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By A. M. Croll

The efforts to mechanize narrow reef tabular orebodies unique to this country, are not new. They began in the early 1900s and have over the last century seen varied rates of progress and success. Efforts to mechanize with the use of scraper winches can be regarded as a success. The scraper winch replaced the hand lashing of ore and development waste into hoppers. The initiatives by Anglo Gold and the then JCI to implement trackless mining equipment into these environments had limited success but in general were looked upon as a failure?at least this is the perception. The Chamber of Mines Research Organization (COMRO) in conjunction with various mining houses tried to make a success of the impact ripper. Diamond wire cutting of the stope face is another, which has been tried and tested. The use of high-pressure water to cut rock has also been trialed. These attempts, amongst others, are just a few of the efforts that have not been successful in the quest to make life at the face safer, more productive and easier for our employees. Against the backdrop of an emerging South Africa, the associated high expectations of historically disadvantaged people within the country, a strong rand, demands for better safety, lower cost of production and more efficient operations, mechanization has the chance to make a difference to Anglo Platinum?s business. Mechanization has certainly changed the way other commodities such as coal, base metals and diamonds are won from the earth. Mining?s image is still one of people crawling around in stopes?a dirty, ?low-tech? business. Anglo Platinum?s latest journey to mechanize its underground operations began in earnest in1998 and has enjoyed some successes and failures. The opportunity to change the way mining is done within the company is there. Technologies are evolving, and the implementation of mechanization can certainly assist with the achievement of the goals referred to above. When mechanization commenced, targets were set for the company to achieve but these have been revised in the light of recent events relating to the strengthening rand and a slow-down in expansion plans. However, the intent to mechanize appropriately in Anglo Platinum still exists.

Jan 1, 2004

By R. P. King

"A model of the flotation process can be used effectively for design and control. For design purposes it can be used to predict the performance of a large plant from laboratory and pilot plant data. It can be used for control purposes to assess the utility of any proposed operating modification to an existing plant, and it can also be used to determine optimal control settings for best operating performance.A model has been developed that will allow for variations in feed properties and for variations in fineness of grind. The model can be used to assess the effects of reagent addition rate, aeration rate and pulp level on plant performance and these are the control variables that are used individually or together in all operating flotation plants. The model provides for a distribution in the values for flotation rate constants, particle size and mineral fraction, and, because of its complexity, requires a large computer when it is to be applied to a typical plant configuration. The computational method that is used to apply this model to such configurations is described in this paper, and particular attention is paid to the problem of allowing for feedback of tailings from cleaners and recleaners."

Jan 1, 2014

By Turgay Gurun

"Digital simulation can be used as an analytical tool to optimize the design of crushing plants without need for large-scale experimental programs.General mathematical description of a crushing operation permits the simulation of a crushing plant flowsheet under various operating conditions. The process model encompasses multistage open- and closed-circuit crushing of hard and soft rock. Crushing balances are analyzed in the light of crusher and screen performance and a comparison of different closed-circuit arrangements is made in terms of process and layout criteria.The simulation model allows comparison of process alternatives to be made in terms of equipment selection and capital and operating cost estimation. It thus provides the pertinent practical information to maximize plant efficiency, and to minimize expenditures in such items as equipment, structures, power consumption, and so on."

Jan 1, 2014

By X. Zhang, E. Li, Y. Xiao, Z. Yu, H. Han, J. Xie, J. Tian, W. Sun, K. Hong

In a pulp environment, the surface properties of magnesite and dolomite tend to be similar, due to the re-adsorption of dissolved calcium species, which makes the flotation separation difficult. In this paper, the chelating reagent EDTA is introduced to eliminate the adverse influence of the calcium species and to restore the selectivity of magnesite-dolomite separation using sodium hexametaphosphate (SHMP) as a depressant. Flotation experiments confirm that the recovery of magnesite improves significantly in the presence of EDTA. Zeta potential experiments confirm that the negatively charged EDTA4+ and HEDTA3+ species can form soluble and stable chelates with positively charged Ca2+ and Ca(OH)+ species preventing their adsorption on the magnesite surface. Adsorption measurements prove the addition of EDTA can decrease the adsorption of depressant SHMP on the magnesite surface. X-ray photoelectron spectroscopy (XPS) measurements further confirm the transformation from the surface of magnesite to dolomite in the presence of calcium ions, and the possible adsorption mechanism of EDTA and SHMP on the magnesite and dolomite surface. Key words: Magnesite; Dolomite; Surface dissolution; Flotation separation

