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By J. M. Paxton, R. L. Roscoe, G. A. McCreary, W. W. Muir, T. J. Drown, D. A. Barr, T. W. Law

"This paper reviews the complete cycle of a small mining operation in a remote section of northern British Columbia, including discovery, exploration, development and production. The discovery of high-grade epithermal gold-silver mineralization occurred in 1969 following a regional geochemical reconnaissance program designed to search for porphyry copper mineralization in the Cassiar-Omineca Mountains. Exploration and development from 1971 to 1979 included geological, geochemical and geophysical surveys; trenching, almost 30 000 feet of surface and underground drilling in about 100 holes and cross-cutting, drifting and raising on the principal goldsilver- bearing vein. This led to the delineation of 100000 tons at an estimated grade of0.9 oz gold per ton and 18 oz silver per [on to an average depth of 120 feet below surface. of a 100-ton per day mining operation employing about 50 personnel with all supporting infrastructure transported to the site by a Hercules aircraft. The operation was subsequently supported by its own Twin Otter aircraft with periodic Hercules campaigns supplying major items including fuel.The mining operation included both open-pit and cut-and-fill methods. The milling operation employed conventional cyanide leach process with cyanide destruction initially by alkali chlorination and subsequently by the Inco SOl /Air process.The fly-in operation, initially structured on a 21-day-in and 7-day-out basis was modified to al-t-day-in and Z-day-out basis with no loss in efficiency and with a significant increase in employee satisfaction. The operation, which earned the B.C. Small Mines Safety A ward in two consecutive years in its Ll-month operating history, emphasized safety and process hazard awareness. Wildlife studies in the environmentally sensitive mine area also showed that industry and wildlife can coexist in harmony.Most importantly, the paper compares the feasibility assumptions with actual operating experience."

Jan 1, 1986

By M. J. Michaud, M. J. Lavigne

"Abstract - North American Palladium Ltd. operates its Lac des Iles open pit palladium mine 85 km north of the city of Thunder Bay, Ontario. The Roby Zone deposit occurs within the mafic/ultramafic Lac des Iles Intrusive Complex (LDI-IC), which was created by multiple pulses of magma of varying composition within several closely spaced chambers. Chaotic lithological distribution, the presence of magmatic breccias, and the rarity of rhythmic layering suggest a dynamic intrusive environment with disruptive magma pulses. As of December 31, 2001, measured and indicated resources for the 950 m long by 815 m wide Roby Zone deposit totalled 159 Mt grading 1.55 g/t Pd, 0.17 g/t Pt, 0.12 g/t Au, 0.05% Cu, and 0.05% Ni at a palladium cut-off grade of 0.7 g/t. The Roby Zone contains an additional 73 Mt of inferred resources at similar grades.The Roby Zone is dominated by varitextured gabbro containing pipes and pods of breccia, and large blocks (~60 m across) of varying lithology. Mineralization at Lac des Iles occurs as: (1) a PGEand base metal-rich magmatic matrix of breccia (breccia ore); (2) mineralized dikes or sills (gabbronorite in North Roby ore); (3) lower-grade mineralization in varitextured units that are host to the distinctive breccia ore and envelope the North Roby ore; and (4) high-grade mineralization associated with strong silicate alteration exemplified by high-grade ore.The close spatial association of the mineralized breccias with both varitextured units and silicate alteration leads to an interpretation that the energetic magma that created breccia was charged with a dissolved fluid, and that this deuteric fluid exsolved at high temperatures to migrate through crystal mush, enhancing crystallization along its pathways, resulting in variable grain size. This transformation occurred at high temperature and produced sulfide-poor, varitextured gabbro-hosted mineralization exemplified by some of the mineralization in the North Roby Zone, and also found throughout the Roby Zone. The association of hydrous silicate alteration with mineralization can be explained by continuing fluid migration during cooling and continued metal transport. Résumé - North American Palladium Ltd. opère la mine à ciel ouvert de Lac des Iles située à 85 km au nord de Thunder Bay, Ontario. Le gisement Roby Zone est encaissé dans le complexe mafique/ultramafique de Lac des Iles (LDI-IC), lequel représente une intrusion polyphasée créée par plusieurs pulses magmatiques de différente composition à l’intérieur de chambres magmatiques fermés. La distribution chaotique des lithologies, la présence de brèches magmatiques, et la quasi-absence de litage rythmique suggèrent un environnement magmatique dynamique perturbé par l’introduction de nouveau magma. Au 31 décembre 2001, les ressources mesurées et indiquées s’élevaient à 159 millions de tonnes titrant 1,55 g/t Pd, 0,17 g/t Pt, 0,12 g/t Au, 0,05% Cu, et 0,05% Ni, pour une teneur de coupure de 0,7 g/t Pd. De plus, la Roby Zone contient 73 millions de tonnes de ressources inférées à une teneur similaire.La Roby Zone est principalement encaissée dans un gabbro de texture hétérogène (varitextured) caractérisé par des cheminées et des lentilles de brèches et des énormes blocs (environ 60 m de diamètre) de plusieurs lithologies. Au Lac des Iles, la minéralisation en EGP et en métaux de base se retrouve dans la matrice magmatique de brèches (breccia ore), dans des dykes ou des sills minéralisés (gabbronorite dans la zone North Roby ore), comme minerai de basse teneur encaissant le minerai de brèche (breccia ore) et enveloppant la zone North Roby. Du minerai de haute teneur est également associé avec une forte altération en silicates dans la zone high-grade ore.L’étroite association spatiale entre les brèches minéralisées et les unités de texture variée (varitextured) et l’altération en silicate suggère que le magma énergique qui a causé la bréchification était chargé de fluides. Ces fluides deutérique"

