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By M. C. Bluteau, G. P. Demopoulos

Arsenic reports in the effluents of many non-ferrous metallurgical operations. The production of scorodite, a crystalline ferric arsenate, is considered as an attractive option for the fixation of arsenic from aqueous effluents. However, scorodite solubility and long-term stability in the pH region of interest for tailings disposal have not been thoroughly investigated. In this study the long-term stability of scorodite in the pH 5 to 9 region and the mechanism of scorodite dissolution were studied. Construction of eh-pH diagrams indicated that scorodite stability is highly dependant on the nature (stability) of co-existing iron-hydroxide/oxyhydroxide. It was also found that when scorodite dissolves, a ferrihydrite phase having very small particles size (nano-scale) forms and that the growth and crystallization of this material are delayed by the presence of arsenate even under accelerated (75°C) ageing conditions. Around neutral pH and ambiant temperature (22°C) scorodite seems to reach an equilibrium with ferrihydrite after 48 weeks yielding soluble arsenic concentrations < 5 ppm.

Jan 1, 2004

By Ruan Chi, Zhenyue Zhang, Zhengyan He

In order to understand what governs the leaching of exchangeable rare earth (RE) and impurities and enhance the RE leaching process, the effects of the concentration of ammonium sulfate, pH and leaching temperature on the migration of RE and aluminum (Al) during the leaching of weathered crust elution-deposited rare earth ore was studied. The elution curves for ammonium ion (NH4 +) were also studied to reduce the consumption of the leaching agent. It was found that a high concentration of leaching agent can enhance the leaching process of RE and Al, reduce the breakthrough volume of NH4 + and more rapidly obtain the equilibrium of NH4 +. However, excessive leaching agent can both increase the cost and the burden on the environment. There is almost no variation on the elution curves of RE and Al in the pH range of 4-8 and control of the pH of the leaching agent can be omitted. It is better for the leaching work to be done in summer since higher temperatures can enhance the RE leaching process and improve the use ratio of ammonium. Using 0.1 mol/L ammonium sulfate for leaching 250 g RE ore, 95.42% RE extraction can be obtained when the volume of leachate is 102.6 mL. At this moment, only 18.17% of NH4 + is used to exchange RE and 49.22% of NH4 + is left in the leachate that can be reused as leaching agent by replenishing ammonium sulfate. The results of our studies can provide theoretical guidance for high efficiency and low consumption exploitation of RE ores.

Jan 1, 2016

By Gustavo Brunello

Motor Failure Rates and Cost ? Motor failure rate is estimated: 3-5% per year. ? In Mining, Pulp and Paper industry failure rate is up to 12%. ? Sometimes process downtime costs are higher than motor ?? Motor failures are due: Electrical 32% Mechanical 31% Environmental 36%

Feb 1, 2008

By Waldbillig. D.

A baseline of the poisoning effect of hydrogen sulfide (H2S) fuel impurities on solid oxide fuel cell (SOFC) anodes was developed using polarization testing. After the baseline behaviour was characterized, tests to study the effect of various H2S concentrations on the rate and amount of cell voltage degradation and recovery were performed. Attempts were made to improve the rate and amount of recovery by various methods. Testing was very reproducible, but significant electrochemical performance degradation was seen after all H2S poisoning tests even at an H2S concentration of 0.1 ppm. Degradation is initially quite rapid, but after a period of time the rate of degradation levels off. After poisoning was complete, the H2S flow was stopped and the cells were allowed to recover. Some recovery was seen after poisoning, but cell performance was never fully recovered.