Jan 1, 2020

By R. Dehghan, M. Zarei, A. Tohry, S. C. Chelgani

Typical depressants for selective reverse flotation of iron oxides from complex silicates do not generally show high levels of efficiency. Therefore, as a hot topic, there are several ongoing investigations in this area. The main aim of this paper is exploring the potential of using humic acid (HA) as a depressant in reverse cationic flotation of hematite from complex silicates. For such a process, the wettability and flotation behaviour of pure minerals (hematite and silicates) was investigated at pH 10 in the presence of HA and cationic collector. Adsorption mechanism of HA on these minerals was measured by zeta-potential and FTIR. Results of flotation tests showed that at the lower concentrations of HA, selective separation of silicates from hematite is beneficial, where the floatability of amphibole was higher than pyroxene. A higher separation efficiency of hematite through reverse flotation was observed in the presence of amphibole, in comparison with the presence of pyroxene. Wettability studies showed that HA has a significant effect on reducing the hydrophobicity of treated minerals with the collector. The adsorption, ZPC and FTIR test results indicated that HA was adsorbed on both silicates and hematite. However, the absorption intensity onto hematite was much higher than silicates. It was found that the adsorption mechanism of HA on hematite takes place through both strong H-bonding and ligand exchange. Keywords: Reverse cationic flotation, humic acid, iron oxide, complex silicates, surface adsorption

Jan 1, 2020

By M. Rudolph, A. van Hall, G. Öktem, S. G. Özkan, A. Hassanzadeh

Despite the four-decade study on ultrasound’s (US) impact on mineral’s floatabilities, there is still not clarity regarding its role in mineral surface wettability. For this purpose, the present investigation endeavours ……the hydrophobicity and floatability characteristics of a chalcopyrite-pyrite-quartz (Cp- Py-Qtz) system in the presence and absence of an ultrasonic pre-treatment. The ultrasonic process was carried out by a sonopuls at a constant frequency of 20 kHz with an adjustable power level from 30 to 200 W. Initially, the impact of sonication time (15, 30, 45, 60 and 90 s as well as 10, 20 and 30 min) and power magnitude (30, 60, 90, 120 and 180 W) were evaluated while the dissolved oxygen, temperature, conductivity and pH were also monitored. Collector-less micro-flotation tests were carried out on the non-pre-treated and the US pre-treated samples at 60 W and 15 s. The samples’ hydrophobicities were determined by the drop shape analysis approach. The dissolved-oxygen level was varied using a mini bench pressurised water reactor to study the effect of O2(aq) concentration on the chalcopyrite and pyrite wettability characteristics. The results showed that the minerals’ hydrophilicities were relatively more sensitive to the sonication’s time than its power that resulted in reducing all three minerals’ hydrophobicities. In addition, it was found that the dissolved-oxygen content and creation of sub-micron sized bubbles led to an improvement on chalcopyrite and pyrite hydrophobicities. Finally, we proved that the Cp’s floatability increased and Qtz’s recovery reduced while being subjected to the ultrasonic irradiation (15 s at 60 W); however, Py’s recovery remained constant. This conclusion confirmed the possibility of a selective separation in ultrasound-assisted copper ore flotation. We recommend that further advanced investigations be conducted, using an X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) to thoroughly understand the surface modifications induced by the ultrasonication

