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By R. Vernon Helm

Four tables listing values for the various physical properties of those sulfur compounds most likely to occur in petroleum and petroleum products are given herein. The data necessary to bring the first compilation2/ in this subject up to date are given in table I -Revised and Additional Data, which includes boiling points, refractive indices, densities, and freezing points. Tables 11-, III, and IV are published for the first time and include refractive indices for the F, C, and G' lines of hydrogen and the helium D:3 line; surface tensions and viscosities, and refractivity intercepts, specific dispersions, specific refractions, and parachors. The need for information concerning the sulfur compounds in petroleum is becoming-more urgent because of the necessity of refining larger quantities of high-sulfur crude oil to meet the rising demand for petroleum products. For a number of years the Bureau of Mines has been engaged in research to make available more information concerning the properties of the sulfur compounds in petroleum. The petroleum industry has recognized the value of such studies, and as a result the American Petroleum Institute has established Research Project 48A to study sulfur compounds. The investigations under this Project are to be done in Bureau of Mines laboratories as a cooperative project in connection with the work already started.

Jan 1, 1949

By Paul M. Tyler

The enormous deposits of greensand in New Jersey and elsewhere in the United States, many of them close to important octant industrial centers, constitute a perpetual challenge for research chemists to convert them into a commercial asset of national importance. Following the introduction of more concentrated fertilizers, comprising synthetic mixtures of more soluble salts, the quantity of greensand used directly upon the soil has diminished, but deposits of such material still have at least potential value locally for use not only as fertilizer but also as a water softener. An annotated bibliography of the already extensive Literature on greensand, virtually complete to about the end of 1929, has been issued by the Bureau of Mines3/, and the commercial aspects as well as the technology of greensand utilization are discussed in available publications, The purpose of the present circular, therefore, is merely to provide a brief outline of certain general essential considerations for use in appraising the potential value of a greensand deposit in any given locality.

Jan 1, 1934

By George McCaa, H. C. Howarth

"During recovery operations following a recent coal-mine explosion, 12 small fires were encountered near the break line of pillar extraction in a large panel. All of the fires except one were quickly extinguished by the rescue and recovery parties. This fire had found its way into a large quantity of loose material at a corner of the cut-through between two rooms, about 100 to 150 feet from the break line of an extensive goaf; had it been necessary to seal the fire, the inclusion of this break line not only would have made the work difficult but would have made the section hazardous as it probably would have given off gas. The fire covered a floor space of about 100 square feet and when discovered was burning briskly, with the flame extending to the roof at a height of 3 or 4 feet; it was the cause of much apprehension on the part of those in charge of the recovery operations and resulted in delaying the work considerablyThe object of this article is to describe in detail the method by which the fire was brought under control and finally extinguished, so that other persons encountering similar conditions may have the benefit of the experience.When the fire was discovered a request for rock-dust, fire extinguishers, and other fire fighting equipment was telephoned to headquarters on the surface. The promptness with which fire fighting equipment and material was provided was a big factor in finally extinguishing the fire and illustrates one of the many advantages of a good organization for fire-fighting. Material was transported in mine cars to a point on the main hauling road about 1,200 feet from the fire. It was then carried to the scene of activity by workmen. The first material to be delivered at the fire was a number of fire extinguishers of various types. The contents of 30 to 35 of these were discharged on the fire and with the aid of a small quantity of rock-dust were sufficient to smother the flame temporarily. It was the opinion of several persons who were present when the fire extinguishers were used that the acid-soda type of extinguisher gave more effective results than the two or three other types used.When the contents of all of the fire extinguishers had been exhausted the fire was temporarily smothered, but as there appeared to be danger that the flame would burst forth again, means for completely extinguishing the fire were"

Feb 1, 1929

By Wilson Blake

The Bureau of Mines used a mathematical model based on the finite element method of stress analysis to calculate stresses and displacements surrounding an open pit mine in a gravity-loaded rock mass. Comparison of the finite element solution for a semicircular notch in a gravity-loaded plate with the theoretical solution for a semicircular notch in a plate under uniform compression parallel to the free boundary demonstrates the inapplicability of the latter method to openings at the free surface of a gravity-loaded medium. High stress concentrations are formed at irregularities along the boundary of an open pit in a gravity-loaded continuous competent rock; however, for this type of rock the magnitudes of the stresses are too low to be considered a major factor in open pit slope stability. High stress magnitudes will occur if, in addition to the gravity stress field, a large horizontal stress field exists.

