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By Charles H. Rice

Coal liquefaction processes can be divided into two broad classifications - direct and indirect. Direct liquefaction processes, in general, slurry coal with a solvent and react it with hydrogen under elevated temperature and pressure. Indirect liquefaction is the term applied to processes in which coal is first gasified to generate a synthesis gas of carbon monoxide and hydrogen. The synthesis gas is then converted to various types of liquid fuels by the proper selection of catalyst and conditions. The first experiments on direct coal liquefaction were undertaken in 1933 by Bergius. Development and commercialization of the Bergius concept was accomplished mainly through the effort of I.G. Farben at the Ludwigshafen plant of its subsidiary, Badische Anilin und Soda Fabrik A.G, under the leadership of M. Pier (1). A demonstration plat having an annual capacity of 100,000 tons of coal was built in Leuna, Saxony in 1927. Six years later, Imperial Chemicals Industries, Ltd., commissioned a plant in Billingham, England (2).

Jan 1, 1981

By F. Touboul, M. Thiercelin, K. BenNaceur

Introduction The need to develop accurate predictive hydraulic fracturing simulators arises from the consideration of vertical containment for the fracture. Fracture height growth from a pay zone into adjacent layers has been shown (see Cleary [I]) to depend on three sets of parameters for the different strata: - elastic properties, - closure stress variations, and, -fracturing fluid leak off, and poro-elastic stresses. Qualitative analysis of the effects of these parameters has been reported in the literature. The first effects were described by Van Eekelen, using simple elasticity considerations [2]. The effect of stress variations was described numerically by Simonson and a1. [3] and experimentally by Thiercelin [4]. Effects of back stresses induced by fluid invasion on fracture propagation were considered by Cleary [5]. In order to couple these effects, a numerical code al- lowing the simulation of three dimensional growth of a hydraulically induced fracture has been developed with the ability of representing the effects of heterogeneities on fracture lateral and vertical extension. The model is based on a new variational formulation of the boundary integral representation of three-dimensional elasticity. The fluid flow and elasticity equations are solved using a moving mesh representation which offers enough flexibility to enable the simulation of any closure stress distribution. Simpler models representing fracture height growth (P3DH models) have been developed [6] [7] that approximate the fracture by a series of one dimensional segments, and the limitation of such approaches is examined in this paper. 1 Description of the model 1.1 Fracture Geometry Hydraulic fracturing simulations involve the coupling of solutions to elastic deformations, fluid flow in the fracture, and fluid leak off into the formation. Since the use of direct solution techniques (i,e,,3D finite elements) is prohibitive, the method used in this study is baaed on a boundary integral representation of the 3D elasticity equations. 1.2 3D Models The classical representation of the problem of a fracture in an infinite medium by boundary integrals is [8]: [ ] where u is the unknown displacement field, r n is the traction operator, I? is the fracture surface, and K is the Kelvin tensor of fundamental solutions to the elasticity operator. Using the notation: [ ] for the displacement discontinuity (or fracture width), one can attempt to solve the boundary integral relation using surface integrals (91 or the displacement discontinuity technique, first introduced by Crouch [lo], and extended to three-dimensional problems [Ill. However, numerical problems arise since the Kelvin tensor has a singularity in

Jan 1, 1986

By Hajime Miki, Michael J. Nicol

Relatively simple techniques have been developed which enable the electrochemistry of sulfide minerals to be studied with particles varying in size from above 100 pm to less than 1 pm. Both oxidative and reductive processes have been studied wing the minerals pyrite, arsenopyrite and chalcopyrite. It has been shown that it is possible to completely oxidise or reduce the minerals during a single voltammetic sweep. The resulting voltammogram produces peaks which are characteristic of each mineral and can be used to qualitatively identify the minerals. In the case of chalcopyrite, it has been demonstrated that the charge involved in the anodic oxidation can be quantitatively related to the amount of copper dissolved. Quantitative information can be obtained using peak fitting techniques. Interesting differences in the behaviour of the minerals in sulfuric and hydrochloric acids have been observed, particularly in the case of pyrite for which a second major peak is obtained which has been attributed to the oxidation of elemental sulfur in the presence of chloride ions. The technique offers the possibility of providing mineralogical information of individual particles based on an electrochemical voltammetic finger print.

