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By Charles L. Kimbell

The final tables of this chapter, tables 25-50, extend and expand the statistical series on production that was started in the 1963 edition of the Area Reports: International Volume of the Minerals Yearbook and that was subsequently updated and expanded in the 1965 and 1967-90 editions. Continuing the practice started in 1989, a column has been included in each of these tables providing a 5-year average for 1987-91, inclusive. This should provide a clearer picture more rapidly of the role of each major producer over the 5-year period. The listing order of major producers, however, continued to be, as in past years, in descending order of rank in the year of review, 1991. This group of tables now includes each of the crude minerals that ranked from? 1st to 19th in 1983 terms of value of their output (as well as four others of lesser rank). These 23 crude mineral commodities accounted for 93 % of the estimated value of world crude mineral production in 1983. In addition, world output of five key downstream products-aluminum, steel, cement, nitrogen in ammonia, and refined oil-is included because of their significance as products.

Jan 1, 1993

Improve the safety of mine workers by developing a means of forecasting impending roof falls in underground mines. Approach The Bureau of Mines, through in-house and contract research, has developed the Roof Fall Warning Device. This battery-operated, portable electronic system forecasts roof falls by detecting and interpreting high-frequency rock noise, The technology has shown potential for detecting stress-related failures in a variety of underground environments. How It Works All geologic materials produce high-frequency acoustic emissions when they encounter an increase in stress. These ultrasonic frequency range events ( >20kHz) are well above the audible range of human hearing, very small in amplitude and duration, and can only be detected with sophisticated electronic equipment.

Jan 1, 1990

Develop a simple and practical technique to measure in situ rock mass properties for realistic design and stability evaluation of underground structures. Background The Bureau of Mines has developed basic principles and techniques to determine in situ rock mass properties including Poisson's ratio, deformation modulus, and yield and failure strengths. An instrumentation package consisting of three pressure cells is installed in a single drill hole. Cell pressure response data are acquired and used to calculate and determine the rock mass properties. How It Works A test hole of BX size (approximately 5.7 cm) or larger is drilled to the approximate depth of the measuring point. The last portion of the test hole is drilled with precision bits to EX size (approximately 3.8 cm). The instrumentation package, which consists of one 3.8-cm-diameter cylindrical pressure cell (CPC) and two 5.7-cm-diameter cement-capsulated, flat borehole pressure cells (BPC's), is then installed. A complete history of cell response to changing strata loads is acquired on a continuous basis with a chart-type hydraulic pressure recorder. From these cell pressure data, Poisson's ratios, deformation moduli, and yield and failure strengths are calculated and determined.

Jan 1, 1990

By R. H. Harrison, D. R. Douslin

The thermodynamic properties H - H° , (H - H° ) /T , S - Sideal , S - S° Fide al F - F° , (F F° ) /T , and activity coefficient Y for perfluorocyclobutane were calculated as functions of temperatures ( 115.22 ° to 350 ° C) and molal density (0.75 to 6.5 moles / liter ) . Improved analytical and graphical correlating techniques are described .

Jan 1, 1964

By Thomas P. Mucho, Dennis Dolinar, Christopher Mark

During the 1990s, the former U.S. Bureau of Mines conducted a number of field studies in which the performance of different types of roof bolts were evaluated in different geologic environments. The studies used a standard suite of measurements, including multipoint extensometers, strain-gauged roof bolts, and roof bolt load cells. The sites were chosen to investigate the effect of a variety of parameters, including installed tension, bolt capacity, grout annulus, and horizontal stress orientation. Although not fully successful, the measurements provided valuable insights into each of these issues. They also showed that instrumentation and monitoring have important advantages over observational methods for comparing the performance of different roof bolting systems.

Jan 10, 2000

By Frederick C. Trutt, Jeffery L. Kohler, Joseph Sottile

Twenty-five years ago, the former U.S. Bureau of Mines funded a research project aimed at developing the enabling technology for incipient failure prediction in electric power system components as a means of reducing the injuries and fatalities that sometimes occur when equipment malfunctions. Over the ensuing years, interest in this has waxed and waned, but recently interest has been growing for both civilian and military applications. This paper addresses the level of turn-to-turn insulation deterioration that can be resolved using an on-line monitoring technique. The detection of turn-to-turn defects is especially important because they are believed to represent the beginning stage of most motor winding failures.

