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By Foster Fraas

One of the lithium minerals most widespread in the earth's surface is spodumene (Li20-A1203-4Si02), a lithium aluminium silicate. For some time, deposits of this mineral were known to exist in the Black Hills of South Dakota, but it was only quite recently that Hess4/ pointed out the great magnitude of the low-grade deposits in forth Carolina. The theoretical lithia (Li20) content of spodumene is 9.04 percent. The only other minerals with such high lithia content are the phosphates, but these occur only in pockets and are not in extensive deposits5/. Actually, however, the lithia content in spodumene is never found to be this high, being nearly always below 7 percent for the pure mineral, and part of the lithia is apparently replaced by other alkalies.

Jan 1, 1937

By D. Bienstock, J. H. Field, M. J. Lempel

A computer program is presented to perform the detailed and numerous calculations required for determining the interface temperatures and steady - state heat flow through a furnace wall composed of several refractories in layers . A method is developed that will allow the designer to determine the various thicknesses for each refractory layer to minimize either the total wall thickness or the cost of the wall per unit of area . A sample problem is presented and analyzed to illustrate the techniques involved .

Jan 1, 1964

By Robert E. Hershey

1. Estimates of reserves were made for three coal beds in Hamilton County the - Lantana, Sewanee, and Richland. Nine coal beds have been mined at one time or another in the county, but not enough information was available to estimate reserves in any beds other than the three given. 2. Known measured and indicated reserves for all beds, based on a minimum thickness of 14 inches and on 1,800 short tons per acre-foot of coal in place, are estimated to be 53 million tons as of January 1, 1954. Of this total 35 million tons is in beds 28 inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics were insufficient for making an estimate conforming with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove re-serves in these areas, such reserves should be added to the total estimated reserves determined by this investigation.

Jan 1, 1956

By J. B. Rosenbaum

Prolonged laboratory and limited pilot plant tests have shown that the Bureau of Mines buffered S02 -H2S process is capable of removing 95 to 99 percent of the S02 from industrial waste gases. Most of the S02 is converted to elemental sulfur; only about I percent converted to sulfate The process comprises (1) washing the flue gas to remove particulates and S03, (2) absorption of the S02 in citric acid or other carboxylate solution, (3) reaction of the loaded solution with H2S in a closed vessel to precipitate the absorbed S02 as elemental sulfur, and (4) separation of the sulfur from the regenerated solution by oil flotation and melting. Two-thirds of the molten sulfur is converted to H2S for use in the sulfur precipitation step by reacting sulfur vapor with natural gas and steam in the presence of an alumina catalyst. The chemistry and mechanism of the process are described, initial laboratory and pilot plant data are summarized, and second-generation laboratory operation and pilot plant design are reviewed. Preliminary cost estimates are presented for recovering sulfur from copper smelter gas, powerplant flue gas, and Claus plant tail gas.

Jan 1, 1973

By Dean H. Ambrose

This paper presents the results of a study using computer human modeling to examine machine appendage speed. The objective was to determine the impact of roof bolter machine appendage speed on the likelihood of the operator coming in contact with. A contact means two or more objects intersecting or touching each other, e.g., appendage makes contact with the operator?s hand, arm, head or leg. Incident investigation reports do not usually contain enough information to aid in studying this problem and laboratory experiments with human subjects are also not feasible because of safety and ethical issues. As an alternative, researchers developed a computer model approach as the primary means to gather data. By simulating an operator?s random behavior and machine?s appendage velocity, researchers can study potential hazards of tasks where it is not possible to perform experiments with human subjects. Analysis information is helpful to the mining industry in terms of making recommendations that reduce the likelihood that roof-bolter operators experience injury due to contact with a moving boom. Data analysis of roof bolter simulations show that the virtual-operator?s response time has little effect on the number of contacts experienced. Based on frequency and cross-tabulation, regardless of other variables, contact incidents were always greater when the boom was moving up, were always greater on the palm, and were always greater for the boom part of the machine. Also, regardless of boom speed, the 25th-percentile-sized operators experienced more contacts than did other operator sizes. Furthermore, regardless of boom speed, the 152-cm mine seam experienced more contacts than did other seam heights tested. Results of a survival analytic approach suggest that controlling the boom speed is the most important factor in determining the risk of an operator making contact. Based on the data collected, boom speed greater than 41 cm/s results in a substantial increase in risk to the roof bolter operator and should probably be avoided. At speeds less than or equal to 25 cm/s are associated with a more modest relative risk, which represents an acceptable level of risk. Also, at speeds between 25 and 41 cm/s, there could be a particular boom speed in this range at which a significant inflection point in the relative risk estimates occurs. Based on the results, this issue needs to be addressed by future research.