Jan 1, 2005

By A. P. Schissler, S. Badr, U. Ozbay, M. D. G. Salamon

Yield pillars are used in deep coal longwall mines, where the depth of cover is so great that a conventional chain pillar design tends to be unsuccessful. The design of yield pillars in deep U.S. mines has been based mainly on experience, pressure arch theories, numerical modeling, and empirical methods that originated in the eastern U.S. coal mines. This paper offers field experience based guidelines for the design of yield pillars through analysis and evaluation of numerous case histories. Case histories of yield pillar applications were collated and critically reviewed to identify trends in data that can be used to formulate the design guidelines. Convincing trends observed in the case of successful case histories indicate that yield pillars should have a width to height ratio in the range from 2.8 to 6.0, a stability factor during development between 0.4 and 0.6, and shed between 94% to 98% of the cover and abutment load, as provided by the Carr-Wilson (1982) method. Also, yield pillars should be utilized in coalmines only where the roof and floor rock have a CMRR rating of 50 or better.

Jan 1, 2003

By R. K. Steinhorst

Multivariate cluster analysis, MANOVA, canonical analysis, and discriminant analysis of hydrochemistry data were used to investigate the directions of ground water movement in basalts in the vicinity of the Hanford Reservation, Washington. The statistical analyses indicate that the hydrochemistry of the ground waters in these basalt formations is distinctly different on each side of the Columbia River. This suggests that the river is a ground water divide or that the river is roughly coincident with a hydrogeologic barrier boundary. The statistical procedures used in this study constitute a quantitative means for differentiating ground waters according to hydrochemistry.

Jan 1, 1990

By Ron M. Canon, John M. Begovich

Chromatography, ion exchange, and other techniques based on the interaction of solutes with solid phases offer versatility, high resolution capabilities, and near-universal potential applicability for the separation of valuable constituents in liquid solutions. The expense associated with obtaining reasonable throughput for these separations has been the only, albeit overwhelming, obstacle preventing widescale use of these methods. Attempts to devise continuous (cheaper) systems have previously resulted in moving, or simulated moving, beds of resin with complicated valving and timing sequences. These disadvantages, plus technical problems associated with the disturbing effects of non-plug flow and reduced resolution of moving versus packed beds, severely limit applicability of these systems. Over the past decade a new device has been developed that overcomes many of these problems. It utilizes a slowly (less than one revolution per hour) rotating annular bed of sorbent material with fixed-feed inlet and product withdrawal points. Numerous units of various diameters and lengths have been fabricated and operated, and a parallel effort has developed a satisfactory theoretical treatment of the device. Several simple control systems have been incorporated to thoroughly demonstrate the simplicity of operation, even for multiple products and multiplecarrier flows. This device has been developed using several metal solutions and has demonstrated its power with some of the most difficult, including the zirconium-hafnium, separations. Design equations are available for sizing units based on simple laboratory data and have been tested for units as large as 18 in. in diameter.

