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By Mengxiong Guo, Xuxin Shao, Yong Bao

In the paper, the adsorption properties of dissolved ions on the surface of collophane and dolomite are studied using zeta potential measurement, ESCA and UV adsorption spectrum both in distilled water and in the supernatant of each other. The effect of dissolved ions on the flotation separation of collophane and dolomite under SCO depressant and oleate is discussed on the basis of above analyses.

Jan 1, 1993

By G. Milojcic

The opencast lignite mines in the Rhinel and Di strict/Germany are equipped with the continuously operating bucket-wheel excavator - conveyor - spreader system. High productivity requires large capital expenditure on main mine equipment as a precondition for efficient mining. In operation, the technology employed leads to a particular cost pattern which is quite different from that of other industries. Labour, auxiliary equipment and mobile vehicles are the most important cost factors which can be controlled by the management. In this respect information processing computer systems are used for systematical and interpretable representation of operational tasks and jobs both in planning and work preparation and in recording the operational data describing the work result and the use of resources. Another aim of the project is to relieve the middle management of major part of its administrative routine work. Job-related work planning and data recording open up various possibilities of analyzing the operational procedures. This analysis shows, for example, what auxiliary machines are particularly suitable for specific tasks, and working groups can be organized so as to take account of the different skills of individual employees for the sake of an optimal work product. Computerized information processing provides the decision makers with topical information related to their respective responsibilities. The mining department of the Hambach opencast mine is the first user of the PERMAD system. Due to the favorable evaluation it has been decided to introduce PERMAD in three other mines in the course of 1992/93.

Jan 1, 1992

By R. E. Johnson, J. E. Dutrizac, B. R. Palmer

Silver sulphide (acanthite) and lead sulphide (galena) dissolve relatively rapidly in FeCl3 media with the formation of elemental sulphur and soluble silver and lead chlorides. Parabolic kinetics are observed, and the leaching rates are controlled by the outward diffusion of the AgCl and PbCl2 reaction products through the constantly thickening elemental sulphur layer formed on the sulphide. Hence, both leaching rates are strongly dependent on those variables which affect the solubility of AgCl or PbCl2 at the reaction interface. The rates therefore increase with increasing temperature and total chloride ion concentration, but decrease in the presence of elevated concentrations of AgCl or PbCl2. By contrast, neither sulphide is significantly attacked by ferric sulphate media, even at high Eh values. Although the reasons for the refractory behaviour of Ag2S in sulphate media remain unknown, the low rate of PbS attack is attributable to the passivating layer of PbSO4 and elemental sulphur formed on the surface of the galena.

Jan 1, 1993

By Z. Sartowski, M. J. Pearse

The authors present laboratory and plant results illustrating the benefits to be gained by using chemical additives, namely flocculants and surfactant dewatering aids, in the Bayer process. Advantages of synthetic flocculants over starch are illustrated in terms of more efficient solid/liquid separation in both the initial settling of blow-down slurries and in the CCD wash train. In addition, it is shown that the use of synthetic flocculants considerably reduce the levels of organic contaminants present in the process liquor. Secondly, very significant improvements in moisture removal were obtained by the application of dewatering aids to hydrate filtration/ washing operations.

Jan 1, 1984

By G. F. Revey

Most commercial explosives contain from 70% to 94% (by weight) ammonium nitrate. When some of the explosives end up in shot rock and ore, through either spillage or incomplete detonation, ammonia and nitrates can leach into the ground water. In recent years, state and federal regulators have applied more stringent water-quality standards, particularly at new mines and development projects. When mining conditions permit, bulk ANFO, a mixture of ammonium nitrate and fuel oil, is the explosive of choice. ANFO is less costly than other explosives but it dissolves readily in water. Several case histories in the United States and Canada show a clear connection between uncontrolled losses of bulk explosives and high nitrate levels in mine effluents. Mining companies have tried several approaches to reduce ammonia and nitrate levels in groundwater. These approaches range from controlling explosive losses to treating the mine effluents. In this paper, controlling explosive losses is addressed For both packaged and bulk explosives, guidelines to limit losses during storage, handling and use are described in detail.