Jan 1, 2003

By B. J. Moore

This publication contains analyses and related source data for 252 natural gas samples from wells and pipelines in 17 States. All of the samples were obtained and analyzed during calendar year 1976 as a part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted in the United States by the Bureau of Mines since 1917. In late 1965, the survey was expanded to include foreign gasfields. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4862 and 576.3 The results of the investigation of the occurrences of helium are published annually to make the information available as soon as possible to the gas industry and the public in general. Eighteen previous publications have presented the results of 11,065 gas analyses prior to 1976. The first 3, Bulletins 486,4 576,5 and 617,6 contain analyses and related source data on 5,218 gas samples collected from 1917 through 1960. The other 15

Jan 1, 1977

By A. A. Berk

In the course of a study of the formation of external deposits on tubes in water-tube boilers it became desirable to determine the sulfur dioxide (SO2) and sulfur trioxide (SO3) in the Due gases. Determinations made by the A.S.M.E. method for SO2 and SO3 in gaseous products of combustion did not give accurate results. It was found that minute quantities of copper, present in the flue gases from the coal in use, caused oxidation of sulfite in the absorption bottle and that the carbon dioxide (CO2) in the flue gases caused high values for SO2. The A.S.M.E. test procedure was revised to prevent oxidation of sulfite in the absorption bottle and to allow for the effect of CO2; subsequent analyses of flue gases produced reliable results. The revised procedure is described.

Jan 1, 1950

By J. P. McGee

A 1,000-hour test with a gas turbine at 1,200° F showed a working fluid of 1 gr of ash per 100 scf of power gas (79 percent of the ash 7 to 35 microns in diameter) to be excessive for acceptable blade wear for commercial practicability. Blades in the turbine consisted of about 20 percent each of chromium, cobalt, and nickel; 3 percent molybdenum; 2-1/2 percent tungsten; and smaller amounts of manganese, columbium, and tantalum. Erosion of both the fronts and backs of the turbine nozzles was particularly heavy, the trailing edges being worn to a featheredge. Erosion of the buckets was less marked, although the leading edges were somewhat pitted. A refractory-lined combustor performed efficiently and with little abrasion of the lining by the ash-laden gas.

Jan 1, 1969

By Calvin K. Lee

This Bureau of Mines report describes a simple fire-retardant treatment for wood. The treatment involves preheating the wood surface at high heat flux (~0.6 cal/cm2 sec) to form an in situ surface char layer (~3 mm thick) on the wood. Laboratory-scale fire tests show that the precharring technique improves the fire-resistance of virgin wood by decreasing and delaying generation of volatile gases through thermal insulation effect of the surface prechar layer.

Jan 1, 1978

By A. E. Back

A method has been developed in the laboratory for successfully treating titaniferous magnetite ore from the deposit at Iron Mountain, Wyo. The ore is roasted with 15 percent sodium carbonate to convert the vanadium to a water-soluble form and fix the soda for the subsequent electric-smelting step. Approximately 90 percent of the vanadium is recoverable in a product assaying 80 percent V2O5. The leached calcine is briquetted and smelted in a graphite-lined electric-arc furnace. Substantially all of the titanium is recovered in a soda slag, assaying 60 percent TiO2 and 2 percent Fe, which can be upgraded to 75 to 80 percent TiO2 by leaching with dilute sulfuric acid. The upgraded slag could be utilized for the production of titanium dioxide pigments or titanium tetrachloride. About 90 percent of the iron is recovered as pig iron, containing only minor amounts of vanadium, titanium, and sulfur. The high TiO2 slag compares favorably with slag containing about 70 percent TiO2 being produced by the Quebec Iron & Titanium Corp. at Sorel, Quebec. The data obtained from this investigation indicate that a feasible process has been developed for treating Iron Mountain ore, and larger-scale testing is warranted to develop engineering data for the ultimate utilization of this deposit as a source of titanium, iron, and vanadium. There are adequate supplies of basic raw materials, electric power, water, sodium carbonate, coal, and petroleum products within fairly short distances of Cheyenne and Laramie, Wyo., the nearest cities and probable plant- and labor-supply points.

Jan 1, 1952

By Doyle A. Ellerbruch

An FM-CW microwave system was investigated for measuring coal layer thickness. Measurements were made in three different mines near Pittsburgh, Pennsylvania, near Fairview, West Virginia, and near Coffeen, Illinois. Microwave frequencies in the range 1-2 GHz were used to measure samples up to 55 cm thick. All samples were backed with a naturally occurring shale. Measurements were also made on coal and shale samples compounded in the laboratory at the Bureau of Mines Pittsburgh Mining and Safety Research Center near Bruceton, Pennsylvania. The results indicate that layer thickness can be determined in most cases, although large anomalies may, in some cases, produce misleading results. Many anomalies that were detected with the FM-CW system were verified visually by drilling into the coal layer. The dielectric constant of coal apparently varies significantly within a coal seam. The form of the output signals from the FM-CW system seem to simplify the data interpretation and analysis process as compared to the manually swept microwave system used previously. It appears that this technique has the potential of measuring changes in the dielectric constant of a coal seam and providing an output that can be used for real-time corrections in layer thickness; measurement.