Jan 1, 2001

By K. Thuro, B. Sellmeier, M. Krautblatter

"Recent rockfall events, like the Tramin rockfall at January 21st, 2014, underline the significance of a comprehensive hazard assessment. A common way of estimating the hazard along infrastructure is the performance of run-out modelling using 3D rockfall codes like Rockyfor3D or RAMMS::Rockfall (Dorren, 2010, Bartelt et al., 2013). The potential block volumes are often roughly estimated from talus material and an overview of the source area, where the magnitude assessment is usually physically and intellectually demanding. Nevertheless especially for increased magnitudes, the volume estimation is crucial in terms of hazard analysis. Mid-Magnitude-Events exceed the load capacity of the most mitigation measures and their date of failure is hard to predict. Here we define the term Mid-Magnitude-Events as block volumes between boulder falls (10-100 m³) and block falls (100-10,000 m³) (Whalley, 1984).The current contribution provides an approach of integral process analysis for a 200 m3 carbonate block above the federal road B 305 near the city of Salzburg in the Bavarian Alps, Germany. We performed detailed analysis of the critical carbonate block exposed to planar failure. The block volume and the dimensions of the failure surface were mapped in detail, due to the unique occasion of an accessible failure surface. The discontinuity persistence was recorded to assess a minimal degree of fragmentation for a potential failure scenario. A maximum degree of fragmentation was estimated due to recording of block dimensions at the talus slope resulting from frequent rockfalls.We performed parameter studies in terms of run-out modelling using the code RAMMS::Rockfall (Bartelt et al., 2013), taking the recorded data for block fragmentation into account. In our contribution, we aim to demonstrate a comprehensive approach for hazard assessment of mid magnitude rockfalls, taking detachment processes, fragmentation and run-out analysis into account."

Jan 1, 2015

By Qing-hua Tian, Xue-yi Guo, Fei Li

A novel process for the preparation of a-Al2O3 from secondary aluminum dross was studied. Factors including alkali dross ratio, salt dross ratio, smelting temperature, smelting time, leaching temperature, leaching time, and the solid-liquid ratio, which possibly influence the transfer of Al into water were studied, and the feasibility of using seed precipitation as a treatment technology of the leachate was discussed. The optimum condition of the process was determined as: alkali dross ratio 1.3, salt dross ratio 0.7, smelting temperature 500°C, smelting time 60min, leaching temperature 60°C, leaching time 30min, solid-liquid ratio 1:4. The results show that using the seed precipitation method, the leaching of aluminum reaches 92.71%, demonstrating the technique as a feasible and effective treatment technology of the leachate.

