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By Lightfoot BW, Bultitude-Paull J

The Sirosmelt top submerged lancing system has many applications in the smelting of base metal and complex materials. It has particular advantages for smaller scale smelting and the treatment of recycle materials in smelters where its low capital and operating costs and its operational flexibility are of immediate benefit. The system can be fueled by oil, gas or coal, as well as by mixtures of fuels. For many applications, the use of coal as a fuel has operating cost advantages over oil and gas, but conventional pulverised coal feeding systems entail very large capital expenditure and this militates against the use of coal. The methods available for improving on conventional technology for coal firing of Sirosmelt systems are discussed and operating experience with alternative systems are outlined. The use of coal as a reductant in the Sirosmelt system is also discussed.

Jan 1, 1987

By Loo R

The Paper discusses the size and extent of in-pit dust suppression problems created by iron ore mining in the Pilbara region of Western Australia. Dust problems associated with drilling, loading, hauling and tipping are discussed indicating the large quantities of water which can be applied for dust control and attempts that have been made to rationalise this water usage to obtain maximum benefits from the applied water. The magnitude of the problem and the quantities of water involved can be appreciated when one realises that 275 000 tonnes of rock are moved on Mt. Whaleback each day and that there are 40 km of haulroad within the open pit. Initially dust suppression was limited to the spraying of haulroads by large water tankers. Now dust suppression is practiced during drilling and after blasting, wind blown dust is reduced by application, using water cannons,of large quantities of water to floor stocks prior to loading operations as well as by the installation of 16 km of automatically controlled fixed sprinkler reticulation on the main semi-permanent haulroads. The methods used to assess the water requirements for in-pit dust suppression are discussed and the extensive development testing used to evolve the present installations are 1. Environmental Superintendent Mt. Newman Mining Co. Pty. Ltd. Newman, W.A. 2. Chartered Consulting Engineer, Perth, W.A.

Jan 1, 1979

By P Lamberg, M Lyyr, S Heimala, J Liipo

Since the introduction of froth flotation for industrial practice, the process has long been developed and improved by making cultivated guesses or by using trial and error methods to a varying degree. Fresh possibilities have emerged after development of new surface sensitive analysing methods and in situ electrochemical methods. Having had the possibility to combine different findings between science and everyday plant practice, Outokumpu has been able to develop a catch-all procedure to manage a flotation process taking into account the specific requirements set by different minerals in a slurry. A number of these procedures are available and offered globally to clients as part of a Plant Audit service. The Outokumpu Plant Process Audit (Process ef-X) concept comprises of mineralogical determinations from process samples and plant data analysis together with electrochemical process measurements using mineral electrodes. Automatic control loop analysis can also be included. The objective is to combine the results for a basis of flotation process improvement. Since this methodology has earlier been an in-house practice, it follows that the results are also reflected in the development and design of the OutokumpuÆs processing equipment. An increasing number of ores have a very intimate fine-grained texture and it may be physically impossible to combine high grade with acceptable recovery by a flotation process alone. For such cases, combinations of different hydrometallurgical û mineral separation û pyrometallurgical processes are available. Mineral specific information and chemical expertise of flotation technology can be utilised in development of other processes, as well.

Jan 1, 2005

By P S. R Reddy, V N. Misra

The iron ore deposits in India are rich in iron content but usually contains high alumina and silica. The current industrial practice results three products namely lump, fines and slimes. The lump and fines with or without beneficiation are directly fed to the blast furnace and sintering plant respectively while the super fines or slimes are presently discarded as tailings. Around eight million tonnes of iron ore slimes estimated as being 15 - 20 per cent by weight of run of mine ore containing ~48 - 62 per cent Fe, is discarded every year causing huge loss to the Indian iron ore industry. In addition, these slimes stored in massive tailing ponds pose enormous environmental and ecological problems. Extensive investigations have been carried out on three iron ore slimes generated at Barsua, Bolani and Meghahatuburu iron ore mines of India. The studies include physical, chemical, mineralogical characterisation and beneficiation studies adopting conventional hydroclyclone and wet high intensity magnetic separator. The characterisation studies have indicated that most of the gangue minerals are accumulated in finer fractions. The studies on hydrocyclone and magnetic separation had indicated that an iron concentrate of 61 - 65 per cent Fe could be obtained by recovering 59 - 78 per cent of the iron values present in the slimes. Depending on the nature of the slimes the alumina and silica levels have been brought down to 2.5 and 1.0 per cent respectively. The effects of different operating and design variables along with detailed characterisation studies have been highlighted.

