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By Robert M. Becker

The evaluation of existing rock stresses from measurements of the change in diameter of a borehole that is stress relieved by overcoring has become a common practice, The stress evaluation has been generally based ,on isotropic relations whereas rock in varying degrees is anisotropic. A plane elasticity solution for a circular hole along one axis of an orthotropic medium is adapted for evaluation of in situ stress from borehole deformation measurements. A consistent triaxial testing approach for determining elastic properties of the overcore is also outlined. Comparison of isotropic with anisotropic interpretations of the state of stress show that large errors in evaluation may occur if the anisotropic character of the rock is neglected.

Jan 1, 1967

By Spencee L. Willett

In 1984, at the request of the Bureau of Land Management, the U.S. Bureau of Mines conducted mineral surveys of the 20,508-acre Blue Lakes (NV-020-600) and 5,142-acre Alder Creek (NV-020-600D) Wilderness Study Areas (WSAs) in northwestern Humboldt County, Nevada. The WSAs are part of an upthrown, north-south trending fault block associated with the Basin and Range province. Both areas are predominantly underlain by the Cretaceous Duffer Peak pluton which intrudes Triassic metasediments and Jurassic plutonic rocks to the east and Permian Happy Creek volcanics to the south. In the Alder Creek WSA and in the southwest portion of the Blue Lakes WSA, Duffer Peak granodiorite and Happy Creek volcanics are overlain by Tertiary basalt. No active mines exist within the Blue Lakes WSA; but, several prospects, claims, and mineralized outcrops are in the south and northeast portions. No mineral resources were identified but samples from discontinuous, vein-type deposits contained anomalous amounts of gold, silver, copper, lead, zinc, molybdenum, antimony, and uranium. Very fine, residual gold was detected in nine alluvial samples collected from a small deposit in the southwest corner of the WSA; average gold value was $3.58 per cubic yard (at $350/ounce). Two mines, several prospects, and mineralized outcrops adjacent to the Blue Lakes WSA contain mineralized, irregular structures which do not appear to extend into the Blue Lakes study area.

Jan 1, 1986

By George H. Holmes

This report describes the results of a reconnaissance survey of areas in California and Nevada considered favorable to beryllium mineralization. Pegmatite dikes, veins, intrusive sills, contact. metamorphic, and disseminated deposits as well as tactite deposits in the former major tungsten-producing districts were investigated. A general geographic pattern of beryllium mineralization was found to be concentrated along a wide belt in eastern Nevada extending from the Ruby Mountains, Elko County, south through the Fish Creek Range, Eureka County, the Snake Range, White Pine County to the Virgin Mountains in Clark County, Nev., and Mohave County, Ariz. Sporadic occurrences of beryllium are in central and southern Nevada, and in the pegmatite dikes of San Bernardino, Riverside, and San Diego Counties, Calif., and the granite masses of the southern Inyo Mountains, Inyo County, Calif. Principal company activities are centered in the Snake Range, Fish Creek Range, and the Virgin Mountains, Nev., and the Inyo Mountains, Calif. Other areas in California and Nevada have been superficially explored with results indicating either limited or widespread, but submarginal, mineralization. Although beryllium was found to occur, to some extent, in many of the deposits, mining has been hindered by the lack of a market for beryllium ores and concentrates other than standard-grade beryl and also by the erratic pattern of mineralization and the high exploration and beneficiation costs required to produce a marketable product.