Jan 1, 2020

By J. E. Dickinson, J. L. Sutherland, J. Zhou, M. J. Cole, K. P. Galvin

Interest in early gangue rejection has grown substantially in the minerals industry to reduce energy and water consumption arising from excessive comminution. Recent developments in coarse-particle flotation have proven successful by promoting a quiescent hydrodynamic environment to limit particlebubble detachment and by helping to convey more buoyant particles to the overflow. Current approaches also benefit from upstream classification to remove the finer particles ahead of the coarse-particle flotation. In this study, coarse-particle flotation was investigated experimentally using a novel hybrid gravity-flotation system called CoarseAIR™ that exploits the hydrodynamic advantages of the Reflux® Classifier. The system consists of a lower fluidised bed housing, with a system of inclined channels above. The inclined channels enhance the segregation and hence rejection of intermediate through to relatively coarse particles containing little or no surface liberation. This approach overcomes the need for pre-classification, while offering strong transport of coarse particles made buoyant through their attachment to air bubbles. The paper explores the strong relationship between the solids transport to the overflow and the input gas flux, showing firstly the potential for significant mass rejection at the relatively low gas fluxes, and robust performance in terms of recovery across the full range of gas fluxes. Keywords: Flotation, inclined channels, coarse particle flotation, Reflux Classifier

Jan 1, 2020

By P. K. Jain

A spiral concentrator is a density separation device used for the beneficiation of coal and various minerals such as iron ore, chromite ore, gold, beach sand minerals etc. The flow pattern developed in the equipment is complex and unique, yet the operation is very simple, with low capital and operating expenditure. Spirals are applied for beneficiation of material in the size range finer than 2 mm and are capable of recovering heavy minerals as fine as .01 mm. The understanding of the unique flow pattern has kept researchers engaged over the last few decades and attempts are being made to explain such flow patterns so that they can be controlled and modified to improve the operating efficiency, Ep (Ecart Probable Error, also known as probable error in separation) and acceptability of spiral concentrators for processing of fines and slimes - currently being discarded and dumped in the tailing ponds. An attempt has been made in this paper to explain the generation of complex flow patterns with application to classical solid mechanics in the fluid and slurry system. The same has been used to explain the selective separation of particles in different zones in a cross-section on the spiral trough. The paper also discusses the application of a force balance model to explain the generation of secondary circulation. Due to the presence of laminar and turbulent flow regimes in the spiral concentrator, varieties of equations have been proposed in the literature, consisting of different equations for different zones. An attempt has been made to present a unified flow equation for calculation of flow velocity at different positions on the spiral trough. Keywords: Secondary circulation, spiral concentrator, density separation, fine particle processing

Jan 1, 2020

By E. J. Walls, W. C. Joughin

"In selecting a suitable method to sink a vertical shaft for underground access, a number of constraints influence the ultimate decision of where and how to develop the shaft, not least among these being safety, development and construction time, and cost. Two additional considerations stand out: these being geotechnical conditions and technology, the latter taking into account existing underground access. Assuming a project for which an existing underground excavation is available, it is tempting to build a shaft sinking project from the outset based on the raiseboring method, which has the potential to be the safest, fastest, and least expensive method provided that geotechnical conditions permit.And therein lies the rub: regardless of project time or cost constraints, when it comes to raiseboring a long (say, greater than 500 m), large diameter (greater than 4.5 m) shaft, the rock mass conditions ultimately dictate what method of shaft sinking will be feasible. Over the course of several studies for a particular project, several geotechnical analyses were carried out specifically for the purpose of developing a shaft by raiseboring. Risk analysis and experience showed that where the rock mass conditions indicated an unacceptably high risk potential, an alternative method needed to be considered, even if this meant increasing both the time and financial requirements.In this paper we present an overview of geotechnical investigation practices for shaft sinking. Decisionmaking thresholds for raiseboring or other methods of shaft sinking are discussed, including probabilities of failure, empirical rock mass classification, basic wedge failure, and back-analysis of a failed case. The design of appropriate support, and analysis of relative safety benefits for various shaft sinking methods, falls outside the scope of this work, and will be presented in a separate paper.IntroductionThe potential for rock mass failure during shaft development and construction affects whether a project is completed safely, on time and on budget. During the course of several studies to establish ventilation shafts for an underground expansion project, geotechnical analyses of rock mass stability and failure potential were carried out. The investigations were guided by the method of McCracken and Stacey (1989) together with insights from Peck and associates (Peck, 2000; Peck and Lee, 2007, 2008; Peck, Coombes, and Lee, 2011)."

