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By D. M. Maijer, S. L. Cockcroft, S. Modak, A. B. Phillion

"A comparison between hydrogen-diffusion-based micro-porosity formation and growth behaviour of two important aluminium foundry alloys, B206 (Al-Cu) and A356 (Al-Si-Mg) is presented in this paper. Specifically, the predicted pore size and pore fraction distribution of these two alloys resulting from directional solidification and identical hydrogen concentration are investigated numerically based on a model proposed by Yao et al. (2011. Met. & Mat. Tran. A. 42A, 4137–4148). This model takes into consideration the initial hydrogen content in the melt, the cooling rate, the partitioning of hydrogen between the solid and liquid phases, and the evolution in solid fraction with temperature. Due to different alloy chemistries, the activity of hydrogen in B206 and A356 are quite different, as are the solidification range and the resulting solidification microstructure. Being a primary alloy, B206 has dendritic microstructure and solidifies over nearly 135°C (505–641°C), whereas A356 contains fifty percent eutectic microstructure, and solidifies over 80°C (533–613°C). This allows a very different behaviour of micropores i.e. the effective pore radius in B206 is quite a bit lower as compared to A356, as is the pore number density. The evolution of local hydrogen concentration in liquid metal is analysed and compared for both the alloys.INTRODUCTION Over the past decades, the demand for materials with enhanced strength-to-weight ratios has significantly increased in the aerospace and automobile industries in order to improved fuel efficiency. For many automotive components, particularly shape castings, the trend is towards replacing ferrous alloys with aluminium alloys. The increase in the use of Al is primarily due to its low density, about one-third that of steel, and its relatively good strength that allows for weight reduction without reducing performance. Presently, Al-Si based alloys (e.g. A356) are the most prevalent due to their good mechanical performance in strength-to-weight ratio and excellent castability (Atwood et.al., 2000). However, superior mechanical properties can be achieved using Al-Cu alloys. For example, the alloy B206 offers a higher strength while retaining excellent ductility (Poirier et.al., 1987)."

Jan 1, 2017

By M. E. Ryan, C. L. Hoebbel, E. J. Haas

DISCLAIMER The findings and conclusions in this paper are those of the authors and do not necessarily represent the official position of the National Institute for Occupational Safety and Health, Centers for Disease Control and Prevention. Mention of any company or product does not imply endorsement does not constitute endorsement by NIOSH. ABSTRACT It has been suggested that effective disaster prevention and response in mining requires that elements of emergency management be incorporated into everyday operations, planning, and decision-making, much in the same way that the industry approaches routine risk management. Since Congress passed the MINER Act in 2006, the newly mandated structural and technological advancements in mine emergency response preparation have been made and are apparent, but measureable improvement in mineworker emergency preparedness is difficult to ascertain. To begin exploring whether measurable indicators of mine workforce preparedness can or should be addressed within a risk management framework, NIOSH researchers examined the datasets from two separate research efforts—one which measured the organizational safety climate and self-reported safety performance, and the other which measured individuals’ perceptions of their own self-escape competency. INTRODUCTION In response to the mine disasters in 2006, the United States Congress passed the Mine Improvement and New Emergency Response Act (MINER Act), which strengthened existing regulations [30 CFR, Part 48] and introduced new provisions to improve mine emergency response. Since that time, new technological and structural features, such as mandated redundant communication systems, personnel tracking systems, and lifelines in primary and secondary escapeways, have been installed in underground coal mines across the country. Additionally, mine operators are required to develop emergency response plans, provide adequate supplies of breathable air throughout the mine, provide more frequent and realistic expectations training, and are required to immediately notify the Mine Safety and Health Administration (MSHA) in the event of an accident. While the structural and technological advancements in emergency preparedness are readily observable and easily measured, levels of individual mineworker preparedness remain difficult to assess. There is a general consensus that deficiencies in competence in the non-routine tasks required for individual miners to effectively respond to a mine emergency likely remain (e.g., National Research Council [NRC], 2013), and NIOSH research continues address this concern (Haas, et al., 2015; Hoebbel et al., 2018). To maximize an operation’s capacity to effectively prevent disasters and/or respond to emergency events, it has been suggested that individual and emergency management efforts be incorporated into everyday operations, planning, and decision-making in much the same way organizations manage routine risks to health and safety (Haddow et al., 2017). To the authors’ knowledge, the mindful intersection of routine risk management policies and practices and emergency prevention and response readiness have yet to be empirically studied within the mining industry.

