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By K. K. Kelley

"INTRODUCTION The Bureau of Mines nitrogen peroxide process (2) 3/ for extracting manganese from low-grade ores is essentially a two-stage process involving the reversible reactionMnO2 + 2NO2 + 6H2O = Mn (NO3)2 . 6H2O (1).At lower temperatures this reaction proceeds to the rigth and affords a means of dissolving manganece and separating it from unreacted ore. At higher temperatures the reaction proceeds to the left and manganese dioxide is recovered and nitrogen peroxide regenerated for recycling. Evidently, therefore, the energy required for decomposition of manganous nitrate is a matter of practical importance. Similar information for certain other nitrates also is desirable beceuse the nitration step of the process produces appreciable amounts of nitrates of other metals, such as iron, aluminum, magnesium, calcium, and barium, some of which are not broken down in the evaporation and decomposition steps. Thus, a portion of the nitrogen peroxide is not directly available for recycling. Whether or not it is feasible to recover nitrogen peroxide locked in the more-stable nitrates depends partly on the energy required and the conditions necessary for their decomposition.To supply information bearing directly on these subjects, several researches were undertaken at the Pacific Experiment Station: (a) Heats of formation (24, 25, 26) of nitrates of manganese, magnesium, calcium, barium, and aluminum were measured at 298.2° K:; (b) low-temperature specific heats (23), in the range 51° to 298.2° K,, and entropies of nitrates of magnesium, calcium, barium, and aluminumm were determined; and (c) heat contents (21) above 298.2° K. of the nitrates of manganese, magnesium, calcium., and barium were measured. The results of these studies, when correlated by thermodymamic methods, permit evaluation, at any temperature of interest, of the energies required to decomposethe nitrates and furnish information concerning the equilibrium pressure temperature relationships."

Sep 1, 1944

By G. Akdogan, I. J. Geldenhuys, Q. G. Reynolds

Efficient recovery of titanium from titaniferous magnetite ores continues to be a promising, yet unrealised opportunity, despite significant occurrences of titaniferous magnetite deposits worldwide and the existence of established industrial-scale practices. Current smelting processes only recover iron and vanadium, while the titanium is discarded in the waste slag. These slags are stockpiled and present massive environmental challenges, while still containing value as residual iron, vanadium and titanium. The complex mineralisation of these deposits does not allow for a significant opportunity to separate the titanium and magnetite minerals through normal physical upgrading processes. An upgrading process is therefore required to derive economic value. An efficient process technology could create an opportunity to unlock all three valuable commodities. South Africa’s Bushveld Complex, the largest known deposit of its kind in the world, is known for the high vanadium content but is also associated with relatively high concentrations of titaniferous magnetite. The quality of the Bushveld Complex was one of the drivers for the establishment of the Highveld Steel and Vanadium Company in the mid-1960s. The unfortunate demise of Highveld Steel and Vanadium created an opportunity to review current practices and evaluate the best available process for this complex ore in the context of the three elements of interest. Past and current processes, the nature of these deposits and the potential to recover titanium are assessed to highlight the potential of fluxless smelting of titaniferous magnetite to produce a titania-rich slag as feedstock to the pigment, titanium metal industry in conjunction with recovery of iron and vanadium. Ilmenite smelting practices are proposed as a suitable alternative to achieve the goal, namely sustainable processing. Keywords: Titaniferous magnetite, titanomagnetite, smelting, titania slags, comprehensive processing

Jan 1, 2020

By S. Fitzel

The Betts process for electrorefining of lead has been in operation since 1902 in the Trail Operations Metallurgical complex. The Betts process allows production of high purity lead in a single electrochemical step. Process improvements and plant expansions have taken place over the many decades of operation of this process which has proven to be robust, flexible, and capable of successfully treating a large range of anode bullion compositions. This paper reviews the history of the Betts lead electrorefining process, the innovations and quick industrial adoption of new discoveries that took place at the end of the nineteenth century. The process was first implemented in Trail Operations and integrated very well with metallurgical needs then and now.

By Carl Belser

Approximately 30 million pounds of tungsten trioxide in the form of ferberite concentrates have been shipped from Boulder County. Since 1940, the production has varied considerably, being affected by the emergency needs of World War II and the Korean conflict. During World War II, attempts to stimulate production were made by the Metals Reserve Company by stabilizing the price for a specified period, the Reconstruction Finance Corporation by small mining development loans, and the Bureau of Mines and the Geological Survey, who cooperatively explored some of the district by surface and underground core drilling. During the Korean conflict and continuing through the first half of 1954) tungsten production was being stimulated by a Government-gauranteed price and by financial assistance loans under the Defense Production Act of 1950 to qualified operators of properties that have merited exploration. This combined program has increased production in Boulder County from about 1,900 pounds in 1949 to an estimated 383,000 pounds of tungsten trioxide in 1953. The 1953 production came from 67 properties. One of the problems confronting producers is the need for improved beneficiaton methods. Ores from the area have not been amenable to flotation concentration and gravity methods have resulted in poor recovery, often less than 70 percent.

