyst layer and a medium for water management. In this paper, we will discuss the modeling and experimental measurement of the reactant distribution in the GDL and to the catalyst layer. This will be done for some new and advanced engineered GDLs. Novel optical technique which correlates measured data with reactant distribution are used. This technique combined with modeling allows optimal design of engineered GDLs.

Jan 1, 2005

By D. M. Baird

Copper mineralization occurs at several places along the shore of Notre Dame bay, Newfoundland, and at one time formed the basis of a considerable mining industry. The sources of the mineralizing solutions and the structural settings of some of the deposits have not been clearly understood. This paper reports new investigations into the origin and structure of the deposits between Bett's cove and Stocking harbour, in a strip about ten miles long and two miles wide along the western shore of Notre Dame bay. The most complete previous descriptions of the area are those of Snelgrove (1929, 1931, 1938), Douglas, Williams and Rove (1940), and the writer (1947). The discovery of the Bett's Cove deposits took place about 1860, soon after the discovery of the well-known Tilt Cove deposits to the north. Several other small prospects were found between Bett's cove and Stocking harbour between 1880 and 1910. At Bett's cove, active mining began in 1875 and a small smelting plant was built near the mine in 1877. .Mining operations came to an abrupt halt in 1883 after a major cave-in. In 1900, and again in 1906, attempts were made to drain the old workings and reopen the mine but were abandoned long before completion. Total production amounted to about 130,000 tons of hand-picked copper ore which averaged about ten per cent copper, and 2,450 tons of pyrite (Snelgrove, 1938, pp. 52-55).

Jan 1, 1948

By Tom Dettweiler

Who We Are A global pioneer in discovery, development and recovery of deep-ocean assets Shipwrecks Deep-sea Minerals Company Overview Founded 1994 HQ ?Tampa, Florida USA Employees 45 Tampa + 150 Abroad Publicly Traded: NASDAQ:OMEX Requires Specific Financial Controls and Reporting

May 1, 2013

By Victor Maksaev, Marcos Zentilli

"Abstract - The Domeyko Cordillera, the westernmost uplifted crustal block of the composite High Andes of northern Chile (20°S to 28°S) hosts a narrow N-S trending belt of Late Eocene-Oligocene giant porphyry copper deposits, which include Collahuasi, Chuquicamata, El Abra, La Escondida, and El Salvador. These deposits are spatially and genetically associated with the closing igneous activity along this range, prior to a 30 km eastward jump of the magmatic front in response to tectonic plate interaction. The porphyry copper deposits are also spatially associated with a major intraarc strike-slip shear system, the Domeyko Fault System. Although the tectonic uplift of the 3000 m to 5000 m high range has generally been assumed to be mostly Miocene in age, field relationships suggest that the Domeyko Fault System and tectonic uplift were active as early as the Eocene, coinciding with porphyry copper emplacement between 41 Ma and 30 Ma. Apatite fission track (FT) thermochronology provides both age data and a time-temperature history for rocks since they cooled below a temperature of ca. 125°C (equivalent to a depth of 4 km to 5 km under normal geothermal gradients) on their way to the surface during exhumation, or after a heating event. Apatite FT data from the Paleozoic crystalline basement of the Domeyko Cordillera indicate that at least 4 km to 5 km of rocks were eroded during exhumation of this tectonic block between ca. 50 Ma to 30 Ma (Middle Eocene to Early Oligocene), a time that immediately precedes and overlaps with the emplacement of giant porphyry copper deposits. The FT data constrain the age and duration of a period of crustal thickening and extensive erosion known as the Incaic compression, an event recognized in the Andes of Chile and Peru. Assuming that cooling was due to denudation alone, modelling of the FT data allow estimation of denudation rates between 200 and 100 m/My during this period. In contrast, exposures of pre-porphyry Paleocene intrusives on the western edge of the Domeyko Cordillera reveal apatite FT ages that are concordant with biotite 40Ar-39Ar dates, indicating shallow emplacement, fast cooling and negligible exhumation. The apatite FT ages of the Chuquicamata and El Abra porphyry copper deposits are only marginally younger than their 40Ar-39Ar dates, implying fast cooling/exhumation of shallow mineralizing systems (ca. 2 km to 3 km). Their FT time-temperature history is compatible with extremely low rates of exhumation (ca. 50 m/My) since about 30 Ma (Early Oligocene). This limited extent of erosion, due to exceptional aridity, has greatly contributed to the preservation of rich supergene enriched blankets above some of the porphyry copper deposits.A model is proposed, which is consistent with field relationships, geochemical, and geochronological data. High relative velocities and intermediate-angle oblique convergence between the Nazca and South American plates in the Eocene-Early Oligocene led to intra-arc transpression partitioned into reverse faults of opposing vergence and a right-lateral shear system (the Domeyko Shear System) localized along the magmatic front. Crustal shortening and thickening led to uplift within the Domeyko Fault System and to erosion of at least 4 km to 5 km. Crustal thickening deepened the zone of magma generation, and magmas accumulated in the lower crust, allowing small volumes to rise rapidly to shallow levels along transtensional domains of the regional shear system. A similar model of crustal thickening and shortening before and during porphyry copper emplacement in zones of transtension may also apply to the Miocene-Pliocene giant porphyry copper province of central Chile."