Jan 1, 2019

By Henry Kreisinger, J. F. Barkley

This book is one of a series of publications being issued by the Bureau of Mines for the purpose of disseminating information in regard to the methods by which the fuels in this' country may be used most efficiently. A knowledge of the temperature of the gases in boiler settings and in other commercial apparatus using heat tends to develop improved designs of apparatus and better methods of operation, thus reducing waste of fuel. The following pages present, for the benefit of those designing, operating, and testing such apparatus, information as to the accuracy of temperature measurements made under certain conditions and the corrections that can be safely applied.

Jan 1, 1918

By M. Blagojev, R. Tomanec

"Studies reported in this paper used polymetallic Pb-Zn-Sb-As-(Ag, Au) ore from Dražnja, Kosovo. The ore is comparatively rich in Zn (6.56%) and Pb (2.87%), but with high rates of Sb and As. Conventional lead and zinc concentration by flotation produced galena and sphalerite rich concentrate with high recovery, but with excessive As and Sb. After chemical analyses, which could not detect the reason for the excessive elements, ore minerals were identified under the ore microscope, their texture characterized, and degree of liberation of useful minerals was assessed. Microscopy of the mineral concentrates revealed complex intergrowths of galena and marmatite minerals mostly with sulphosalt minerals (boulangerite, jamesonite and bournonite) and also with arsenopyrite mainly responsible for the unsatisfactory quality of the concentrate. These complex sulphosalts, among other things have similar behaviour during the flotation concentration, and in spite of their interlocking with galena, therefore inadequate liberation, sulphosalts remain in the lead concentrate. Microscopic analyses indicated that a better galena concentration product is possible with a higher rate of mineral liberation, and then by selective floc flotation of some sulphosalt minerals. Purpose of this work was to show that only chemical analysis is not sufficient, according to that we solved the problem by precise mineral identification and time consuming mineral liberation measurements. INTRODUCTION The polymetallic Pb-Zn-Sb-As-(Ag, Au) ore body of Dražnja, Kosovo, fairly rich in Zn (6.56%) and Pb (2.87%) was repeatedly explored and once even worked. Mineralization at Draznja was primarily represented by sphalerite, galenite and marcasite/pirite. Some sections comprise massive sulphides, and others are lower grade zones of semi-massive sphalerite/galena or marcasite/pyrite dominant sulphides. The ore body II was formed in the southern gallery in the structure Çukë – Lajthishtë (with content of 3.16% Pb and 7.31% Zn). Pb-Zn ore with increased content of As, Sb sulphosalts is not rare phenomenon in the world. While previously treated as unprofitable, economical uninteresting ore, today with development processing and new reagents (organic, ecologic), are the topic of scientific papers. The examination of Pb-Zn ore with high content of sulphosalts we find in deposits as: The hydrothermal vein deposit of Harja in the Baia Mare area, contain a wide variety of sulphosalts [Cook, N. & Damian, G., 1997]; also the deposits Fankou Mine in Guangdong Province and the Dachang Mine in Guangxi Province, where the flotation concentration of galena and jamesonite takes place [Runqing Liu et al. 2015], [Zhang Ting, Qin Wen-Qing, 2015];. On a samples from Tibet in China flotation separation test of galena and jamesonite was conducted [Sun Wei, Han Haisheng, Tao Hongbiao, Liu Runqing, 2015]. According to history of investigation, the mineralized area of Dražnja has a long history of exploration and possible exploitation activities [Slowey, Galen, 2009]. Recent workings were carried out in three stages through the 20th century."