Jan 1, 1955

By D. Prince, G. Nollet

"Since 1994, Aur Ressources has operated Louvicourt mine, a zinc and copper mine close to Val d’Or, at a rate of 4300 t/d. Ever since the start-up of the plant, management has encouraged innovative approaches in reliability. The first of three papers will discuss the vibration monitoring program in place. The program will be described and two examples will be given: detection of a rolling bearing defect on a pinion driving the ball mill and identification of wear on the bearings of the flotation cells. Figures on the return on investment and the costs of a monitoring program will also be given.The second article will discuss the lubrication aspect. Since the establishment of a good monitoring and oil analyses, Louvicourt mine decreased its oil consumption by more than 38 000 L/yr. In addition, the company set up an oil regeneration system that restores the original properties of oil.The third article will cover the management aspect. Work organization as well as the management philosophy enabling the employes to push predictive technology to higher levels will be examined in detail. The key elements which made it possible for Louvicourt mine to position itself among world-class companies in the organization of maintenance will be discussed."

Jan 1, 2002

By G. Wren

As base metal sulphide resources become increasingly challenging to process, producers seek alternative options to treat concentrates. This study considers the mineral, elemental, and leaching character of a West Australian nickel sulphide deposit (Cosmos Nickel Project). After a brief review of the published work bench top leach tests were conducted to examine the factors which impact the kinetics of nickel sulphide leaching such as particle size, temperature, acid strength and type, concentration of copper sulphate and sodium chloride, and oxygen partial pressure. The effect of sodium chloride was considered due to the common occurrence of hyper saline water at West Australian nickel sulphide mine sites. Ultrafine grinding to an 80% passing size of 10 µm resulted in high nickel leaching efficiency. Moreover, higher concentrations of acid, copper(II) and sodium chloride also gave higher nickel and cobalt leaching efficiencies but arsenic precipitated as FeAsO4. Under the most suitable conditions the extractions of nickel, cobalt and arsenic at 90oC after 6 hours were >95%, 90% and <5%, respectively. The comparison with results from high pressure operations indicates the possibility of using a hydrometallurgical flowsheet based on fine grinding and atmospheric pressure leaching and warrants further investigations.

Jan 1, 2014

By Amanda R. Parry, Chris R. Pray

Predicting and modeling the soil structure interaction of laterally loaded piles with significant unbraced lengths is one of the challenges faced in designing many waterfront structures. Designers often rely on pile specific design software to calculate forces in an embedded pile and then couple that with either a structural design software to capture the behavior of the rest of the structure or use potentially overly conservative assumptions to omit modelling the piles entirely. Given that some projects have hundreds of piles coupled with hundreds of loading conditions, the shuttling of results from the structural analysis software into the pile analysis software can become cumbersome, difficult to track and manage, and prone to user input errors. An alternative approach recently used on two large marine infrastructure projects consisted of calibrating a structural analysis software to replicate the resultant outputs from a software developed specifically for pile analysis. This calibration was done using thoughtfully placed springs along a pile modeled in the structural analysis software to replicate the soil-structure interaction of the piles. The focus of this paper will be on the methodology used to calibrate the two software programs and an evaluation of the results which showed close agreement. Based on the two case studies, calibrating a generic finite element analysis software via this method should be considered as a reasonable and time saving design approach for pile-supported structures.

Sep 8, 2021

By O. D. Maurice

Feldspar mining in Canada came to an end during 1972 after many years of continuous activity. The deposits are not exhausted and the domestic demand for this product is expected to continue at about the same level as in recent years. The size of the industry does not justify the installation of expensive equipment in the mills, but it is believed that a modest profit could be made by a small operation using rudimentary methods of separation. Largescale and accurate mapping of the pegmatite dykes could help in planning mining operations for a better recovery of a uniform product.