Jan 1, 1963

By N. S. Dalal, X. Shi

"This study reports a new property of the important NAD(P)H-dependent flavoenzymes, glutathione reductase, lipoyl dehydrogenase and ferredoxin- NADP oxidoreductase, that can catalyze a one electron reduction of metal ions such as chromium(VI) and vanadium(V). During the enzymatic reduction process, molecular oxygen is reduced to H2O 2 , which reacts with the reduced metal complexes to generate hydroxyl radicals. Since the hydroxyl radicals have been suggested to play an important role in Cr(VI) toxicity, this study provides a basis for a recent observation that Cr(VI) mutagenesis is strongly oxygen dependent. These results also point to an enzymatic pathway for the metabolism of some metal ions and concomitant generation of hydroxyl radicals. l. INTRODUCTIONThe purpose of this communication is to report that some important NAD(P)H-dependent flavoenzymes (glutathione reductase, lipoyl dehydrogenase and ferredoxin-NADP+ oxidoreductase) can catalyze one electron reduction of metal ions such as chromium(VI) and vanadium(V) and simultaneously reduce molecular oxygen to generate Hi02 and, eventually, the ""OH radical. This finding is significant because (i) the known substrates for the flavoenzymes are organic species and not metal ions, and (ii) the report on the enzymatic formation of the ""OH radical provides a new pathway for understanding the mechanism of genotoxicity of some non-ferrous metal ions. For example, it has been suggested that OH radical is likely to be the major species responsible for Cr(VI) genotoxicity [1-5). The 'OH radical is generated through the reaction of Cr(V) complexes with cellular Hi02 [4,5]. Cr(V) itself is known to be generated from Cr(VI) in various biological systems, in particular, microsomes [ 6), mitochondria [7] and mitochondrial electron transfer chain complexes [8]. However, no specific enzyme responsible for the Cr(V) generation has been identified except possibly glutathione reductase [4]. In this study we have used ESR and spin trapping techniques to show that the flavoenzymes can generate Cr(V) and provide a catalytic redox cycle for 'OH formation in such reactions. Herein we present our results on Cr(VI) and summarize those on other systems. Correspondence address: N.S."

Jan 1, 1990

By Lon D. Santis

The Code of Federal Regulations Title 30, Parts 56, 57, 75, and 77 require that detonators and explosives be separated by four inches of hardwood or equivalents when transported together in mines. This standard was developed to protect the explosives from initiation by the more sensitive detonators. The research reported here is an attempt to quantify the fire protection offered by four inches of red oak and other materials. Boxes with a volume of 6.75 cubic feet were made from four-inch thick rough green oak (RGO), two-inch thick RGO plied, two-inch thick #1 common (dried) red oak plied, and a metal/plywood composite. These and boxes meeting the Institute of Makers of Explosives' (IME) Safety Library Publication No. 22 were tested in bonfires. The boxes were instrumented with thermocouples, filled with detonators, and placed over a kerosene fire imparting about 16 kilowatts per square meter heat flux for up to 3 hours. Tests showed that the wood boxes protected the detonators for over an hour with variations between the different trials. In the IME 22 container tests, detonators began exploding in as little as 17 minutes in one test and not for 2-/12 hours in another test. Detonators in the metal/plywood boxes began to explode in about 15 minutes but with minor alterations, were able to contain the detonators. The test results show that the exterior of an IME 22 container significantly affects its thermal properties. Defects in the form of cracks and the manner in which the container is closed have a significant effect on the performance of a detonator container in a fire.

By Bruce Cantrell, K. L. Rubow

"INTRODOCTIONMeasurement of the contribution of diesel exhaust to respirable aerosol in mine environments has become increasingly important because of current concerns over the occupational health effects resulting from exposure to diesel emissions. In response to this, the U.S. Bureau of Mines is developing and evaluating new sampling methods for measuring diesel aerosol in underground mines. Two such techniques are being studied by the Bureau, size selective sampling and Chemical Mass Balance (CMB) modeling. These techniques use measurable physical or chemical characteristics of a mine aerosol sample to infer the amount of diesel particulate material contained in the sample.Size selective sampling is being adapted for measurement of diesel aerosol by the Particle Technology Laboratory (PTL) of the University of Minnesota under sponsorship by the Bureau. 1 It is based on the premise that diesel and mineral dust aerosol can be physically separated by size and collected during sampling using inertial impaction. An independent effort by the National Institute for Occupational Safety and Health to develop a size selective sampling technique was also sponsored by the Bureau.The second technique, CMB modeling, is being developed by the Bureau as an alternative measurement technique to referee the results obtained using size selective sampling.3 It compares measured trace element ""finger prints"" of aerosol sources with similar profiles of mine aerosol samples. From these, the portions of the sample contributed by each source can be determined. Results of these investigations in underground coal mines have confirmed that diesel and coal dust aerosol are of different size and can be measured separately using size selective sampling techniques.A major difference in diesel usage among underground mines is the requirement for exhaust gas cooling systems in coal and gassy noncoal mines. Nongassy mines usually employ limited exhaust conditioning in the form of catalytic converters, which have limited effect on primary exhaust particulate. The cooling system in most general use in gassy mines is the water scrubber. This device has little effect on most of the gases but removes particulate material from the exhaust. 5 Because of this, exhaust aerosol characteristics in nongassy mines are expected to be different. To see if size selective sampling techniques can be used in such mines, the Bureau and the University of Minnesota conducted a second study in three metal and nonmetal mines, two nongassy and one rated as gassy."