Apr 1, 2019

By K. Moxham, R. G. B. Pickering

Over the last few years Lonmin Platinum and Sandvik have embarked on a unique partnership of collaboration through a systematic approach to developing equipment to mechanize and automate narrow reef platinum mining. After the initial design and manufacture of the equipment the key aspect is the integrating equipment, people and method into a mining system. Another key a spec of mechanization is the optimization of equipment utilization and this philosophy has ensured continual evolvement of mining methods. This paper describes the trials and development that have resulted in the mining method described as Lonmin mechanized breast.

Jan 1, 2006

By John W. Harbaugh, Alfredo Prelate

The goal of the study described here is to develop objective. quantitative methods for estimating the outcome probabilities of exploratory oil wells. The study employs the 're-experience' approach, in which historical data are used in a manner which attempts to recreate the past. Our past experience, of course, is the principal guide to the future. To appraise present-day oil prospects, however, we must analyze prospects that have been drilled in terms of how these former prospects were interpreted before they were drilled. An analysis of how they are interpreted after they were drilled is an inadequate guide to the future because our hindsight knowledge is superior to our foresight knowledge. Objective calculation of future outcome probabilities, then, requires that we attempt to treat past information in a manner analogous to that in which we must treat present information in forecasting future outcomes.

Jan 1, 2014

By D. A. Hayman, N. Rambuda, N. A. Sithole, C. Hockaday, J. D. Steenkamp

"Mogale Alloys operates two alternating current (AC) submerged arc furnaces (SAFs), and two direct current (DC) open bath furnaces. These furnaces are capable of producing two products, silicomanganese (SiMn) and ferrochrome (FeCr), with a total production capacity of 110 000 t/a. This paper focuses on the silicomanganese process specific to Mogale Alloys, with a two-furnace operation facility that produces 55 000 t of SiMn per annum.IntroductionMogale Alloys is situated in Krugersdorp in the West Rand District Municipality in South Africa’s Gauteng Province. The Krugersdorp facilities were initiated by Palmiet Chrome Corporation in February 1963 to produce charge chrome (Basson, Curr, and Gericke, 2007). Mogale Alloys bought the Palmiet Chrome facilities in 2005 from Samancor Chrome. The Afarak Group currently owns 90% of Mogale Alloys.SiMn is produced in two 20 MVA submerged arc furnaces (SAFs), which were originally built for chromite processing, and ferrochromium (FeCr) in two DC open bath furnaces rated at 40 MVA and 10 MVA. When this paper was compiled, the 10 MVA furnace was not operational due to the high cost of production, and one of the 20 MVA SAFs was recently converted to produce FeCr due to market constraints. Mogale Alloys has 290 permanent employees with four contracting companies on site. The paper presented here focuses on the production of SiMn at Mogale Alloys.The high-level process flow at Mogale Alloys is summarized in Figure 1, which details the raw material input and the products produced by the two 20 MVA furnaces. SiMn is produced by carbothermic reduction of manganese-bearing raw materials from four different sources, namely Wessels, Mamatwan, and UMK ores, and BHP sinter feed. The carbon sources are bituminous coal from Forzando and Msobo, local suppliers in Mpumalanga."

