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By F. S. Hoseinian, M. Irannajad, M. Safari

In this study, the effect of chemical interactions of materials used in ion flotation on the removal of Ni(II) ions from low concentration synthetic wastewater was studied. Sodium dodecyl sulfate (SDS) and ethylhexadecyldimethylammonium bromide (EHDABr) as collectors and methyl isobutyl carbonyl (MIBC) and Dowfroth250 as frothers were used. To investigate the effective parameters and interactions of them, 16 experiments including 6 level variables were performed by supporting DX7 software and on the bases of 2-level factorial method. In the first step, the tests were conducted in a Hallimond tube. The result showed that collector of SDS and frother of Dowfroth 250 had appropriate interaction with each other at pH = 3. In the second step, optimal results from the first step were evaluated in a mechanical flotation cell. The removal of Ni(II) ions increased by increasing the time of flotation and they have a direct relation with the water removal. The kinetics study shows that the order and the rate of removal of the reaction do not follow any of the zero-order, first-order and second-order equations. The flotation rate curve on the removal of Ni(II) ions will divide the separation process to two stages, a fast flotation rate at the first stage and a slow flotation rate at the second stage. Ni(II) ions removal was obtained 88% at the best condition.This study showed that the use of ion flotation was a very effective method for Ni(II) ion removal from industrial wastewaters.

Jan 1, 2016

By Malcolm Powell

"Predicting the performance of the whole mining process is surely the holy grail of predictive simulation. This can be named ‘Integrated Process Prediction’.The objective is to be able to predict the response of the processing chain, from mining to concentration, to changes in the ore type. This can apply to greenfields design – selecting processing options to optimise the overall mine performance within the constraints and aspirations of the greater community and environment; expansion and optimisation of existing plant to deal with changes in economic drivers and ore types; and on-line control – predictive reaction to ongoing changes in ore processing types in an operation.In order to achieve this there are several broad key components that are required: ore characteristics based on in-situ rock properties; a reliable 3D map of the ore body by the key processing parameters; prediction of how the rock fragments and the energy requirement to break it; the ability to predict and track progressive mineral liberation of the rock through the reduction process; the response of rock to separation processes as a function of the rock mineralogical properties. This requires the identification of primary rock properties and associating them with the rock particles as they move along the mining process chain to a concentrate or various forms of waste.This paper looks at the value of this integrated approach; the challenges it poses; the technology and capability we require; and how as a mineral processing community we can address the challenges."

Jan 1, 2016

By Bradley Stoughton

The magnetic oxide of iron, F eO4 , contains a theoretically larger amount of iron ( 72.4 per cent.) than any other commercial ore. It is probable that it has originated in many cases by the prolonged exposure of the hydrated oxide, ZF e20 a + 3H20 to heat and pressure which converts it first into hematite, F e20 3, and then into magnetite. It would thus appear as if nature had already done part of the work of removing all the oxygen and that magnetite should be relatively easy to reduce. That it is, in fact, less reducible than either limonite or hematite, is due chiefly to its dense and compact physical structure, which makes it less pervious to the furnace gases, and also to its characteristic action in resisting crushing to a uniform size, with consequent irregularity in reducing conditions within the furnace. The net result is that the magnetic oxide requires more fuel and more time for its reduction in the blast-furnace than any other iron ore of similar iron content and physical condition. There is another very important reason why the smelting of magnetite is more costly than that of hematite, and its treatment viewed with a great deal of adverse prejudice by blast furnace operators, namely, that magnetite decreases the proportion of heat developed by the fuel in the stack of the furnace, and increases the already excessive heat requirements of the heart.