Jan 1, 2011

By M. Maldonado, P. Olivares

"A submersible sensor for real-time gas holdup measurement in the collection zone of industrial flotation machines is introduced. The working principle is based on the generation and measurement of a pulp flow using a gas-exclusion cell immersed in the aerated slurry. The gas exclusion cell consists of a variable-area open vertical tube designed to be filled only with pulp by preventing gas bubbles entrance. The higher density of the fluid column within the cell generates a downward flow of pulp; the rate of this flow is proportional to the gas holdup outside the cell. The gas holdup measurement is achieved by tracking the velocity of the pulp flow leaving the gas-exclusion cell, using a magnetic flowmeter. Construction details of a prototype and its testing in two- and three-phases are discussed.INTRODUCTIONFlotation process optimization consists of finding and maintaining operating conditions that maximize flotation performance measured in terms of recovery and grade. The selective separation of mineral particles proceeds in two interactive zones where different and simultaneous phenomena take place: in the collection zone, the valuable particles are separated by collection on the surface of bubbles, while in the froth zone, the bubble-particle aggregates are gathered, drained to remove entrained particles, and taken into the concentrate stream. The cell overall performance, which can be determined from proper stream sampling, is a function of the recoveries in the individual zones. These zone recoveries cannot be independently measured nor calculated from operating variables. Progress in the assessment of these recoveries has been slow because on-line and reliable sensors to measure properties of the drastically different dispersions existing in both zones are not available.In the case of the collection zone, it has been demonstrated that the recovery of hydrophobic particles on the surface of bubbles, considered as a process with first-order kinetics, correlates with the bubble surface area flux (Finch et al., 2000; Hernandez, et al., 2003; Lopez-Saucedo et al., 2012). Bubble surface area flux (bubble area generated per unit time and cell cross-sectional area), is a variable affected by gas flow rate, bubble size distribution, and frother type and concentration. Gas holdup (volumetric fraction of gas dispersed in the slurry) is also affected by the same variables, and as such, carries information on the interacting variables that define the performance of the process. Therefore, a correlation between gas holdup and bubble surface area flux was expected and demonstrated (Finch et al, 2000), and since gas holdup is easier to measure as no bubble size is required, it has the potential to be the basis of a cell control and optimization strategy if a continuous sensor is available."

Jan 1, 2016

By Douglas A. Karvonen

"Competition in the world potash market has increased significantly since the late 1970s. The failure of consumption to grow at expected levels has led to industry over-capacity, a situation which is likely to persist at least until 1990. Individual Saskatchewan producers and their offshore marketing company, Canpotex, have responded to this challenge by increasing mining efficiency, developing more cost-effective and reliable transportation systems and establishing innovative financing and market development programs tailored to customers' special needs. Investment in warehouse facilities to serve U.S. customers and exploration of opportunities for intermodal distribution through the Great Lakes and the Mississippi River system have maintained individual producers' position in the highly competitive domestic market.Export sales through Canpotex have been bolstered by utilization of CIDA funds, Exp ort Development Corporation financing guarantees and other innovative payment plans which enable heavily indebted developing countries to maintain the import levels which are necessary for their agricultural development.IntroductionPotash is the general term applied to various potassium salts both natural occurring and commercially derived. The most common of the commercial product s are potassium chloride, potassium sulphate and potassium magnesium sulphate. The potassium content of potash is measured in units of K20 equivalent. The common grades of potassium chloride produced for agriculture average at least 60 0/0 K20 compared with approximately 50% Kp for potassium sulphate and 22% for potassium magnesium sulphate."