Nov 1, 2018

By G. Bueno, L. M. Tavares, T. M. Campos

Iron ore pellet feed pressing has been one of the first and most successful applications of High- Pressure Grinding Rolls (HPGR) in the minerals industry. Vale S.A. has been one of the pioneers in this application, currently with six HPGRs in operation in the pelletising plants of the Complexo de Tubarão (Brazil). In spite of the important advances in the technology, risks still exist when scaling-up the process from small-scale information. The present work takes advantage of the recent advances in the mathematical modelling of the HPGR performance, using the population balance model to evaluate the modified Torres and Casali model prediction in iron ore pellet feed pressing for different scales of operation. Results are presented that compare the HPGR performance in different operational scales for iron ore pellet feed pressing, demonstrating the confidence of this model-based approach for scale-up to full-scale HPGRs used in pressing iron ore concentrates. Keywords: Scale-up, HPGR, pellet feed, modelling, simulation

Jan 1, 2020

By N. Coulson, P. F. Stewart

The Mine Health and Safety Act No. 29 of 1996, as amended, embeds an occupational health and safety management system that facilitates communication between representatives of the state, capital, and labour. In underground mines, two communication loops between these role players serve to separate the production chain of command from the political tripartite relations. Worker-elected health and safety representatives are involved in both communication loops, but are severely constrained in escalating their occupational health and safety concerns to the legalpolitical level. This has a direct bearing on the exercise of the Right to Refuse Dangerous Work (RRDW). As previously reported, health and safety representatives were found to primarily consult their production supervisors in preference to their trade-union representatives. This follow-up article presents production supervisor perspectives on the RRDW. The study demonstrates how, for mineworkers, the two distinct communication subsystems constrain, rather than facilitate, implementation of the RRDW.

Apr 14, 2024

By J. Arzuúa, U. Castro-Filgueira, L. R. Alejano, F. Malan

"Pillar design for underground mining is typically done using empirical formulae or numerical modelling. Practical experience and recent literature, nevertheless, illustrate the shortcomings of these design approaches. Ongoing monitoring of pillars is therefore recommended to minimize the risk associated with these designs.In a mine where a large number of pillars are cut, different pillar strengths can be expected owing to variations in rock mass strength from area to area. This problem is compounded by the fact that in mining environments the pillars are not always cut according to the prescribed dimensions. Although the original design using either empirical methods or modelling may predict stable pillars, unstable pillars will be encountered in reality. Very conservative designs with large factors of safety may circumvent this problem, but this approach is uneconomical.A possible solution to localized stability problems may be to enhance the strength of a few unstable pillars. It may even be hypothesized that reinforcing a few critical pillars may prevent ‘pillar runs’ on a much larger scale. Rockbolting, strapping of pillars, and pillar shotcreting have occasionally been used in the past as possible solutions. It appears that these have not been successful in all cases and large collapses have occurred in spite of the pillar remedial work.The authors investigated the strapping of pillars by conducting laboratory tests on cabled rock specimens. The results were qualitatively compared to actual attempts of pillar reinforcement available in the literature, as well as additional observations in an old haematite roomand- pillar mine in Spain. Based on these results, the value of steel cabling and mesh wrapped around pillars to improve stability is demonstrated. Some cases where this approach will not be successful are also discussed."

Jan 1, 2017

By J. A. Theron

"This paper provides guidelines on performing mass and energy balance modelling involving coal and coal derivatives. Usually, the inputs to a pyrometallurgical process would be specified in terms of elements and compounds. Reliable thermochemical data is more widely available for species involving uniquely defined, relatively smaller molecules. However, in the case of coal, the molecules are extremely large and not uniquely defined. Consequently, modelling processes involving coal and its derivatives have several potential pitfalls. These are outlined in the present paper. The main findings are as follows:•,Coal proximate analysis should not be regarded as absolute; it could vary with several parameters, including heating rate •,For modelling, the use of ultimate analyses should be considered a preferable option to proximate analyses, where, ‘fixed carbon’ and ‘volatiles’ are not defined in terms of chemical composition •,Significant errors could be made if the larger molecules are neglected during calculation of the calorific value (CV) of coal gas (the gas liberated when coal is heated in the absence of oxygen) •,For elemental analyses, the oxygen content (which is calculated by balance) should be checked to ensure it is within the expected range •,For representation of sulphur in coal, double-counting due to SO3 in the ash analysis should be avoided •,Potentially, oxygen in coal could be represented as O2, H2O, CO, or CO2; however, use of some of these species without considering the experimentally determined gross CV results in significant errors in the energy balance. If coal enthalpy is calculated from elemental analyses without correction, representation of coal oxygen as H2O(l) gives reasonable accuracy (up to 6.9% error for a set of South African coals). Coal volatiles could be represented by a complex mixture of compounds, even using different oxygen-containing species than the abovementioned four, provided the enthalpy is corrected •,It is recommended that an ‘enthalpy correction value’ is incorporated in energy balances involving combustion, devolatilization, or conversion of coal and coal derivatives, e.g. coke, char, or tar. That would imply that proximate analysis, elemental analysis, as well as the gross CV would be required for all solid or liquid coal-derived substances being modelled. No other correction due to the form of carbon being different than graphite should be used, as that would imply doublecounting some effects."