Jan 1, 2005

By S. Huang, K. Xia

"During crushing, rock particle is subjected to complicated loading and the particle shape influences the fragmentation outcome. Thus, a highly controlled laboratory test is desired to establish the relation between the loading and the fragmentation parameters for better understanding the rock crushing mechanism. In this work, a split Hopkinson pressure bar system in combination with high speed cameras is utilized to carry out a dynamic ball compression test, in which the spherical rock sample is adopted to avoid the shape effect. Using the elasticity theory, the history of the axial symmetric tensile stress perpendicular to the diametrical direction along the loading axis is determined, from which the loading rate and the dynamic indirect tensile strength are calculated. With the aid of the moment-trap technique, the total energy absorbed by samples is accurately determined from the one-dimensional wave analysis. Furthermore by considering the kinetic energy of the sample fragments using the high speed camera snapshots, the surface energy is determined for each sample. The relations between the loading rate and the fragmentation parameters, i.e., the number of fragments and the surface energy are established. The application of this method to a granitic rock shows that it is flexible and can be applied to the crushing study of generic brittle solids. INTRODUCTIONCrushers are widely used to break rocks to extract specific minerals in the mining industry, and to obtain rock fragments with desired size distribution in construction industry. During crushing, the breakage of particles can be in either the single-layer mode or the multi-layer mode. In the single-layer mode, the particle breakage can be assumed to be isolated, in which the interaction between particles can be ignored. It is thus suggested by many researchers that highly controlled single particle test should be performed to establish the relation between the input mechanical energy and size reduction for better understanding the crushing mechanism (Yashima et al., 1987; Tavares, 2007; Pitchumani et al., 2004)."

Jan 1, 2015

By Pingchao Ke, Zhihong Liu

Fe(III)-As(V) precipitates were synthesized from the Fe(II)-As(V)-SO42--H2O system at 90°C in initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The synthesis were carried out by introducing oxygen gas into the system to oxidize Fe(II) ions into Fe (III) ions, and at the same time, adding aqueous sodium carbonate solution into the system to neutralize the acid released by the hydrolysis reactions, with the purpose of keeping the pH constant at 1.5±0.05. The precipitates obtained were characterized by XRD, chemical composition analysis, SEM, XPS, and Raman spectrum. The results indicated that the particles in the precipitates were in the morphology of irregular aggregation with their sizes in the range of about 1–4 µm. The precipitates consisted of scorodite, ferric arsenate and amorphous hydrated ferric oxide, of which amorphous hydrated ferric oxide formulated as Fe(OH)x(SO42-)y. The characteristic XPS peaks of Fe-AsO43- and Fe-O in the precipitates located at 711.8 and 713.3 eV, separately, and the existence of amorphous hydrated ferric oxide led to two series of shake off lines developed over the end of high binding energy of Fe2p XPS. The precipitates were stable in TCLP tests at pH 4.93 for 60 hours with the arsenic concentrations in the leaching solutions being 0.27 mg/L and 0.59 mg/L for the precipitates prepared in the initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The tests for the long-term stability of the precipitates were carried out by leaching them for 40 days at 25°C under various media in the pH range from 9.50 to 10.57, and the results showed that the precipitates synthesized in this study were much more stable than those by previous researchers.

Jan 1, 2017

By Étienne Yvenou, Martin Désilets

Le procédé d’électroaffinage du Cu est nécessaire pour atteindre les niveaux de pureté requis pour les applications les plus courantes telles que son utilisation comme conducteur électrique ou thermique.

May 2, 2024

By Jehan Rondot

Les bancs de quartzite inhabituellement purs et epais decouverts lors de la cartographie geologique de la region de Charlevoix sont maintenant entres au stade de !'exploitation et se revelent etre une richesse naturelle durable pour cette region. Les etudes stratigraphiques effectuees dans cette partie (Quebecia) du bouclier canadien indiquent que la succession: lo. complexe a amphibolite et leptynite a la base, 2o. quartzite et gneiss a sillimanite, muscovite et gneiss calcosilicate et conglomeratique au sommet est constante sur de grandes distances (de Charlevoix a la Basse Cote Nord) et represente une sedimentation continentale et de plateforme, peu epaisse, du proterozotque inferieur. La purete et la grande epaisseur du quartzite s'expliqueraient par un processus de sedimentation continentale complexe ou se succedent climat tropical-humide et glaciaire-aride et transport fluviatile et eolien. Parmi la multitude de depots de quartzite qui existent dans le monde, peu sont de qualite superieure. Or, de par sa composition chimique, le quartzite de La Galette se compare avantageusement a ceux des meilleurs gisements des Etats-U ni s, de l'Europe de l'Ouest et de I' Afrique du Sud. D'acces facile pour l'exploitation, les gisements ne sont qu'a une quarantaine de kilometres de Baie Saint-Paul ou de La Malbaie, sur le SaintLaurent. L'utilisation en metallurgie du quartzite de La Galette comprend la production de silicium, de ferro-silicium et d'autres alliages de silicium . La composition du quartzite est en outre appropriee pour la production de carbure de silicium et de silicate de sodium. Les fines peuvent etre utilisees pour la fabrication du verre et comme matiere de charge.