Jan 1, 1985

By R. G. L. McCready, R. O. van Everdingen, M. Kalin, R. van Everdingen

"This paper is based on data generated between October, 1986 and October, 1989, during the implementation of an Ecological Engineering close-out for a zinc mine in Northern Ontario, where 690000 tonnes of tailings contain 41.1% pyrite and 4.1% pyrrhotite. The objective was to determine rates of sulphide oxidation and iron precipitation in the tailings. Those rates are relevant for the assessment of the long-term effectiveness of biological systems employed in the removal of heavy metals from contaminated drainage issuing from tailings.Data were collected on the topography and stratigraphy of the tailings basin, subsurface temperatures and groundwater levels, and chemical analyses were made of water samples collected from a number of piezometers. The thickness of unsaturated tailings varied widely between individual piezometer locations; annual maxima ranged from 0.67 m to 3.55 m, and annual minima from 0 to 2.68 m. Sulphate concentrations ranged from 36 mg/L to 20180 mg/L; iron concentrations from 0.36 mg/L to 9938 mg/L; and zinc concentrations from 0.33 mg/L to 1123 mg/L.The geochemistry of the piezometer samples suggests that some of the initial Fe content, resulting from metal sulphide oxidation, is subsequently precipitated in the tailings pile and, possibly, in the underlying unconsolidated sediments, probably in the form of iron-hydroxide and Na-jarosite. Other metals such as Zn may be co-precipitated with Fe. The discharge of a portion of these metals to the environment would be delayed by this process. Some of the initial sulphate may also be lost from solution, probably by precipitation of gypsum; approximate saturation degrees for gypsum ranged from -3.27 to +0.47. The precipitated minerals will somewhat decrease the porosity and permeability of the tailings.Sulphide-oxidation rates, calculated using the analytical results and the estimated amount of annual recharge at the tailings site, average 0.0057 mol/kg/yr. Calculated iron-precipitation rates average 0.000386 mol/kg/yr. It is concluded that the characteristics of seepage from mining wastes may change with time, reflecting the solubilization of precipitated secondary minerals."

Jan 1, 1992

By L. Xu, A. Vazirnegad, R. Bhaskar

"Respirable dust samples are collected by the U.S. Mine Safety and Health Administration (MSHA) and mine operators as part of the requirements of the Federal Coal Mine Health and Safety Act of 1969. About 1.85 million respirable dust samples collected by MSHA were analyzed for the period 197/ to 1990 f or the states of Alabama, Colorado, Illinois, Kentucky, Ohio, Pennsylvania, Utah, Virginia, and West Virginia. Trends in coal dust exposure of continuous miner operators, helpers, and roof bolters were analyzed. The reported production in each of the nine states was analyzed. The relationship between average dust exposure and coal production was evaluated. In addition, the differences between mine operator and MSHA inspector collected data were examined for each state. The average exposure levels for the three occupations - miner operator, miner helper, and roof bolter were also compared.The data indicate that the dust exposure levels have significantly dropped over the last twenty years, while at the same time production has increased, attesting to the ability of the U.S. mining industry to adapt successfully to the stringent dust control regulations. In terms of coal production, it appears that some states, such as Utah, Illinois, and Kentucky, were able to increase their production significantly relative to others, such as Pennsylvania and Virginia. The relationship between dust concentration and coal production is, at best, tenuous. 11 implies that existing dust control technology has assisted several mine operators to meet dust standards, while, at the same time, enabling mines to produce more coal than before. Comparison of data collected by MSHA and mine operators indicate that MSHA inspectors recorded higher dust levels and lower shift production relative to mine operators."

