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By David J. Kusler

This report describes a primary or direct, continuously sampling, and automatically averaging gravimetric method for analyzing gaseous mixtures of carbon dioxide, carbon monoxide) hydrogen, and (by volume measurement) nitrogen. The gaseous mixture is analyzed by passing it at a controlled and definite rate through a system that permits carbon dioxide and water retained by appropriate absorbents to be determined and the residual-gas volume (essentially nitrogen) to be measured. The accuracy and dependability have been established by comparison with very carefully conducted Orsat analyses. The method was developed for, and has been satisfactorily applied to, the analysis of blast-furnace top gas. It permits relatively attention free operation, using simple and low-cost materials usually found as basic equipment in the analytical laboratory. It provides, over a wide range of time or sampling intervals (from less than 1 to over 24 hours), the average composition, in terms of volume-percent, for those components usually determined in blast-furnace gas, if (as is usual) the flow rate of gas from the blast furnace is essentially constant over a selected analysis interval. Oxygen and methane are not determined; but, since these gases are normally absent or present only in traces, their analysis is seldom required.

Jan 1, 1959

By C. Golumbic

Most early research on solvent extraction of coal has been concerned with the molecular structure of coal. Although rush work is continuing, practical aspects of the subject also are being emphasized. For example, development of the Pott-Broche extraction process resulted from the discovery of very efficient solvents for the pressure-extraction of coal. Recently, Orchin and Storch reported the use of even more efficient solvents under similar conditions. In addition to the discovery of more effective solvents, the possibility of efficient extraction at atmospheric pressure is obviously of practical interest. H. J. Rose observed that phenanthrene at its atmospheric boiling point readily dispersed 80 percent or more of Pittsburgh-bed bituminous coal. This fact served as the starting point of the present investigation, ill which determination of the chemical specificity of this solvent and the chemical nature of the resulting extracts was undertaken. This paper represents a progress report of the results obtained to date.

Jan 1, 1950

By F. D. Everett

The exploration work on a seleniferous tuff deposit near Lysite, Wyo., was confined chiefly to an area of approximately 1 square mile selected on the basis of prior examination and sampling work by the Bureau of Mines. This area was superficially explored by digging and sampling over 2,000 feet of trenches and 15 test pits. The surface sampling indicated that the deposit might contain a multimillion-ton reserve of easy-to-mine volcanic tuff assaying more than 0.01 percent Se. Later, 11 holes, ranging in depth from 57 to 135 feet and totaling 929.4 feet, were drilled under contract using a dry rotary drill. Samples for assay were cut at 5-foot intervals or at noticeable physical changes in the formation being drilled. Of the 206 samples assayed from the drilling, only 8 contained more than 0.005 percent selenium, and 2 of these assayed as high as 0.012 percent Se. Chemical analyses of samples obtained from six holes drilled by the Nugget Coal & Timber Co. to the south of the area explored by the Bureau of Mines showed that no selenium-bearing formations were encountered in that work. Two of 72 samples taken from 42 validation pits dug by claim holders contained more than 0.005 percent selenium. The exploratory work established that the selenium mineralization is erratically distributed in small irregular bodies and is not confined to any one tuff bed. Because of the lack of correlation between the infrequent showing of low-grade tuff, neither the extent nor grade of the reserves could be calculated.

Jan 1, 1957

By R. V. Ramani

In this report, the application of the Open Pit Materials Handling Simulator (OPMHS) to a mine located in Illinois using bucket wheel excavator (BWE) and a stripping shovel in tandem for overburden removal is described. The specific objective of the study is to demonstrate the application of the simulator to analyze mine planning and scheduling problems and to generate and analyze alternatives for increased production. On the basis of the simulations it was concluded that the maximum productive capacity of the system in raw coal was around 3000 tons per shift. At this production level, the equipment combination and availability also satisfy the match requirements for the stripping shovel and the BWE, and the overburden and coal removal systems. Several alternatives requiring new equipment are proposed and analyzed for increasing production. However, no economic analyses of these proposals were done.