Jan 1, 1984

"Introduction The first documentary record of coal nurung on Vancouver Island was that of the Hudson Bay Company operations in the Suquash area in 1836. Between 1836 and 1862, the Hudson Bay Company mined some 65,000 tonnes from this Suquash field and the Nanaimo coal fields discovered in 1851. However, systematic mining of coal did not take place until the Hudson Bay Company holdings were sold to the Vancouver Coal Company in 1861, and a rival company under Robert Dunsmuir was established in 1869. These two interests under various organizational names and jointly as the Canadian Collieries (D) Ltd. (1928) developed and exploited the coal seams of the Nanaimo and Comox Basins from 1852 to 1966. Because of the proximity of the coal outcrops to tidewater, the coal was readily marketed to ocean-going and coastal ships for fuel. However, during the turn of the century the main market was to meet the demand of the developing cities along the west coast of Canada and the United States for residential and commercial heating. Island-based copper smelters and brick factories, and the coming of the railroads motivated by steam engines increased the demand. This economic success of the industry continued until 1922 when a peak production of over 1,750,000 tonnes was reached. Following 1922 labour unrest in the industry, which affected the certainty of supply, and the availability of alternatives in the form of California petroleum and mainland coal combined to cause a rapid and steady decline in the demand for Island coal. In spite of post-and pre-wartime prosperities the trend could not be reversed. Serious coal mining phased out in the Nanaimo area in 1939 and in the Comox area in 1967. puring the 114 years in which the industry flourished over 75 million tonnes of coal were mined from more than 30 mines and a minimum of ten new mining communities were established on Vancouver Island."

Jan 1, 1985

By J. Donovan

Underhand cut and fill mining is being planned for selected areas at the David Bell Mine where high ground stresses have resulted in particularly challenging mining conditions. In order to test the placement and performance of a variety of underhand cut and fill paste mats three different designs have been installed and extensively instrumented along the A-Zone 9C ore sill. The sill is approximately 87m long, 4.0m high, and 5.0m average width. The sill was broken into 3 sections each of which will contain one of the sill mat designs. The underhand sill will be mined 3.75mW x 4.0mH, allowing for some overbreak while minimizing the risk of the back span exceeding the design limit of 4.0mW. Each test sill mat includes pre and post-support and includes 0.5m (18?) broken muck mat placed along the sill floor. Upon developing beneath these mats quantitative and qualitative measures will be used to determine which design is the most suitable for application in underhand mining at David Bell.

May 1, 2007

By R. M. Berry

A brief outline of refining methods used to (1) upgrade yellowcake to nuclear purity and (2) convert the uranium to the chemical and physical forms required by the fuel fabricators is presented. The uranium hexafluoride (UF6) production facility now under construction at Eldorado, Port Hope, is discussed. Technological improvements in uranium refining are considered.