Jan 1, 1993

By I. S. Thompson

A program of geochemical till prospecting, carried out by Derry, Michener & Booth in 1974, was instrumental in t~ e discovery of a copper deposit in Currie Township, Ontario, beneath thick lacustrine deposits of the Abitibi Clay Belt. The prospecting system involved the continuous collection of glacial sands and gravels beneath the clays, using a track-mounted, dual-tube rotary drill, and the separation and geochemical analysis of the heavy mineral content for Cu, Zn, Pb, Ag and Au. In one of 22 holes drilled down-ice from nine Canadian Nickel airborne EM conductors, fragments of chalcopyrite-bearing graphitic argillite, assaying 12% Cu, were recovered from a 14-foot gravel section beneath 83 feet of clay. Ultimately, mineralization was identified in 10 of 11 additional holes drilled up to 3,000 feet down-ice from the Currie deposit. The glacial fan, when compared to the 1,200- by 165-ft area of the subcropping mineralization, is at least 20 times the area of the deposit and is the result of glacio-fluvial reworking of the mineralized ground moraine. The Currie deposit is contained within a Keewatin succession of graphitic argillite, dacite tuff and graywacke, which is intruded by dacite and feldspar porphyry sills and dykes and truncated by a Keweenawan diabase dyke. Grade and thickness of the mineralization, which lies chiefly within the argillite, is related to felsic intrusives and hydrothermal alteration, and to fold hinges.

Jan 1, 1979

By David M. Parkes, George E. Davies

"Mathematically, the proposed formula is: ""Human Effectiveness + Technological Improvement = Success in the Nineties"". A brief review is made of geology, level of technology, management and labour situations, and range of production costs in coal producing countries. This comparison shows keen competition for Canadian coals, especially from the People's Republic of China, South Africa and Australia. Domestic competition comes from nuclear energy, hydro-electric generation, natural gas (if permitted) and eastern United States coal.The huge increase in the size and power of surface mining equipment in the last forty years led to modern large-scale open pit mining. While conventional truck and shovel operations will continue to be widely used, more continuous mining and conveying systems will be installed as pits become deeper and haul distances longer. Computer systems will become more sophisticated and their applications more widespread, leading to higher productivity and closer control of all operations and equipment performances and to partial or complete automation of certain operations.The underground revival will be driven by a new generation of mining people, cooperating to produce over 3 million t/y from 300 m longwall faces retreating over 3 km resulting in mine productivities of over 40 tonnes per man shift, as is already achieved in several mines throughout the world. Continuous operation using on-line control system will assist in consistent production with availabilities over 75%."

Jan 1, 1991

By A. L. Holloway, N. M. Soonawala, L. S. Collett

"Since the late 1970s, a major R&D program has been under way in Canada to assess the concept of disposing of nuclear fuel wastes in deep plutonic rock. Atomic Energy of Canada Ltd . (AECL), a federally-owned corporation, has been given the responsibility of directing this research (Rummery et al., 1983).The Underground Research Laboratory (URL), constructed in a granite pluton 15 km east of Lac du Bonnet, Manitoba (Fig. 1) is a major component of the Canadian Nuclear Fuel Waste Management Program. A diverse geotechnical experimental program is being carried out during both the construction and operating phases of the URL. This program involves detailed geological mapping, rock mechanics and hydrogeology studies, and geophysical surveying, to characterize the rock mass surrounding the shaft, and it has been described by Simmons et al. (1983). As part of the construction-phase program, ground-penetrating radar (GPR) surveys are being carried out during excavation, in an attempt to delineate fractures both ahead of the excavation and behind the walls of the excavation. This paper presents the results of surveys performed during shaft excavation and describes a procedure for plotting the data.Ulricksen (1982) cites examples of radar surveys to evaluate surficial deposits, such as peat, sands and gravels, and cavity detection in subsurface hard rock. Fowler (1981) used radar for fracture and clay vein detection in coal seams.In Canada, pioneering work in GPR has been done by Annan and Davis since the mid-seventies (Annan and Davies, 1976). Their work concentrated on problems relating to permafrost in the Arctic ."