By D. G. Kuehn

Studies were conducted by the Bureau of Mines to determine the positive ions and neutral species produced in glow discharges of gas streams containing 1.0 percent NO in helium, 29 percent dry air in helium, and 1.06 percent NO in N2, Mass spectrographic measurements were conducted for gas pressures from 2.3 to 10.0 torr and dc currents from 10 to 20 mAo Ion species observed included NO+, N2 +, O2 +, N+, and 0+ with lesser amounts of He+, He2+, and N02+. Variations in various ionic and neutral species with discharge duration were interpreted to be consistent with an electrically induced dissociation of NO to produce N2 and O2. No nitrogen oxides were observed to form in glow discharges of the helium-air mixture.

Jan 1, 1975

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

5. General Escapeway Requirements 5.1 Escape Routes Present escapeway regulations state "Every mine shall have two separate properly maintained escapeways to the surface which are so positioned that damage to one shall not lessen the effectiveness of the other, or a method of refuge shall be provided when only one opening to the surface is possible." "Escape routes shall be a. Inspected at regular intervals and maintained in safe, travellable condition, b. Marked with conspicuous and easily read direction signs that clearly indicate the ways of escape." "Application. "Regular" intervals means at intervals no greater than monthly where conditions are stable and oftener where conditions may change." "Designated escapeways inclined more than 30* from the horizontal shall be equipped with stairways, ladders, cleated walkways, or emergency hoisting facilities." As can be noted in present and proposed regulations there must be two separate properly maintained escapeways. In most operations, the escapeways will consist of one route that is the normal travelway used in day to day operations. The second route is usually a return airway through old work areas. Based on this generally accepted practice, we will designate the two types as primary and secondary.

Jan 1, 1976

Roof bolting is a slow, expensive, and absolutely necessary mining activity. Roof-bolting activities also account for the largest percentage of lost-time injuries in underground coal mines. Dull bits result in the application of excessive force, which bends drill steel; and changing starter and finisher steel was the most significant source of injuries associated with roof bolting. The tungsten carbide (WC) roof-bolt drill bits currently used in American, Canadian, and Australian coal mines are capable of drilling only one or two 4-ft holes and then they are resharpened once or twice to drill another one or two holes. Often, in medium-hard rock formations (sandstone), as many as 20 to 30 bits may be required to drill a single 4-ft hole. Objective To compare the performance, longevity, and cost of newly developed polycrystalline diamond compact (PDC) roof-bolt drill bits against WC bits. Research and Background Diamonds for industrial use have been scarce throughout history and continuous attempts have been made to produce synthetic diamonds. The first synthetic diamonds were manufactured in 1953. Economically produced synthetic diamonds are 1 to 10 µm in size, but in this size range, they are totally unsuitable for industrial applications. In 1972, General Electric Co. developed a process to sinter the artificially developed, minuscule diamond particles into usable products. In this process, several layers of diamond-particles-and cobalt mixture are overlaid on WC substrates and sintered at 2,350° F and 1,000,000 psi. The final product is known as PDC. Today, PDC's are available in many shapes, but their size is limited to 3/4 in, or less, in length or diameter, because pressures greater than 1,000,000 psi are required to manufacture larger PDC's. At present, diamond and PDC arc the hardest and strongest commercial materials available for wear surfaces. The PDC used in this study had a hardness 3.61 times greater than that of WC.