Jan 1, 1999

By Claudia Gasparrini

"Silver occurs in about 200 minerals in variable amount s. Silver ores usually have 5 or 6 and in some instances as many as 10 species of silver minerals. All these minerals may have different flotation and leaching properties and should be correctly identified for successful recoveries. Grain size and host minerals which are critical in gold recovery, are not always as important for silver minerals.IntroductionMineralogical factors affecting the metallurgy of silver are , as for other metals: (i) the silver-bearing mineral s ; (ii) their grain size, and when dealing with very fine sizes; (iii) their host minerals; and (iv) the association they form with the silver-bearing minerals. Of these, the silver-bearing minerals are more often the cause of problems during recovery as opposed to gold whose metallurgy is generally more affected by grain size and host minerals. The problems derive mainly from the complexity of the silver mineralogy: over 200 minerals exist bearing the element in major, minor and variable amounts.As a member of group I-B of the periodic table, silver forms extensive so lid solutions with the other two elements in the same group , copper and gold. It combines with sulphur, tellurium and selenium in covalent bonds and with chlorine, bromine and iodine in ionic bonds. Where the fluid composition, temperature and pressure during crystallization allow it, silver also combines with arsenic, antimony, lead, bismuth, tin, mercury, indium, thallium, and germanium in many instances as a minor element in sulphide , sulphosalt and native element minerals. Cations which silver replaces to a lesser extent than copper and gold are iron, manganese, zinc and probably nickel and cobalt."

Jan 1, 1984

By Yves Prévost, Guy St-Amant, Guillaume Dion

In 2010, the foreseen increase of copper grade in feed concentrate at the Horne Smelter was a significant challenge to maintain a steady copper flow throughout the process. The Horne Smelter process includes a Noranda Reactor, a Noranda Converter, pyro refining vessels and anode furnaces. Of the many challenges involved, improving the single casting wheel performance was one of the key topics. Its reliability had to be improved to meet the new production objectives, as anode copper production was to increase from 170 000 to 225 000 tonnes/year. A multidisciplinary team was dedicated to improve the casting wheel availability. The improvement project allowed pinpointing failure modes and reviewing operational and maintenance practices. The common understanding developed by the team allowed improving small components with a high gain-to-effort ratio. The project allowed reaching operational targets without any significant investment. INTRODUCTION In operation since 1927, the Horne Smelter, located in Rouyn-Noranda, in Quebec, has undergone several technological changes since its original construction. Built to smelt the Horne mine concentrates, the smelter also accepted some local custom feeds from the first years of operation. When the Horne mines stopped production in 1976, the plant became a 100% custom smelter. With the development of the Noranda Reactor (1973) and Noranda Converter (1997), the Horne smelter increased its productivity and improved its environmental performance. Continuous improvement of the Horne process allowed maintaining a high level of flexibility in the operation of the smelter, while improving its overall capacity.