Jan 1, 2002

A portable surface impedance meter has been tested extensively over a wide variety of geological formations both in Australia and elsewhere. It has proved a useful geophysical too] for relatively shallow mapping (i.e less than 100 metres depth) of faults, intrusions, dykes and conductive ore veins and can be used as a depth probe for overburden and glacial ice. Case studies involving coal seam mapping at Collide (Qld. Australia), galena ore vein location at Zeehan (Tas. Australia) and glacial ice probing on the Brewster Glacier (South Island, New Zealand) are detailed. The first results of a similar unit using a lower frequency with consequential increase in depth of penetration will be presented. The application of VLF measurements to monitor blasting in mines and in the location of earthquake epicentres will also he introduced.

Jan 1, 1987

The problem of spontaneous combustion has long exercised the minds of Mining Engineers. The idea of inertising an area with a non combustible gas has seemed to be an attractive way to overcome the problem. Various agents have been tried but nitrogen has particular attractions and advantages. Britain adopted the idea from the German industry and found that it was particularly suitable for the conditions in British Mines. Over 8 years much development work has been done and specialist equipment has been developed as the requirements came to be better identified with experience. There is a continuing programme of innovation and the technique can be further developed in the future as a means of protecting the very heavy investments which are being made in today's large capacity, heavily capitalised faces.

Jan 1, 1988

With some notable exceptions, marine placers located just below, or just above, present sea level, are responsible for much of today's production of detrital ilmenite, rutile, zircon, and other minerals of value. The purpose of this paper is to discuss the paleogeographic and paleo-oceanographic factors which may have determined the location of presently submerged marine placers. These factors-include changes in sea level, burial by recent marine sediments, stream capture and other i changes in drainage patterns, and recent changes in climate. Selected geologic situations in the Yellow Sea off the coast of Korea, in the Atlantic Ocean off the coast of Portugal, in the Bering Sea off the coast of Alaska, and in the Arabian Sea off the coast of India, will be used to illustrate the author's point of view.

Jan 1, 1980

By Misk A

Several logging methods are presently available to the oil industry for the evaluation of formation porosity: the Sonic and Neutron logs are already widely used, the Gamma-Ganmia log is being progressively introduced. The readings of these instruments are primarily a function of the rack-porosity, hence the general term of "porosity tools". Apart from porosity, however, other variables such as type of fluid in the pores, nature of matrix and degree of shaliness have an important influence.The response of each device is a different function of such parameters: therefore, a cci bination of porosity tools can lead to information on these variables in addition to the evaluation of effective porosity.For example, the presence of gas; rather than water or oil, in a formation which is not deeply invaded, will tend to give Neutron derived porosity values which are too 'low; on the other hand, the Sonic derived porosity: value will be too high in such- a case. For the same porosity, the Sonic gives a longer transit time in sandstone than limestone, whereas in the low porosity range, the Neutron will read more counts per second in a sandstone than in a limestone of the same porosity. The presence of shale also affects the readings of the various porosity tools in different ways so that the combination of two or more methods may lead, in some cases; to an evaluation of both the-effective porosity and the shale, content.In conclusion, it may be said that the various porosity tools pre-sently available, are, to a large extent, complementary, and that in many problems the use of two porosity tools, instead of one, is very likely to bring valuable additional information.