Jan 1, 1992

Roof falls continue to be the greatest single safety hazard faced by underground coal miners. During 1996-99, 44 coal miners lost their lives in rock falls, and nearly 2,400 were injured. In addition, nearly 6,000 noninjury roof collapses were reported. Roof supports are installed to protect the miners, but support system failures contributed to most of these incidents. Reducing the terrible toll taken by ground falls continues to be a major goal of research by the National Institute for Occupational Safety and Health (NIOSH). The purpose of these proceedings is to provide the mining community with a comprehensive survey of coal mine roof supports. Drawing on many years of research undertaken by the NIOSH Pittsburgh and Spokane Research Laboratories, this volume describes what types of support are available, how they work, and when they should be used. The major subjects covered include roof bolts, standing roof supports, cable supports, and longwall shields. Some special topics are also addressed, including an analysis of roof fall accident statistics, techniques for better skin control, material handling considerations, and longwall mining through recovery rooms. This proceedings volume also contains information on several important new technologies, which are described here for the first time: •Guidelines for selecting roof bolt length, pattern, and capacity that were derived from statistical analysis of the roof fall experience at 37 underground mines; •A new design method for longwall tailgate supports; and •A technique for measuring loads developed within cable bolts. The papers in these proceedings were presented at open industry briefings conducted by NIOSH on New Technology for Coal Mine Roof Support. The briefings were held in Norton, VA, Charleston, WV, Evansville, IN, Tuscaloosa, AL, Price, UT, Glenwood Springs, CO, and Washington, PA. The papers were also presented at the Mine Safety and Health Administration (MSHA) Preventative Roof-Rib Outreach Program (PROP) Seminar, which was held at the National Mine Health and Safety Academy near Beckley, WV.

Jan 10, 2000

By Francis Crowley

Elementary concepts of seismic wave properties are reviewed to establish a framework for discussing seismic noise and its suppression. A liberal number of references is included for those who wish to pursue the topic in detail. A base motion noise level is established for a single surface seismometer. It is argued that simple array processing and seismometer burial should regularly permit us to approach this base noise level which is found in areas free of conspicuous man-made seismic noise sources. The sensitivity of the base seismic level to a number of common disturbances is presented. Solutions that promise to hold the "effective" seismic noise at a site near the base level are given for acoustic, meteorological and fixed local surface sources. Guidelines are suggested for controlling other local man-made sources, e.g. vehicular traffic, by keeping them at sufficiently large distances away from the seismometers to keep noise at permissible levels. These guidelines are speculative and conservative. They should be the subject of future study. The ability to process against general local activity, drilling, and intra- mine sources is limited. Certainly no dramatic gain is to be expected. When strong man-made and/or intramine noise sources are not controllable, detection may well be impossible to achieve, unless the seismometer can be moved close enough to the suspected miner position, i.e. via very deep holes, to compensate for the likely vast differences in strength of the miner signal and the uncontrollable man-made noise sources. However, many intramine sources, e.g., falling water, rock bursts, explosions, etc., may well preclude the existence of a hale miner in their vicinity, and therefore any need to attempt detection of a miner at such locations. The following recommendations are made to enhance the detection and location of a miner signaling seismically. They are: 1. Seismometer burial in slim holes. 2. Narrow band detection, using multiple narrow band filters to cover the likely signal band. 3. Broadband recording and analysis for time-of-arrival estimation.

Jan 1, 1974

By Thomas M. Barczak

Purchasing a new set of longwall shields requires a substantial investment. A poor shield design can lead to economic hardships, safety concerns for the mine workers, and closure of the mine. This paper addresses several key points that should be considered in the procurement process: (1) understanding your goals and the logic in selecting a higher capacity shield, (2) the importance of completing performance testing before production shield fabrication begins, (3) making sure performance testing is properly done, (4) measuring load(stress) development during performance testing, (5) testing a shield to failure, and (6) the value of buying extra shields. In addition, several challenges are proposed for consideration in future shield designs. These include (1) 100,000 life-cycle expectancy, (2) improved hydraulic diagnostic capability, (3) smart load control by optimizing setting pressures, (4) lubricated link joint design concepts, (5) composite material applications to reduce shield weight, (6) incorporating periodic weighting predictive algorithms into the data-processing software, (7) advanced component load measurement on two to three specially instrumented shields to detect loading in the structural components, and (8) constant set leg cylinder design.

