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By K. K. Kelley

The entropy values at 298.1° K. for the elements and inorganic compounds, on which sufficient data were available for calculation in 1931, were discussed in a previous publication (96).3 Since that time the specific beats at low' temperatures of many more inorganic substances have been determined, and considerable advances have been made in the realms of spectroscopy applicable to the determination of thermodynamic properties. Moreover, a critical study of the existing vapor-pressure data made by the author (98) furnishes entropy of vaporization results suitable for obtaining approximate values of the entropies of a number of gases from the entropies of the solids or liquids. Consequently, it appears worth while at the present time to supplement the former publication, giving the new values now obtainable and making such revision in the older values as the data warrant. The methods of calculating entropies were discussed in previous publications (96, 98) and will not be repeated here. ENTROPIES AT 298.1° K. FOR INORGANIC SUBSTANCES In the following pages, the same arrangement is followed as in the previous publication (96). All entropy values are expressed in 15° gram-calories per degree Kelvin per gram-formula mass of substance. The figures given for gases do not include the effect of nuclear spin, as is nearly universally customary at present. The estimates of accuracy in the case of the values obtained from heat-capacity data apply only to the existing measurements and to the necessary extrapolations as they are made. It is assumed usually that the substances are in such an energy condition at the lowest temperatures reached in the specific-heat measurements that the usual normal type of extrapolation may be made. No allowance is made for error in this assumption. The recent work on Gd2SO4. 8H2O and FeC13 illustrates the difficulties that may arise in obtaining the entropies of some paramagnetic substances. Also the data and calculations for such substances as CO, H20, and N20 show that the correct entropy is not obtained in all cases by indiscriminate application of the usual

Jan 1, 1936

By S. M. Dar

The U.S. Bureau of Mines constructed a full-scale model of a 15-ft-wide coal mine entry to use in combination with finite-element analyses to investigate roof support systems and various types of roof bolts. The objective was to enhance understanding of the fundamental mechanics of the interaction between rock and supports and the relative integrity of bolted mine roof as a function of roof bolt type, length, spacing, and tension, and the basic characteristics of the roof strata. The laboratory test results, when correlated with computer simulations using fmite-element analysis and underground verification tests, should provide a basis for desigillng safer, more cost-effective roof control systems and help to establish guidelines for employing fully grouted resin and mechanically anchored bolting systems. The background for this research, the research approach, the methods and equipment employed, and the results are described in this report.

Jan 1, 1989

By C Harwood

Underground coal mines in the United States are in the process of completing installations for tracking and communication systems, mandated by Congress after a number of recent coal mine disasters. Yet, evaluation, modelling and testing of such systems has lagged due to legislated changes, abruptly introduced into the coal mining industry. System installation in a wide array of mine types, configurations, layouts and characteristics has provided a wealth of information regarding their potential in underground environments. Data collected from numerous installations for a variety of systems can be used to further define true capability and accuracy of communication and tracking packages. This paper describes a uniform means of evaluating the performance of a communication and tracking system. Several performance measures are proposed and described. These measures can also be predicted using an interactive software program. This program predicts the signal propagation, given the input mine characteristics and layout, with numerical and visual feedback. New or alternative system installations can also be more accurately designed to potentially minimise initial system cost and time required for trial and error installs. The focus of this research is to develop tools and protocols that can evaluate and measure the effectiveness of installed underground communication and tracking systems.

Nov 22, 2011

By Norman] [Seldle

This report describes the development of a mine machinery training system from initial conception through a task and skill analysis, a training system analysis, implementation of a prototype system, and initial validation of the prototype system. The objectives of the training are to improve safety and productivity simultaneously via complete, thorough training. A task and skill analysts was executed for shuttle cars, continuous miners, cutters, loaders, face drills, tractors, and scoops. The prototype training system is for shuttle car operator training.