Jan 1, 1986

By B. E. Jones

"The area of uranium deposition is situated within the Churchill Province on the western edge of the Wollaston Iithostructural domain where it underlies the eastern edge of the Helikian Athabasca Formation. The Collins Bay deposit is 6 miles north-northeast of the Rabbit Lake mine. Two principal zones of uranium mineralization are described.The ""A"" zone is a partly eroded, high-grade pod of metal oxide and arsenides sheathed by clay-like minerals. It trends north-northeast and lies under 25 to 40feet of water. Uranium mineralization is localized at or adjacent to the unconformity between the Athabasca Formation and the basement rocks. The basement comprises a granitoid Archean terrain overlain by paragneisses of the Aphebian Wollaston Group. ""A "" zone ore contains phyllosilicates, quartz, pitchblende, rammelsbergite, pararammelsbergite, carbonaceous material, galena, gersdorffite, niccolite, carbonate and a trace of sphalerite.The ""B "" zone lies 6,000 ft south of the ""A "", and subcrops under till cover. It is a partly eroded zone composed of metal oxide and arsenides which occur within variably altered Athabasca Formation. Minerals recognized are phyllosilicates, pitchblende, niccotite, gersdorffite, millerite, carbonaceous material, pyrrhotite, skutterudite and a trace of galena. The Athabasca Formation varies from 90 to 160ft thick. Granitoid gneisses of probable Archean age and paragneisses of the Wollaston Group underlie the deposit. An easterly dipping thrust fault transects its length.The deposit is typical of the ""unconformity-type"" uraniumnickel deposits of the Athabasca Basin. Observed features fit well with the ""diagenetic-hydrothermal"" model for such deposits, as envisioned by Hoeve and Sibbald (/978)."

Jan 1, 1980

By D. Mraz

"Under high pressure in a deep potash mine, the salt rock behaves in accordance with the concept of a generalized, perfectly plastic substance. The paper presents the evidence of this behaviour and engineering concepts f or room-and-pillar design. IntroductionThe mining and refining facilities at International Minerals &. Chemical Corporation (Canada) Limited are located near Esterhaz y at the southeastern edge of the Saskatchewan evaporites. Ore extraction began in 1962 and at the present time the annual mining capacity is in excess of eleven million tons of potash ore.A generalized geological section is shown in Figure I. The mining horizon is overlay in by 100 feet of rock salt followed by a thin bed of competent dry shale. The strata in the next 1,500 feet are generally competent and locally water bearing. The Blairmore formation contains strata of water-bearing unconsolidated sand. Below the mining horizon, rock salt is interbedded with anhydrite bands.The 8-foot mining bed is distinguished mainly by grade and clay content, as there is no definite bed boundary. The chief mineral s are halite, sylvite and, in some cases, carnallite, with up to 2 per cent disseminated clay. The ore is coarse grained, with crystals averaging one-half to three-quarters inch across.The major mining problem is related to the fact that the Dawson Bay formation, overlying the evaporites, contains areas and channels that are highly porous and permeable and are filled with unsaturated brine under high pressure. Consequently, all mining areas, with no exception, must be so designed that the overburden salt stratum remain s competently supported for the duration of the mine .This paper outlines a successful engineering method of determining the stability of the pillar s and designing a stable room -and-pillar mining system."

Jan 1, 1980

By S. W. Brooksbank, R. A. Benkis

"IntroductionThe Republic of Indonesia is a developing Southeast Asian country that unites the Indian and Pacific oceans, and spreads across nearly 14000 islands with a total land area of about two million km-. The distance across the country approximates the distance across Canada: Indonesia extends for more than 6000 km from the northern tip of Sumatra to the eastern border of Irian Jaya in the middle of New Guinea. With a population of around 180million, Indonesia is one of the world's most populous countries. A mix of 366 ethnic groups populates the country and there are some 250 distinct languages spoken. The topography of Indonesia generally is quite rugged because of its numerous volcanos. For example, the island of Java has 121 volcanos, of which 15 rise above 3000 m and another 44 reach heights between 2000 m and 3000 m.Indonesia has a diversified resource base, with plentiful energy resources (coal, oil, gas and hydroelectric), significant mineral deposits, large timber potential and a developed system of agricultural commodity production and export. A high proportion of the primary resources are on the sparsely populated islands of Sumatra and Kalimantan, whereas 7'3 of Indonesia's people reside on Java, or on 70/0 of the country's land area. Around Jakarta in western Java the population density is around 8000 per krn2. This contrasts with less than nine people per km- on Sulawesi (Fig. I)."