Jan 1, 1977

By Milton B. Hall

This report discusses in detail laboratory and pilot-plant tests conducted from January 1951 until January 1955 at the Northwest Electrodevelopment Experiment Station of the Bureau of Mines, Albany, Oreg., on defluorination and recovery of evolved fluorine from phosphate rock. Results of use tests of defluorinated phosphate rock by cooperating agricultural colleges and the United States Department of Agriculture are also included. In 1954 the consumption of fluorspar, the only domestic fluorine-bearing mineral of commercial importance, was approximately 478,000 short tons; 245,000 tons was from domestic mines. The production of marketable phosphate rock in the same period was about 13,800,000 long tons. Of this total amount, approximately 15 percent was produced in the West. From the viewpoint of conservation and utilization of fluorine as a natural resource, it is interesting to note that the total estimated quantity of fluorine in domestically produced phosphate rock is more than double that present in domestically mined fluorspar.

Jan 1, 1958

By Jaffrey Y. Foley

Placer gold and platinum-group metals (PGM) In the Slate Creek area, northern Chistochina Mining District, are derived from silicified and carbonate-altered, Cretaceous-Tertiary (?) dikes and related mafic and ultramafic rocks. Gold In the placer deposits is also derived from Tertiary conglomerate and altered Jurassic-Cretaceous argilllte. The argilllte and Igneous bedrock sources show a unique Ag-Au-Cu-Hg-PGM association that Is attributed to a combination of magmatic, hydrothermal, and supergene processes. The bedrock and placer deposits contain a variety of gold silver-lead-copper and PGM alloys. The observed geochemical, mineralogic, and alteration features are consistent with current geological models for turbidite-hosted gold deposits. No economic gold or PGM lodes were Identified, but several areas warranting more detailed investigation were Identified. Conventional geochemical sampling and analysis of small sample splits weighing between 10 and 30 grams were shown to be unreliable as a consistent means of identifying gold- and PGM-bearing bedrock. Pan concentration of pulverized rock samples was shown to be a more effective, but still Imperfect means of Identifying gold and PGM source rocks. Geochemical data and mineralogic examination indicate that gold and PGM in potential lode sources are very finely and erratically disseminated, are chemically combined with other elements, and may not be entirely free-milling or amenable to simple gravity concentration.

Jan 1, 1990

By G. W. Jones

[As a part of its investigations pertaining to the promotion of safety, the Bureau of Mines is investigating various means, useful for the elimination or mitigation of the explosion hazards of combustible gases encountered in mining and industry. Information has been obtained and a procedure developed whereby the explosibility of many complex, gaseous, combustible atmosphere may be calculated in a simple manner without the necessity of performing laborious laboratory experiment. In a previous publication4/ data were given and a method described whereby the limits of inflammability of gaseous mixtures, including methane, hydrogen, carbon monoxide, nitrogen, carbon dioxide, and oxygen, could be determined by calculation. The information published in that retort enables one to calculate the limits of inflammability of such gases are liberated by mine fires, gases from explosives, automobile exhaust gas, gases present after mine explosions, blast-furnace gas, and other gases containing part of or all of the above-listed constituents.]

Jan 1, 1938

By Byron A. Baker

The Bureau of Mines used a windowed cell to measure the phase-boundary pressures of two related series of gas-condensate fluid mixtures. Normal butane was added to the mixtures incrementally to determine its effectiveness for lowering phase-boundary pressure. All the experimental data were correlated, so that the pressure required to maintain light oils mixed with natural gas in the single phase may be computed for secondary recovery applications. The heavy hydrocarbon parts of the mixtures were distillation fractions of a Gulf Coast condensate. Intermediate normal hydrocarbons in the butane-heptane range and natural gas were added to the fractions in selected proportions, so that phase-diagram pressures of 26 fluids were actually studied. The experimental range of temperatures was 50° to 280° F. Two correlations were developed to represent phase-boundary pressures by means of a polynomial. Independent variables represent natural gas content, disparity of properties of components comprising the mixtures, and temperature. A fourth variable, for one correlation only, was the quantity of normal butane added to the original mixtures. The latter correlation with four independent variables contains 15 coefficients and is estimated to be accurate to 135 psi.