Jan 1, 1973

By W. W. Adams

Coal mining in the United States, had a somewhat higher death rate per million man-hours of exposure among the employees in 1937 than in 1933 to 1936. However, the rate in 1937 was lower and therefore more favorable than that in any year since 1921 but previous to 1933. The nonfatal injury record, which began in 1930, was lower and therefore better in 1937 than in any other year since 1930. Separate figures covering bituminous-coal mines in all States showed a lower fatality rate in 1937 than in any year since 1920 but before 1933, and a lower nonfatal injury rate than that of any year since 1930 except 1933 and 1936. Reports for anthracite mines in Pennsylvania revealed a better safety record for fatal accidents in 1937 than in any year since 1930 except 1933, 1934, and 1936 and a better record for nonfatal injuries than in any year since 1930 except 1933.

Jan 1, 1940

By I. J. Geldenhuys

South Africa’s mining and metals industries have an illustrious history dating back to the Late Iron Age. We live in a complex and data-intensive world that has already fundamentally changed how we work and live. The outbreak of the global COVID-19 pandemic in 2020 resulted in immeasurable suffering worldwide, but the crisis also accelerated many technological developments and altered the way we think about, and experience, technology and work. Problem-solving requires new and rapidly changing skills to manage the data tsunami. Whether at the rock face or on the processing plant, the fundamentals have not changed, although how we interact with minerals and their properties has changed dramatically. Sustainable processing and design are non-negotiable if we genuinely want to achieve the aim of the cradle-to-cradle principle. As we venture forth, what can scientists, engineers, technologists, and mathematicians learn from history? History is data presented in a context; sometimes, the context is also important. We exist in an age of data, with most of the world’s data created in only the past two years. History can enhance our understanding of the present and enhance our future outcomes. Lessons from history can help provide insights into making ethical and sustainable choices related to technology or engineering in the mining and metallurgical industry. Shifting the perspective of mining and metallurgy professionals from a narrow focus on complex technical solutions towards a broader context for problem-solving and designs that includes the entire ecosystem is crucial. In other words, using or reflecting on historical process development is, at its core, systems thinking.

Sep 1, 2021

By Cesar Carrasco

Mine reconciliation is the art and science of comparing predictions and real-world outcomes with the intent of revealing the true quality of performance of models, planning, mining, and mineral processing. When mine reconciliation is conducted in a systematic, transparent and sustainable way it can play a central role in the governance of Mineral Resource and Mineral Reserve (MRMR) estimation and reporting. The core processes of modelling, planning, mining, and processing need to be transparent to be able to demonstrate that MRMR are reliable predictors of mine performance and value. Transparency is also necessary for mine technical staff to generate meaningful analyses, conclusions, and business improvement actions that demonstrably maximise value for all stakeholders. Most mines have some form of mine reconciliation practice, however because there is no agreed industry standard, and because mine reconciliation is difficult for a variety of reasons, it is often unsustained and/or ineffective at delivering the required transparency of performance. To deliver true governance of MRMR and business value, mine reconciliation must be sustainable. There are two categories of issues that combine to make mine reconciliation extremely difficult to sustain, these are technical, and people related. Technical issues include defining standard terms, accurately tracking material flows, data availability/adequacy/quality, calculation of key performance indicators and tolerance limits, analysis, and interpretation of results, understanding limitations of modelling techniques, and defining appropriate actions that can deliver value. These technical challenges are non-trivial, however compounding these are a range of people issues that include personal agendas, scepticism, lack of knowledge and experience, poor teamwork, absent leadership, toxic workplace culture, staff turnover, ineffective communication, siloed organisational structure, and lack of deliberate change management. All these problems can be solved with clarity of purpose, definition of the process of mine reconciliation, discipline in following the process, appropriate resourcing, and commitment to success across the entire organisation. Outlined in this paper is a management system that delivers sustainable mine reconciliation by addressing both the technical and people issues described above. This approach can deliver significant value for a mine and adds a robust, defensible governance over MRMR estimation and reporting.

Oct 1, 2024

By Z. Pokrajcic

The traditional comminution circuit is a major consumer of energy ? both as electrical energy and through consumption of media and wear resistant liners. Up to 40% of electrical energy con-sumed at a mine site is attributed to comminution however only a few percent of this energy is used in the generation of new surfaces from size reduction. This paper describes the evaluation of modifications using simulation models based on two operating comminution circuits. The aim of these modifications is to decrease both the amount of electrical energy consumed in the size reduction process, known as direct energy, as well as to decrease the consumption of grinding consumables such as steel grinding media and mill liners, designated as indirect energy. The approach is two-fold: ??Employ, where possible, autogenous grinding techniques to eliminate the need for grinding media and reduce mill liner wear. ??Optimise the use of the grinding energy distribution in the comminution circuit by using more energy efficient grinding devices to target typically problematic features of a comminution circuit such as critical size material from the primary mill and overgrinding in the secondary mill. The investigations show that significant total energy savings, as high as 50% in some cases, can be achieved by employing the techniques described while maintaining circuit throughput and product size. Investigations also show potential benefits in downstream flotation processes as the product size distribution generated from the eco-efficient circuit is generally ?narrower? in shape for improved flotation performance and containing less material in the coarse fraction for overall better liberation.