Jan 1, 1962

The first stage in the refining of lead blast furnace bullion is the removal of copper and this is normally done as a batch process in open kettles,A number of attempts have been made in the past to establish fontinuous processes operating in reverberatory type furnaces, but the growth of accretions in the furnace has always presented a serious problem.This has been overcome in the plant of the Broken Hill Associated Smelters Pty Ltd at Port Pirie by the construction of a reverberatory furnace and ancillary cooling system of novel design.Although a number of mechanical and metallurgical problems still remain to be solved, it is claimed that a workable continuous copper drossing process has been established.

Jan 1, 1963

By Kitzinger F

The economic climate of the Canadian mining industry forced an increased interest in rapid, continuous excavation techniques for hard rock formations. The potential applications and advantages of continuous mining over the present drill- blast-muck labour intensive cyclical methods are considerable. Noranda investigated an electrical technique, Plasma Blasting showing considerable promise for mining hard rock. The background of the technology and the theory of blasting rock with electricity is described. The Plasma Blasting process is based on the fast discharge of stored electrical energy into a small amount of electrolyte, suitably located in the rock. The electrical energy converts the electrolyte into high pressure plasma, which expands very quickly, thereby, generating a shock wave. This shock wave produces a stress field inside the rock, resulting in a blast similar to that made by chemical explosives, but without the deleterious fumes. Noranda is currently blasting boulders of 4-5 tonnes and is at present constructing a mobile, autonomous secondary rock breaker for underground and open pit applications. Tests on in situ hard rock formations will lead to the development of a continuous mining machine. Production rates of 500 tonnes per man-shift could be obtained with such a machine.

Jan 1, 1990

The first introduction of automatic control systems for flotation occurred about fifteen years ago. The early control work coincided with the introduction of on-line assaying using XRF techniques. This OSA availability, coupled with the emergence of small digital computers suitable for process control in the late 1960-s, meant that the necessary process information and control hardware existed for flotation control experiments. A period of intensive research related to flotation control. ensued. A great deal of effort was devoted to the development of mathematical models of flotation. Plant experimentation sought to understand the effects of a range of flotation variables on the process. Finally, control loops were proposed and plant tested. An evolutionary pattern emerges when the range of flotation control installations is examined. The earliest systems had as objectives process stabilisation using reagent control. There were also some early attempts at flotation optimisation procedures, again using reagent variation. Current work is still associated with the same objectives. One of the difficulties with flotation control has been to recognise and define clear and precise control objectives. More emphasis is now placed on cleaner control which has the advantage that the objectives are usually well defined. A number of flotation control systems which cover a range of control system types is discussed. Based on this accumulated experience,a list of good and bad practice in flotation control is Proposed.

Jan 1, 1983

By P Waters

BHP Billiton Iron Ore initiated a program in January 1995 at the Mt Whaleback operation in Newman, Western Australia to develop a closure plan for the overburden storage areas (OSA), which have the potential to generate acid rock drainage. The primary research program includes the development of technology for the long-term performance of OSAs with respect to slope stability, surface run-off, erosion, water infiltration and vegetation. The objective is to control acid rock drainage by preventing moisture movement into and through the OSA material. Infiltration to the underlying OSA material and closure costs are minimised due to the presence of the run-of-mine (ROM) cover material. A summary of the field data is presented to illustrate low percolation rates to the underlying OSA and key performance characteristics of the moisture store and release cover system design. Field data collected to date demonstrates that a moisture store and release cover system constructed with suitable ROM material has good potential as a final cover system at the Mt Whaleback site. The performance of the cover system on a sloped surface was significantly different as compared to placing the cover system on a horizontal surface.

Jan 1, 2003

By C F. Prins, C LantuTjoul

Mineralisation in alluvial diamond or vein gold deposits is often hosted in trapping mechanisms. For instance, diamonds are nested in bedrock depressions such as gullies and potholes which were carved out by the sea long before the diamond deposition took place. Similarly, gold mineralisation can precipitate in the necks of a boudinage structure. In such deposits, the spatial distribution of the mineralisation is governed by the mutual arrangement of the trapsites and by the grade variations within each trapsite. Reliable estimates can be obtained only if they rest on a proper knowledge of both degrees of variability. This creates a challenging sampling problem, as during the exploration phase it is important to have a good global mean estimate to enable decision making towards the future. A similar problem occurs for local estimates at a later stage of development. To understand and manage the sampling for global means, specific sampling procedures are required based on an appropriate choice of sample support size and spacing. Estimates from such sampling campaigns should be unbiased, and the less variability they display, the better the sampling parameters. The performance and impact of sampling parameters are tested and compared on different simulated deposits.

