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By F. R. McDonald

This report presents a discussion of the spectra of 39 condensed thiophenes in which the structure includes at least 1 benzene ring. The vibrational bands present in three regions of the infrared spectra of these thiophenes were interpreted by comparing the similarities of the spectra of condensed thiophenes with the spectra of substituted benzenes. In the overtone-combination region 23 of the 39 condensed thiophenes had spectra which contained sufficient detail to be usable for correlating this region of the spectrum with the appropriate benzene spectrum. In the in-plane deformation region it was possible to make correlations for the vibrations of 18 of the 39 condensed thiophenes whose infrared spectra were studied. In the out-of-plane deformation region the C-H out-of-plane vibrations for hydrogen on benzene rings in the condensed thiophenes can be correlated using known data from substituted benzenes.

Jan 1, 1967

By T. L. Joseph

The size and accessibility of the Minnesota manganiferous iron ore deposits make them attractive as a potential source of erromanganese, which is essential in the production of steel. For several years the Bureau of Mines has been conducting experiments to determine the feasibility of producing ferromanganese from these ores by a three-step process which involves (1) the smelting of the ores in the blast furnaoe to produce a high-phosphorus spiegel; (2) the treatment of the spiegel produced from step 1 in an electric or open-hearth furnace to separate the manganese from the phosphorus and the iron; and 3) the smelting of the high-manganese slag from step 2 to produce forromanganese. The details of the first two steps of the process and the results of tests with the experimental furnaces Lave been given in previous reports.5 The m$ or part of the experimental work on the second step has been conducted in a half-ton open-hearth furnace. Some preliminary tests showed, however, that the electric furnace has some distinct advantages over the open hearth for producing, from high-phosphorus spiegel, a slag containing from 45 to 55 per cent manganese and phosphorus and iron in amounts required for ferro-grade ore. The electric furnace tests described in this paper were made to get more information as to the possibilities of the electric furnace in connection with this problem and to study the fluxing effect of alumina on high-manganese slags. Herty, Conley, and Royer have reported' results of laboratory tests which showed that slags containing from 60 to 75 per cent MnO, from 8 to 10 per cent S102, and small amounts of CaO MgO, and FeO, were sufficiently fluid at 1,450° to 1,550° C. to pour readily if 12 to 14 per cent alumina was present. With a normal A1203 content resulting from the A1203 in the

Jan 1, 1931

By D. L. Sawyer

Aqueous C12-02 leaching procedures developed by the Bureau of Mines to produce zinc chloride from zinc sulfide bulk concentrates were effective in extracting 99 pct of the zinc and 97 pet of the silver contained in samples of massive seafloor sulfides from the southern Juan de Fuca Ridge. Zinc sulfide (sphalerite and wurtzite) mineralization comprised 55 and 88 pct of two specimens provided by the U.S. Geological Survey for this study. Minor occurrences of galena, chalcopyrite, and other minerals in the sulfides permitted the recovery of pregnant liquors that were low in metal values other than zinc, which were successfully purified by a two-step cementation procedure using zinc dust.

Jan 1, 1983

By Lloyd M. Kniffin

[This paper is one of series being prepared by the United States Bureau of Mines on mining methods, practices, and costs in the various mining districts of the United States. It describes the mine of the Hanover Bessemer Iron & Copper Co. at Fierro, Grant County, N. M., which is the only operating iron mine in the southwestern part of the United States. This mine is in a district noted for the great variety of ores that it produces. Within a small area, as shown is Figure 1, there are noteworthy deposits of nearly all the common metals. The ore occurs in lenticular masses dipping at about 50°. An underhand stoping method has been developed that requires but a very small amount of handling of ore. As the ore is very irregular in iron content and also in the distribution of the impurities--chiefly sulphur, silica, and magnesia--a method has to be used that will permit selective mining and will also allow ore and waste to be taken out separately as conditions change. A magnetic cobbing plant raises the grade of the ore shipped about 10 per cent.]