Jan 1, 1992

By Yongfeng Jia, Shaofeng Wang, Danni Zhang

Arsenic in mineral processing solutions and effluents is commonly removed and immobilized via iron(III)-arsenatecoprecipitation. The effect of re-crystallization of 2-line ferrihydrite on the long-term stability of iron(III)-arsenate coprecipitate is still not fully understood. This work investigated the redistribution of arsenic and iron during 2-line ferrihydrite transformation at different pHs and temperatures over time. X-ray diffraction (XRD), transmission electron microscopy (TEM) and chemical extraction were employed to characterize the crystallinity of the iron oxyhydroxides. Results showed that the amount of arsenic released into solution during aging increased significantly with increasing media pH.

Jan 1, 2014

By R. D. Studer

"The Snow Lake massive sulphide deposits are hosted by Aphebian volcanic rocks of the Flin Flon - Snow Lake greenstone belt, which in this area were deformed and metamorphosed to the amphibolite facies during the Hudsonian orogeny. All the known deposits occur in felsic rocks a short distance below the contact with an overlying mafic rock unit.The Stall Lake copper deposit occurs close to the top of an explosive felsic volcanic sequence. Rocks stratigraphically underlying the deposit have been hydrothermally altered by the mineralizing fluids. The sulphides were probably deposited from submarine volcanic vent(s) on the flanks of a felsic dome. The ore has been tightly folded, flattened and elongated parallel to the northerly trending lineation of the surrounding rocks during the several periods of deformation. Strike lengths of the lenses range from 60 to 300 feet and plunge-to-strike ratios are as much as 15:1.Ore lenses I to 4 typically consist of massive coarse-grained pyrrhotite, chalcopyrite and pyrite. A stratigraphically higher lens differs in that it contains fine-grained pyrite and chalcopyrite, with an increase in sphalerite toward its hanging wall. The No.4 orebody has a distinct footwall alteration zone characterized by brecciation and abundant chlorite-staurolite- garnet schist, with minor kyanite, anthophyllite, cordierite and anhydrite, as well as sulphide minerals. Chemically, the alteration zone is distinguished from the unaltered felsic rocks by Na20 depletion and Mg-Fe enrichment"

Jan 1, 1982

By A. B. Luz, A. Middea

Kaolin clay is heavily used in the paper industry as a coating and a filler, however to attend the specifications required by the industry it has to be processed. Kaolin is also used as a filler and pigment in various materials, such as paint, plastic, rubber etc. Some crude kaolins as mined in Northern Brazil, contain colored impurities such as iron oxide and rutile/anatase. These minerals normally are stained by iron and as a result vary from yellow to dark brown in color. The kaolin beneficiation process used in that region consists mainly of degritting, fractionation by centrifuge, high gradient magnetic separation, bleaching with sodium dithionite, filtering and drying. In some kaolin clays from that region, titanium oxide mineral occurs in fine fraction, lower than 2 µm, and so making the industrial process more difficult. The conventional method of classification and bleaching with sodium dithionite, markedly improves kaolin brightness, but has little effect on anatase removal. In fact, the fine fractions resulting from centrifugation, in many cases contain more TiO2 minerals than the original whole clay or the coarse fraction. The present work is related to purification of Brasilian kaolin clay using selective flocculation for removing its colored impurities such as rutile and anatase. This study was conducted in bench scale and it consisted of: blunging, screening, conditioning and decantation. Overflow and underflow resulting from settling of the flocculated material were then dried and submitted to TiO2 and brightness analyses. Sodium polyacrylate and sodium silicate were added to kaolin clay suspension as dispersant and ammonium hydroxide was also added to adjust pH. After degritting, the minus 44 µm fraction was conditioned with hydroxamate surfactant and then polymers of different anionic charge were added. The influence of pH and type of polymer on efficiency of TiO2 removal, as well as kaolin mass recovery were studied. The results obtained in the present study are quite promising. It was possible to diminish TiO2 content and increase kaolin brightness (ISO) from 82 to 88%.