Jan 10, 2000

By Joseph C. Zelanko, Christopher Mark

During August, two eastern Kentucky coal miners died in a roof fall during retreat mining operations. They had just finished extracting one pillar block and were moving to the next one when the intersection they were standing in collapsed. Regrettably, this was not an isolated incident. Since the end of 2000, there have been 28 ground fall fatalities in U.S. coal mines. Of these, 10 occurred during pillar recovery operations. Although pillar recovery has been associated with about one third of recent ground fall fatalities, it accounts for only about 10% of U.S. underground coal production. Statistically, a coal miner engaged in pillar recovery is several times more likely to be killed in a ground fall than a miner on an advancing section of a longwall. Pillar recovery is dangerous because it creates an inherently unstable situation. Once the pillars are extracted, the roof is expected to cave. Safe pillar recovery does not mean preventing roof collapse, it means ensuring that it only occurs after the miners have completed their work and have left the area. Fortunately, there are a number of proven techniques that can greatty reduce the hazards of pillar recovery. These include better mine planning, improved roof support, and safer work procedures. The goal of this article is to describe the most significant "risk factors" associated with pillar recovery, and prescribe control techniques that, taken together, can reduce the overall risk to miners. The conclusions are based on extensive studies conducted by the National Institute for Occupational Safety and Health (NIOSH) and the Mine Safety and Health Administration (MSHA) that have included detailed analysis of every fatal retreat mining incident since 1992 (25 incidents resulting in 30 fatalities). Risk reduction strategies for pillar recovery can be divided into three main groups: Global Stability: Prevention of section- wide pillar failure; Local Stability: Prevention of roof falls in the working area; and Work procedures and worker location: Minimizing exposure to hazardous areas.

Many different types of structures and materials have been used to build mineral processing facilities throughout the years. Although structure type and building material were not viewed as significant factors affecting the health of employees in these facilities when they were built, the National Institute for Occupational Safety and Health (NIOSH) has found that building type can impact respirable dust and noise levels. NIOSH performed a study in which it evaluated three building types: masonry, an open-structure design, and a steel-sided design. This study indicated that an open-structure design (no walls) was superior from both a dust and noise (health) standpoint when compared to the other two structure types. Therefore, companies may want to consider this design when building new structures.

By W. E. Miller, Kennedy. R. E., G. W. Jones

"INTRODUCTION Ethyl mercaptan (CH3,CH2SH), a combustible organic liquid of the thioalcohol type, is employed at an odorant in many types of fuel gases and dangerous atmospheres, which in themselves are devoid of characteristic odors, to give warring against leakage of such gases or atmospheres into places where they might constitute health or explosion hazards.Ethyl mercaptan has a penetrating disagreeable odor resembling that of onions, garlic, hydrogen sulfide, or rotting cabbage, that exceedingly low concentrations of it can be detected. The of odorants as a beans of detecting leakage of gases and atmospheres has been investigated extensively by chemists and engineers of the Bureau of Mines, and numerous reports as to its value have been published."

Jun 1, 1942

By W. W. Weller

Heat capacities of ferrous molybdate (FeMoO4) and ferrous tungstate (FeWO4) were measured over the temperature range 51° to 298.15° K. Ferrous tungstate has a lambda type heat capacity anomaly at 74° K. The 298.15° K entropies are FeMoO4) 30.9 cal/deg mole and FeW04) 31.5 cal/deg mole.

Jan 1, 1966

By Natalie A. Sapola, Knox Van Dyke, Jean Rabovsky, Vincent Castranova, William H. Pailes, Melanie McPeek, Deloris J. Judy