Jan 1, 2019

By D. S. Harries, R. I. L. Guthrie

"The use and development of scientific disciplines involved in heat transfer technology, related in general to steel masses and in particular to batch annealing, is demonstrated.The measurable benefits of cooperation are tabled; on industry's side, this includes a 10 to 20 per cent decrease in annealing time, and a corresponding higher productivity potential. The returned benefits to the academic engineer include the development and refinement of new computer algorithms related to heat transfer mechanisms.IntroductionThe object of this discussion is not really to describe an improvement in the batch annealing operation, but to use the project as an example of joint work between industry and the academic field. Both parties have derived a number of substantial benefits. These benefits will be listed, of course, but the batch anneal project will be used just as a typical example of cooperation. Why it happened will be explained, what actually happened will be described and finally some thoughts about areas in the field of heat transfer, where cooperation will continue in the future, will be highlighted. The paper will close with a message.Industry OverviewAt the outset, perhaps it should be understood that, in general, the Research Department at Dofasco believes that the universities and their staff are not destined for the problem-solving role in industry. Its opinion is that the university staff is best suited to the gathering and dissemination of knowledge. There are other more professional problem solvers for industry, including the steel industries' own individual investigation groups. Dofasco, therefore, looks to its academics for consultation. It benefits by bouncing ideas off them, and through rubbing shoulders with them in such a way that their knowledge can be tapped, and thus establish more effective scientific routes. In addition, the younger and brighter engineer s can broaden their scope through the intellectual contact with experts. The university professors can, it is believed, benefit through closer contacts with result-orientated research. They can also develop an appreciation of the fiscal control necessary for industrial investigations, without government subsidies, grants, etc., and with massive overheads."

Jan 1, 1982

By N. J. Bunce, B. Vollick, A. F. Souza, D. Bejan, P. Maharaj, C. Shamshoom

"Copper electrodeposition from synthetic and authentic acid mine drainage (AMD) is inhibited by ferric iron (Fe(III)), through re-oxidation of copper. Polarization to –2.5 V versus standard hydrogen electrode prevents the dissolution of predeposited copper from the cathode. Above pH 1, copper deposition is independent of Fe(III) concentration to approximately 25 g/L. Fe(III) is reduced to ferrous iron (Fe(II)), with a high combined current efficiency for iron and copper reduction. In a divided cell, the conversion of Fe(III) to Fe(II) is almost quantitative, with efficient transfer of acidity from catholyte to anolyte. Prospects for developing electrochemical technology for complete remediation of AMD are discussed.RÉSUMÉ En raison de la réoxydation du cuivre, le fer ferrique (Fe(III)) nuit à l’électrodéposition du cuivre à partir de drainage minier acide (DMA) véritable et synthétique. Une polarisation à -2,5 V par rapport à l’électrode standard d’hydrogène empêche la dissolution du cuivre déjà déposé de la cathode. À un pH supérieur à 1, la déposition du cuivre est indépendante de la concentration en Fe(III) jusqu’à environ 25 g/L. Le fer ferrique est réduit en fer ferreux (Fe(II)) avec une efficacité combinée élevée pour la réduction du fer et du cuivre. Dans une cellule divisée, la conversion de Fe(III) en Fe(II) est près de la quantité théorique, avec un transfert efficient de l’acidité de catholyte à anolyte. Les perspectives de développement d’une technologie électrochimique pour la remédiation complète du DMA sont discutées."

Jan 1, 2016

By R. H. McCorkell

Measurements of radon in air and aqueous solutions can be affected by leakage from vessels in which samples and standards are kept and by absorption and later release of radon by the materials of these vessels. The author had received various oral communications concerning the se processes : e.g ., that natural rubber and greases absorb large amounts of radon, whereas silicone rubber and grease do not; and that radon is readily lost from polyethylene bottles and that inverting glass bottles containing aqueous samples reduced radon loss from them . However, the results of actual tests and quantitative data showing these effects were not available. For this reason, it was necessary to make numerous measurements of the leakage and absorption of radon in the course of designing apparatus and methods for measuring radium and radon concentrations. It was thought that the data obtained might be of use to others, and consequently they are compiled in the present note .