Jan 1, 1930

By George S. Rice, J. W. Paul, E. H. Denny

Data assembled by the Bureau of Mines , coupled with requests from coal companies , have emphasized the desirability of establishing standardized specifications for brattice cloth with particular respect to durability and fireproofing . Brattice cloth is a canvas or other material , often covered with some fireproofing composition , which is used extensively in coal mining for temporarily deflecting air into pillar workings and maintaining ventilation at the working faces . These specifications will be established , it is planned , through a cooperative program in which the U. S. Bureau of Standards will make a series of tests of various brattice cloths treated with respect to fire- resisting qualities and the U. S. Bureau of Mines will continue to assemble field data on the use of brattice cloth . Plans now are being made for this cooperative work. Without attempting to make a complete survey , the Bureau of Mines has made preliminary studies and investigations , and verious representative coal - mining companies have furnished detailed information . The information thus gained will be used as the basis for the cooperative investigation , but the Bureau of Mines would welcome additional information from mine operators on the character and weight of brattice cloth , conditions of use , durability , quantity employed and price . Such information should be sent to the Director , Bureau of Mines , Washington , D. C. The mine operator is interested in procuring at reasonable cost a brattice cloth with lasting fireproofing quality and of as great durability and strength as possible . There has been a lack of assembled data and knowledge regarding the subject , but the Bureau of Mines feels that this lack of knowledge may be overcome if the coal -mining companies will lend their hearty support to the cooperative investigation and submit information relative to the use of brattice cloth in their own properties . Information contained in this report is based on data obtained from coal operators in bituminous districts of Pennsylvania , Alabama , Utah , Indiana , Illinois , Colorado and Nova Scotia .

Feb 1, 1923

By J. Bennetts

As part of its mission to develop technology that will help increase the supply of critical and strategic minerals from domestic resources, the Bureau of Mines has investigated methods for beneficiating platinum-group metal ores from the Stillwater complex, Montana. This report presents the result of a bench-scale study employing froth flotation to recover a sulfide concentrate containing platinum-palladium values from a mineralized gabbro. Best results were obtained with a flotation scheme utilizing a mercaptobenzothiazone collector and sulfuric acid. Rougher concentrates containing approximately 11 oz Pt-Pd/ton and 90 pct of the metal values in the ore were obtained. Subsequently, cleaner concentrates containing approximately 26 oz Pt-Pd/ton and between 80 to 85 pct of the Pt-Pd values in the ore were prepared.

Jan 1, 1980

By Allen D. Look

Use of two-way radio communication at the Santa Rita open pit of the Kennecott Copper Corp. has furnished a satisfactory answer to the problem of communications for an operation covering an extended area. Coordination of operations has resulted, with little loss of time in making changes during the shift. Repairs are facilitated, and safety of operations is increased through better control of blasting and hazardous conditions. INTRODUCTION Expansion of mining operations brings increasing needs of improved communications to coordinate the mechanized operations that contribute to the efficiency of present-day open-pit methods. Equipment found satisfactory when first installed becomes inadequate as distances and demands increase. It is the, purpose of this paper to record the progress being made by one mine in meeting this problem.

Jan 1, 1952

By Leland E. Paulson

This investigation examined the feasibility of altering the inorganic component of North Dakota lignite by ion exchange. Lignite of specific size consist was washed with various ionic solutions and examined for evidence of exchange. Ions of higher valance substituted preferentially at equivalent concentrations. Results indicate that a major portion of the inorganic material associated with lignite is combined in exchangeable form with the organic component. Particle size of the treated coal is a critical factor in determining the rate of exchange. The data indicate that monovalent ions are easily replaced by divalent and trivalent ions, and the presence of ionic material in slurries containing finely divided lignite significantly increases filtration rates.