Jan 1, 1967

By d&apos, Kathleen J. Amico

THIS SUMMARY appears in Minerals Yearbook volumes I and III, which cover mineral production in the United States, its island possessions, the Canal Zone, and the Commonwealth of Puerto Rico, as well as the principal minerals imported into and exported from the United States. The several commodity and area chapters contain further details on production. A summary table comparing world and U.S. mineral production also is included. Mineral production may be measured at any of several stages of extraction and processing. The stage of measurement used in the chapter is normally what is termed "mine output." It usually refers to minerals in the form in which they are first extracted from the ground, but customarily includes for some minerals the product of auxiliary processing operatons at or near mines.

Jan 1, 1963

By Robert E. Manning

The Federal Coal Mine Health and Safety Act of 1969 has placed stringent limitations on the noise levels in which employees may work. This act can result in both increased labor costs because of noise-exposure time limitations and in high capital costs for modification of present equipment, and the design of new equipment, to comply with the law. The development of new noise-control systems is thus of immediate interest to industry. A current Research program at U. S. Steel is aimed at developing methods of controlling both the exhaust-air noise and the mechanical noise of a Stoper drill, a pneumatic percussive tool used for roof-bolting purposes in coal mines which has an approximate air consumption of 100 cubic feet per minute. This program is being performed under a contract between USS Engineers and Consultants, Inc. and the Pittsburgh Mining and Safety Research Center of the U. S. Bureau of Mines. In previous work at U. S. Steel, kidney-shaped mufflers were designed that wrap around the air leg of the drill for control of the exhaust noise. These mufflers were designed with the aid of a digital computer program that predicts the acoustic performance of mufflers.

Jan 1, 1975

By C. W. Smith

The U.S. Bureau of Mines; Tuscaloosa Research Center, in cooperation with the U.S. Army Corps of Engineers under interagency Agreement No. 14-09-0078-1510, conducted a comprehensive sampling program of 10 upland disposal sites along the Alabama, Black Warrior, and Tombigbee River systems in Alabama. Samples from each site were characterized according to particle size, chemical analysis, mineralogical content, and potential end use. Additionally, samples were subjected to the Toxic Characteristic Leachate Procedure to determine the presence of potentially harmful heavy metals. Based on the results of these studies, each sample was determined to have properties amenable for use as aggregate in general-purpose portland cement concretes and certain asphalt concrete applications.

Jan 1, 2010

Oil from shales has long been a source of fuel in foreign countries; however, in the fuel economy of the United States this source is classed as a reserve for future needs. In fad, shale oil has never been produced here in quantities necessary to establish oil-shale utilization as a sustained industry. The first known resources of stored energy that man endeavored to utilize were probably wood and water, and from these he directly obtained heat and power, respectively. With the evolution of man came the search for and the development and use of other natural fuel resources, the series progressing through the solid, liquid, and gaseous fuels until today those of one type can be converted into another, depending upon the use for which they are intended. The most important fuels are those that appear naturally in the most concentrated, conveniently obtainable, and usable forms. With the discovery of each new and more concentrated fuel there has been an appreciable increase in the importance of and number of devices for converting these fuels into energy.

Jan 1, 1938

By R. E. Head, Virgil Miller

"INTRODUCTIONRecent investigations at the Intermountain Experiment Station of the Bureau of Mines at Salt Lake City indicate that metallurgists have given little attention to the occurrence of jarosite minerals in the oxidized ores of lead and silver. These investigations have also emphasized the importance of knowing when these minerals occur in the oxidized ores, especially those containing lead, silver, and gold, as their presence is a material factor in selecting a suitable kind of treatment. Since the question of the occurrence of jarosites in oxidized ores has come to the attention of the Bureau of Mines, investigation has indicated that plumbojarosite and argentojarosite are quite common. These two minerals appear to be widely distributed and probably escaped recognition by persons who had attempted to treat certain oxidized lead ores in which the jarosite minerals represented a material portion of the metal content.Consideration of the physical characteristics of the jarosites also indicates that in many cases failure to treat some of the oxidized lead ores with success has been directly due to the fact that the greater portion of their lead and silver content was present as plumbojarosite and argentojarosite. The data and the description of these minerals given in the body of this paper indi¬cate that attempts to recover lead and silver from ores in which appreciable amounts of the metals occur as plumbojarosite and argentojaeosite would be unsuccessful if confined to gravity methods of concentration. There are un-doubtedly considerable tonnages of oxidized lead ores in the various mining regions of this and other countries, and it is quite probable that in some of these ores the metal content of lead and silver may be largely anglesite (lead sulphate) and cerussite (lead carbonate) but that they will also contain cerargyrite (silver chloride), argentojarosite, and plumbojarosite. The treatment of such ores therefore presents an important problem, since a product is discarded from ores from which the recoveries of lead and silver have been below 70 per cent which is probably too low-grade to warrant aftertreatment by any process now in use."