Jan 1, 1969

By Luis Bergh, Juan Olivares, Juan Durán, Juan Yianatos

"In the last decades heuristic approaches based on logic rules have been one favored tool to control flotation units and plants on top of distributed control systems. Fundamental knowledge on flotation processes, expressed in reliable models, and programs to assure the quality of the information, contained in available measurements, are still insufficient to develop robust predictive control strategies. In this paper the idea of using simplified models, when a known disturbance is coming into the process, is explored. As a first approach, the set points of the froth depth and air flow rate controllers are estimated based on this model. Since these target predictions are only approximate, a conventional feedback expert system, based on logic rules, continues the task of calculating the set points of the distributed controllers, in order to decrease the gap between actual and desirable metallurgical targets. This combined actions permitted a fast response of the process to change the operation of the circuit when a measured disturbance is detected. This control system was implemented and experimentally evaluated in a pilot rougher flotation circuit, with three pneumatic cells, with froth depth and air flow rate controllers in each cell. Since the circuit is operated for the air-water system, a phenomenological model, with parameters estimated from industrial data, is fed on-line with real operating variables and virtual values, characterizing the feed (grades, solids%, particle size distribution), in order to predict the metallurgical targets (recovery and concentrate grade). Several cases are discussed showing the benefits of this control system and the possible improvements to work on. INTRODUCTIONToday, large size mechanical flotation cells of 100 to 300 m3 are used in rougher operation in different flotation industrial plants, in Chile and worldwide. However, in spite of the advances in fundamental research and the notable growing in equipment size, with more complete instrumentation systems, there are still a lack of reliable data for industrial flotation modeling and simulation to advance in better control systems design."

Jan 1, 2016

By S. Forgeron

Presentation ? Introduction ? Canadian Underground Coal Mines ? Standardization of Geological Assessment ? Geomechanics Base-line Studies of Canadian Coal Mines ? Cape Breton Development Corporation Prince Mine ? Quinsam Coal Corporation ? 2 North and 4 South Mines ? Smoky River Coal Corporation 5B-4 Mine ? Conclusions and Baseline Comparison ? Figures

May 1, 2001

By Phillip J. Mackey, Susumu Okabe

Copper mining and smelting has been carried out in Japan for over 13 centuries and in fact stretching back into antiquity. In 1889, the first electrolytic copper refinery in Japan based on Elkington’s principles was started by Furukawa Mining at Honjyo in downtown Tokyo based on the multiple or parallel system. Within two decades, a number of other copper refineries had begun operation. Interestingly, but perhaps not surprising given Japan’s long history of copper production, this first refinery in Japan commenced just ten years after the first refinery in the USA (1879), and not long after the first plants in Europe. By 1935, as a result of growth in copper demand, there were six domestic copper electro-refineries in Japan with an installed capacity of 97,800 tonnes/a, while actual production was 71,200 tonnes/a. Since about 1932, the majority of these plants were based on the more common parallel or multiple system. In 1946, just after World War II, domestic production capacity had dropped considerably to 29,000 tonnes/a, however with reconstruction, capacity and production expanded rapidly, with production reaching 81,000 tonnes/a in 1955, 187,000 tonnes/a in 1960 and 307,000 tonnes/a in 1965. The introduction of the first refinery and the early ones that followed and subsequent developments are discussed in this paper. The major technical achievements during the high growth period from 1945 to 1963 included: the use of fire- refined anodes; the introduction of newly-developed rectifiers; the introduction of lead-lined or vinyl-lined concrete cells; improvements in the electrolyte heating system; application of improved anti-corrosion materials and the introduction of heat-insulating surface coverings. In 2018, Japan’s refined copper production totaled 1,595,000 tonnes of copper, with Japan ranking third in the world after China and Chile. INTRODUCTION In 2018, Japan’s refined copper production totalled 1,595,000 tonnes of copper and Japan ranked third in the world for refined copper after China and Chile (Wood Mackenzie, 2019). There are now eight copper refineries in Japan which provide Japan’s production of refined copper. These plants are listed in Table 1 (Wood Mackenzie, 2019), also showing the production trend since 2013; in general, production over this period has been relatively steady. The Toyo plant is now the 7th largest copper refinery in the world after several large plants as rated by capacity in China, Russia and India (ICSG, 2019).

Jan 1, 2019

By Jim Hazzard

A numerical investigation is presented to examine fluid flow in fractured rock slopes. In mining geomechanics, different numerical modelling approaches are used to estimate fluid pressures in open pit mines. The most common technique is the Equivalent Porous Medium (EPM) approach in which the fractured rock is assumed to behave as a porous continuum. Depending on the geometry and properties of the problem, this may not always be the best approach. The paper presents a parametric study to examine the effect of fracture spacing, fracture and matrix diffusivity and excavation rate on the fluid behaviour in rock slopes. Based on the model results, guidelines are provided as to when EPM models can be used and when different modelling approaches (e.g., discrete fracture flow) may be necessary.