Jan 1, 1990

By C. J. Thompson

Two sulfur compounds--the 2,2,5-trimethyl- and the 2,2,5,5-tetramethyl derivatives of thiacyclopentane--were identified in Wilmington, Calif., crude oil, using microdesulfurization and gas-liquid chromtography techniques.

Jan 1, 1963

By Yael Miron

ANFO blasting agents may undergo an exothermic reaction when they contact warm ore bodies that contain pyrite and its weathering products. The reaction is very fast at temperatures above 80° C. Urea, when present in sufficient amounts, inhibits this reaction at temperatures below 180° C. But urea-ammonium nitrate mixtures are very hygroscopic and, in certain climates, may be difficult to handle in the field. Reaction-inhibiting characteristics of three compounds were reported by the Bureau of Mines in 1979. Recently, the Bureau investigated the reaction-inhibiting qualities of five additional compounds. Mixtures of ANFO, pyrite, weathering product, and prospective inhibitors were slowly heated, under conditions simulating a hot borehole, to determine prospective inhibitor capability at temperatures up to ~175° C. Small-scale thermal tests of the same mixtures were used for verification and clarification of results. Two organic compounds, phthalimide and xanthine, similar in structure to urea, failed to inhibit the reaction. Zinc oxide and calcium carbonate were found inferior to urea, though zinc oxide raised the onset of reaction from 80° C to about 140° C. Only magnesium oxide was found to be similar to urea in its inhibitory ability at temperatures below 175° C. Based on results from analysis of quenched residues, the use of more than 5 wt-pct magnesium oxide is recommended.

Jan 1, 1982

By Fei Chen, Lesley J. Gaydos, Laurence M. Demers, Douglas C. Kuhn

The fibrogenic effects of silica in experimental animals and humans has been extensively studied (I 7, 20). However, the pathogenesis and molecular mechanisms underlying lung injury and fibrosis resulting from silica exposure remain to be elucidated. It is well-documented that silica can stimulate monocyte-macrophage lineage cells to produce cytokines and growth factors, including interleukin-I (IL- I) (20), tumor necrosis factor-ex (TNF-cx) (I 7), insulin-like growth factor-I (IGF-1) (4), and transforming growth factor-P (TGF-P) (24). Consequently, it has been suggested that the fibrogenic effect of silica may be mediated by cytokines in the fater stages of silicosis. During the early phase of interaction between silica and the pulmonary alveolar macrophage, several direct and indirect lines of evidence suggest that reactive oxygen intermediates (ROI) may play a pivotal role in silica- induced tissue damage (2I, 22). One of the most important components of and contributors to ROI is nitric oxide (NO) produced from L-arginine and molecular oxygen under the catalytic influence of NO synthase (NOS) (I 9). At present, at least three NOS genes have been cloned: a constitutive neuron NOS, a constitutive endothelial cell NOS and an inducible NOS (iNOS) (16). A number of factors have been shown to differentially induce iNOS gene expression in different cell lines including bacterial cell products and foreign antigens. During inflammation, NO is a double-edged sword in terms of the host immune defense mechanisms and the physiologic response to an inflammatory insult. The macrophage is one of the major cellular sources of NO. During the early phase of acute inflammation, NO produced from the macrophage appears to facilitate the clearance of pathogens and promotes a local relaxation effect on the microcirculation of vascular smooth muscle. When the production of NO is left unattenuated, especially under oxidative stress, direct cytotoxic effects of NO can emerge through the formation of peroxynitrite as a result of a reaction between NO and superoxide (2).