Jan 1, 1968

By Russell J. Gartrell

This report describes the engineering feasibility and economic advantages of using a steep angle conveyance (SAC) system in conjunction with medium and large draglines to transport spoil in a typical Western Coal Mine. The SAC system, including a receiving hopper, a steep angle conveyor and a sticker/spreader, is capable of processing overburden material at the rate of 7,000 tons/hr. The unique feature of this system is the steep angle conveyor which transports the overburden material from the pit bottom to the top of the spoil at angles to 45 degrees. Compared to other means of cross-pit conveyance considered during this study, the SAC system offers the advantage of easier operation, lower conveyance cost and greater mobility. The results of this study have shown that integration of the SAC system into both established and planned new mines would improve the overall mining operation, expand the operating capability of existing equipment and reduce mining end reclamation cost.

Jan 1, 1977

By G. L. Leumann

"INTRODUCTION AND SUMMARYThe Andover-Sulphur Hill iron mines in Sussex County, N. J., have a production record extending over 100 years. The last production recorded was about 1880. These mines produced high-grade ore of two types: Red ore (hematite) and blue on (magnetite). Some sulfides (lead, zinc, and copper) were found underlying the iron deposits. Data as to size and grade of these sulfide bodies are very sketch"",Howard J. Hewitt of Elizabeth, N. J., lessee of the Sulphur Hill mines from 1940-45, prospected for lead, zinc, and copper. .His only production was several hundred tons of low-grade iron ore, which was crushed and used as heavy aggregate to make concrete blocks for ship ballast.In October and November 1942 made a magnetic survey of this area and bored six-diamond-drill holes with the dual objective of prospecting for sulfides and testing for extensions of the iron-are deposits indicated by the magnetic survey. 2/ In 1944, an iron-mining company examined this property and diamond-drilled seven holes. Between December 1949 and March 1950, the Bureau of Mines in search of sulfide deposits, bored three additional diamond-drill holes. Two of these were on the Sulphur Hill tract and one on the adjoining Tar Hill tract."

Sep 1, 1952

By J. M. Davidson

The potassium mineral polyhalite (K2SO4.MgSO4.2CaSO4.2H2O) found in large deposits in western Texas and southeastern New Mexico is associated with varying amounts of halite (sodium, chloride, NaCl) and anhydrite (calcium sulphate, CaSO4). Although the anhydrite, because of its low solubility and slow rate of solution, is relatively inert, the halite is dissolved immediately in any process solution with which the polyhalite comes in contact. Limited quantities of sodium chloride in the liquors used for the hot extraction of polyhalite materially improve the results obtained, but only a very small sodium chloride content may be desired in the entering polyhalite in other procedures, such as Bureau of Mines process. In all of the processes suggested for the recovery-of potassium sulphate from polyhalite the control of the sodium chloride content will be desirable, if not absolutely essential to efficient operation.

Jan 1, 1934

Severe whipping of shuttle car trailing cables occurs when the car stops suddenly or reverses direction. This causes cable damage, and can seriously injure personnel near the cable. FMC has contracted with the U.S. Bureau of Mines to design, build and demonstrate a reel control system that will significantly reduce or eliminate whipping. II. CONCLUSIONS Results of engineering effort show that the following conditions are primarily responsible for the whipping problem. Causes may exist individually, or in combination.

Jan 1, 1972

By V. F. Swanson

As part of the Bureau of Mines titanium resources examination program, samples of altered rock (saprolite) and unaltered rock from the Roseland anorthosite near Roseland, Nelson County, Va., were tested for amenability to beneficiation by flotation. A flotation technique was developed to produce bulk concentrates of ilmenite, rutile, sphene, and leucoxene. It was necessary to first float apatite using oleic acid as the collector, in an alkaline pulp with dextrine as a titanium mineral depressant. The titanium minerals could then be floated from the apatite tailing, using fluosilicic acid to depress the remaining apatite, morin to depress ferromagnesian minerals (when present), and oleic acid as the collector. A bulk titanium mineral concentrate, analyzing 66.0 percent Ti02 and 0.08 percent P205, was obtained from a sample of the unaltered rock which contained 5.45 percent TiO2 and 2.81 percent P205. Overall recovery in the concentrate was 47.1 percent of the total TiO2 in the ore. About 55 to 65 percent of the saprolite sample was clay and was removed by attrition scrubbing and decantation. The apatite prefloat procedure was applied to the saprolite sands; subsequent titanium mine: 1 flotation recovered 72.2 percent of the Ti02 in a bulk concentrate containing 65.1 percent TiO2 and 0.20 percent P205.