Jan 1, 1924

By Candido Bariáin

A new vapochromic material of formula [Au2Ag2(C6F5)4(bipy)2]n (bipy = 2,2´ bipyridine) has been developed and used for the detection of some volatile organic compounds as acetone either in vapour or in water solution. The material is presented in the form of powders which colour changes with acetone vapours turning from bright yellow in the absence of vapour to white in the presence of vapour. By using the sol-gel technique, the powder ? dispersed in tetraethyl orthosilicate- was easily deposited on optical fibres. In order to study experimentally the behaviour of this material for construction practical optical fibre sensors, a sol-gel material doped with the vapochromic material is deposited onto an extreme of a monomode fibre connected to a coupler. The behaviour of the material was studied for different wavelengths and concentrations of acetone vapours and acetone/water solutions. Changes up to 4dB in the reflected optical power were detected. Optical fibre sensors have many advantages over conventional ones, such as electromagnetic interference immunity, passivity behaviour, possibility of using multiplexation techniques, low weigh and little size, etc. Actually, there is an increasing interest in developing optical fibre sensor for vapour detection in the chemical industry and in fact many sensor had been developed [1]. Some are based on the deposition of a sol-gel-based material either over the core of an optical fibre [1] or onto the thinner zone of a biconically tapered optical fibre [2]. Others are based on Fabry-Perot interferometers [3]. Also there are sensors based on the reflection of the light on films, on the fluorescence of dye-doped polymer cladding in fibre, on colorimetric reagents in the core of a silica fibre or on surface plasmon [4]. The possible materials for the construction of such sensor should be colorimetric reagents able to change the colour or refractive index in the presence of same organic vapours. There are not many metallic complexes with these properties, although same interesting examples have been reported in the chemistry of palladium and platinum as [Pt(p-R-C6H4NC)4][Pd(CN)4] described by Nagel [5] and Mann [6], which reported the construction of some LEDs. We recently reported the preparation of a novel vapochromic material (Fig 1) [7] which can be used for the construction of optical fibre tapered environmental sensors [8,9] of vapour organic compounds (VOC´s). Also we reported other nickel and palladium derivatives which present this type of behaviour [10]

Oct 1, 2003

By Amin Jafari

Macrosegregation has always been an important issue with the solidification processes, particularly in Direct-Chill Casting of Aluminum alloys, where uneven properties, surface and bulk defects and limitations in productivity can be arisen due to macrosegregation in the cast product. Following the global attempts to practically predict the macrosegregation, in the present work, a numerical model was developed based on an industrial scale DC casting process to simulate the solidification and macrosegregation in an Al-4.5%Cu billet. Interesting aspects of this investigation are concerned with an efficient numerical scheme to keep simplicity, consistency and desired physical resolution of the solidification phenomena together. In the mathematical model, coupled conservation equations of mass, momentum, energy and species were solved numerically using finite volume method. A different numerical scheme, called SIMTLE, was introduced to link the energy and species equations with the phase diagram of the alloy. Calculations were performed on an industrial case and obtained results were compared to available experimental data to assure the performance of the model. Different macrosegregation features were predicted and discussed on the solidifying Al-alloy billet.

Oct 1, 2011

By H. C. Cooke

"The Part of the Eastern Townships dealt with in this paper is shown in the accompanying figure. Each rectangle represents one of the topographic maps published by the Department of National Defence on a scale of one mile to one inch. Each sheet covers an area approximately 24 miles long and 17 miles wide, or slightly more than 400 square miles. The north-western part of the area figured, comprising the Upton, Aston, Becancour, and the two unnamed sheets, (Three Rivers and Yamaska), together with most of the Lyster, Drummondville, and St. Hyacinthe sheets, is largely covered by clays and sands deposited in interglacial and post-glacial time in the Champlain estuary, so that outcrops are widely scattered and in-formation is correspondingly sketchy. In the remainder of the area figured, comprising more than 4,000 square miles, outcrops are reasonably numerous and have been mapped on a scale of one mile to one inch, and the structure is moderately well understood.The Eastern Townships was an area of intense orogenic disturbance, apparently beginning late in the Cambrian or early in the Ordovician, and continuing till well on in the Devonian period. During this long period, which may have lasted for a hundred million years or more, the area was subjected from time to time to intense thrusts from the east and southeast. Each of these caused folding of the rocks, accompanied by faulting, raised parts of the area above sea-level, and presumably created ranges of mountains. Long periods of erosion cut away the mountains and reduced the area nearly to sea-level after which subsidence carried it below sea-level, and permitted further sediments to accumulate before the next thrust initiated the next cycle.The first of these movements, as stated, appears to have been in late Cambrian or early Ordovician time. The group of rocks known as Caldwell was folded and, south and east of the town of Asbestos, was thrown into great drag-folds before deposition of the next overlying series, termed the Beauceville, began. Unfortunately, the date of this orogeny is very imperfectly known, because both series of rocks have been so crushed and sheared that almost all fossil remains have been destroyed. Graptolites, found in one place in slates generally considered Beauceville, give that series a tentative Middle Ordovician age. In the Caldwell rocks, which underlie the Beauceville with great unconformity, no fossils whatever have yet been found. Thus, if the Beauceville rocks are correctly dated as mid-Ordovician, the best that can be said of the movement folding the Caldwell is that it took place at some time before Middle Ordovician."