Jan 1, 1976

The Effects of Collector and Grinding Environment on the Flotation Selectivity of Rosh Pinah Pb/Zn Ore

Sep 13, 2010

By E. H. Denny

A most interesting safety record has been made by the Colorado Fuel and Iron Co. s. Robinson ho. 1 mine located at Walsen, Cola. Mr. J. L. McBrayer has been superintendent of the Robinson No. 1 and 2 mines for the past 2 1/2 years, and Mr. David Muir has been foreman of the Robinson No. 1 mine since June, 1913. The last fatal accident at Robinson No. 1 mine occurred on July 27, 1915, and the tonnage produced at this mine since July 28, 1915, has been as follows:.

Jan 1, 1929

By T. M. Barczak

This U.S. Bureau of Mines report investigates shield mechanics and component stress development in a two-legged longwall shield for unsymmetric canopy and base contact configurations. Previous studies analyzed shield behavior for symmetric contact configurations. The goals of these efforts are to improve longwall support selection and design. This study provides vital information that will help develop improved procedures for performance testing of longwall supports and will benefit future research to improve support design through stress optimization and evaluation of failure mechanisms. Combinations of six canopy (three symmetric and three unsymmetric) and six base (four symmetric and two unsymmetric) contacts provided a total of 36 configurations for evaluation. Of these 36 configurations, 10 were eliminated because of fixture limitations or shield instability. Controlled vertical and horizontal displacements were applied by the Bureau's mine roof simulator to the remaining 26 configurations. Component responses were determined from pressure transducer and strain gage instrumentation in order to identify contact configurations and boundary displacements that produced maximum loading in each of the support components. This report describes these test results and provides conclusions relevant to critical contact configurations for performance testing of longwall supports.

Jan 1, 1990

By W. B. Agocs

"AbstractThe airborne magnetometer data of the Marmora iron ore deposit at Marmora, Ontario, have been used as an example to show the mapped results obtained by the use of line spacings of from 1 mile to 14 mile. The maps are illustrative of the results which could be obtained from such line spacings for any type of geophysical survey, and they show the probability of 'missing' a feature of economic value if the line spacing is too coarse.The probability equations are given for the crossing of randomly oriented features whose maximum dimension is less than the spacing of the control lines for circular, elongate, and rectangular outlines. The equations are P = D/S; P = 2L/S; P = 2(L+W)/,.S; P = A/,.S; P = (2L(S+T)-L2),.ST; and P (D(S+T-,.D)) ST, respectively; where P is the probability; D is the diameter; L is the length; W is the width; and S and T are line spacings.IntroductionTHE EFFECT of station spacing, and the effect of the distance between the plane of observation and the plane of the source of the potential field anomalies, have been studied by geophysicists in the past.The purpose of this paper, however, is to illustrate the effect of line spacing •on the resultant mapped magnetic anomaly for a known magnetite mass, and to present the elementary probability equations for determining the optimum control spacing for detecting a particular type of feature. The effect of line spacing which is illustrated by the magnetic maps presented herewith would be comparable to results which would be obtained by any geophysical survey, since the contours between lines are of necessity interpolated."

Jan 1, 1955

By Art Cooper

Granulation systems are customarily viewed as problem areas in metallurgical operations. The inherent risk of explosion when combining a high temperature melt with water creates a safety hazard. Separation of the granulated material from the quenching medium generally involves equipment that can have significant maintenance and operating costs. Granulation systems' reliability and availability can negatively affect the plant production. Against this background, granulation systems have been treated by design firms and producers as an add-on and a necessary evil. The technology is becoming better understood and solutions to common problems are being found. This paper will discuss typical problems in common systems, and some of the improvements that have been made, with particular reference to non-ferrous applications.