Jan 1, 1973

By H. M. Cooper

The determination of moisture in coal is an empirical test, because the time, temperature, and equipment are specified. The essential features of the equipment and details of the procedure are given in A.S.T.M. Designation: D271-44.:2. According to the specifications, the following features should be incorporated in the equipment used: 1. Oven must have uniform temperature in all parts. 2. Oven must be constructed with minimum of air space. 3. Oven must have means of changing the air two to four times per minute. 4. Air must be dried over sulfuric acid (sp. f-7. 1.84). The analytical procedures governing most of the nation's coal purchases are those given in A.S.T.M. Standards referred to above. These standards are general arid of such scope as to cover all ranks and types of coal. In cases where only the moisture is required, a faster method than the standard procedure is desired.

Jan 1, 1948

By G. W. Jones

As a part of it investigations pertaining to the promotion of safety, the Bureau of Mines is investigating various means, useful for the elimination or mitigation of the explosion hazards of combustible gases encountered in mining and industry. Information has been obtained and a procedure developed whereby the explocibility of many complex, gaseous, combustible atmospheres may be calculated in a simple manner without the necessity of performing laborious laboratory experiments. In a previous publication4/ data were given and a method described whereby the limits of inflammability of gaseous mixtures, including methane, hydrogen, carbon monoxide, nitrogen, carbon dioxide, and oxygen, could be determined by calculation. The information published in that report enables one to calculate the limits of inflammability of such gases as are liberated by mine fires, gases from explosives, automobile exhaust ran, uses present after mine explosions, blast-furnace gas, and other gases containing part of or all of the above-listed constituents.

Jan 1, 1938

By Clarence O. Babcock

This Bureau of Mines publication presents guidelines for mining near surface and underground bodies of water. The guidelines were based on information developed under contract in three phases of study, as follows: (1) Collection and documentation of data from worldwide sources; (2) application of existing guidelines, foreign, Federal, and State, to case histories of previous inundations; and (3) development of recommended guidelines for underground coal mining near bodies of water aimed at maximum efficient utilization of underground coal resources consistent with minimizing inundation hazards. While the contract guidelines were for the mining of coal seams, they may also be used for mining any tabular sedimentary mineral deposit. Tables are given for the determination of the size of coal pillars needed; for other bedded deposits, similar tables could be determined based on their strength properties.

Jan 1, 1977

By L. C. IlsLey

"Nearly every piece of electrical equipment used in mines ""breathes."" In other words, motors, controllers, rheostats, switches, and other similar equipment, even though encased in seemingly tight compartments, breathe in the atmosphere that surrounds them.As the apparatus is used, the temperature of metallic parts is changed generally in positive direction through the heat by friction and the heat due to the electric current. When the apparatus is idle it gradually cools down to the temperature of the surrounding atmosphere.This increase of temperature during operation and return to normal temperature when operation stops alternately raises and lowers the temperature of the atmosphere within the compartments which, in strict accordance with Charles' law -will expand or contract in proportion to any given temperature change.As compartments are not gas-tight, such expansion and contraction will force the atmosphere out of the compartment =on expansion and suck the surround¬ing atmosphere into the compartment during contraction, hence the term ""breathing.""Investigators2 of explosion-proof equipment have recognized that such an interchange would take place and have designed their equipment to safeguard possible explosions within the compartments."