Jan 1, 1949

By H. K. Fredrickson

"Midwest Joint Venture (MJV) owns a high-grade uranium deposit in northern Saskatchewan. The deposit is located too deep below surface to be mined economically by open pit methods, and as a consequence, present plans are that it will be mined by underground methods. High-grade uranium ore of the type at MJV, encased in weak, highly altered ground and with radon-rich water inflows, has not before been mined by underground methods.The test mining phase of the project, completed in 1989, had three objectives: 1. to evaluate radiation protection requirements associated with the handling of large quantities of radon-rich water and mining highgrade uranium ore in an underground environment; 2. to investigate the quantity and quality of water inflows into the mine; and 3. to investigate ground conditions in and around the ore zone as an aid in determining the production mining method to be used.With information gained from the test mining project, a mining method for the production mine has been devised. Level plans have been drawn up, ventilation system designed, pumping arrangements made and methods of ore handling considered. All this is to be done in a manner that will be safe for those doing the work underground. Some of the mining methods planned are felt to be unique in that they are designed to cope with mining problems not known to have been encountered before. New problems underground have required new methods to handle them. Remote drilling, blasting, mucking and backfilling form the basis of the planned mining method."

Jan 1, 1992

By T. A. Postolski, A. J. Sinclair

"Abstract- Two examples are used to describe how geological features impact on the development of semi-variogram models to be used for geostatistical resource/reserve estimation of porphyry-type deposits. In the Main zone of the Huckleberry porphyry copper deposit, mineralization is concentrated in fracture zones localized in volcanic rocks, along the eastern and southern margins of a granitic stock. Mineralized volcanic rocks can be subdivided into three separate domains, each with its own preferred direction of mineralization that is reflected in contoured Cu diagrams and semivariograms.The East zone at Huckleberry deposit, spatially distinct from the Main zone, is controlled by a fracture zone elongate roughly east-westerly and bounded on the south by a major fault (easterly striking and steeply dipping) across which there is a dramatic drop in grades. The eastern part of the East zone appears to be coaxial with a large intrusive body; the western part contains a small, elongate dike-like intrusion. Contoured Cu values for many levels suggest that the principal direction of geological elongation of the east and west domains of the East zone differs significantly. Independently derived semi-variogram models for each domain are different and reflect this difference in trend.In both Main and East zones of the Huckleberry deposit, block estimates by ordinary kriging are significantly different using a domain-specific semi-variogram model than using a deposit-general semi-variogram model. The domain-specific estimates are deemed better because they are based on local controls of mineralization and have less conditional bias than those generated by the depositgeneral semi-variogram model."

Jan 1, 1998

By Z. F. Lodhi, J. H. W. De Wit, H. A. Terry

Zinc and its alloys have been extensively used as replacements for Cadmium coatings in aeronautical and automobile industries. Zn alloys with low Co or Fe have been highly investigated but coatings with higher amount of Co are very difficult to achieve due to anomalism associated with these coatings. Anomalous Zn-Co-Fe alloy is a relatively recent addition to the family of Zn alloys. It is found that the addition of Fe in the electrolyte assist in overcoming the anomalism. In this research Zn-Co-Fe alloys especially with higher amount of Co (>15%) and Fe (~1%) are investigated, after overcoming the anomalism associated with its deposition, and the corrosion resistance is compared with pure Zn and Cd. It is found that an increase in Co to higher than 25 % accounts for a shift in the OCP to a level near Cd yet keeps it electronegative to steel. The coating shows superior corrosion resistance, in terms of its sacrificial and barrier properties in 3.5% NaC1 as compared to Zn and Cd.