Jan 1, 2018

By Robert A. Siokler

Approximately 75 percentage of the earth's land surface is comprised of shale or shale-like materials. Shale itself is composed of the residue from an almost infinite variety of weathered parent materials which have undergone deformations ranging from intense to negligible. Under standard test procedures, shales exhibit a very wide range of physical properties particularly if the test specimen is subjected to a change in moisture content, when the original test values may vary from 0 to 100 percentage. It is this wide variation in physical property values compounded by its ubiquitous presence that makes shale such a problem material to engineers. In reviewing the literature relating to shale, it is evident that the "problem" has been approached from many directions. In order to understand why shales behave as they do, investigators have sought mineralogical, geological, chemical, electrical, and physical answers. Each study yields valuable academic information, but few contribute much of value to the engineer in the field. Many valid relationships between shale strength or competency and clay type, clay content, organic content, water content, grain size, cementation, density, porosity, etc, have been established. Yet it is very difficult to extend these understandings to the in situ condition with results that can be used by the field engineer. One major reason earlier work has not produced better information lies in the ambiguity of the definition of shale. It is apparent that no one laboratory parameter can be successfully used to provide sufficient engineering information to properly describe in situ conditions. For example; shale with swelling clays will produce low strength values provided: the swelling clay is in sufficient quantity, the clay is dispersed throughout the medium involved, and there is a low value of cementation. Shales with high unconfined compressive strengths have been found with very low shear strengths. Sandy shales often provide as many ground control problems as clay shales. Shales of similar nature may provide good roof conditions in one part of a mine yet in another part of the same mine the apparently identical shale may cause substantial problems. A clear need exists to classify shale in a manner which will enable the engineer to better predict the strength and durability of shale-like materials. Studies at the University of Missouri-Rolla (UMR) have focused on finding parameters which influence durability and competency, while being discretely discernible through uncomplicated testing. Initial research concentrated on distinguishing shale8 on the basis of standard physical tests such as: unconfirmed compression, triaxial shear, and slake durability. As results accumulated, however, it became evident that moisture content played a much greater role in determining competency than had been recognized previously. As a result the focus of the research turned to developing tests which would evaluate the influence of moisture on shale behavior. The above work then became a foundation for a second phase of investigation in which a suite of standardized tests were developed to provide a classification procedure. From this study five tests were identified as being critical: Moisture Activity, Atterberg Limits, Submersion, Unconfined Compression, and Shore Hardness.

Jan 1, 1986

By M. Epiney, A. Ghahreman, R. Kim1and

"Pre-oxidation and cyanide leaching behavior of gold in the presence of sulfide minerals were reviewed, focused on the effects of oxygen injection in the gold leaching process. Generally, pre-oxidation and gold leaching kinetics from iron sulfide refractory minerals, such as pyrite, pyrrhotite, marcasite, pentlandite and arsenopyrite, can be enhanced with higher dissolved oxygen (DO) concentration. However, most of copper sulfide minerals dissolved well both in water and cyanide solutions, and copper from the minerals consumed DO and cyanide to oxidize and leach. Only in the presence of chalcopyrite, gold leaching was effectively occurred with increasing DO. However, chalcocite and covellite severely retarded gold leaching. Stibnite, an antimony mineral, formed a passive film on the gold surface under any DO conditions, and it slowed gold leaching. This impeding effect can be alleviated by leaching at low pH or adding lead salt. Using oxygen and lead together can make synergistic effect in oxidation of sulfide minerals and can enhance gold extraction. Depending on the mineralogical characteristics of the ore, the optimum DO and lead concentrations can be optimized. However, lead can cause environmental problems, and so its dosage should be minimized or eliminated by substituting it with oxygen injection.INTRODUCTIONGold ores containing sulfide minerals are becoming more significant as high grade gold oxide deposits are continuously becoming difficult to find. In light of this situation, to produce more gold, recovery methods from refractory gold ore containing various sulfide minerals should be investigated. Generally, sulfide minerals have impeding effects on gold leaching: formation of a passive film on the gold surface, high consumption of chemicalssuch as cyanide and oxygenduring leaching, reduction of gold cyanide by sulfide ions, etc. (Senanayake, 2008). Therefore, sulfides must be properly treated for better gold recovery. Pre-oxidation of sulfide minerals by injecting pure oxygen can decrease the impeding effects in gold leaching. Prior to cyanidation, sulfide minerals can be oxidized to metal hydroxide and sulfate form, which consume negligible cyanide in the following cyanidation circuit (Bodnaras et al., 1993). Moreover, gold cyanidation can be enhanced by increasing concentration of the dissolved oxygen (DO). In general, the optimum concentration ratio of [CN-]/[O2] is calculated as 6, but it goes higher in the real system (Marsden &House, 2006), which means that the reaction is typically controlled by DO concentration."