Jan 1, 1998

By Peter G. Kovalchik

To compare the viability of the new fuse wire arc test (FWAT) as a substitute for the comparative tracking index (CTI) for determining surface resistance to electrical tracking, the Bureau of Mines constructed a fuse wire arc tester and undertook a detailed testing program for testing insulating materials used on explosion-proof enclosures. This report describes the Bureau's apparatus, the two methods (CTI and FWAT), and the results of the Bureau's testing, showing comparisons of the FWAT with the CTI. Results showed strong correlation between the two methods, as all specimens tested that had CTI ratings of 400 V ac rms and above passed the 10-test sequence with the FWAT, whereas all specimens with lower CTI ratings failed, with the number of tests to failure corresponding roughly to the descending CTI rating order.

Jan 1, 1987

By L. D. Tracy

For many yeirs natural gas has been the principal fuel used in the he·1 ting furnaces in those mills located in the. Pi t-c;s. b.urgh district· \7hich manufacture bolts ., nuts, rivets, pick$, mattocks and srr.&11 for6ine;s. For a nUI.1"'.::>er of years the steady supply of this fuel has been more or less interrupted owing to the increased4and f·or d9mes tic use and to the increasing difficulty in securing an ad.eq_ua te c.1mount of natural gas. This condition has led a number of the steel compa.nies to substitute -oulvsrized coal a.s a fuel for the.furnaces. Elaborate irista.llations have been made for pulverizing tne coal ar!d _ coriveyi16 i -c to the fur:waces. • Soon after the furnaces ·-:commenced .. to operate ·,Vi th :pulverized coal, large quanti ties O::f.' fine dust beg.::in to accumulate on the platforms over the fu:rna. ces, the. roof trusses, on the outside of the va.rious· pip·e ·line electric cables a.i.1.d even on the roofs of the buildings. Some of tha comi:,a.n:;.0s, becomin·g alarmed, requested the Bureau of ;Unes to rr.c1ke an investigation to ascertcliin the.· licibili ty of this dust to cause an explosion.· Nhi le conducting this inves ti ga ti on,· an explosion· occurr-2! d in a.nothe:2 nill ·,7hich caused he death of one man and severely burned t;io others. Eleven sc1nrcles of the dust (which for convenience has been termed "mill d.ust 11 ) from various locations in the different mill' buildings were taken and submitted to chemical analyses, microscopic examination and also to flame and explosion tests. From the chu,1ica.l analyses it was found that· the volatile matter in th..:: dusts xanged -from 6.3 per cent to 23,54 per cent, fixed carbon from 50.88 per cent to 67.08 per cent and ash from 32.29 per cent to 32.16 per centw

Dec 1, 1919

By H. W. Davis, W. W. Adams, O. E. Kiessling

"Current economic problems frequently have focused attention upon the lack of adequate quantitative information indicating the relationship between human effort and output in various branches of the mineral industry. With the exception of complete records covering coal mining, only scattered information on the units of human energy required to produce a unit of raw material is available for most of the important industrial minerals. Fortunately a virtually complete statistical record is available covering this phase of the iron-ore mining industry.For many years iron-ore mining companies, whose interest in safety work is well-known, have reported annual data on employment to be used in the compilation of accident statistics. These data on hours of labor and other detailed employment information have been correlated with the statistics on production also reported annually by producers. The outstanding trends shown by this composite record for the 10-year period 1923-32 are included in the following discussion, supplemented by a summary table that presents the principal statistical background of the study. 5The substantial reduction in the number of men needed to produce the annual iron-ore requirements of the United States, as shown strikingly in the graphs, illustrates that in iron-ore production improvements in technology have been consistently winning a battle over the difficulties of nature. In 1923, for example, 41,294 men working 107,551,244 hours were required to produce 69,351,442 gross tons of merchantable ore, equivalent to an average output of 0.645 ton per man-hour. In 1929, however, only 30,763 men working 77,111,686 hours 'zero required to produce 73,027,720 tons of merchantable ore, equivalent to an average output of 0.947 ton per man-hour. Thus, from 1923 to 1929 the average number of men working decreased 25.5 percent and the total man-hours worked 28.3 percent, while the average output per man-hour increased 46.8 percent and total merchantable ore production 5.3 percent."

Feb 1, 1935

1. In 2003, a total of 7,070 sand and gravel mining operations reported employment to the Mine Safety and Health Administration (MSHA). The largest percentage of all mining sectors was sand and gravel mines (49.1%). • Sand and gravel mines are found throughout all 50 states.