"INTRODCJCTJONPlatelet activating factor (PAF) is a glycerophospholipid (1-0-alkyl-2-acctyl-sn-glycerol-3-phosphoryl choline) which has been shown to mediate a broad range of biological activities. 1·3 Its pulmonary actions include contraction of pulmonary tissue,4 secretion of leukotrienes from leukocytcs,5 airway constriction,6 pulmonary edema,7 and enhanced migration of neutrophils into the airspaces of thelungs.8-9PAF can be released from several different cell types, such as, basophils, neutrophils and alveolar macrophages, in response to a variety of particulates or membrane stimulants which include zymosan, calcium ionophore, phorbol esters, chemotactic agents, and endotoxin. 1~1 3 Therefore, PAF may play an important role in the development of pneumoconioses by mediating pulmonary responses of lung cells to a variety of occupational dusts. To investigate this possibility, we determined the effects of P AF on several physiological parameters of neutrophils, alveolar macrophages, and alveolar type Il epithelial cells.METHODSIsolation of CellsNeutrophils were isolated from human blood by dextran settling and centrifugal elutriation.14 Isolated neutrophils (93% pure) were resuspended in HEPES-buffered medium (145 mM NaCl, 5 mM KCI, 10 mM HEPES, 5 mM glucose, and 1 mM CaC12; pH = 7.4). Cell number and volume were determined with an electronic cell counter equipped with a sizing attachment.Rat alveolar macrophages were obtained by pulmonary lavage with ea2+, Mg2+-free Hanks balanced salts solution. 15 Alveolar macrophages (94% pure) were resuspended in HEPES-buffered medium, counted, and sized electronically.Rat alveolar type Il cells were isolated by enzymatic digestion for 35 minutes at 37°C with 40 µ/ml type I elastasc and 0.1 % collagenase and purified by centrifugal elutriation. 16.17 Type Il cells (92 % pure) were resuspended in HEPES-buffered medium for measurement of membrane potential, oxygen consumption, and trypan blue exclusion. Type Il pneumocytcs were resuspended in 0.1 M NaCl plus 0.05 M HEPES (pH = 7.8) to measure cytochrome P450-dependent activities and aggregation. Cell size and number were determined electronically."

Jan 1, 1990

By J. W. Walkiewicz

The Bureau of Mines investigated alloys containing mischmetal (MM), cobalt, copper, magnesium, and iron for use in permanent magnets in place of the scarce samarium-cobalt alloys. The magnetic properties of MM-Co, MM-Co-Cu, MM-Co-Cu-Mg, and MM-Co-Cu-Fe-Mg alloys were evaluated. Magnets were fabricated by powder metallurgy consisting of arc-melting the metals, crushing and grinding the resultant alloys, alining and compacting the powder, and sintering the compacts. Magnetic values of MHc = 4.7 kOe, BHc = 4.07 kOe, Br = 6.81 kG, and (BH)max = 10.0 MGOe were obtained with a MM-Co alloy containing 36±0.5 wt-pct MM. By substituting copper and magnesium for part of the cobalt, the values for MHc and BHc were increased to 29.0 kOe and 5.89 kOe, respectively. This intrinsic coercivity value exceeded that of Sm-Co alloy obtained in our laboratory. The addition of iron to MM-Co-Cu-Mg alloys resulted in an increase of Br to 6.90 kG and (BH)max to 10.3 MGOe. Copper and magnesium contents of these alloys were optimized to obtain maximum values of MHc.

Jan 1, 1981

By Walter E. Pittman

This Bureau of Mines study surveys the current state of technology and the various research efforts that have been undertaken to dewater the dilute phosphatic clays generated in the production of phosphate rock. The research described includes early dewatering experiments, fundamental studies of clays and of flocculation, and minor dewatering techniques such as freeze-thaw methods, the ANDCO process, moving screens, sand wick, crust development, and overburden pumping. Some methods that are currently being evaluated are described. They include the Estech sand-clay mix process using the Enviro-Clear thickener, sand-clay sandwiching, dredge mix, dredge process, and the sand-spray process. Developing technology for dewatering phosphatic clays also is described, including the Bureau of Mines rotary trommel method and the Gardinier process.

Jan 1, 1984

By G. F. Friel

A series of experiments in the U.S. Bureau of Mines Safety Research Coal Mine at the Pittsburgh Research Center evaluated the effects of crosscuts on the travel time of carbon monoxide (CO) along an entry to improve the accuracy of a mine-fire locator program. Three entries, ten single crosscuts, and three double crosscuts were instrumented with CO sensors. One-percent CO in nitrogen was released and monitored as it traveled the entries. In addition to dispersion of CO at the front of the CO wave, CO was entrained from the entry into the crosscuts. It was determined for an entry and single-crosscut configuration that the measured travel time for a concentration change of 5 ppm was 27% greater than the predicted time based upon entry volume only, but 13% less than the predicted time based upon entry and crosscut volumes. For an entry and double-crosscut configuration, the measured travel time for the same concentration change was 25% greater than the predicted time based upon entry volume only, but 10% less than the predicted time based upon entry and crosscut volumes. An effective dispersion coefficient for CO dispersion along one of the entries was estimated to be 1.5 m2/ s.

Jan 1, 2010