Jan 1, 2014

By D. J. Briggs

The use of backfill for regional and local support is receiving increasing attention in the South African mining industry. To ensure that fill materials meet the purposes for which they are intended, a test procedure to characterize the load-deformation characteristics for a particular fill was developed. The major variables identified as influencing the load-bearing proper- ties of backfill include particle size distribution, porosity, width-to-height ratio, strain rate, confinement, water content, and additives. The influence of these variables on the performance of backfill is described in relation to crushed waste, dewatered tailings and deslimed tailings. These investigations confirmed that no single test could be used to define the overall stress-strain behaviour of a selected fill. Nevertheless, resulting from this work, a preliminary standard test procedure for uncemented backfill materials, com- prising a suite of tests in unconfined and confined compression, has been formulated. This test procedure is a significant advance towards a more meaningful evaluation of fill materials. Test results will also provide numerical information for input use in computer programs for the design of mine layouts incorporating backfill.

Jan 1, 1988

By Xiaoxu Sun, Jianchao Yao, Qiheng Zhu, Dubo Wang, Jiancheng He, Shijie Lu

Tower mill is considered to have a better regrinding and fine grinding effect compared with ball mill, and its application is much broader. The spiral agitator of the tower mill is driven by the motor. Media inside the mill is under the combined actions of the spiral mechanism, the cylinder, and media nearby, and these parameters are key factors affecting the grinding effect. However, it is not possible to obtain detailed information of kinematic law of media based only on traditional laboratory experiments, let alone the relationship between parameters of kinematic law of media and grinding effect. Experimentation is the only way to develop industrial equipment. However, this is time-consuming and costly, which hampers the further research of the tower mill’s grinding mechanism. The paper selects two structural parameters (gap between the edge of the spiral agitator and the cylinder wall, ratio between the diameter of cylinder and that of the spiral shaft.) and three operating parameters (diameter of media, filling ratio, the speed at the edge of the spiral agitator) as variables to do an orthogonal designed experiment of five factors, four levels, and thereby obtaining change law of grinding indicators of different parameters. Experimental equipment may be simplified to enable an applicable simulation strategy. Simulation based on a discrete element method is conducted to obtain the change law of the speed of media, collision frequency, normal force, and radial force. The relational curve between parameters of kinematic law of media and energy consumption of grinding is clarified, and key factors affecting grinding efficiency are determined. Those factors will be used for optimising the design and operating process. The research result of this paper obtained from laboratory experiments and computer simulation provides data support and theoretical bases, and has directive meaning and applicable value for tower mill’s optimisation and large-sized design. Keywords: Tower mill, discrete element method, kinematic law of media, energy consumption of grinding