Jan 1, 1980

By A. J. Smethurst, S. B. Hearn, S. Boskovic

"The problem of crud in solvent extraction is well known and can be a major handicap and operational issue. Colloidal silica can cause a number of problems including interfering with flocculation, initiating crud formation in solvent extraction (SX), decreasing SX extraction kinetics and increasing SX phase disengagement times. Flocculation can be utilized to remove some of the troublesome particulates but colloidal silica does not flocculate well and presents a different problem requiring innovative chemistry to solve. Coagulants can assist by facilitating the removal of this colloidal silica by promoting the agglomeration of the particles to a size which can be more readily settled or flocculated in solid/liquid separations. This is achieved when the coagulants bind to the surfaces, displacing water and destabilizing the colloids, whereupon they bind to each other which facilitate their amenability to conventional flocculation.INTRODUCTIONSilicate minerals are abundant in the upper layers of the Earth’s crust, and there are few mineral deposits without significant levels of gangue silicates. Silicate minerals include the pure silicas, such as quartz and other silicate containing minerals such as clays, chlorites, feldspars, as well a vast number of less common silicates.During the acid leaching of ores, two types of fine silica particles are released in solution from the dissolution of the host mineral. The first consists of partly depleted silicates, and the second is colloidal silica, which forms in solution. It is this second type which has the potential to cause crud formation as well as poor solution clarities, slow filter rates and excessive flocculant usage (Figure1)."

Jan 1, 2016

By R. Flood

"Oil has been discovered off Newfoundland in a number of locations on the Grand Banks, the most notable and exciting being in 1979 when Hibernia was discovered. This discovery has brought new challenges to the province as well as to all of Canada. During the seven years"" since its discovery, both industry and governments have attempted to define its parameters and to find the most efficient and economical way to develop the field.A number of studies have been completed during the interval and in 1985, Mobil Canada Ltd. and partners stated that they would prefer to develop the field by using a concrete Gravity-Based Structure (GBS). IntroductionHibernia is located in an environmental climate much more severe than that of any previously developed oil field. The wind and wave conditions are similar to those of the North Sea, but unlike the North Sea, any structure on the Grand Banks would have to contend with ice floes and icebergs. Decisions had to be made on whether fixed structures could be put in place that would withstand the pressures of the ice and the impact of an iceberg, or whether structures that could be removed when such impacts were imminent would be used.Early studies in 1981, determined that it was possible to build a concrete Gravity-Based Structure which could withstand the impact of the largest icebergs that are anticipated to float in that area of the banks.Additional studies increased the knowledge of icebergs: their patterns and size, and verified the original conclusions that Concrete Gravity-Based platforms would provide a practical solution."

Jan 1, 1988

By A. M. Cann, C. I. Godwin

"The Kemess porphyry copper-molybdenum deposit occurs in the Intermontane Belt of north-central British Columbia. The deposit is in andesitic to basaltic flows and tuffs which may be correlated with the Savage Mountain Formation of the Upper Triassic Takla Group. Most known chalcopyrite and molybdenite is associated closely with a 500-m-diameter zone of intense quartz-sericite-pyrite alteration. A zone of supergene enrichment, up to 30 m thick, underlies a leached capping about 20 m thick. The age of mineralization and the surrounding granodiorite and quartz monzonite pluton is Early Jurassic. K-Ar and Rb-Sr analyses indicate that the mineralization and alteration is slightly younger (l82±6 Ma) than the granitic intrusion (KAr: about 205±6 Ma; Rb-Sr: 190±4 Ma). The low 87Sr/J6Sr initial ratio for the granodiorite is typical of plutons in the Intermontane Belt.IntroductionKemess is a medium to small porphyry copper-molybdenum deposit with significant gold and silver values (Pilcher and McDougall, 1976). This paper describes the lithologies and alteration at this property; geochronology by Rb-Sr and K-Ar methods defines the ages of mineralization and surrounding plutons to be Early Jurassic.The property, located in the Thutade Lake area of northcentral British Columbia (NTS Map 94E; lat. 57°04'N; long. 126°44'W), is about 425 km northwest of Prince George (Fig. 1). Closest road access is 35 km southeast of Kemess. Final access must be by float plane or helicopter. The British Columbia Railway right of way passes 70 km to the southwest of theproperty.A prominent gossan zone at Kemess was staked in 1967 by Kennco Explorations (Western) Ltd. following detection of geochemical anomalies during stream sampling the previous year. During 1968, 1969and 1971, Kennco completed 232 m of X-ray diamond drilling, conducted geological mapping and carried out geochemical sampling of silts and soils (Stevenson, 1969; B.C. Ministry of Energy, Mines and Petroleum Resources, G.E .M., 1969 and 1971). Getty Mines Ltd. optioned Kemess in 1975and 1976. They remapped the area and diamond drilled 12 BQ and NQ holes, totalling 2065 m (B.C. Ministry of Energy, Mines and Petroleum Resources, Expl. B.C., 1975)."