Jun 1, 2012

By C. L. Lewis

"The development of computer process control at the Lake Dufault concentrator is reviewed and the on-stream X-ray analysis -computer system is described briefly. Some applications of the computer in metallurgical process control are described.The computer sequences slurry sample streams to the analyzer and translates the analytical results from voltage signals to elemental percentages. The required flotation reagent flow rates are calculated from analyses and mill-feed tonnage rates and the reagent feeders are set automatically to provide such flow rates. X-ray calibration time has been reduced from about 45 minutes to 15 minutes by the use of a computer program. Metallurgical and operating personnel have acquired the ability to program the computer and have extended the system capability to allow the calculation of recoveries, averaging of mill data, application of ore specific gravity in grinding control, control of oxidized ore flotation and the development of an economic recovery program."

Jan 1, 1971

By Zhibao Li, Lanmu Zeng

The behavior of dicalcium silicate in NaOH-NaAl(OH)4-Na2CO3 solution is of significance for controlling the silica level in the production of alumina via the sintering process. Dicalcium silicate samples were obtained through a twostep approach: coprecipitation of calcium and silicate from CaCl2-Na2SiO3-NaOH solutions; and calcination of the hydrated precursor at 1200°C for 4 hours. The optimization of the synthesis parameters including temperature, solution concentrations and aging time was also investigated. Xray diffraction (XRD) and chemical analysis show that the calcined solids include dicalcium silicate with trace amounts of wollastonite. The solubility of the synthesized dicalcium silicate in HCl, NaOH, mixed NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was determined. It was found that the solubility increases with increasing HCl and NaOH concentration. The effect of temperature on the solubility in HCl solutions is limited, but the solubility decreases with increasing temperature in NaOH solutions. The solubility of dicalcium silicate in NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was shown to increase with increased temperature, Al(OH)3 and Na2CO3 concentration. The BromleyZemaitis model for the aqueous electrolyte system was selected to predict the solubility of dicalcium silicate. The model’s predictions yielded certain success compared with experimental solubility data.

Jan 1, 2014

The AG/SAG circuit discharge P80 is now increasingly referred to as the “Transfer Size” or T80 for short. From the literature it is apparent that in circuit design some approaches to the sizing of AG/SAG mills as well as the ball mills that they feed use this parameter. This paper reviews whether the use of the T80 is appropriate in this context. In the course of the review examples of AG/SAG discharge size distributions measured from range of operating circuits are used to illustrate the arguments made.

Jan 1, 2012

By Fathi Habashi

Teaching mining, metallurgy, and geology preceded that of the other engineering disciplines. The first School of Mines was founded in 1756 in Potosi (Fig. 1) in New Spain (now Bolivia), 38 years before the first Polytechnic School (École Polytechnique) was founded in Paris. The schools of mines were also pioneers in the teaching of chem- istry. The teaching staff at these schools cre- ated the basic literature on metallurgy, mining, and geology. They analyzed and dis- covered numerous minerals and discovered the metals tungsten, beryllium, chromium, uranium, zirconium, vanadium, indium, and germanium. The history of some of the first schools is given together with biographies of some of their distinguished teaching staff.

Nov 1, 1997

By R. Thierbach, W. Kahnt, Oberthür. T., D. Eisenburger, V. Gundelach

ABSTRACT: The ground penetrating radar (GPR) method was used in a platinum mine in Zimbabwe by members of the Federal Institute for Geosciences and Mineral Resources (BGR). The measurements were carried out in boreholes and drifts. Electromagnetic re?ections from a fault that consistently trends parallel to the mineralization zone permitted the mapping of the economically minable parts of the deposit. An introduction is given to the geology of the studied area and the application of the GPR method. The electrical parametres of the rocks are measured in situ, the GPR measurements are displayed with radargrams, and the visible structures are explained in illustrations.

Jan 1, 2010