Jan 1, 1985

By B. H. Johnston, B. N. Doyle

Introduction In 1983-84 Kidd Creek Mines Ltd. in Timmins, Ontario, started up the second commercial zinc pressure leaching plant based on the Sherritt Gordon Mines Ltd. direct pressure leach process. The first plant using this process was that of Cominco Ltd. at Trail, B.C. (Parker, 1981; Martin and Jankola, 1985). The Kidd Creek plant was constructed to take advantage of the extra capacity that the existing purification, cell house, and casting sections had in comparison to the roasters and acid plant. In addition, pressure leaching offered flexibility in other areas such as treatment of low grade concentrates. The process design package and the detailed design of the autoclave system was carried out by Sherritt. The detailed design for the rest of the plant was done by Cambrian Engineering Ltd. under the direction of Kidd Creek. The construction and commissioning of the plant has been described earlier (Johnston, 1983). This paper describes, briefly, the application of the direct pressure leaching process for zinc concentrates and the integration of the pressure leaching plant into the main zinc plant at Timmins. It discusses some of the startup problems and changes made to the plant. The damage following a fire inside the autoclave is also described. The subsequent repair and recommissioning of the autoclave has enabled Kidd Creek to demonstrate the originally sought advantages of pressure leaching and to take advantage of their extra cell house and casting capacity to produce more zinc. Process principles The development of the direct pressure sulphuric acid leach of zinc sulphide concentrate at temperatures above the melting point of sulphur and at elevated oxygen pressure has been described in detail in a number of papers (Martin and Jankola, 1985; Johnston, 1983; Veltman and Bolton, 1980; Kawulka et al., 1975; Veltman et al., 1977). The most significant aspect of the process is that sulphidic sulphur is converted to elemental sulphur in reactions that can be simply described as follows. ZnS + H2SO4 + 1/2 O2 ZnSO4 + S° + H2O (1) FeS + H2SO4 + 1/2 O2 FeSO4 + S° + H2O (2) The rates of these reactions increase with temperature. However, at temperatures above the melting point of sulphur, 12°C, the presence of a surface active agent is necessary to prevent the occlusion of the sulphide particles by elemental sulphur and the consequent termination of the leach. The zinc that is dissolved according to reaction (1), after purification of the zinc sulphate solution, is recovered by electrowinning. The iron that is put into solution according to reaction (2) is further oxidized to the ferric state and subsequently, as the acidity decreases, precipitates as hematite or as complex basic sulphates. MINERALS AND METALLURGICAL PROCESSING Examples of this are shown below. 2FeSO4 + H2SO4 +1/2O2 - Fe2(SO4)3 + H2O (3) Fe2(SO4)3 + 6H2O - Fe2O3.3H2O + 3H2SO4 (4) 3Fe2(SO4)3 + 14H2O - 2(H3O)Fe3(SO4)2(OH)6 + 5H2SO4 (5) (hydronium jarosite) The conventional zinc process involves concentrate roasting to produce zinc oxide and sulphur dioxide. The zinc oxide is leached in spent electrolyte and the sulphur dioxide is converted to sulphuric acid. The pressure leaching process can, therefore, be used to replace conventional concentrate roasting, sulphuric acid manufacture, and atmospheric leaching with one unit operation. Integration of pressure leaching into the Kidd Creek flowsheet A block flowsheet of the Kidd Creek zinc plant, with the new pressure leach plant integrated, is shown in Fig. 1. The original plant, which was constructed in 1972, is based on standard electrolytic zinc plant technology. Concentrates are dead roasted to remove sulphur. Sulphur dioxide is treated to produce sulphuric acid. Calcine is leached in two stages using cell-house electrolyte. Iron is precipitated as jarosite and solutions are purified to remove copper, cobalt, nickel, and cadmium to provide feed for a partially mechanized cell house. Zinc is plated from solution, and the resulting cathode is melted, cast, and sold (Johnston, 1983). The integration of the pressure leaching plant into the main zinc plant is relatively simple. As shown in Fig. 1, a fraction of the zinc concentrate and spent electrolyte are fed to the pressure leach autoclave, while part of the calcine from the roaster is used as a neutralizing agent in the oxidation step along with. the jarosite leach solution. The main exit stream from the pressure leaching plant is the slurry discharged from the oxidation step, consisting of neutral zinc sulphate solution, unreacted calcine, and precipitated iron oxides. This slurry is transferred to the neutral leach step in the main zinc plant. The leach residue from the pressure leaching step, consisting of basic iron sulphate and elemental sulphur, is washed and impounded along with the jarosite residue produced in the main plant.

Jan 1, 1987

By Michael Schultz, Gregory Sanders

The City of New Haven is proposing to construct Downtown Storm Sewer Infrastructure Improvement project to mitigate on-going stormwater flooding in the Long Wharf District. The proposed project includes a 200 cubic feet per second (cfs) stormwater pump station; and a 914 meter (3,000 linear feet) long tunnel segment with an internal diameter of 2.1 meters (84-inches). The tunnel alignment will cross under the Long Warf railyard and then continue parallel to the Vison Trail Route. This paper presents the local geology and subsurface conditions, as well as discusses the major project challenges and risks including construction in soft marine soils and encountering remnants of the former wharf.