Jun 1, 1927

By James C. Barker

Alluvial cassiterite concentrations are widespread in river gravel and high level terraces within the Ray River watershed. The area lies in unglaciated terrain of Alaska's northern interior. Cassiterite originates from several calc-alkaline plutons of the Ruby batholith. Extensional stresses resulted in graben-like Tertiary basins that were flooded by a 200 ft thick section of mid-to late- Tertiary basalt flows. Basalt blocked local drainages, and 50- to 100-ft of terrace gravel was eventually deposited on top of the flows. Further downwarping and eventual fluvial downcutting of the flows resulted in cycles of accelerated sediment transport, deposition, and reconcentration. Repeated erosional cycles concentrated heavy minerals and resulted in development of tin placers. Preliminary resource estimates of contained tin in Recent alluvium range from 62 to as much as 172 million lbs-Sn in 300 million yd3. Grade of about 90% of the gravels is estimated to range between 0.2- to 0.5- lbs-Sn/yd3. Associated gold and rare earth elements (REE) in monazite and xenotime may be recoverable. Most of the tin is considered a subeconomic inferred resource, though, at least some of the gravels contain 2-to 6-lbs-sn/yd3. Estimates are projected on the basis of surface sampling and several auger drill holes and are provided for the purpose of land-use management planning.

Jan 1, 2011

By R. T. Johansen, R. J. Heemstra

In water flooding the gradual accumulation of insoluble materials on the sand face causes the injection pressures to increase while decreasing the amount of water injected . This plugging material often is composed primarily of insoluble precipitates of calcium , iron , and magnesium . Treatment with sodium tripolyphosphate ( STP ) either eliminates or reduces the formation of precipitates . Field tests are discussed showing the almost immediate effects of using STP in the injection water . Methods of treatment , solubility of STP in fresh water and brines , and precautions to observe when starting to treat a waterflood with this chemical are given . Laboratory data show that the preferential wettability of a crude oil for reservoir rock can be reversed by adding a small amount of STP to the flooding water . This reversal in wetting tendency should not only decrease the injection pressures but also increase oil recovery by improving the sweep efficiency of a water flood .

Jan 1, 1964

By Eric R. Bauer

This Bureau of Mines publication describes and illustrates the physical signs of excessive loading on mine roof supports, installations, and openings. It is designed to assist mine personnel in recognizing potentially hazardous ground conditions, by emphasizing the preliminary effects of developing unstable ground. Increased worker awareness can be expected to reduce the injuries and fatalities resulting from falls of roof, rib, and face.

Jan 1, 1985

By J. R. White, S. W. Lambert, C. M. McCulloch

Examination of several coalbeds in Walker County, Ala., Cambria, Greene, and Fayette Counties, Pa., and Raleigh and Wyoming Counties, W. Va., indicates that cleat orientations are similar throughout a vertical sequence of strata. Studies of cleat orientation were carried out in underground mines that are operating in separate coalbeds vertically above one another. The data show that over a vertical separation of 100 to 400 feet, the average difference in coal cleat orientation between mines is 04° for the face and 08" for the butt cleat. Variations of coal cleat direction between coalbeds examined in strip-mined areas show similar values. Cleat orientations measured at outcrops agree well with the directions measured underground, suggesting that the amount of vertical separation between coalbeds has little effect on the resulting differences in cleat directions. The largest variation of cleat directions between adjacent coalbeds occurs where a large horizontal distance separates two sample locations. Cleat orientations for deeper coalbeds are most reliable where the data are taken from directly above.

Jan 1, 1976

By H. G. Iverson

Solid state reactions of manganese with silica were investigated in high-temperature tests. Reactions of 0.5 to 4.0 moles manganese (Mn) with 1 mole silica (SiO2) at 1,100° C and of 2.0 Mn:SiO2 mole-ratio mixtures at 1,000° to 1,150° C yielded products consisting of a slag phase and a metallic phase. At 1,100° C, the slag phase from reactions of the low Mn:SiO2 mole-ratio mixtures was composed of SiO2 and rhodonite (MnSiO3), and the slag phase from the high Mn:SiO2 mixtures was composed of MnSiOs and tephroite (Mn2SiO4). The metallic phase from the corresponding low Mn:SiO2 mole-ratio reactants consisted of two manganese silicides, Mn5Si3 and Mn3Si; from the high Mn:SiOg mixtures, it was Mn and the manganese silicide (Mn5Si). For the higher mole ratios of MnSiO2 the manganese content in the metallic phase increased, while the manganese and silica contents of the slag phase remained nearly constant. The slags did not contain free or uncombined manganese oxide (MuO). For the 2.5 to 4.0 Mn:SiO2 mole-ratio mixtures reacted at 1,100° C, the maximum quantities of silica reduced and of the manganese in the slag appeared to become asymptotical at about 41 and 48 percent, respectively. A brominating procedure was developed that was highly selective in removing the metallic constituents from the reaction product, leaving the slag phase as residue. X-ray diffraction patterns were obtained on prepared silicides Mn5Si, Mn3Si, and MnSi.