Jan 1, 2006

A field method combining solvent extraction and paper partition chromatography permits a simple and rapid semiquantitative estimation of gold in siliceous, argillaceous and sulphide ores. The method will facilitate the eyaluation of prospect samples in which the gold is too fine for separation by panning.Ethyl alcohol-hydrobromic acid mixtures are suitable for chromatographic development of the gold complex, and give clear reproducible definition of the gold zone. Substitution of commercial "methylated spirits" for the ethyl alcohol gives equally good definition, improving the potential of the method for field use.A batch of six samples in the range of 0·5 to 5·0 dwt/ton can be completed in two hours. The range may be extended by simple modification to higher or lower values.INTRODUCTIONIn a chromatographic method described previously (Lever 1958, Nevill and Lever 1959), gold from a standard volume of ore clamped between -plate glass was extracted by aqua regia on to the paper. After cautious drying the chromatogram was developed by an ethyl acetate-nitric acid-water mixture and gold was identified by spraying with stannous chloride solution. Sensitivity of the method in the low range was poor. The brown line obtained in the 1-3 dw/j ton range, caused by movement of gold in the reduced form, was not considered to be a satisfactory confirmation of the presence of gold. It was felt that the method would be improved by using a more elegant extraction and applying developing conditions which would produce a well defined purple line at all gold values. Iron was a limiting factor, and a method of eliminating its interference was needed.The method now developed overcomes these shortcomings, and gives a reliable result with a purple line for assay values of 0·5 dwtjton and over. Gold is dissolved from an...

Jan 1, 1964

By James A. Wasson

The Mitchell and Berea sands were cored and logged in Fred Link well K-l, Lower Newport field, Washington County, Ohio. Core and reservoir fluid analyses and available field data were studied to determine if these sands could be successfully waterflooded. The results of the study indicate that there is insufficient oil in place to form an oilbank in either the western Mitchell pool or the Berea sand, and that no commercial recovery of oil by waterflooding can be obtained in these reservoirs.

Jan 1, 1967

By Mamookho Elizabeth Makhatha, Mbal Henock‑Michel Mwanat, Kubangala Brest Kasongo, Ntumba Edward Malenga

This study investigated the operating parameters that affect the kinetic dissolution of copper and cobalt from sulfidic ores. The sulfuric acid concentration, temperature, sodium chloride concentration, particle size range, and leaching time were selected to deduce the kinetic mechanism of the leaching reaction. Other parameters, such as a stirring speed of 250 rpm and the percentage solid 10% w/v, remained constant. The results reveal that an increase in acid concentration enhances the leaching rate of copper and cobalt. Copper and cobalt dissolution was positively affected by the addition of sodium chloride. The highest leaching rates of copper and cobalt were 24.71% and 15.65%, respectively. The chemical control and diffusion control by shrinking core models are well fitted as the kinetic models representing the dissolution of the minerals. The respective activation energies for copper and cobalt dissolution of 10.92 and 31.023 kJ mol− 1 for the chemical control and 18.83 and 37.28 kJ mol− 1 for diffusion reaction control were established from temperature-based experiments.

Aug 26, 2022

By A. H. Mokken

Failed attempts at amalgamation of a gold/osmiridium concentrate, recovered behind pebble mill liners during re-lining, led to the discovery that the gold particles were coated and that nitric acid only could remove the coatings. Following this treatment amalgamation was rapid and resulted in a complete recovery of the gold that otherwise would have been lost in plant residues. Investigations into the nature and formation of the coatings led to the realization that the coatings were impregnations of harder elements, associated with the gold during grinding and driven into the softer gold surface by high pressure, impact and attrition. It was further realized that this phenomenon could be part of gold ore milling, world-wide. With these thoughts in mind the question is asked whether concentration down to micron sizes prior to cyanidation, should not play a greater role in gold recovery.

Jan 1, 1999

By Ernest Baafi

A simulation model RoadSIM using the ARENA modelling system has been developed to evaluate roadway development options for a given development panel configuration. The RoadSIM simulation system has provisions for variability/randomness in operations including cutting and loading at the face, tramming and discharge of coal to the boot end and availability of equipment. The modelling system provides a means for assessing the operational limitations of roadway development practices at a particular coalmine. It is a ?what if? tool that allows a range of equipment, configurations and operating practices to be assessed in terms of achievable advance rates and equipment utilisation. Output from the system is in the form of a dynamic visualisation as well as summary reports and detailed logs of operations over time.