Jun 13, 2021

By M. Gunter, M. Buzon

"Talc formed by hydrothermal alteration of preexisting carbonate rocks is known to be nearly monomineralic, and lacking in amphiboles. In southwest Montana, talc formed from hydrothermally altered dolomitic marbles, and is still actively mined. These talc deposits are typically in contact with quartzofeldspathic gneiss and marble. Accessory minerals vary between these rocks and the ore producing body; the identification and characterization of such minerals requires carefully selected analytical methods. Recent litigation and ensuing confusion over the petrology and asbestos content of these deposits challenges the talc mining industry in Montana, and elsewhere in the world. INTRODUCTION Commercial talc has been mined from the deposits in southwest Montana since the 1940s, and by 1956 the region had output 200,000 tons of talc ore (Chidester et al., 1964). Commercial talc refers to rocks containing more than 20% of the mineral talc (McCarthy et al., 2006); the ores from Montana typically contain upwards of 90% talc. This region remains the leading domestic source of talc in the U.S. partly due to the reserves in the area, and partly due to the diagnostic purity of the ore compared to that of other regions, some of which are no longer actively mined. The mineral talc, a sheet silicate, is expressed by the formula Mg3Si4O10(OH)2, and therefore can form in geologic environments that are rich in Mg, Si, O and water. The protolith for the talc deposits in southwest Montana is a dolomitic marble, but other common protoliths include ultramafic igneous, mafic igneous, and siliceous dolomites (McCarthy et al., 2006). Physical properties such as hardness of 1 on Mohs hardness scale, white streak and slippery feel are among some of the reasons why talc is so widely used as fillers in a number of industries. In decreasing order, ceramics, paper, paint, roofing, plastics, rubber, and cosmetics are the leading domestic industries that use talc despite the decreasing trend in U.S. talc use and production since 1994 (Virta, 2015). The purpose of this paper is to describe the mechanism of talc formation in southwest Montana by focusing on talc deposits and surrounding rocks in the Ruby, Greenhorn, and the Gravelly Ranges, and to relate the mechanism of formation to the composition of talc ores. The compositional data show mineral content of selected ores, and the major and trace element content of those minerals, specifically talc. Our electron microprobe (EPMA), powder x-ray diffraction (XRD) and x-ray fluorescence data for samples from five mines in these three ranges provide continued evidence of the purity of these ores despite claims made during recent litigation that these ores contain asbestos. The five mines that we discuss include the Beaverhead, Treasure, Regal, Willow Creek, and Yellowstone Mines (Figure 1.)"

Jan 1, 2016

By Fred W. Stuart

Microprocessor technology has revolutionized the business community by placing tremendous computing power in the hands of the end-user for a very inexpensive price tag. The range of applications covers process control, to office automation, to personal computing capabilities. With the influx of this new technology, which these systems have to offer, also comes some unique operational and control considerations. But before we address these items, let us lay a foundation of common terms to be used throughout this presentation. Due to the rapid advances in microprocessor technology, where a new generation of computers is announced every two or three years, it becomes difficult to define a microprocessor system and have it valid for an extended period of time! Therefore, for this presentation, we will be dealing with a subset of microprocessors called Personal Computers or PC's. At the heart of a PC is a Central Processing Unit or CPU. The CPU performs the actual program and command execution. The programs dealing with driving the various peripheral equipment is referred to as the Operating System (for example: DOS : Disk Operating System, CP/M - Control Program/Microcomputers, etc.). The CPU is normally housed in an enclosure which contains power regulators, peripheral equipment interfacing 'cards', and expansion 'slots' to enlarge the capabilities of the PC system.

Jan 1, 1989

By George P. Demopoulos, Vladimiros G. Papangelakis, Dimitrios Filippou, A. J. Monhemius, G. W. Warren, E. Peters

A new method developed for the estimation of the activity of Ht in mixed sulfate solutions is described and examples of application of this method to the system H2SO4-ZnSO4-FeSO4-Fe2(SO4)3 from 298 to 473 K are offered. The method makes use of an "extended Debye-Hiickel" type of equation that was originally put forth by Das for pure H2SO4 solutions at ambient temperature. The treatment of mixed sulfate solutions was made possible by combining that equation of Das with a speciation algorithm which calculates the abundance of all species formed. The developed method, which also takes into account ionic strength and temperature effects, was used to generate hydrogen ion activity and speciation data for all possible acid/metal sulfate pairs of the system H2SO4-ZnSO4-FeSO4-Fe2(SO4)3. Finally, under the light of the reported data, specific examples of hydrometallurgical reaction systems are analyzed in terms of thermodynamics or kinetics. In particular, the systems discussed are: hydrometallurgical precipitation of hematite, solvent extraction of Fe(III), acid leaching of zinc ferrite, and oxidation of Fe(II) to Fe(III) by O2(aq).