Jan 1, 1962

By C. M. Harrer

The location, features, quality, and extent of iron ore deposits are evaluated in this Bureau of Mines report. The results of pioneer beneficiation on Wyoming taconites and their success are discussed along with developments in the iron-ore mining industry, markets, and economics. Market potential, transportation, resource developments, taxation, cost of iron ore enterprises, and the future of Wyoming iron resources are evaluated. Although occurrences of iron ores in Wyoming were known prior to 1870, early production to 1900 was as a nonferrous metallurgical flux and as mineral pigment for paints. In 1901, the Hartville-Sunrise hematite deposits were available to the Western iron and steel industry and in 1962, the first western taconite operation was placed in production at Atlantic City, Wyo. This investigation disclosed the probability of other large iron deposits in Wyoming. Taconite in the Bradley Peak area of the Seminoe Mountains has a potentiality of 100 million tons; that in the Owl Creek Mountains may prove very large also. Pioneer beneficiation testing has been included, and results have been generally encouraging. Research continues on the large titaniferous magnetite deposits of Albany County, Wyo. At present high-density titaniferous magnetite is being mined and processed at Iron Mountain for heavy-aggregate and as a sized coating for underwater pipelines. Ample mineral raw materials needed for mining and processing Wyoming iron ores are available. Investments for iron-ore processing plants will generally be large, particularly for taconite and titaniferous magnetite.

Jan 1, 1966

By C. M. Harrer

The location, features, quality, and extent of iron ore deposits are evaluated in this Bureau of Mines report. The results of pioneer beneficiation on Wyoming taconites and their success are discussed along with developments in the iron-ore mining industry, markets, and economics. Market potential, transportation, resource developments, taxation, cost of iron ore enterprises, and the future of Wyoming iron resources are evaluated. Although occurrences of iron ores in Wyoming were known prior to 1870, early production to 1900 was as a nonferrous metallurgical flux and as mineral pigment for paints. In 1901, the Hartville-Sunrise hematite deposits were available to the Western iron and steel industry and in 1962, the first western taconite operation was placed in production at Atlantic City, Wyo. This investigation disclosed the probability of other large iron deposits in Wyoming. Taconite in the Bradley Peak area of the Seminoe Mountains has a potentiality of 100 million tons; that in the Owl Creek Mountains may prove very large also. Pioneer beneficiation testing has been included, and results have been generally encouraging. Research continues on the large titaniferous magnetite deposits of Albany County, Wyo. At present high-density titaniferous magnetite is being mined and processed at Iron Mountain for heavy-aggregate and as a sized coating for underwater pipelines. Ample mineral raw materials needed for mining and processing Wyoming iron ores are available. Investments for iron-ore processing plants will generally be large, particularly for taconite and titaniferous magnetite.

Jan 1, 1966

By George J. Carter

Data obtained from field and laboratory examinations were used by the Bureau of Mines to evaluate 82 silica deposits in the Pacific Northwest. A total of 94 field samples was taken from 64 deposits, and an additional 18 deposits were investigated that did not warrant sampling. Of the 37 deposits found to be of high quality, only 16 were large enough to be classified as industrial silica resources. Another 27 deposits did not meet quality requirements. Methods of simple low-cost beneficiation and rapid classification of a large number of samples were investigated in the laboratory. These tests indicated that high-intensity electromagnetic separation was equal or superior to either high-or low-intensity electrostatic separation. In general, the electromagnetic method gave higher recoveries and produced equal or better grade concentrates. A glass button method developed for estimating iron oxide content of silica samples proved to be highly satisfactory as a means of classifying field samples and evaluating beneficiation tests.