Jan 1, 2006

By H. Somekawa

The fracture toughness and deformation structures an AZ31 magnesium alloy processed by equal-channel-angular extrusion (ECAE) were investigated. The average grain sizes of as-ECAE and annealed-ECAE alloys were 4.0 and 16.3 µm, respectively. The plane-strain fracture toughness, Kip, in as-ECAE and annealed-ECAE were estimated to be 27.3 and 23.5 MPam1/2, respectively, by stretched zone analysis. The fracture toughness indicated higher value with grain refinement. From optical microstructural observations in samples after fracture toughness tests, although deformation twins were observed in annealed-ECAE, no deformation twins were observed in as-ECAE. From TEM observations, the dislocations on basal and non-basal planes were activated in as-ECAE. With grain refinement, the activations of dislocations on both basal and non-basal planes were possibly related to the reduction in formation of deformation twins in as-ECAE. In addition, in comparison with direct extruded process, ECAE process was more effective method to improve the fracture toughness in magnesium alloys.

Jan 1, 2006

By P. R. A. Andrews

"Areas of bubble contact were delineated for cassiterite in the presence of chloride, fluoride, sulphate, phosphate, oxalate and citrate ions using dodecylamine hydrochloride collector. The limits of pH, and the minimum collector concentration were established using the bubble pick-up technique.Bubble contact did not occur below the p.z.c. (point of zero charge), estimated to be 4.7, in the presence of chloride ion, and fluoride ion showed only a weak response in the same pH range. These anions are considered to act as indifferent electrolytes. Activation at pH values below the p.z.c. was obtained with sulphate, phosphate, oxalate and citrate ions; the greatest response was by oxalate and phosphate ions extending pick-up to between pH 2.0 and 2.5.Activation appeared to be strongest when anionic protonated species were in maximum concentration. Strong activation also corresponded to the formation of very stable metal ion species, thought to be formed on the surface of cassiterite, between exposed stannic ions and modifying anions; dodecylammonium ions being absorbed on the surface so modified."

Jan 1, 1991

By Jaroslaw W. Drelich

Despite the success of DLVO and extended-DLVO models that have been developed for homogeneous and smooth surfaces, a vast majority of practical surfaces encountered in mineral ore beneficiation are typically rough at various scales; they are also typically heterogeneous. The interactions of gas bubbles with particles having rough and heterogeneous surfaces are much more complex than the commonly used DLVO or extended-DLVO models predict. The effects of surface roughness on flotation and colloidal interactions have been reported many times in the past, although a clear understanding of their origins has been lacking. To explain differences in colloidal interactions for spherical hydrophobic particles, a theoretical analysis of the interaction potential was carried out for a model rough particle interacting with a bubble surface in an electrolyte solution in this study. The attractive hydrophobic interaction potential was added to repulsive retarded van der Waals and repulsive electrical double layer interaction potentials. The rough microscopic particles were modeled as spheres decorated with nano-sized asperities. Parameters that reflect common flotation separation systems were selected for testing this theoretical model and computation of the energy barrier applicable to particle – flat bubble surface interactions. It was found that hydrophobic asperities with the height of only several nanometers can reduce the repulsive interaction energy by an order of magnitude. Theoretical analysis also reveals that surface coverage of microscopic particles by nano-sized asperities is important as well. The findings of this research suggest that manipulating and engineering the particle surface topography could lead to better control over flotation separation.