Oct 1, 2009

By D. J. Bauer

The Bureau of Mines has conducted extensive studies on the recovery of alumina from kaolinitic clay by a HCI leaching-HCI sparging process. The current study reports a modification of the process, which involves a double-leaching system. The first leach of the calcined clay is made at as high a HCI acid strength as possible so that the dissolution of aluminum chloride hexahydrate (AlCI3*6H20) is suppressed, Most of the impurities, but very little aluminum, are soluble in the strong acid. After liquid-solid separation and washing, the solids are leached with recycled weak HCI, which dissolves the AICI3'6H2O. The pregnant liquor is separated from the gangue, and AICI3'6H2O is crystallized from solu-tion by injecting HCI gas. A proposed flowsheet is presented, and the effect of bleedstream size on AlC13'6H20 purity is discussed.

Jan 1, 1984

By L. Flett, S. Woods, C. Deredin

"Following a significant reduction in world Imperial Smelting Furnace (ISF) capacity from 2003 to 2008, a major optimization initiative was successfully carried out on the lead upgrading and bulk (zinclead) flotation circuits in the Brunswick Concentrator.This paper describes the process improvements that have taken place in order to reduce the quantity of bulk concentrate:•,Increase in lead upgrading rougher flotation circuit capacity•,Installation of a closed-circuit bulk regrind utilizing MillPebs and 150 mm Cavex hydrocyclones•,Installation of two additional cleaner flotation stages on the bulk circuit•,Optimization of the manipulated variables in the lead upgrading and bulk circuitsINTRODUCTIONThe Brunswick Mine (Xstrata Zinc Canada) is located near Bathurst, New Brunswick and is one of the world’s largest lead/zinc mines. Milling of ore commenced in 1964 from the No. 12 orebody, with an expansion in 1966 to accommodate ore from the No. 6 open pit mine. The planned closure of the mine will take place at the end of the first quarter in 2013. The ore is a complex massive sulphide, consisting of approximately 20% valuable minerals, 60% pyrite and 20% silicates.A simplified flowsheet for the concentrator is given in Figure 1. The overall flowsheet involves SAG milling, secondary ball milling, selective flotation, and dewatering by thickening, filtering and drying. The complexity of the flowsheet evolves from the requirements for fine grinding and the production of four concentrates: zinc (sphalerite), lead (galena), copper (chalcopyrite) and bulk (sphalerite plus galena).Primary hydrocyclone overflow feeds the copper-lead aerator-roughers for flotation at pH 9.0 with soda ash. Plant xanthate (80-20 sodium isopropyl and potassium amyl) and AP407 are used as collectors in the copper-lead circuit. The rougher concentrate is directed to the copper-lead regrind circuit and the tailings are fed to the secondary grinding circuit. The secondary hydrocyclone overflow from the secondary grinding circuit feeds the copper-lead rougher-scavenger banks. Rougher concentrates are reground to a P80 of 28 µm prior to three stages of copper-lead cleaning. The first stage of cleaning is done in an open circuit with the tail reporting to the cleaner scavenger. The cleaner scavenger concentrate reports to the regrind circuit and the cleaner scavenger tail combines with the rougher/scavenger tail to feed the zinc circuit. The second and third stages of cleaning are performed in closed circuit with the cleaner tail being recycled to the copper-lead regrind circuit. The average final concentrate grades 23% Pb, 3% Cu and 704 g/t Ag, and is fed to the copper separation circuit."