Jan 1, 2017

By Hans Chr Andersen

Almost every form of iron ore and carbon material has been used as a raw material in the production of pig iron in electric reduction furnaces. Experience derived from the operation of the large 33,000-kva. Tysland-Hole furnaces, however, indicates that production results are very much influenced by the raw material conditions. The author presents the principle pattern of the metallurgical structure of the interior of an electric pig iron furnace. On the basis of this, he discusses the variations of electrical and metallurgical conditions for the process which will take place with changing raw materials. The formation of a coke bed underneath the electrodes, and its influence on the furnace operation, is illustrated. Quality and grain size of the coke added to the charge will influence the build-up of the coke bed and will thereby also affect the electrical re-''Elektrokemisk A/S, Oslo, Norway. resistance and reduction potential in the furnace.

Jan 1, 1963

By William H. Schiffbauer

This report details a microcomputer-based control and monitoring network that was developed in-house by the U.S. Bureau of Mines and installed on a continuous mining machine. The network consists of microcomputers that are connected together via a single twisted-pair cable. Each microcomputer was developed to provide a particular function in the control process. Machine-mounted microcomputers, in conjunction with the appropriate sensors, provide closed-loop control of the machine, navigation, and environmental monitoring. Off-the-machine microcomputers provide remote control of the machine, sensor status, and a connection to the network so that external computers can access network data and control the continuous mining machine. Because of the network's generic structure, it can be installed on most mining machines.

Jan 1, 1993

By Florian Kongoli

New operating conditions and process parameters are often necessary in today's industrial practice of non-ferrous smelting and converting in order to accommodate various new chemical compositions of mineral charges and environmental requirements or to conceive new and more efficient industrial technologies. An important parameter in non-ferrous smelting and converting is the liquidus surface of multicomponent slags. This surface is affected by multiple factors such as temperature, gaseous potentials, the content of each component in the slag, etc., and cannot be quantified by the existing ternary liquidus diagrams. In this work a new type of representation of the liquidus surface of multi component systems has been presented by means of a thermodynamic model. This representation waives the need of the multidimensional representation of multi component systems and yields practical two-dimensional diagrams, which can be easily used in the industrial practice.

Jan 1, 2000

The Leuna Factory of the I. G. Farbenindustrie A. G., situated near Merseburg, is the biggest heavy-chemical plant in Germany and produces a very wide range of products, mainly based on hydrogen or hydrogen and carbon monoxide. Its principal products are ammonia, synthetic petrol derived from the hydrogenation of brown coal, and synthetic alcohols made from hydrogen and carbon monoxide. The plant was first, visited on April 21, 1945, by a team including E. Cotton, V. Haensel, E. B. Peck, P. K. Kuhne, H. M. Weir, L. L. Hirst, W. W. Odell, G. U. Hopton, H. Hollings, J. F. Ellis, and H. G. Simpson. It was again visited on May 8-24, 1945, by a combined British and American team consisting of R, Holroyd, M. A. G, Banks, D. A. Howes, A. J. V. Underwood, R. A. Taylor, W. F. Faragher, H. Schindler, and J. G. Allen. This team was later joined by J. F. Ellis and R. J. Morley. A third visit with particular reference to catalyst manufacture was made by W. F. Faragher and W. A. Horne, and the notes of these latest investigators have been taken into account in preparing the report. This report was edited by Dr. R. Holroyd.