Jan 1, 1962

An active list of permissible explosives was published in July, 1931, as part of United States Bureau of Mines Report of Investigations 313, under the title of "Active List of Permissible Explosives and Blasting Devices Approved Prior to June 30, 1931." Changes in that list were authorized in August, September, October, November, and December, 1931, and. January and March, 1932, as published in Reports of Investigations 3l40, 3147, 3l50, 3155, 3158, 3161, and 3163, respectively. By these changes the following explosives were added to the active permissible list: [Austin Red Diamond No. 1, L. F. Gel-Coalite W. L. F. Austin Red-Diamond No. 5, L., F. Gen-Gel No. 2. Black Diamond Nu-Gel No. 1 Genite C-1 Burton 1, L. F. Liberty No. 4 Burton 2, L. F. Liberty No. 5 Burton 10, L. F. Peerless D Burton 12, L. F. Permigel 1, L. F. Burton F, L. F.]

Jan 1, 1932

By L. A. Schutz

Personnel of the Bureau of Mines have conducted investigations in the principal asbestos mines and mills in the United States, to determine the concentration of airborne asbestos fibers in the workplace, and to establish the exposure of workers to such fibers. 'The surveys were conducted using the sampling and evaluation method recommended by the National Institute for Occupational Safety and Health. The method consists of collecting the air-borne sample on filters and, after appropriate sample preparation, counting the fibers utilizing phase contrast microscopy. The results of the investigation show that fiber concentrations are low in the asbestos mines but high in the asbestos mills, ranging well above 5 fibers/ml of air based on a count of fibers greater than 5 urn in length.

Jan 1, 1973

By J. M. Pugliese

The Bureau of Mines, in support of its overall goal of helping to meet future U.S. demand for minerals, undertook this study to aid the quarry entrepreneur and/or operator in developing quarries near urban areas. In response to increased environmental concerns, the quarry operator often must take steps beyond those required in the last decade toward gaining permits for quarrying near metropolitan areas. Following the steps suggested in this report should increase the chances to obtain the permits to open and develop a quarry. Each task and question in the general plan flow diagrams are described in detail, with the flow diagrams aimed at the goal of acquiring the necessary permits. The appendixes include (1) types of projects for which Environmental Impact Statements (EIS's) may be prepared and Federal agencies responsible for preparing them, (2) State contacts for information regarding environmental impact assessment requirements and mining and mineral land reclamation laws, (3) a checklist of environmental inventory factors, (4) a tabulation of different regulations that affect mining in Michigan and the number of townships and counties that have each of the listed regulations, and (5) environmental logic associated with site selection. A central recommendation is that the quarry entrepreneur and/or operator coordinate plans at the beginning with local government officials (such as township supervisors and/or city and county planning board members), State and Federal officials, and public groups that will be affected.

Jan 1, 1979

By K. Hanna

This U.S. Bureau of Mines report describes a rock mechanics instrumentation program conducted in a shallow underground coal mine in central Illinois. This research program was designed to provide a basic understanding of the structural behavior of entry intersections. A wide variety of instruments and measurement techniques including hydraulic borehole pressure cells, multiple-point borehole extensometers, roof bolt compression pads, and overcoring were employed to monitor roof stresses, pillar loading, strata movement, floor heave, and bolt loading before, during, and after intersection development. A summary of intersection design theories, failure modes, and support techniques is included and instrumentation installation procedures and analysis methods are presented. The study identified two critical parameters that affect intersection stability: in situ horizontal stresses and geological discontinuities. Important design parameters for improving intersection stability are roof span and intersection geometry.

Jan 1, 1991