Jan 1, 2013

By A. Nieto

This article is a review of previous discussions about underground mining method selection and classification with the purpose to clearly define and classify the two groups of variables (indicators) involved in the mining selection process: key deposit indicators (KDIs) and key mining method indicators (KMIs). This paper provides a simple and clear approach for the classification and selection of a feasible underground mining method based on a predetermined set of favorable deposit characteristics, which are defined as key deposit indictors (KDIs). This article also gives a summary of the key advantages and disadvantages associated with every underground mining method based on their key mining indicators (KMIs). The selection method given in this paper is based on defining field KDIs and comparing them to the KDIs that are favorable to every considered mining method. By cross validating a matrix of favorable KDIs, the paper presents a simple approach to rank several underground mining methods using a scale from favorable to less favorable accordingly to the ore deposit characteristics (KDIs). KMIs are used to further complement KDI rankings by analyzing every method’s KMI performance based on the expected productivity of the mining operation being considered. To further assist the reader through the selection process, this paper gives basic sketches representing each of the primary underground mining methods discussed in this paper. Each method is given using the same 3D isometric view as spatial reference to assist the reader with visual interpretation and comparison between methods.

Jan 1, 2010

By Dayang Datu Khalil, Charle Amoah, Fred Kock

Abosso Goldfields Limited has been optimizing the comminution circuit at the Damang Mine Operation for the treatment of 100% primary ore. The optimization process started at a base rate of 343 tph when treating primary crushed primary ore, and was increased to above 600 tph with partially crushed primary ore. Abosso Goldfields engaged Orway Mineral Consultants (OMC) to assist with the optimization process in 2009 and the two companies have been working together since, to further refine the process. Continuous improvement was achieved through crushing circuit modifications, changes in operating processes and grinding control system utilization. This paper discusses the improvements developed for the increase in milling capacity and improvements in final product size.

Jan 1, 2012

By Benedetto Corain

The production and dispersion of metal nanoclusters onto inorganic supports and amorphous carbon rest on well consolidated technologies belonging to the realm of industrial catalysis and of basic catalysis research (1). In spite of the existence of a variety of specific synthetic strategies, their very rationale relies on three main approaches i. e.: A: precursors of both the metal nanoparticles and of the relevant supports (or the support itself) are intimately mixed (even let to react) at ambient conditions and then thermo-reduced according to very controlled protocols (2); B: precursors of metal nanoclusters are let to be adsorbed onto suitable supports from the gas or liquid phase and subsequently thermally decomposed (3); C: metastable size-controlled metal nanoclusters are previously generated in a liquid medium and subsequently transferred onto pre-formed support particles (4). The production and dispersion of metal nanoclusters onto organic soluble supports is also a rather well documented academic praxis (5, 6, 7, 8) able to provide e.g. size-controlled Au0 nanoclusters of 4.4±1.7 nm (5). Our group started in 1997 developing (9) an innovative approach to the synthesis of metal nanoclusters dispersed inside insoluble, albeit accessible (see below) mechanically robust gel-type resins (10), which procedure was tested so far on palladium metal. Metal ions are previously dispersed upon ion-exchange inside of the polymer framework, followed by chemical reduction and by the aggregation of born metal atoms into nanoclusters, the size of which is templated (11, 12) by the three-dimensional intercommunicating meshes that build up the overall polymer framework (Figure 1).

Oct 1, 2003

By J. Drelich

The wetting behavior of liquid polymers at solid surfaces and the adhesion forces involved at polymer-filler interfaces should always be considered in the fabrication of high quality polymer composites, including those made with mineral fillers. Spontaneous polymer spreading over the filler surface is a basic condition in the fabrication of the polymer-mineral composites. In this regard, the wetting and adhesion characteristics of polymer-mineral systems are reviewed in this contribution. It appears that several aspects of wetting phenomena at mineral filler surfaces are not well described in the literature and require further systematic study. Specifically, it is clear from this review that efforts should be made to determine the effects of mineral surface contamination (including surface hydration) on wetting and adhesion phenomena, and to determine the wetting characteristics of molten polymers at mineral filler surfaces. It is expected that any improved fundamental understanding of wetting and adhesion phenomena for the polymer-mineral composites will provide the basis for further technological development.

Jan 1, 1995