Jan 1, 1997

By F. M. Doyle, P. E. Richardson, E. Peters

A number of studies have attempted to correlate the semiconducting properties of mineral sulfides with their chemical reactivity. Frequently such studies are conducted on polished or abraded electrodes. Defects produced by abrasion may mask the influence of the semiconducting properties of electrodes, e.g., by pinning the Fermi level at the surface or by reducing the lifetimes of photogenerated charge carriers. It is shown that pyrite and galena electrodes have photocurrents that are extremely sensitive to abrasion of the electrodes. On freshly fractured galena surfaces, the space charge layer is readily polarized. Wet-abrasion is shown to produce a relatively thick ptype layer on galena electrodes and this p-type layer has a pronounced effect on the photoresponse. On freshly fractured pyrite surfaces, the Fermi level at the surface is pinned by a surface state. Wet-polishing reduces the magnitude of the photocurrent by over an order of magnitude.

Jan 1, 1993

By M. Selamat, J. Nirdosh, S. V. Muthuswami

High-grade uranium ores of Cluff Lake and Key Lake mines from the province of Saskatchewan in Canada are treated with nitric and hydrochloric acids with the objective of leaching 230 Th and 226Ra simultaneously with uranium to produce environmentally safe mill tailings, h is found that optimum conditions for uranium leaching are 50°C, 4 h, 30% solids in leach slurry and an acid concentration of 1 mol/L for HNO, for both the ores. In the case of HCl, a 3 mol/L acid concentration is needed and addition of an oxidant is required because otherwise 230Th and 226Ra extractions remain poor.

Jan 1, 1990

By Helen Leung, Colin R. Phillips

The performance of personal alpha dosimeters in mixed radon daughter and thoron daughter atmospheres in Ontario uranium mines is described together with monitoring developments which enable the radon daughter working level to be determined separately. The theoretical bases for continuous and integrated working level measurements based on individual and gross counts are presented in terms of the weighting factor for combining the thoron daughter working level with the radon daughter working level, and in terms of the in-growth time of the air. Implications for the determination of working level in the presence of thoron daughters are discussed.

Jan 1, 1981

By T. E. Burns

The process engineer is frequently requested to select equipment to separate brine from solids, In many cases, this is a more difficult task than the selection of most other pieces of process equipment because quite often the operation of the various types of debrining equipment cannot be predicted by calculations, One must rely to a great extent upon experience or empirical test work to predict performance - that is to say one must use a practical rather than a theoretical approach. This is not to say that the solutions to liquid-solids separating problems are wholly an art but rather it is to emphasize that the approach demands a fair knowledge of commercially available liquid-solids separating equipment, some background on the advantages and limitations of each type and in many cases might necessitate a fair amount of test work, or at least, a study of performance of equipment on similar applications.

Jan 1, 1966

By C. E. Tackett

The Greenwich Collieries Co. is a subsidiary of the Pennsylvania Mines Corporation, and a wholly owned subsidiary of the PP&L Co. which serves the northeastern portion of Pa. PP&L annually consumes about 11 million tons of coal per year and is the largest consumer of both bituminous and anthracite coal on the eastern seaboard. Development work for Greenwich started in 1969. The coarse coal plant was constructed in 1970, with the raw fines bypassed. This worked very well for our requirements at that time; however, the Greenwich mining plans were extensively changed, longwall mining units were installed and low coal was encountered, resulting in dirtier coal, a finer coal and an ever increasing ash in the shipped product. All this demanded a more efficient ash removal process for the fine coal fraction. In 1971, the Pennsylvania Department of Environmental Resources and the Federal Environmental Protection Agency were pushing for the now stringent sulphur emission limits at our power plants. The Greenwich Mine coal reserves contained large quantities of 3.5 to 4% sulphur along with some low sulphur reserves. It was, therefore, essential that any new plant have the capability of efficient sulphur removal to meet the Pennsylvania Department of Environmental Resources and the Federal Environmental Protection Agency required limits. To meet these limits our design would have to be capable of producing a product of 2.0% sulphur or less.