Jan 1, 2014

By E. J. Lintner, J. R. Thoenen

During the period 1937-40 and until peacetime research was superseded in 1941 by wartime activities , the junior author was engaged in studies regarding the relative efficiency of operating methods in quarries producing crushed stone for mineral aggregates . The results of some of these studies were published as reports of investigations in 1939 and 1940 ; / others were discontinued due to war demands on personnel and time . The published reports discussed the efficiency of particular quarry operations with respect to the time consumed and without reference to costs or mechanical factors . • At the time , the field data were collected for the published reports other data were collected relative to the relationship of the numerous variable factors inherent in the operation of a churn drill to the ability of the drill to produce blast holes . The churn drill is essentially a crusher and depends. for its performance upon the foot-pounds of energy it can impart to the cutting edge of its bit . The gravity stamp mill , so well-known in western gold mines , is essentially the same type of crusher . The ratio of foot- pounds necessary to crush the rock , to the total theoretical energy developed by the falling churn- drill tools , affords a good means of evaluating the efficiency of the tool . This does not include to tal over-all efficiency involving the mechanical equipment of the drill itself or its power unit .

Jan 1, 1947

By Jodie Robertson, Isabel Barton, Cristian Caro

Prior to mining, all rocks contained in a mineral deposit must be placed in one of several categories known as ore types. Each ore type describes a different way that the rock will behave in processing. The ore type determines which process stream a particular mined unit will be sent to, sets expectations for process engineers and metallurgists, and forms the basis for recovery predictions and production estimates. At first, ore types are assigned mainly by geologists based on visible geological criteria (dominant ore mineralogy, estimated grade, rock type, alteration type). As metallurgical tests are carried out and process data accumulate, the resulting criteria may be factored into the ore typing process, typically as assays and recoverable metal using the relevant process(es). Other variables may also be incorporated into ore typing at operations if they are particularly important, such as grindability, preg-robbing, gangue reagent consumption, and the presence of especially deleterious minerals such as talc or smectite. The mine operation department may also redefine ore types and/or process destinations based on economic criteria. A “best” ore type is designated that (in theory) best describes how the rock will behave in processing. Codes representing this ore type are entered into the drill hole database, then interpreted on cross sections and level plans, and finally added to the block model. Ore types are iteratively reexamined and adjusted over the life of a project. Major difficulties in effective ore typing are (1) lack of communication between geologists and metallurgists, (2) the imprecision inherent in imposing clean categories on messy natural systems without discrete divisions, (3) the need for ore types to provide useful information for a wide range of processes, (4) difficulties in scaling up laboratory test results to mine production, and (5) conflict among geological, metallurgical, and economic criteria for ore typing.

Nov 8, 2023

By Kristen Dunlap

There are several thousand remote stream crossing structures in the Tongass National Forest in need of removal. In 2007 thirty-three collapsing log bridges, log culverts, and metal culverts no longer in use were removed with explosives. Species of salmon, trout, char, and sculpin are present in the project area. Blasting overpressures may injure or kill fish in streams and ground vibrations can damage salmonid embryos in streambeds. Regulatory agencies offer guidelines with limits for blasting induced overpressures and vibrations. However, there has been no quantification of blast overpressures in shallow streams. Methods used to predict lethal levels for various blasting applications have not been completely validated. This research provides guidance for analyzing ground vibrations and water overpressures during blasting activities in or around fish streams.

Jan 1, 2009

By A. L. Engel

IN the treatment of complex ores by flotation, one of the most important steps is conditioning the feed. Conditioning primarily consists of the addition, in the grinding circuit, of an alkaline reagent, for example sodium carbonate, which neutralizes any acidity of ore and mill water, counteracts the effect of &apos;harmful soluble salts, disperses colloids, and provides the necessary alkalinity for the best metallurgical results. The several minerals of the ore should be put in such condition that they may be floated or rejected as desired, through the action of further reagents thereafter used.