Feb 1, 2005

By K. E. Stanfield

The oil yields of sections of Green River oil shale in Colorado, Utah, and Wyoming are presented as part of a continuing project to determine oil-shale reserves in the United States. Oil-yield logs, based upon analyses obtained from 1945 through 1952, are presented to show the thickness and richness of 202 sections of Green River oil shale. The logs are based on analyses of approximately 20,500 samples, representing 179,000 feet of shale, which were made by the Bureau of Mines, and upon analyses, representing approximately 26,000 feet of shale, which were made by other agencies. The samples consisted of cores from a Bureau of Mines coring program in U. S. Naval Oil-Shale Reserve 1, Garfield County, Colo., and cores, drill cuttings, and channel samples provided by other agencies, chiefly oil companies. Most of the samples of oil shale from Utah and Wyoming were derived from oil-well drilling operations. As a result, the oil-shale sections were widely scattered and were not extensive or reliable enough to be representative of the significant deposits of Green River oil shale in these States. The oil-shale sections for Colorado, however, were more comprehensive, and a number of the sections were used in a previous report as a basis for estimating oil-shale reserves in Colorado. The present report does not give estimates of oil-shale reserves but is limited to presentation of oil-shale analyses that may be used for future reserve estimates. Other sections of Green River oil shale are being analyzed, and the results will be published in subsequent reports.

Jan 1, 1954

By Robert W. Freedman

In the Bureau of Mines study, a filter with a 20-by 20-inch-square cross section was inserted into the exhaust ducting of a 4-stroke-cycle, 90-hp diesel engine, and the efficiency of removal of total particulate was measured gravimetrically as a function of time. Removal efficiencies were close to 90 pct during the main portion of several extended runs employing several combinations of filter beds. Variations in engine load had little effect on collection efficiency. Particle size as measured by a Bureau-developed online instrument centered on 0.07 m based on number count. Removal efficiency increased rather sharply for both larger and smaller particles.

Jan 1, 1979

By G. R. Hopkins

A recently completed survey , made by the Bureau of Mines to determine the trend of fuel consumption at refineries in the United States , showed the following outstanding points : A decrease in the use of oil for fuel in 1927 of over 5,000,000 barrels as compared with 1926 ; a decrease in the use of coal of over : 1,000,000 short tons ; small increases in the use of both natural gas and refinery gas ; an increase in the use of petroleum coke . The decrease in fuel - oil consumption was approximately 2,000,000 barrels each in the Atlantic Coast , Texas , and Louisiana- Arkansas districts , with an increase of 1,000,000 barrels in the Indiana - Illinois district , or a net decrease of 5,000,000 barrels . The decrease in fuel- oil consumption by refineries in the Texas and Louisiana- Arkansas areas was offset largely by increased consumption of natural gas and refinery gas , whereas the increased consumption in the Indiana- Illinois region was more than offset by the decrease in coal consumption . The use of coal for fuel declined from 6,052,000 short tons in 1926 to 5,031,000 short tons in 1927. Practically all of this decrease was recorded in the Appalachian and Indiana- Illinois districts , which at the same time showed the largest percentage increase in the use of oil for fuel . It is probable , therefore , that although coal prices also fell off , a considerable quantity of oil replaced coal in this area in 1927. In addition , the group of refineries , which are by location more or less definitely committed to the use of coal for fuel , undoubtedly succeeded in saving a material amount of coal through the use of more efficient fueling methods . A total of 130,815,000,000 cubic feet of natural gas was consumed for fuel at refineries in 1927. This represents an increase of 8 per cent over the 1926 total . Nearly all of this increase resulted from the opening of a line from the Monroe field to Baton Rouge , La . Had this line not been opened , there would have been a decrease in the use of natural gas , as a number of districts , particularly the Rocky Mountain , reported decreases in its use . The use of refinery or still gases for fuel did not change materially during 1927 , there being a total of 52,807,000,000 cubic feet burned as compared with 52,077,000,000 cubic feet in 1926. Refinery gases are largely a product of cracking and , it was probably more than a coincidence that a few districts in which cracking slowed down in 1927 also reported less refinery gas used as fuel .