Apr 1, 1928

By Brian G. White

The Coeur d'Alene Mining District of northern Idaho is remarkable for its number of large ore bodies and for the amount of its historical production of lead, zinc and silver (Fig. 1). Since veins were first discovered in 1884, more than 127 Mt (140 million st) of ore have been produced from narrow, high-grade veins. Mining continues at the Lucky Friday, Galena and Sunshine mines (Fig. 2). All have been in production for decades. At these mines, more efficient mining and exploration techniques have reduced costs while adding significant new reserves. Even the old Bunker Hill Mine, where ore was first found in 1875, continues operation on a limited basis, partly involving production of world-class pyromorphite specimens. Until recently, the Coeur Mine was also a profitable silver producer. Other large producers have included the Star-Morning, Hecla, Page, Standard-Mammoth, Hercules and Gold Hunter mines (Fig. 2). The first deposits were discovered by prospectors who spilled over from the Murray gold mining district, 24 km (15 miles) to the north. The Bunker Hill Mine was founded the year after the first veins were discovered. Bunker Hill has now operated for more than 100 years. Production includes 2.3 Mt (2.6 million st) of lead, 1.1 Mt (1.2 million st) of zinc and 4.1 kt (132 million oz) of silver. Total district production through 1996 (Springer, 1997) amounted to 7.3 Mt (8.1 million st) of lead, 3 Mt (3.3 million st) of zinc, and 34.5 kt (1.109 billion oz) of silver. This record establishes the district as the largest recorded producer of silver in the world, while also yielding major quantities of lead and zinc. Only Potosi, Bolivia, may have produced more silver, although records are unclear. Despite the district's longevity, historic production and current activity, the published literature on the district lags behind with regard to recent concepts of district geology. The most recent comprehensive US Geological Survey (USGS) bulletins (Hobbs et al., 1965; Fryklund, 1964) are dated. Much research in the last half century has been short-lived or geographically restricted because the district is large and its geology is complex - and even this research tends to remain unpublished. Thus, it has been difficult for in- [ ]

By Leon W. Dupuy

"INTRODUCTION Scheelite occurring in tactite at the Black Rock tungsten mine, near Benton in Mono County, Calif., was investigated by the Bureau of Mines in cooperation with the Geological Survey as part of their search for additional sources of supply of strategic minerals authorized under the Strategic Materials Act. 3/4/The work accomplished by the Bureau, and the assays of samples taken are described in this manuscript. The ore found aided materially in prolonging the operating life of the mine during the recent national emergency, supplying much-needed tungsten for war use. ACKNOWLEDGMENTSIn its program of investigations of mineral deposits, the Bureau of Mines has as its primary objective the more efficient utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. The Mining Division, under the direction of Lowell B. Moon, chief, conducts preliminary examinations, performs the actual development work, and prepares the final report. The Metallurgical Division, under the direction of C. C. Ralston, chief, analyzes samples and performs beneficiatibn tests."

Mar 1, 1948

By D. Cummins

This Information Circular presents a brief history of the lead-acid battery and describes ways to prevent serious injury from battery explosions when servicing and charging lead-acid batteries, particularly in the surface mining industry. The Mining Safety and Health Administration (MSHA), U.S. Consumer Product Safety Commission, battery manufacturers, and the mining industry have all contributed information as well as recommendations for injury-free handling for this report.