Jan 1, 2004

By C. J. Rockingham

"A comparative study of sulphide textures has been carried out on samples from four Archean copper-zinc massive base metal sulphide deposits: Kidd Creek, Ontario; Lake Dufault -Norbec, Quebec; Hood River-41, N. W. T.; and Geco, Ontario. These deposits have undergone metamorphic recrystallization under a range of conditions, and results of this study indicate that certain sulphide textures may be used as qualitative indicators of metamorphic grade, whereas other cannot.The sulphide textures of most value in this regard are sulphide grain sizes, which increase with increasing metamorphic grade, and the presence or absence of sedimentary/diagenetic textures, which are destroyed at the lower amphibolite facies of metamorphism. Chalcopyrite and pyrrhotite intergrowths in sphalerite increase in size, in degree of coalescence and in the ratio of unmixed pyrrhotite to chalcopyrite inclusions with increasing metamorphic rank. With increased metamorphic grade, the pyrrhotite intergrowths change from rounded inclusions on grain boundaries to rod-like shapes along sphalerite twin planes. There is also a general increase in the relative proportion of pyrrhotite in the deposits. Textures that appear to have little value as indicators of metamorphic grade are sulphide deformation textures, and triple junction point angles and their standard deviations, which show little variation from the lower greenschist to the upper amphibolite facies of metamorphism. The presence or absence of myrmekite-like magnetite also has little value in determining the relative metamorphic history of these deposits, as it is a product of local contact metamorphism."

Jan 1, 1980

By G. R. Webber, P. J. Whittaker

"A multielement (Au, Cu, Pb, Zn, Ni, c-, Ag, As, Hg, Co, and S) geochemical rock sampling survey was carried out in 1977 in the Munro Township area of Ontario to assess the application of rock geochemistry for gold exploration in the region. Detailed sampling with analysis for gold and arsenic was done in 1986 in the immediate vicinity of the Croesus Mine.Samples of quartz veins and rock formations were taken in regional traverses and in more detail near old showings, prospect pits, and trenches. Quartz, graywacke, carbonate rock, and rhyolite contain the highest concentrations of gold for samples taken away from the old workings. Ultramafic rocks and gabbro have uniformly low gold. Basalt samples have slightly higher geometric means, but individual samples contain high gold concentrations. Multielement highs are mostly in mineralized quartz samples. Gold distribution is independent of other elements in most other rock types. Samples near old showings possess elevated concentrations of gold indicating that prospecting for individual mineral deposits by bedrock sampling is feasible. Concentrations of gold greater than 100 ppb are mostly within 30 m of old workings. Those samples which contain greater than 1000 ppb Au were obtained from quartz veins, basalt, graywacke, and rhyolite.High concentrations of gold were not notably concentrated near the Contact Fault although some anomalous samples came from near and on both sides of the fault. Arsenic concentrations are elevated near the Contact Fault. Detailed sampling near the Croesus Mine suggests that gold was introduced with faulting, alteration and quartz veining. Gold and arsenic have been added to the wallrock in the vicinity of the main veins."

Jan 1, 1989

By P. Fellner, A. Sýkorová, J. Thonstad, J. Jurišová, V. Khandl

Adsorption of S02 on alumina used in the aluminium industry, so-called smelter grade alumina, was studied in the temperature range 15 C-120 C. The specific surface area of the smelter grade alumina was 88 m2/g. It was found that at temperatures lower than 40 C, sulphur dioxide is bonded to alumina reversibly by physical forces, and the adsorption can be described satisfactorily by the Langmuir adsorption isotherm. The heat of adsorption was estimated to be -33 kJ.mor1. At temperatures in the range 80 C- 120 C, which prevail in dry scrubbers in the aluminium industry, the heat of adsorption was determined to be -56 kJ.mor1. When S02 was adsorbed at temperatures higher than 80 C, about 30 % of the S02 could not be desorbed when heating the samples up to 250 C. In the presence of S02 and oxygen, the formation of sulphate was determined at temperatures above 90 C.

Jan 1, 2006