Jun 1, 1924

By G. W. Birge

Carbonizing properties of the principal coalbeds of Elk, Clarion, Jefferson, Clearfield, and Centre Counties, Pa,, are described in this Bureau of Mines report, Twenty-six samples, representing the Upper Freeport, Lower Freeport, Upper Kittanning, Middle Kittanning, Lower Kittanning, and Brookville beds, were carbonized by the Bureau of Mines--American Gas Association (BM-AM) method, and yields of products and physical properties of cokes were determined. Expansion or contraction of the majority of the samples was measured in the Bureau of Mines sole-heated oven. Chemical analyses, agglutinating values, and free-swelling indexes are given for all samples. In this area the coals generally are characterized by high sulfur and moderately high ash content, and their suitability for metallurgical use would depend largely upon satisfactory cleaning. The samples from Elk, Clarion, and Jefferson Counties were high-volatile A bituminous In rank, whereas, most samples from Clearfield County and all those from Centre County were of medium-volatile rank. Coals from Clarion County had dry, mineral- matter-free fixed-carbon contents ranging from 56.5 to 60.3 percent and were weakly coking. With the exception of two samples which contained excessive ash, the medium-volatile coals of Clearfield and Centre Counties were strongly coking and, as indicated by sole-oven expansion results, would require blending with lower rank coal to avoid oven damage.

Jan 1, 1963

By J. B. Gayle

The rate of oxidation of coals with nitric acid has been used by earlier investigators4 5 6/ for determining fusain and for studying petrographic composition. These workers accumulated considerable evidence indicating that, for coals ranging from lignite to low-volatile in rank, the method gives values for fusain that agree satisfactorily with those obtained by optical methods. One group5/even concluded that, when discrepancies are noted between results obtained by chemical and microscopic methods, the results based on the oxidation reaction are probably the more reliable. Unfortunately, after concluding that the method was valid, most of these workers apparently lost interest. As a result, no attempt to exploit or apply the method to problems of utilization has been reported. Recent studies of the influence of inert petrographic constituents on the properties of cokes made from various coals7/ have indicated a need for additional means of characterizing coals and blends used for carbonization.

Jan 1, 1960

By R. T. Johansen

A gradual decrease in injection rates commonly occurs as a water-flooding project becomes older. This decrease can be attributed to changes in reservoir conditions, such as swelling of clay minerals, fillup, or gradual plugging of the sand face. However, a rapid decrease in the rate of injection indicates abnormal behavior and is cause for alarm. Extreme plugging conditions can completely stop injections into a formation. Such behavior in wells was the main concern of the tests described in this report. An accepted method of alleviating this condition is by backflowing input wells - closing the supply lines to the wells and allowing the reservoir pressure to force water back into the wellbore and to the surface. If backflowing is not successful, a string of smaller diameter pipe sometimes is run inside the casing, and the sand face is flushed with a waterspray. More drastic treatment is to inject acid into the wellbore to dissolve extraneous matter, or even part of the reservoir material, in an attempt to restore the permeability of the sand immediately around the wellbore. Any of these procedures can he coordinated with bailing and swabbing of the well for cleanout purposes.

Jan 1, 1957

By G. H. Keith

Oxygen and nitrogen cause strain aging in electrorefined vanadium, as evidenced by maxima in yield and tensile strengths and by Snoek internal friction peaks. Alloys containing up to 0.22 percent oxygen and 0.11 percent nitrogen were investigated. Tensile strengths of oxygen-and nitrogen-containing alloys were 66,000 and 68,000 psi at 300° to 400° C, compared with 53,000 and 62,000 psi, respectively, at room temperature. Total elongation decreases to about 7 percent at the temperature of maximum strength. At 600° C, strain aging is not evident. Based on interstitial contents calculated from internal friction measurement, the increases in strength caused by nitrogen and oxygen were 440,000 psi per weight-percent nitrogen and 260,000 psi per weight-percent oxygen. Application of the Schoeck and Seeger treatment to the Snoek effect in these systems results in a calculated lattice distortion of 0.24 and 0.15 caused by the presence of an interstitial nitrogen or oxygen atom, respectively. Alloys containing boron or carbon were also investigated. Both elements refine the grain size but have no other effect because of their low solubility in vanadium.

Jan 1, 1969