Jan 1, 1976

By R. D. Leitch

"INTRODUCTION The character of mine drainage from areas of low pyritic coal3 and from average pyritic coal4 has been investigated, and to complete the study it seemed desirable to select a number of mines situated in high pyritic are as to determine whether or not this variation determines the relative acidity of drainage from mines operating in these characteristic coal fields. Advantage has been taken of some worked on in 1918 by Henry Leighton 5, then Professor of Economic Geology, University of Pittsburgh. He visited and has reported certain areas of high pyritic coal which we also visited during this study. Many of the mines were found to be idle in 1930 and a few were caved shut, apparently for several years. However, samples of the outflow from all mines visited were collected if possible and analyzed, and some general information was gathered for each mine. The map (fig. 1) shows the location of these areas as given by Leighton.ACKNOWLEDGMENTSThe information and assistance obtained from officials and others at the mines visited during this study are gratefully acknowledged, as well as the original suggestion from Dr. Glenn V. Brown of the State Sanitary Water Board who called attention to the desirability of such a study.Thanks are also especially due the coal laboratory of the United States Bureau of Mines, under the direction of H. M. Cooper, for the analyses and determination of sulphur forms in the large number of solid samples necessary to the work reported,This study has been carried on under the direction of R. R. Sayers, chief, health and safety branch, and W. P. Yant, supervising engineer, Pittsburgh Experiment Station, of the U. S. Bureau of Mines."

Jan 1, 1932

By S. J. Aresco

The Bureau of Mines has been active in promoting the purchase of coal for Government use under specifications that define the requirements in terms of heating value of the coal, expressed in British thermal units, and the composition as shown by proximate analyses. To these, when required, are added the ash-softening temperature, the free-swelling index, and the Hardgrove grindability index. Under most of these specification contracts the bidders guarantee the quality of the coal, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled in accordance with instructions4/ issued by the Bureau of Mines, the samples are analyzed in the Bureau laboratory to determine whether the coal is of the quality guaranteed by the contractor and, if it is not, a price adjustment is made. Analyses of the delivered coal and tipple samples (samples collected at mine tipples as coal is being loaded into railroad cars or trucks) provide valuable data for use in evaluating future bids. In addition, the continuous sampling of coal as delivered is a check on the practical results obtained in burning the coal.

Jan 1, 1957

By John A. Johnson

The first report of investigations5/ in this series pertaining to the investigation of stemming at the Mount Weather testing adit dealt with dust produced from blasting. The present report discussed the effect of stemming on eases generated by blasting, describes the test procedure, and analyzes the results from, blasting 61 standard rounds. Following care the types of stemming that are being investigated: 1, No stemming. 2. Sand in 2 paper cartridges. Clay in 2 paper cartridges. Commercial hydrated lira in 2 paper cartridges. 5. Combustible blasting plugs. 6. Ceramic is blasting plugs with clay in 2 paper cartridges.

Jan 1, 1940

By John A. Johnson

The first report of investigations5/ in this series pertaining to the investigation of stemming at the Mount Weather testing adit dealt with dust produced from blasting. The present report discusses the effect of stemming on eases generated by blasting, describes the test procedure, and analyzes the results from, blasting 61 standard rounds. Following care the types of stemming that -,re being investigated: 1, No stemming. 2. Sand in 2 paper cartridges. 3. Clay in 2 paper cartridges. 4. Commercial hydrated lime in 2 paper cartridges. 5. Combustible blasting plugs. 6. Ceramic is blasting plugs with clay in 2 paper cartridges.

Jan 1, 1940

By S. J. Broderick

[Huge camp heaps coat. in-.n,- ta._ur nd o tons of coal :'efuse are a familiar sight in coa).--:1'_ni`l ; res io The;;' repre£e: t considerable economic loss, are very ~JZ':Si~i,tly, and tr:_ e u.: mach v lua-ble :price. Consequentl;;* their remcva7. is ,-,reatl:r de sir^~t~ a_." ar return that c,-u? be obtained would. be especially rel.co c to the coal T,-e "a_ste nat(~ria1 commrioes large pieces of bore cca1., lumps rf c12;', -)nd finer refuc3 coming from the 'acxcor~-, Tnc e'-:s: rr;I refuso contains some Food coal. Th1S coal and the better crams of _,)ore Pre t'--:e na.torials considered. in ohis in¬vestigotion. T'.-.r, heavier fractions of the vas ier,,refuse a rd. the large pieces of slate a n i roc _r contain little carbcnacaous r..aterinl -.nd axe ~vir¬ tually worthless ra'., :,atcria1. for activated carbon. In the E i 1i 11?'ar 1 dictrict~ n1ab a :1 ut irfl percent of the' coal mined is wa^,hed., and in district rc_a e -c-cnuatcs at the r..-ate of I to 2 Million tons a year?]