Jan 1, 1980

By M. Hertzberg

This Bureau of Mines report proposes a new methodology for estimating industrial dust explosion hazards in terms of three probabilities or co-factors: The dispersion of the dust, the existence of a flammable dust concentration, and the presence of an effective source of ignition. This method or rationale is proposed as a replacement for the "explosibility index" that was first suggested 25 yr ago, but which, by consen-sus among leading researchers in the field, is now outdated. This report presents a detailed critique of the deficiencies of that old, material-oriented index, and develops the logical rationale for its re-placement by an approach that is better suited for quantitative hazard evaluations. A variety of such evaluations are illustrated, which show how a quantitative prediction of explosion frequencies can be obtained from laboratory measurements and operating conditions in a given indus-trial facility. The method has some pitfalls, particularly as they re-late to the correlation of events or their randomness. These are discussed, as well as the method's other limitations and uncertainties. This work is intended to provide a beginning to a quantitative approach to explosion hazard assessment. To that end, a new method is proposed for estimating thermal ignition probabilities in terms of the measured laboratory autoignition temperature of a dust, its relationship to the operating temperature, and its distribution within a given industrial system.

Jan 1, 1987

By J. M. Stuve

In this Bureau of Mines investigation, the low-temperature heat capacities of polycrystalline phases corresponding to the sulfide compounds CoSO?89' CoS1?33, and CoS2 were measured by adiabatic calorimetry within the nominal temperature range 5 to 300 K. The derived absolute entropies S298 were 10.36±O.02, 12.96±O.03, and 16.31±O.03 cal?mol-1?K-l, respectively, assuming third-law behavior. In addition, the standard enthalpy of formation 8Hf298 of CoSO?89 was determined by bromine solution calorimetry. The derived value of 8Hf298 was -50.63±2.1 kcal?mol-1, based on the 8Hf298 of Co0. This result is considerably more negative than previously published formation values based on high-temperature gas equilibrium studies.

Jan 1, 1985

By Farrel W. Lytle

An X-ray emission spectrographic method of analysis is presented for determining rare-earth elements in fractions obtained from bastnaesite ore. The method includes determination of yttrium, thorium, lanthanum, and the rare-earth elements in various complex mixtures. The analysis technique is based upon comparing the samples with synthetic standards approximating the composition of the samples. Working curves are plotted on an absolute-intensity basis, with no correction for back-ground. Examples of working curves and the analyses of typical rare-earth concentrates are included. The selection of spectral lines for the various sample matrices is discussed. A special technique is used for samples in which rapid hydration and carbonation occurred. By analyzing synthetic samples of known composition, the accuracy of the method was determined. The average error of analysis was about 3 percent of the amount present in the range from 5 to 100 percent and about 7 percent in the 0.2-to 5-percent range. A maximum of about 40 samples per day may be analyzed for 7 elements each.

Jan 1, 1957

By W. Hermanson

This report, which covers the period from January 16 to October 21, 1974, describes the work performed in compliance with the requirements of contract no. H0242028 and modifications 1 and 2 thereto. The purpose of the contract was to further reline and modify three of the canopies (shuttle car, loader, and roof drill) which were developed under contract no. H0220031, and to conduct further testing and demonstration of the relined designs. Modifications I and 2 involved conducting further in-mine evaluations of the face. drill and cutter canopies, also developed under contract no. H0220031. In addition to the canopy modifications, the contract involved an evaluation of an operator's seat concept for a shuttle car which was developed for the USBM by another contractor.

Jan 1, 1974

By Gustav Wade

"INTRODUCTION Analyses of samples of crude oil from several Texas oil fields have been published from time to time in Bureau of Mines reports, some of which are out of print, but many other analyses of Texas crude oils have not been published. The purpose of this paper is to make available in condensed tabular form under one cover all analyses of the Texas crude oils that have been examined by the Bureau of Mines.DIVISION OF TABLEThe table of analyses is divided into six parts in accordance with the geographic subdivisions of the State. (See fig. 1.) This grouping of the oils corresponds only in a general way with the principal formations in each area from which oil is being produced. In general, the principal oil-producing formations in the Texas Panhandle and West Texas areas are of Permian age; those of North Texas are of Pennsylvanian and older ages; those of the East Texas Basin and of Central Texas are of Cretaceous age; and those of the Texas Gulf Coast are of Eocene and younger ages.For convenience in presentation the name of the geologic age has been assigned to each group of the table although same of the oils included in the group may be of another age.Group 1 includes oils of Permian age produced in the Texas Panhandle area, which comprises the following counties: Dallam, Sherman, Hansford, Ochiltree, Lipscomb, Hartley, Moore, Hutchinson, Roberts, Hemphill, Oldham, Potter, Carson, Gray, Wheeler, Deaf Smith, Randall, Armstrong, Donley, Collingsworth, Parmer, Castro, Swisher, Briscoe, Ball, and Childress."