Jan 1, 1993

By C. Bazin

The fundamental error associated to the sampling of heterogeneous ore particles is unavoidable and can only be minimized by an adequate selection of the sample mass and/or size reduction of the sample before division into sub samples for testing or assaying. The preparation of ore batches to carry out the mineral processing evaluation of an ore is a sampling process. The fundamental error associated with the division of the ore into batches is responsible for the differences in the composition of the batches. This paper attempts by various means to assess the reproducibility of the gold content of test batches prepared from a gold ore sample. The results of the investigation shows that for fine gold grain sizes the variability in the composition of the batches is less than that predicted by Gy?s formula and that the gold grain size is a strategic information in the assessment of the gold content variability of test batches.

Feb 23, 2014

By J. Schleifer

On short term, planning techniques require more details to ensure feasibility, giving importance to operation constraints and use of available resources. In GUEMASSA (Morocco), the ore mass is mined by cut-and- fill method. Correct organization requires to forecast a few weeks ahead the schedule of blocks to be mined, in order to respect ore quantity and grade constraints. While operating constraints are tackled, feasibility is assumed with an average production capacity suggesting that resources will be available. In ST-SALVY (France), scheduling operations is not possible if not considering account resource allocation. In any stope within the vertical vein zinc deposit, the cut-and-fill method enables to mine each horizontal slice according to various strategies, de- pending how to use manpower and equipment, and selecting among predefined scenarios known as realistic. For KOFFIEFONTEIN (South Africa), the kimberlite pipe is mined by a sub-level-stoping method. To achieve the production target, precise organization over one month is obtained, using on& resources when available and respecting all mining rules. This combined operation scheduling and resource allocation is called sequencing. While following the BONANZA concept, providing a planning- retrieval process, sequencing offers more. Very detailed, it is possible to check the impact of resource parameters and mining rules. The sequencer, like a simulation platform, enables expertise. Each sequencer must be tailor-made to fit to each specific mine. The next challenge is to produce a generic environment.

Jan 1, 1996

By E. S. Bianchin

The more complex control needs of today's mineral processing plants combined with ever-changing digital technology have brought numerous improvements to process control systems. This paper discusses recent advancements in distributed control systems (DCS) which facilitate the implementation of process plant automation. Some of the topics of discussion include integrated function controllers, weigh scale and analyzer interfacing, operator interfacing, personal computers, process information management and process plant management.

Jan 1, 1988

By N. Nemeth

The filter is an apparatus designed to hold the filter medium. At such a medium takes place the entire liquid-solid or gas-solid separation process. Hence, the medium is really the essence of filtration. Yet, the medium, an originally clean porous substance with trapped solids in it, is perhaps the most neglected part of filtration research. Basically three problems prevail at the medium: 1) Penetration of solids and their blinding of the medium and the influence of such blinding on the resistance to flow. ii) The behavior of the medium in long term repetitive filtration. iii) The filter effect phenomenon whereby the flow rate on filtering an apparently clear liquid through a medium decreases with time. This study undertakes to investigate these fundamental processes.

Jan 1, 1968

By Robert F. Jones

INTRODUCTION Upflow Solids Contact Clarification is a process long employed in the treatment of potable water, wastewater and municipal sewage. This process incorporated in a fiberglass conical structure seems to offer an economical solution to problems encountered in reduction of particulates in uranium effuents. CONCEPT OF UPFLOW CLARIFICATION Use of suspended solids contact units date back to the 1930's. These types of units produced by Infilco and the Permutit Company, among others, were used in the Lime-Soda softening process to precipitate calcium and magnesium salts from hard water. In general, the process operated as follows: (a) Raw water entered a central chamber where it was mixed with chemicals. The chamber had provisions for agitating and circulating the chemicals so that mixing and reaction zones were formed. (b) The water, precipitated chemicals, floc and turbidity flows to a clarification chamber (the Permutit precipitator used a truncated cone). In most cases the influent then passes upward through a blanket of suspended floc and other solids before it leaves the chamber at effluent weirs or launders.