Jan 1, 1967

By Steven J. Page

Accurate measurement of workplace respirable dust concentration is an essential step in eliminating lung disease in any occupational setting. In the United States (U.S.) coal mining industry, this measurement process has relied upon a personal sampler that includes a 10 mm Dorr-Oliver (DO) nylon cyclone operated at a flow rate of 2.0 L min-1 to collect a respirable dust sample. Dust concentrations measured with this sampler are multiplied by 1.38, which was empirically derived, to convert them to measurements approximating the United Kingdom British Medical Research Council (BMRC) definition of respirable dust upon which the health effects of coal mine dust are based. The International Organization for Standardization (ISO) subsequently refined the respirable dust definition and the U.S. National Institute for Occupational Safety and Health (NIOSH) 1995 Criteria for a Recommended Standard presented a conversion multiplier of 0.857 to apply to the 2.0 L min-' DO (in addition to thel.38 multiplier) to obtain equivalent ISO concentrations, as approximated by the 1.7 L min-1 DO. However, the conversion multiplier 0.857 was derived indirectly from a limited size distribution data set rather than a direct comparison of the DO samplers. The present analysis focuses on providing a more accurate conversion multiplier derived from direct comparisons of the 2.0 L min-1 (with 1.38 BMRC equivalency multiplier) and 1.7 L min-1 DO cyclones. A weighted linear regression analysis of this database suggests that a more accurate estimate of the conversion multiplier is 0.815.

Jan 1, 2009

By R. L. Crosby

A part of the liquidus of the magnesium-zirconium system was determined by chemical analysis of suction samples taken from the melt in the approximate temperature range of 850° to 1,450° C. The melt was prepared in a furnace pressurized with an inert gas. The average zirconium value in weight-percent of the liquidus composition at each sampling temperature was 0.96 at 867° C, 1.40 at 1,062° C, 2.05 at 1,262° C, and 2.96 at 1,402° C. The equilibrium solid phase was zirconium.

Jan 1, 1965

By Doris M. Hyde

The impact of mining activities on the economy in both 1983 and 1984 was minimal. The most recent available data on the gross domestic product (GDP) indicated a level of $1.6 billion in 1983.2 The estimated value for the production of cement, aragonite, and salt was about $17 million in that year, down from the estimated $20 million in 1982. No data are available on the economic impact of the large petroleum refinery at Freeport on Grand Bahama Island, but it represents the major mineral-related activity. Cement production remained at only a fraction of the 800,000 tons per year of plant capacity. The offshore search for hydrocarbons continued in 1984, and some companies were about to enter the third year of seismic and geological surveying around Andros and Grand Bahamas Islands. Getty Oil (Bahamas) Co. Inc.; Breoco Ltd., a subsidiary of REO Development Corp. of Tulsa, Oklahoma; and Natomas Petroleum (Bahamas) Ltd. were the first companies to be awarded exploration licenses. These companies were committed to drilling at least one well before the end of the third exploration year. Other companies actively engaged in exploration included Exxon Corp., Atlantic Richfield Co. (ARCO), Chevron Oil Bahamas Ltd., and Esso Oil Bahamas Ltd. Geophysical Services Inc. (GSI) of Dallas, Texas, and Petroleum Services (Bahamas) Ltd. of Englewood, Colorado, ran another seismic survey line during 1984. This 1,533-mile line was in the Great Bahama Bank and Cay Sal Bank areas off the southeast Florida coast, and tied in with a 4,530-mile program GSI ran in 1981-82. These surveys were nonexclusive and publicly available through GSI.

Jan 1, 1986