Jan 1, 1977

By Richard Stoltz, Gary Smith

This paper presents the findings of a face ventilation investigation, conducted by the Ventilation Division, Pittsburgh Health Technology Center, at a underground coal mine operating in the Illinois No. 5 coal seam. The purpose of the investigation was to evaluate the effectiveness of a blowing face ventilation system in controlling methane liberation in the face area while mining with brattice distances up to a maximum of 40 feet from the face (extended cut). The continuous miner on this section was remotely controlled and equipped with a machine mounted dust collector. Data collected during this investigation included methane concentrations, intake and return air quantities in the face area, and scrubber air quantities. In addition, a time study was conducted to correlate the methane peaks to activities in the face area. In conjunction with the face study on Section A, separate methane liberation studies were conducted on three additional sections: B, C, and D. This was done in order to compare intake methane concentrations and methane liberations from other sections in the mine to the test section. Calculations indicated that the minimum intake air quantity necessary at the inby end of the line brattice for the section investigated was 7,000 cfm. Due to the higher intake methane concentrations and average methane face liberations measured on three other sections, the minimum air quantities necessary at the inby end of the line brattice were determined to be 13,900 cfm, 11,100 cfm, and 15,000 cfm, respectively.

Jan 1, 1991

By M. A. S. Martins, H. Medeiros, B. Y. B. Dos Santos

This paper contains the geometallurgical studies, performed for Mineração Rio do Norte bauxites, applied to a selected area belonging to Plateau Saracá III, referring to an exploitation period of one year and three months, approximately. It is worth mentioning that Mineração Rio do Norte has the biggest bauxite operation in Brazil producing 8,500,000 tons of concentrate per year. The studies included wide investigations directed to the final objective of establishing a precise mining and production planning, based on the different behavior of the distinct bauxite ores, when submitted to industrial processes. Geometallurgy can be defined as the study of the regionalization (space distribution) of the metallurgical variables of a mineral deposit. This study involves and integrates all process engineering, geology, geostatistics and mining planning, among others. The development and application of the geometallugical studies to Mineração Rio do Norte were motivated by several reasons and necessities, among them: 1. Improving the forecast of the amount of concentrate (metallurgical mass yield) produced; 2. Improving the equipment operational efficiency, providing a more homogeneous feed; 3. Conducting a more precise material balance that permits a better daily, monthly and yearly production control; 4. Improving the forecasts for the final products generated by each ore type; 5. Obtaining better knowledge of the behavior of several ore types, submitted to the different process unit operations; 6. Promoting adequate ore blending, producing an homogeneous feed during mining operation.

Jan 1, 1998

By F. M. Doyle, Jun Li, Milton E. Wadsworth, Ximeng Zhu, E. Peters

The electrochemical behavior of pyrite in borate/sulfate solutions was investigated using cyclic voltammetry. Three anodic peaks at approximately -0.8 V, -0.1 V and +0.5 V (SCE) were detected along with their corresponding reduction peaks. The first two peaks correspond to the oxidation of surface products. The third peak corresponds to the direct oxidation of pyrite with reaction products FeO oxides. sulfate ion and partially oxidized sulfur intermediates present as a surface film of polysulfides and So. The Few oxides and sulfur intermediates were reduced to ferrous hydroxide and HS during the negative-going scan. The HS interacted preferentially with Fe(OH), on the surface to form FeS. Excess fenous hydroxide continued to reduce to metallic iron. During the return positive-going scan, metallic iron was oxidized to ferrous hydroxide and FeS was oxidized to pyrite. These reactions are characterized by a unique double peak observed in the region -0.8 to -0.65 V. The growth kinetics of the surface sulfur film formed during anodic oxidation were studied using chronoarnperomeay. Potentiostatic measurements were well correlated by a paralinear rate equation, suggesting the formation of an intermediate passive film, associated with the simultaneous dissolution of the outer layer of the film. The reaction rates were affected by applied potential, solution pH and temperature, but were independent of electrode rotation speed. A reaction kinetics model which fitted well with experimental results, was developed.