Jan 1, 2016

By G. Vibert Douglas

It often happens that the field geologist encounters a fault in ground where there is little to guide him with regard to the throw, or vertical displacement, and the heave, or horizontal displacement. The following construction gives both of these components of the fault, and the writers hope that it may prove a help to others. The construction is applicable to both normal and reversed faults. Briefly the procedure is as follows: Take a point which is common to the faulted geological feature and to the fault plane and on the downthrow side of the fault. Move this point in the horizontal plane in the direction indicated by the fault striæ. Rebat the point down to the plane of the fault and obtain its throw. Next consider the other side of the fault and truncate it down by the amount of the throw just determined. Then project the line of the geological feature through to the trace of the fault-plane at the lower horizon. The result is the relative positions of the two parts of the original geological feature as severed by the fault. In Figure r, let us consider a typical normal fault, that is, a fault in which the hanging-wall has gone down relative to the footwall. This characteristic, or its alternative, the reversed fault, is determined by observation on the ground. Let AB be the line of any geological feature such as the edge of a dyke, vein, or bedded sediment. The plane of which AB is the trace may have any dip; in the present case let us say 70° right. Let FF be the trace of a fault-plane which may have any dip; let us say 35° left in this case.

Jan 1, 1928

By William Petruk

Mineralogical investigations in connection with gold metallurgy are usually performed to find the reason for poor recoveries by cyanidation or by other leaching techniques. Poor recoveries most commonly are obtained when (I) native gold is encapsulated in an insoluble mineral as "invisible gold"; (2) native gold is coated with a precipitate; (3) gold-bearing products are insoluble in cyanide solutions; (4) carbonaceous material in the ore adsorbs gold; and (5) associated minerals decompose and consume cyanide. Samples of refractory material quite often have low gold tenors. It is difficult to find the gold-bearing minerals in such samples with an optical microscope because the probability of finding trace minerals in samples is small. The probability decreases with decreasing grain size of the gold-bearing mineral and with decreas¬ing gold tenor of the sample. Techniques have been developed to increase the success rate of finding gold grains; some are (1) concentrating heavy minerals; (2) preparing special polished sections; (3) searching with an image analyzer; and (4) dissolving associate silicate and sulphide minerals.

Jan 1, 1989

By Michel Carreau

Renewable assets have large upfront capital costs but minimal operating expenses over their lifetimes. In some instances, deals can be structured so that direct capital investment is feasible, with paybacks typically within 5-7 years. In others, the burden of renewable CAPEX must be removed in order to create an attractive alternative to fossil-fuel-fired generation. Hatch has designed and oversees the construction of a renewable installation, which is financed, owned and operated by a special-purpose entity. Renewable energy is then delivered to the mining company via a customized power purchase agreement at a price that is lower than the levelized cost of fossil fuels. In this way, the mining company removes the burden of the renewable energy CAPEX from its balance sheet, thus freeing up capital, decreasing risk, and making the predictable, lower cost of renewable power more attractive than the variable cost of fossil fuels. This paper presents the above business model and success stories of hybrid power at remote sites (wind and solar coupled with diesel engine).

Aug 1, 2013

By R. Therrien, L. Gosselin, J. Raymond

ABSTRACT: The ground-source heat pump is a low-carbon technology that uses the earth’s renewable geothermal energy to heat and cool buildings, with an ef?ciency 3 to 4.5 times that of conventional systems. These high performances are achieved by exchanging heat with the earth using a ?uid that is groundwater, surface water or closed loop water. Expensive installations, such as water wells or buriedcoils, are however necessary to transport the ?uid in and out of the earth, making ground-source heat pumps more costly than conventional systems. Installation costs can be reduced in mining environments due to the abundance and the accessibility of resources to be used with heat pumps. Examples of system design calculations using data from the Mouska and Doyon mines in Abitibi show signi?cant installation cost savings using dewatering mine water or ground heat exchangers installed below oxidizing waste rocks. Ground-source heat pump technology is reviewed and scoping calculations are presented to illustrate how such systems can be installed in mining environments.

Jan 1, 2010

By Gerald Sanders

Presentation Topics ? We?re Going to the Moon Again? ? What is Lunar Mining ? In-Situ Resource Utilization? ? What Are The Challenges to Lunar Mining? ? What is NASA Currently Doing?