Jan 1, 1946

By L. Iacopetti, A. Calderara, M. Perego, P. Perrone, T. Furusawa

De Nora, a global leader in the development, manufacture and sale of all DSA® anodes based on titanium coated with mixed metal oxide (MMO) for electrochemical processes will present key advancements made to Self-Protected Anodes (SPA) for metal electrowinning. (DSA® is a registered trademark of Industrie De Nora S.p.A., Italy). In 2017 pre-commercial demonstration cells were operated in industrial environment. The program’s focus was to fully demonstrate the SPA anode’s superior mechanical and electrochemical robustness during normal and induced dendrite shorting occurrences while providing quality of plating in commercial operation. De Nora specialists focus on key components, in particular the engineering of the self-protection system, DSA® anodes and catalyst formulation capable to cope with high levels of pollutants while providing long service life in the meantime. Results of field trials confirmed the expected anode performance and enabled the selection of the most suitable “SPA” structure, based on resistive protective elements. Summarizing the economic benefits to copper electrowinning tankhouse operation with De Nora’s self- protected all DSA® anodes are; Double-digits power savings Cobalt-free electrolyte operations Minimal dendrite shorting damage incurred at the SPA anode Smoother, uniform cathode deposits with tangible improvement on current efficiency Tankhouse operations producing lead-free copper quality cathodes, in addition to elimination of lead waste for improved operator health and environment. INTRODUCTION De Nora’s engineered “Value Technology Package” (“VTP”) for electrowinning, consisting of our DSA® anodes coated with mixed metal oxide specifically formulated for copper electrowinning in conjunction with an advanced self-protected full titanium anode (“SPA”), underwent an intense field qualification program, inclusive of the behavior under massive short-circuits as part of the field investigation, with the goal to select and appoint the ultimate design configuration of “SPA”. Optimized wireless-based monitoring system was included in the field program, demonstrating good functionality for cell parameters monitoring and remote shorts detection.

Jan 1, 2019

By A. J. Forney

Recent experiments used catalysts of plate assemblies in synthesizing high-Btu gas and gasoline indirectly from coal. A gas with a heating value of 925 to 943 Bt-: per cubic foot has been prod u la the hot-gas-recycle pilot plant from synthesis gas (3H2+100) with lathe turnings used as catalyst in the first reactor, and assemblies of parallel sprayed plats of nickel in the second. Solid plates made of Raney nickel, and steel and aluminum plates sprayed with Raney nickel or nickel oxide were tested. Those catalysts had very low resistance to gas flow; 90 percent lower than nickel granules used in previous experiments. In a single stage of synthesis thee nickel plates were only partially successful. Although the heating values of the product gas ranged from 856 to 941 Btu per cubic foot, the carbon monoxide content of he gas was above 0.1 percent. Both steel and wrought turnings were tested in single-stage synthesis, but the conversion of hydrogen and carbon monoxide was too low to attain the desired heating value of 900 Btu per cubic foot in the product gas. Assemblies of plates thermally sprayed with fusel iron were tried in an experiment to make gasoline. A gasoline yield of 52 percent (of the hydro¬carbons produced) was obtained using a 1H2-10O feed These sprayed assemblies were in service for 1,500 hours, the longest that this type of catalyst has been used. When a second reactor containing Raney nickel catalyst was added in series with the first reactor, complete utilization of the feed gas was obtained because in addition to the liquid product, a high-Btu gas with a heating value of 800 Btu per cubic foot was made.

Jan 1, 1965

By Lloyd Williams, James R. Boyle

The mining methods and practices used at the Young zinc mine, American Zinc Co. of Tennessee, have resulted in a low-cost, high-yield operation. Zinc ore (sphalerite) occurs in limes tone- dolomi te beds of the Kingsport Formation and is mined by modified room and pillar method. Utilizing trackless mining equipment which incorporates a high degree of flexibility, this operation has had a steady increase in productivity.

Nov 1, 1964

PIP is regularly engaged in businesses where Greenfield Capital Projects are under- delivering on the expected business case. In most of these projects, we can identify that rigorous review has been carried out on the design and financial cost elements and substantial reporting is maintained to Boards on progress versus plan of project completion and cost. However, in all sites of this nature that we have worked at, the planning, design and execution of the operational elements or æwiringÆ of the organisation have fallen short and resulted in significant extra cost or opportunity cost (lost tonnage or quality) during start-up. When compared to the amount of planning and resources that have been poured into the capital side, the ledger on the æwiringÆ side is typically fairly sparse. This presentation outlines the importance of running a disciplined, rigorous process to prepare the human and wiring side of a start-up to ensure rapid start-ups and put the site on the pathway to high performance. It gives an outline of the rigorous process PIP has used with projects to ensure excellent start-ups.