Jan 1, 1993

By Louis W. Cope

Placer material, regardless of the value of gold, tin, titanium, diamonds or other value mineral it contains, remains worthless until the valuable constituent is separated from the bulk of the material. This separation is no mean task when considering that a gold placer containing 0.01 to 0.03 oz/yd3 of gold, which is the range of grade of typical placer deposits; yes, 1:3,000,000! It is a miracle that gold placer mining has ever been profitable. Added to the situation of minute quantities of gold are several other problems, such as the gold often being very finely divided, the association of boulders and clay, and running and/or ground water. As each placer deposit is individual and distinctive, many factors have to be considered in planning the method for gold recovery from the alluvial deposit. Previous chapters have shown that in the exploration and sampling stage, some knowledge of the amount of each size of coarse and fine material which occurs in the deposit as well as the size distribution of the discrete gold particles is determined. Unless informed to the contrary, as a general rule of thumb, plant designers will consider that 40 percent of the material will pass through a 5/8-inch screen or punched plate hole. Also that there may be an occasional nugget and normally considerable amounts of fine gold. The designer must

Jan 1, 1992

By Cherie M. Tilley

The Stillwater Mining Co. of Nye, MT, is operating a platinum-palladium mine that requires an extensive system of footwall laterals to facilitate mine production. The 10-year mine plan calls for more than 48,300 lineal m (160,000 lineal ft) of footwall lateral. A rapid tunneling and raising system is necessary to sustain mine production schedules and achieve production goals. This article describes the results of using a Robbins 4.1-m-diam (l3.5ft-diam) tunnel boring machine (TBM) to develop the footwall laterals and a Robbins RBM-6SP raise boring machine to develop raises at the mine. The Stillwater Mining Co is a partnership between Chevron Resources Co. and Manville Corp. Chevron Resources is the managing partner. When the mine began production in September 1986, the owners were primarily concerned with the actual production of platinum and palladium, the grade minable and the amount that could be mined. As mine development and mine production proved feasible, the owners considered higher production levels. The Stillwater Mine is developed by a system of adits (known as footwall laterals) that are driven parallel to the ore bearing zone. This led mine officials to consider using a mechanical boring machine in the primary mine development. Previously, tunnel boring machines have not been used successfully in mining applications. Therefore, the owners decided to purchase a used machine to reduce the potential risk.

Jan 1, 1991

By G. E. Tooker

This paper (1) presents new data on the use of horizontal curves to optimize the alignment of belt conveyors. The operating concept of a horizontal curve is simple. As an element of the belt passes through the curve, it is motivated to drift toward the center of the curve by unbalanced tension forces in the belt. This lateral drift is resisted by the forces of friction and gravity, which in turn can be stated as a function of drift. Resisting forces, as a function of drift, are stated in terms of variables such as the amount of load on the belt, and parameters such as the trough angle, tilt angle, and super elevation angle, and number of rolls in the idler. The trick is to determine that the belt will drift to a position of equilibrium within predictable limits, without physically constraining the edge of the belt. In practice this prediction is not easy to make without the aid of a computer. The motivating force is easy to calculate, but its value is continually changing throughout the angle subtended by the curve arc. The resisting forces are constant throughout the curve for a given drift and load condition, but the calculations are very complex. Data in this paper will assist the conveyor designer in making preliminary calculations for horizontal curves. Presented is the equation for calculating the motivating force, and a family of curves that show the resisting force as a function of lateral drift for some commonly encountered conveyor design criteria.

Jan 1, 1985

By J. R. Diehl, R. W. Lai, R. W. Hammack, S. U. M. Khan

Cyclic voltammetry (CV), flotation response, evolved-gas analysis (EGA), and X-ray photoelectron spectroscopy (XPS) were employed to evaluate the major differences in the surface property and surface reactivity of a selected coal pyrite and a mineral pyrite. Surface properties of pyrite were evaluated in terms of flotation response in the presence of both an anionic fluorosurfactant and sodium hydrosulfide. The charge transfer adsorption and oxidation potential of sodium hydrosulfide were evaluated using cyclic voltammetry. Drastic differences in the flotation response have been observed between the coal pyrite and the mineral pyrite. Significant differences in the cyclic voltammograms at pyrite surfaces of these two sources were also observed. Measurements by XPS and EGA were used to determine the oxidation products and the rate of oxidation of the coal-pyrite and the mineral-pyrite surfaces.