Jan 1, 2020

By H. Ramazi, A. Amini

"This article is devoted to the introduction of a new technique of electrical resistivity data processing called residual resistivity (RR). We define RR as measured resistivity minus background resistivity. To determine the background resistivity, the data acquired from electrical resistivity measurements along a given survey line is evaluated, and then an equation is fitted to the data corresponding to a chosen measurement station as a function of current electrode spacing (or array length). The RR technique was applied to several synthetic models to compare the conventional resistivity inversion of each model with its RR-based inversion. A case study was carried out in a karstic area in Zarrinabad, Lorestan Province, western Iran, to detect the location and geometry of probable cavities by conventional resistivity inversion and RR-based inversion. The results showed that the anomalous zones are better highlighted in the RR-based inversion images in comparison with the conventional inversion images. In some cases, anomalies detected by the RR-based images were hidden in the conventional method. IntroductionThe geoelectrical resistivity method has been widely used since the early 20th century, and plays an important role in several fields such as groundwater and subsurface mineral exploration, geotechnical and environmental investigations, and archeological studies (Bayrak and Senel, 2012; Candansayar and Basokur, 2001; Fehdi et al., 2011; Hee et al., 2010; Osella et al., 2003; Wilkinson et al., 2010). The goal of geoelectrical resistivity surveys is to determine the distribution of subsurface resistivity by measuring the current-potential difference on the ground surface (Aizebeokhai et al., 2010). In the electrical resistivity method, an electrical current is injected into the ground by two electrodes, called current electrodes (AB), and the potential difference is measured between another pair of electrodes, the potential electrodes (MN). Several methods of interpretation are available for application to electrical resistivity data, the simplest being the graphical interpretation of the apparent electrical resistivity pseudo-sections along each survey line. A second method, electrical resistivity inversion, has been developed to create relatively accurate two- and threedimensional computational resistivity models of subsurface sections (Loke and Barker, 1996; Niwas and Mehrotra, 1997; Nordiana et al., 2014; Oldenburg and Li, 1994; Papadopoulos et al., 2009; Yilmaz and Narman, 2014). In the inversion method, models of subsurface objectives are mathematically inverted to reach optimal solutions subject to prescribed objective functions, constrains, and convergence criteria. A common problem when using the electrical resistivity inversion method is that the inversion model of an electrical resistivity profile may be non-unique because different inhomogeneities in the investigation media can result in the same electrical response (Smith and Vozzof, 1984)."

Jan 1, 2016

By L. A. Cornish, J. W. van der Merwe

"The hydrofluoric acid (HF) industry in South Africa uses normalized mild steel (SA 516 Gr 70) for the storage and distribution of its technical-grade product (70% HF). The technical-grade acid is split from the anhydrous hydrogen fluoride (AHF) product during distillation just after HF is produced, in a stainless-steel-lined kiln, from the reaction of calcium fluoride (CaF2) with sulphuric acid (H2SO4). Uniform corrosion of the storage tanks is mitigated during commissioning by contacting the steel with 70% HF. A corrosive reaction takes place (2H+ + 2F- + Fe - H2 + FeF2) to form scale inside the tank which diminishes the attack of the steel by fresh HF, thus prolonging the service life expectancy of the vessels. This iron fluoride scale in the vessel grows continually, resulting in corrosion of the vessels continuing at a predictable rate (approx.0.5 mm/a) since the first commissioning of the tanks at Necsa in 1993. In early 2012, an increase in the average corrosion rate of the tanks to 3 mm/a measured at and below the liquid band in the storage vessels was noted. Three months later the corrosion rate had increased to 30 mm/a, just before the first leak from the tank was detected. The tanks were decommissioned shortly afterwards and an investigation revealed that the rapid corrosion was due to the presence of increased levels (>50 ppm) of nitric acid (HNO3) in the tanks, which attacked the fluoride layer protecting the steel.The oxidation characteristics of high concentrations of HNO3 with low concentrations of HF on stainless steel surface treatment are well documented. The effects of low levels of nitric acid on the corrosion of steels in sulphuric acid are also known, but no suitable published data currently exists on corrosion by high HF concentrations with low HNO3 concentrations. Establishing the rate and mechanism of corrosion by HNO3 (0.1 to 1%) in 70% HF is currently a high priority for the HF industry in South Africa and will become increasingly important in the near future due to depleting fluorite reserves and cheaper, but less efficient, processes producing H2SO4 with higher impurity levels, which were not anticipated in the original plant design. The aim of this study is to simulate the corrosion conditions in the plant on a laboratory scale in order to establish the corrosion characteristics of the steels used in the HF plant, which are increasingly exposed to the HNO3 impurities that tend to concentrate in the final technical-grade HF acid product."

Jan 1, 2016