Jan 1, 2006

By C. K. Eilerts

Knowledge of the phase relations of the fluids that exist in the porous spaces of rocks constituting natural petroleum reservoirs and of the behavior of these fluids under various field conditions of operation is essential to the conservation of petroleum and natural gas and to their efficient recovery. The problem of determining whether these fluids axe in the liquid or gaseous state send of recognizing the transitions that may take place as the material in the reservoir is subjected to different conditions of pressure and temperature confronts many producers today, especially in certain fields. The subject has grown rapidly in importance since the discovery of and production from deeper reservoirs that have correspondingly higher pressures rind temperatures as compared with shallower

Jan 1, 1938

By F. A. Baczek

The Electroslurry TM electrowinning concept has been incorporated into a process flowsheet for recovering copper from smelter flue dusts. The process has averaged 96% recovery of the copper as high-grade electrowon while at the same time removing a majority of the impurities that degrade drawn copper as a result of recycling flue dust and liberator cathodes: The dust is processed through several stages consisting of leaching, copper precipitation, Electroslurry TM electrowinning and waste liquor treatment. The process may be integrated into a smelter operation and become an effective and feasible means of maintaining good product purity.

Jan 1, 1980

A computer simulation of the automatic control of continuous mining machines has been prepared, similar to previous simulations of longwall mining systems and coal thickness sensors. The simulation allows for programmed variation of the horizon detection method, the azimuthal guidance system, the type and configuration of the miner, varying hardness in the unmined face material (leading to varying error in the machine heading), and the miner's cutting cycle. It simulates control of the miner in three axes. Use of the simulator makes it possible to anticipate problems arising from the complex character of underground mining, which include unpredictable multi-pass coupling and unpredictable variation in geological conditions.

Jan 1, 1993

By A. Visnapuu

The Bureau of Mines, as a part of its goal to minimize occupational hazards associated with mining and mineral processing operations, has developed and field tested a compact exhaust air muffler for mechanized, jumbo-mounted pneumatic rock drills. The muffler is constructed of 1/8-inch sheet steel and has nominal dimensions of 1-3/4 by 9 by 13 inches. A directed air passage, flexible neoprene baffles, and an expandable slit-type outlet are incorporated to reduce drill exhaust air noise and eliminate muffler icing. Field tests in actual mining operations showed a l5-dbA reduction in exhaust noise and an 8-to 12-dbA reduction in overall drilling noise with no icing problems or decrease in drill performance. Data are presented on muffler construction, laboratory, and field test results.

Jan 1, 1979

By Paul Pedini

The challenge of Contract C19E1 of Boston's Central Artery Project called for the construction of two roadways under the commuter rail yard at North Station. Two options were offered for the method of their construction: Slurry Wall Roof-First or Soft Ground Tunneling. The instability of the indigenous soils seemed to rule out the use of tunneling, so the slurry wall method was chosen. However, these soils were incapable of holding up during slurry trench excavation. After many episodes of ground loss on early panel excavations, Modem Continental Construction suggested a method of trench wall stabilization. The Contractor (MCC) both suggested wall stabilization method and requested that the owner participate in the funding for the effort. The Project and the Contractor were able to agree on a solution which resulted in collapse-free excavation...and found an innovative way to fund the solution.

Jan 1, 2002

By D. R. Tweeton

The U.S. Bureau of Mines, the University of Arizona, Sandia National Laboratories, and Zonge Engineering and Research Organization, Inc., conducted cooperative field tests of six electromagnetic (EM) geophysical methods to compare their effectiveness in locating a brine solution simulating in situ leach solution or a high-conductivity plume of contamination. The brine was approximately 160 m below the surface. The testsite was the University's San Xavier experimental mine near Tucson, AZ. Geo- physical surveys using surface and surface-borehole, time-domain electromagnetic (TEM) induction; surface controlled-source audiofrequency magnetotellurics (CSAMT); surface-borehole, frequency- domain electromagnetic (FEM) induction; crosshole FEM; and surface magnetic field ellipticity were conducted before and during brine injection. The surface TEM data showed a broad decrease in resistivity. CSAMT measurements with the conventional orientation did not detect the brine, but measurements with another orientation indicated some decrease in resistivity. The surface-borehole and crosshole methods located a known fracture and other fracture zones inferred from borehole induction logs. Surface magnetic field ellipticity data showed a broad decrease in resistivity at depth following brine injection.

Jan 1, 2010