Jan 1, 1991

By G. I. Voiloshnikov, V. E. Dementyev

Wide use of adsorption methods for metal recovery is one of the most important achievements of gold metallurgy of the last decades. Anion exchange resins or activated carbons may be used as adsorbents. This paper presents a brief overview of IRGIREDMET effotts on development, testing and implementation of techno­logical flowsheets using both adsorbent types and attempt to compare their technological properties. IRGIREDMET Institute was founded in 1871 as a laboratory for gold smelting and gold ore testing. In 1930 it obtained the status of the Research Institute. IRGIREDMET functioned as leading research center for gold mining industry in the former Soviet Union. At present it is the Open Joint Stock Company dealing with all s01t of research and design works for gold min­ing (ranging from geology to gold refinery). IRGIREDMET started development of ion exchange technol­ogy in 19641• The first stage of work (1964-1970) including development of principle flowsheet of RIP process was carried out jointly with the Moscow VNIIKHT Institute (All-Russian Scientific Research Institute of Chemical Technology)2• The flowsheet of RIP process is presented in Fig. I and includes the following basic operations: gold adsorption from pulp; washing of loaded resin; acid treatment; thiourea adsorp­tion; gold elution by acid thiourea solution; resin washing to remove thiourea; alkaline treatment of resin; resin washing and gold recovery from eluates by electrowinning. The technology developed and equipment used were tested for treatment of clayey ore of Kuranakh deposit at a pilot plant of the Lebedinsky gold complex ("Aldanzoloto" company, Yakutia, Russia). The pilot plant throughput was 200 t/day. At the same time IRGIREDMET conducted the tests on ion exchange technology for ore and concentration products of oper­ating gold plants and for ores of new deposits. Laboratory and pilot plant tests were done and developed initial data and process design criteria for designing of 15 plans of the former Soviet Union. In the course of this work a great number of newly synthe­sized anion exchangers including strong and weak base resins was studied, the peculiarities of anion exchange resins using two different raw material types ( ores and concentrates includ­ing clayey, carbonaceous, silver bearing, arsenic, antimony and base metals bearing products); some theoretical regularities of adsorption process were investigated; the technology of two stage adsorption of gold and silver from silver gold ore, improved flowsheet for gold elution and resin regeneration, design of adsorption equipment including pulsation columns, design of electrowinning cells were developed; conditioning technology for pulp with complex ion composition prior to gold and silver adsorption was developed, etc.3·8• IRGIREDMET specialists took part in commissioning of practically all the plants in the former Soviet Union using RIP and RIL process including Lebedinsky, Kuranakh, Sovetsky, Karamken, Matrosov's plant and Mnogovershinny plants. Due to this works RIP process became standard technology for Russia and the CIS.

Jan 1, 1998

By Ethan B. Eilertsen

Titanium solves corrosion, maintenance and environmental problems in many reactor and autoclave applications. Titanium clad construction permits autoclave designers a great deal of flexibility combined with significant cost reduction. Titanium alloys can be selectively applied in specific regions of the autoclave to accommodate local environmental conditions. Resistance to general corrosion, crevice corrosion, abrasion, and ignition conditions can be accomplished selectively and economically. Explosion clad pressure vessel fabrication and performance have been proven through three decades of experience.

Jan 1, 1997

By Wilbur J. Morin

Construction of Flaming Gorge Dam in northeastern Utah necessitated the construction of a new state highway, Utah-260, to provide access to the dam and the town of Dutch John. A 550-foot arch structure was designed to span Cart Creek, about one mile southwest of the dam. The rock exposed at the site is highly fractured quartzitic sandstone with interbedded shale of the Precambrian Uinta Mountain Group. Eight exploratory holes were drilled, four in each abutment area, to determine rock types, the extent of fracturing at depth and rock strength. Drill cores in the west abutment revealed blocks of quartzitic sandstone loosened by the weathering and partial removal of underlying shale beds. The rock in the east abutment area was found to be highly fractured to depths of 70 feet and as far east as 50 feet from the footing locations. Selected core sections were tested for unconfined compressive strength but the values were not considered-representative of the in-situ fractured rock. To prevent movement along or, perpendicular to open fractures, four drilled-in columns were provided at the base of each footing. These extended 50, feet beyond the base of the footing, along the bearing and inclination of the thrust reaction.

Jan 1, 1963