Jan 1, 1980

By B. A. Sparkes, J. H. Reeves

"The St. Lawrence Granite hosts vein-type fluorite mineralization that was mined until 1977. Recent drilling identified a significant fluorite-bearing structure hosted in adjacent meta-sedimentary country rocks. Several phases of vein fill and brecciation indicate there are three phases of fluorite mineralization, of which the later two phases are volumetrically significant. The earliest fluorite is purple and occurs along joint and fracture surfaces, in fault-breccia matrices, and as stockwork veins. The second phase comprises primarily red, yellow, blue-green, and white colours of fluorite. The latest phase is green with lesser clear fluorite. Identification of fluorite veins in the meta-sedimentary rocks opens up new areas for exploration.RÉSUMÉ Le granite St. Lawrence contient une minéralisation filonienne de fluorite, laquelle a été exploitée jusqu’en 1977. De récents forages ont permis d’identifier une structure importante contenant de la fluorite encaissée dans des roches métasédimentaires adjacentes. Les nombreuses phases de remplissage de filons et de formation de brèches indiquent qu’il y a eu trois phases de minéralisation de fluorite et les deux dernières sont importantes d’un point de vue volumétrique. La plus ancienne fluorite est mauve et se trouve le long de surfaces de joints et de fractures, dans les matrices de brèches de failles et en tant que stockwerks filoniens. La deuxième phase comprend surtout des fluorites de couleurs rouge, jaune, bleu-vert et blanc. La fluorite de la plus récente phase est verte avec des quantités moindres de fluorite claire. L’identification des filons de fluorite dans les roches métasédimentaires ouvre de nouveaux secteurs pour l’exploration."

Jan 1, 2016

By K. Turgeon, D. Larivière, L. Whitty-Léveillé, J. -F. Boulanger, C. Bazin

"The processing of ore containing rare earth elements leads to the production of an impure solution of these elements. The separation of the rare earths from the impurities and the production of individual elements is usually carried out by solvent extraction. The effectiveness of the extraction conditions and of the reagents is generally tested in the laboratory. This paper deals with the processing of results from solvent extraction laboratory tests planned to generate data redundancy. A method is proposed to take advantage of the data redundancy by accounting for the pH variation during the extraction. The parallel processing of several tests also allows estimating the equilibrium constants for the extraction. The proposed method produces equilibrium constants that are more reproducible than values estimated using conventional approaches. The method is illustrated with solvent extraction tests conducted on synthetic solutions of rare earth elements.INTRODUCTIONThe processing of ores containing rare earth elements (REE) usually includes the production of a concentrate of the minerals carrying the REE. These minerals, for instance monazite and bastnäsite, contain the 14 elements from La to Lu plus yttrium and scandium. As an example monazite has the general formula of (La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy…Lu)PO4 with a typical lanthanum content of 20-26%, cerium content of 40-50%, praseodymium of 4-6%, neodymium of 16 to 20%, and decreasing concentrations of heavier elements (Gupta & Krishnamurthy, 2005). During the processing of a REE mineral, it is generally not possible to isolate and separate a single REE from all the rest. The mineral molecules need to be broken (usually via a heat treatment followed by leaching with a base and/or an acid) to produce an aqueous solution of the REE of the ore. After purification of the solution, the REE can be precipitated as a bulk concentrate and sold to a refinery that separates the REE into particular groups of REE such as the light versus heavy REE or into individual elements such as lanthanum, neodymium, or europium oxides to yield value-added products."

Jan 1, 2016