Jan 1, 1984

By Jim Finley, Adam Bedell, Eric Schrader

The CSO 52 Storage Tunnel and Pump Station project consists of 4,700 ft of hard rock tunnel, 2 intakes, and a 4 MGD wet pit pump station. During the geotechnical investigation, it was determined that the host geology contained abundant suldes. The purpose of this paper is to detail the investigation and subsequent determination that acid producing materials would affect the project during construction as well as long-term exposure of tunnel lining and permanent components during the operational life cycle of the tunnel and pump station. Details regarding the interaction between tunnel components and the acid producing material are also provided.

Jun 23, 2024

The effect of the chemical composition of pulverized bituminous coal particles on their physical transformation during the initial stages of combustion has been investigated. The results suggested that cenosphere formation does not require extensive thermal decomposition of the coal particles. The vitrinites in the bituminous coal softened earlier and developed larger cenospheres than the othe macerals. The coal particles swell to a higher extent during combustion than in pyrolysis; however, the cenospheres formed in the former process experienced a higher extent of fragmentation. The development of microporosity occurred predominantly after the resolidification of the swelled char particles. The type of macerals originally in the coal did not significantly affect the microporosity of the chars. Conversely, the morphology and anisotropy of the chars were strongly dependent on the maceral composition of the coal.

Jan 1, 1986

By Louis M. Schlesinger

KMG Minerals, Inc., a mica-feldspar-quartz producer in Kings Mountain, N.C., uses about 50% of its plant's -200 mesh slimes to manufacture brick. However, the company is unable to market the remaining 50% of this fine mineral mixture. The NCSU Minerals Research Laboratory operated a pilot plant to process these slimes to produce an additional product. The process, consisting of blunging and hydraulic sizing, was designed to separate a kaolin-enriched -270 mesh product from the bulk of the coarser +270 mesh "grit" minerals. Size analysis showed that this product was 80% finer than 20 microns and 50% finer than 6 microns (in equivalent spherical diameter). An evaluation indicated that it is a hydrous aluminum silicate that might be suitable in the filler and extender markets for traffic paint, some types of plastics, joint cements, and dusting compounds. Because of its high viscosity, it will be difficult to use more than a small percentage in cast ceramic bodies. However, it might be possible to use up to 10% in extruded ceramic bodies (i.e., electrical porcelain). The 15.2 cm (6 in,) diameter Linatex Hydrosizer was tested using a range of teeter water flowrates, so that the net rise velocity was varied from 0.10 cm/s to 0.40 cm/s. The solid feed rate to the sizer was maintained at approximately 1.1 t/hr/m2 (0.12 ton/hr/ft2). Tests were run using both "shallow" (i.e., 6 in.) and "deep" (i.e., 15 in. teetered beds. The best overall result was obtained when the sizer was operated with the "deep" teeter bed and a net rise velocity of 0.10 cm/s. About 97% of the +270 mesh material was rejected and approximately 79% of the -270 mesh material was recovered in a 14% solids slurry.

Jan 1, 1994

By Philip A. Bucci

The Florida phosphate industry successfully uses froth flotation to concentrate phosphate in: the particle size range of approximately 28 to 150 mesh. However, as recently as 1965, coarse particles in the range of 14 to 28 mesh generally had not been beneficiated by conventional flotation methods at recoveries high enough to be considered adequate. It has been customary to upgrade this coarse material; by "agglomerate flotation" or "skin flotation" using belts, tables or spirals. While these devices have proved commercially effective, their capacities are much lower than those of froth flotation cells. To determine whether coarse phosphate material could be recovered successfully by froth flotation, Armour Agricultural Chemical Company began a series of pilot and plant tests; in April 1965. Objective of the tests was to compare over-all performance of a froth flotation cell design relatively new to the phosphate industry with results from the belt circuit at the Bartow, Fla., plant.

Jan 1, 1966