Jan 1, 1941

By E. L. Garton

The Bureau of Mines for a number of years bas been conducting an investigation of crude petroleum from producing fields in the United States and the Western Hemisphere and has published a series of reports on these fields. Analyses of crude-oil samples from many oil fields of Oklahoma are given in Bulletin 2915. Analyses of 21 representative crude oils from various producing zones of the Oklahoma City field are given in this report. A close study of the analyses reveals very few differences in the general characteristics and chemical properties of these oils.

Jan 1, 1932

By J. P. Capp

This experiment, one of a series on underground gasification of coal, was an investigation by the Federal Bureau of Mines of hydraulic fracturing as a means of increasing the air acceptance of a coalbed to permit introducing combustion air and removing product gases. Specific objectives of the investigation included: (1) Fracturing a coalbed; (2) determining the distance the coal was physically affected; (3) ascertaining the effect of the fracture on air acceptance of the coalbed; and (4) gasifying the coal. The coal was fractured with a fluid consisting of 15,000 lb. of sand mixed with 10,000 gal. of fuel oil and 5,000 gal. of kerosine, injected at pressures up to 900 p.s.i.g. and rates up to 425 g.p.m. The oil served as the fracturing medium, and the sand as a propping agent to hold the fracture open. From the fracture point, (the place in the bed where the fluid was injected), the fracture extended 200 ft. or more along the face cleats, somewhat less along the butt. cleats, and was confined to the coalbed. At the fracture point, the bed accepted about 500 std. c.f.m. of air, which was an etghtyfold increase. Fracture effects were extensive, as airflow was noted from old mine workings and outcrops 600 to 800 ft. from the fracture point. It is probable the actual fracture was much less than 600 ft. and that normal coalbed permeability beyond the fracture limits was responsible for this flow. This indicated that effects of the fracture extended beyond the area of coal physically affected. Although no attempt was made to gasify coal more than 200 ft. away, these effects plus the natural permeability of the bed likely would permit combustion beyond the outer limit of the fracture. As these experiments continued for more than 2 years, and greater air acceptance due to the fracture was observed at the beginning of each test, it is apparent that the effects of the fracturing persist for a considerable time.

Jan 1, 1960

By Maurice J. Peterson

THE VISUAL-ARC spectroscopic method of rapid qualitative analysis of complex inorganic compounds has been popularized in the past few years and is being employed by an increasing number of laboratories. The mineralogy and chemistry departments of several universities recently have added visual spectroscopy to their laboratory curricula. This revival of interest in a somewhat dormant analytical method has been stimulated through the publication of three papers 4 by members of the College Park staff of the Bureau of Mines. These virtually are the only recent sources of information on visual-arc spectroscopic analysis. They include data on the spectroscopic assembly, the analytical procedure, and the practical application of the method to determinative mineralogy and related fields. Requests for reprints of these papers continue to be received; at present only a limited number of copies are available for distribution. In order that these requests may be adequately answered, material from the three papers has been combined and, with some additional data, is presented in this bulletin. Numerous specific inquiries have been received regarding types of equipment available, problems in instrumentation, and information on the approximate sensitivity limits of the elements that can be detected by this method. Some of this material was not included in the original papers. Accordingly, the table of wavelengths has been revised to include the approximate visual-arc spectroscopic sensitivities, and a section on commercially available equipment has been added.

Jan 1, 1953

By E. P. Youngman

The basic mining law of Esthonia is the law that was passed by the Parliament (Riigikogu), or State Assembly, on March 17, 1927 (effective Avril 1, 1927), superseding the Russian Mining Law Book VII of the Code) issued in 1912. References in this digest are only to articles of the Law of Merch 17, 1927. However, the law concerning all industrial enterprises (Riigi Teataja No. 28, 1920, Law No. 106) governs not only mills and refineries but also mining operations themselves (arts. 2 and 3). No access was ad to that law. Esthonia is not well supplied with minerals; its industries are primari- ly agriculture and dairy farming. Natural gas, prites, lead, zinc, iron ore, salt, and mineral waters have been found but never as yet in deposits of commer cial size. The production of oil shale is of some importance; and peat, which covers as much as 5 per cent of the total area of the country, is mined in sub- stantial quantities. Cement rock, gypsum, fire clay, and phosphate rock likewise are produced, though only on a small scale.

May 1, 1930