Dec 1, 1934

During the 20th century, the increased emphasis on worker health and safety and the advent of new mining equipment and methods led to many changes in mine face ventilation practices. Efforts by government and private industry to improve and modify ventilation practices resulted in better health and safety conditions for workers. This article focuses on U.S. Bureau of Mines (USBM) and National Institute for Occupational Safety and Health (NIOSH) research to examine factors that had a significant influence on mine face ventilation design during the past century. Several "milestone" events are discussed along with the impact they had on worker health and safety. Significant ventilation research efforts by government and private industry are presented. This brief ventilation history highlights innovative face ventilation designs and a consistent commitment to mining health and safety. Ventilation has always been a concern in underground coal mining. For many yeas, there was no appreciation of how ventilation could be used to remove harmful contaminants from the air or how to control airflow quantities. The first known problems with ventilation date back to the 14th century, when it was recognized that lack of air was a major impediment to the expansion of mines. The common method of solving ventilation problems at that time was to abandon the existing mine and start a new one nearby. Ventilation in the early days of coal mining was accomplished by means of a natural draft, created principally by a difference in the weights of columns of air between the intake and return openings. Later, in the 18th and 19th centuries, a furnace was introduced underground to increase the updraft in the return shaft. This allowed for a larger quantity of air in circulation. When mines went deeper and became larger, mechanical ventilation became necessary and was first accomplished by steam-driven fans. These fans became more prevalent as furnaces were prohibited in underground mines, especially after the Avondale disaster in Pennsylvania in 1869 (Roy, 1876). Eventually, these fans were replaced by more powerful, electrically [ ]

By J. Mutmansky, C. Lee

"The size distribution of coal mine dust is one of its most important characteristics because the particle size is known to govern the region of deposition of dust within the human respiratory tract. In addition, dust characteristics, particle settling rate, transportability of the dust and the efficiency of dust control measures are all affected by the particle size. As a result, particle size distribution of the airborne dust in a coal mine is a fundamental property that impacts on the health of underground workers.This paper deals with some basic findings on the size distribution of cool mine dust based upon the results of data collection in six underground coal mines using continuous miners. All airborne dust sampling was performed on development sections using eight stage cascade impactors and permissible 2. O l / min pumps. Samplers locations were fixed in the sections with respect to the continuous miner and roofbolter or with respect to the intake and return airways • Sampling times varied from 45 minutes to 6 hours , depending upon the dust concentration. The first topic of analysis was the test to determine whether the commonly used lognonnal distribution is valid when applied to airborne coal mine dust. Secondly, the conventional method of representing the· distribution using two parameters, the geometric mean and the geometric standard deviation, is questioned. Since almost all size data were found to show some degree of bimodality, the two parameter lognonnal distribution may not represent the total airborne coal mine dust size , quite adequately. Bimodal lognonnal distribution was tested to be a good approximation in the case with two modes in the size distribution.The final topic discussed in this paper is the 'locational variation of the airborne dust size distributions within the continuous mining section. The size distributions varied considerably at the different sampling locations with the continuous miner and roofbolter producing the coarser distributions. Fine size modes in the range of 2 to 4µ m including mostly respirable dust particles were present in almost all samples • Second dust generating sources such as the shuttle car movement were found to be major causes of high respirable dust concentrations in some cases ."

Jan 1, 1988

By Robert P. Vinson

This report describes three coal mine ventilation studies by the Bureau of Mines in which sulfur hexafluoride (SF6) was used as a tracer gas. One of these studies was conducted to determine air movement and leakage in a sealed area. Another was run to determine the ventilation efficiency of a bleeder system. Finally, a study was made of air leakage across permanent stoppings of parallel intake airways. These studies proved sulfur hexafluoride to be a useful addition to the equipment commonly used in coal mine ventilation analysis.

Jan 1, 1976