Jan 1, 1932

By Jun Enriquez

Kennecott Utah Copper aims to extend anode furnace campaigns to more than three years. As part of that goal improvements are sought on anode-furnace tuyere-area refractory performance. Kennecott and Praxair developed high pressure nitrogen refining for the Oxidation Stage which shortened anode furnace fire refining cycles by up to two hours per cycle. Future developments include optimizing the Reduction Stage’s steam-gas reforming and achieving coherent jet tuyereless refining.

By D. J. McLaren

"Arctic Canada is one of the largest undeveloped terrains remaining in the world, and is in many ways unique. The ecological balance of the region is more delicate than tropical or temperate regions of similar size. This region is likely to be developed by research for and production of resources, primarily petroleum, in the immediate future. As well as sensitive terrain surface caused by permafrost in some areas, many large and small mammals and birds are also in a delicate balance with the environment. Small changes in this balance can have large effects.The probability of finding petroleum in different regions varies widely, but already there are good indications on the mainland and in the Islands that both oil and gas are present. Geophysical work in the offshore, particularly the Beaufort Sea, suggests further promising potential. Possible reserves in the Islands and mainland Arctic may amount to 50 or more billion barrels.A responsible approach to problems facing exploitation in an Arctic environment includes the careful monitoring by industry of likely effects of their activities. The Mackenzie Valley Pipeline Research Association test loop at Inuvik provides an example of such monitoring. Outside Canada, the operations at Prudhoe Bay on the north coast of Alaska show how major companies may operate responsibly and reduce environmental interference to a minim'.::at. Nevertheless, four variables must affect any decisions to be made concerning energy resource exploitation in the Arctic. These are man's need for energy, economic and industrial pressures to develop energy sources, the desire to preserve a deteriorating environment, and the role of government as representing all individuals in the country and their several points of view. Factors that must be taken into account in making any decisions include the importance of Canadian oil in a world picture, the need for alternative sources of energy in the near future, the depletion of nonrenewable resources at an accelerating rate and the increasing awareness that the major problems facing man have no direct technical solution and that social or political decisions must precede further techno-logical development."

Jan 1, 1971

By R. Sullivan, K. Joiner, B. Emery, M. de Vries, F. A. Stober, L. R. Nelson, J. M. A. Geldenhuis

Keywords: Pyrometallurgy, smelting, converting, furnace design, furnace retrofit, high-intensity smelting, copper coolers, plate coolers, waffle coolers, tap-blocks, lower sidewall air-cooling, wall hold-down system, platinum group metals, ferroalloys, ferrochrome, ferrocobalt, ilmenite smelting, ironmaking, operational readiness, operational support The paper describes the development of furnace designs by Hatch in conjunction with the smelting plants in Africa to meet the intense process requirements in certain applications; continued improvement in operating efficiency through increased throughput from existing crucibles; and improvement in campaign life and furnace integrity. The era of Hatch in Africa has seen the doubling of furnace power in retrofit projects using existing crucibles to developing the highest intensity immersed electrode operations in the world. This has resulted in minimized OPEX and CAPEX per unit of production. Through the continued development of its cooling, binding and furnace power supply technologies and working with the experienced and knowledgeable personnel at the smelting facilities in Africa, Hatch has managed to meet the challenges of ever increasing furnace process requirements associated with increased power density and superheats prevalent in the operations. In addition to developing furnace crucible designs, Hatch has also intensified its ?after sales service and support? with the construction, commissioning and start-up technical assistance and operational readiness and operational support for ramp-up to nameplate capacity and beyond. The key areas of furnace risk associated with high superheat molten material tapping has also seen the development of diagnostic systems to mitigate risks and produce early warning signals for the operators.

Jan 1, 2006

By J. B. Zink

The Bureau of Mines developed a spectrochemical method to determine six constituents in coal ash in the following concentration ranges: silica 9 to 63 percent, alumina 7.5 to 35 percent, ferric oxide 2 to 30 percent, calcium oxide 1 to 29 percent, magnesium oxide 0.5 to 6 percent, and titanium oxide 0.5 to 4 percent. Samples of coal ash are fused with a mixture of lithium tetraborate and vanadium pentoxide. The resulting beads are crushed, mixed with powdered graphite, and briquetted. The pellets are analyzed spectrographically, using controlled high-voltage spark excitation. Vanadium serves as the internal standard. Effects due to matrix variations are minimized by fusion with lithium tetraborate. Intensity ratios of selected analytical lines are determined photometrically, Concentrations are read from analytical curves, prepared from synthetic standards, relating log intensity ratios to log concentration. A combustion procedure is used to determine sulfur tri-oxide. The method is most useful when large numbers of coal ashes must be analyzed but a high degree of accuracy is not essential.

Jan 1, 1967