May 1, 2009

By R. Bonnar, R. J. McH. Clark

"The Cheminis gold mineralization zone is approximately 6.5 km west of the Kerr Addison Mine along the Larder Lake Shear Zone, in the southern part of the Abitibi Greenstone Belt. The zone is very similar in appearance to the flow ore at the Kerr Addison Mine and occurs at the same stratigraphic position. Drilling has demonstrated that the gold mineralization at Cheminis persists to a depth of over 3000 ft .The mineralization is hosted by a pyritic, tuffaceous sediment which occurs within a sequence of volcanics and sediments which have been pervasively carbonatized. The gold is largely enclosed within pyrite grains and the amount of gold in the layers of pyrite increases in the layers closest to a graphitic f ault zone.It is suggested that the gold mineralization may be primarily related to the syngenetic sulphide concentrations formed during fumarolic activity on the seafloor along the Larder Lake Shear Zone. At a later stage a hydrothermal event associated with alkalic volcanism may have resulted in regional carbonatization and further concentration of the gold in the vicinity of fault zones."

Jan 1, 1987

By Ann Lamontagne

Le parc à résidus de l?ancienne mine Dunraine contient des résidus générateurs de drainage minier acide. Le concept proposé pour la restauration du site est d?utiliser le fort potentiel alcalin des boues rouges, résidus d?aluminerie, afin de neutraliser les résidus miniers. En appliquant une certaine quantité de boues rouges à la surface du parc, on provoquera une neutralisation de l?acidité. De plus, les alcalis contenus dans les boues rouges vont provoquer la précipitation de minéraux stables (sulfates tel la jarosite). La précipitation de ces minéraux provoquera la formation d?une couche indurée qui rendra difficile la circulation de l?oxygène et de l?eau. Bien que ce concept ait été vérifié en laboratoire, ce sont là des hypothèses qui restent à vérifier dans des conditions réelles d?exposition. Les principales questions soulevées par l?utilisation des boues rouges, mis à part le contexte géochimique, est le contexte technico-économique. En effet, le transport de quantité importante d?un matériel argileux humide présente un défi économique important. Outre le défi économique, la manipulation et l?épandage de ce produit sur des parcs à résidus constituent également un défi important. Cet article présente les conclusions d?une étude technique sur le transport, la manutention et l?épandage de boues rouges sur un parc à résidus situés en Abitibi : le site de Dunraine.

Nov 1, 2002

By G. J. Simandl, H. -L. Jacob, S. Paradis, G. Valiquette

"Nos travaux de terrain dans le Grenville, effectués dans le cadre d'un projet d'inventaire des gîtes de wollastonite, ont démontré qu'il existe un secteur exceptionnellement favorable à l’exploration pour la wollastonite. Ce secteur s'étend de la municipalité de Grenville jusqu'au pare du Mont-Tremblant (nord de St-Jovite). D'autres secteurs favorables a 'exploration pour la wollastonite ont été délimités dans les regions du Lac-Saint-Jean, de Shawinigan et de la Gatineau. Neuf categories litho-structurales de gites de wollastonite furent identifiées. L'importance d'un système ou vert pour la formation des gîtes de hautes teneurs fut établie. Un guide de prospection pour la wollastonite propre à la province tectonique de Grenville fut développé. Plusieurs des indices sont prometteurs et mériteraient des travaux de raise en valeur afin de determiner s'ils représentent une source de wollastonite exploitable à profit. Lac-Saint-Jean, Shawinigan and Gatineau areas. Deposits may be classified into nine categories depending on their relationship to intrusive rocks, discordant or concordant contacts with the host rocks, morphology, and major structural controls. Deposits consist mainly of wollastonite, calcite and clinopyroxene. They may contain one or several of the following minerals: feldspar, scapolite, quartz, titanite sulphides, zoisite, clinozoisite, garnet, idocrase and prehnite. Wollastonite content may reach over 70%. Some deposits are associated with graphite veins. Better understanding of the geology, combined with the proposed classification provides new exploration guide for wollastonite. Several deposits have grades of economic interest. Further work is needed to determine if any of these deposits can be exploited for profit."

Jan 1, 1990