Jan 1, 2005

The Jurassic Walloon Coal Measures crop out over much of the Moreton Basin and contain numerous thin, banded coal seams which have been mined at various locations since the 1870s. Historically most mining has been by underground methods. Increased exploration during the 1970s and 1980s has led to the delineation of significant open cut coal resources and to the development of the Oakleigh, Jeebropillly and Ebenezer open cut coal mines in the Rosewood-Walloon area. Over 2 170 million tonnes in-situ of shallow, high volatile bituminous coal with a mean maximum vitrinite reflectance of between 0.5 and 0.6 have been proven in the Basin.

Jan 1, 1991

The Mineral Research Centre is located at Perth in the suburb of Waterford, adjacent to Curtin University of Technology and within a Technology Precinct which includes Technology Park. The Centre, constructed by the WA Government at a cost of $16 million and occupied in late-1994, comprises three separate buildings housing the CSIRO Division of Minerals, Curtin University's School of Chemical Engineering and the Mineral Processing Laboratory of the Department of Minerals and Energy. The emphasis on R&D at the Centre is primarily in hydrometallurgy as a result of staff expertise, extensive bench and pilot-scale facilities, track record with the industry and, very importantly, two of the occupiers being partners in the AJ Parker Cooperative Research Centre for Hydrometallurgy. Staff in the Centre have a long involvement with R&D agencies such as AMIRA and MERIWA. The hydrometallurgical focus of the Centre complements that of pyrometallurgy at the GK Williams CRC in Melbourne and the Centre for Mining Technology and Equipment in Brisbane, to ensure that the mineral processing industry in Australia has access to a complete range of expertise and facilities to serve its needs.

Jan 1, 1996

An empirical kinetic model is discussed that enables the number of stages in a carbon-in-pulp plant and the amount of carbon in each stage to be calculated for any desired metallurgical performance. It is shown that a knowledge of the kinetics of gold extraction by activated carbon in each stage assists plant operators in the important' areas of process control and optimization. Factors such as mixing efficiency, concentration and distribution of carbon through the plant, bypassing of pulp through a stage, and carbon poisoning are examined. The resin-in-pulp process for the extraction of gold cyanide is also discussed, and the chemistry of absorption and elution on strong- and weak-base resins is examined. In addition, operating results from a small-scale resin-in-pulp pilot plant are presented, and various applications in which resin-in-pulp may be preferable to carbon-in-pulp are discussed.

Jan 1, 1982

By C V. Putnis, T Geisler, A Putnis

In nature, ilmenite (FeTiO3) undergoes weathering through oxidation and removal of Fe to form an apparently continuous series of compositions from ilmenite to pseudorutile (ideally Fe2Ti3O9), and with further weathering, to leucoxene. To determine the mechanism of acid-leaching of ilmenite to ultimately form rutile, we have carried out an experimental study of ilmenite alteration in autoclaves at 150¦C in HCl solutions. Resulting products were studied by X-ray diffraction, scanning electron microscopy, electron microprobe and Raman spectroscopy. In some experiments the solution was initially enriched in 18O and the distribution of the isotope in the alteration products mapped from the peak shift in the Raman spectra. The results indicate that the alteration may proceed in two stages, each with a sharp interface between the parent phase and the product. The alteration begins at the original ilmenite crystal surface and along cracks through which the fluid can migrate. The first alteration product is pseudorutile û no phases intermediate between ilmenite and pseudorutile were detected. The textural relationship between ilmenite and pseudorutile suggests a coupled dissolution-reprecipitation mechanism rather than a solid state continuous oxidation and Fe diffusion mechanism. The second stage involves a further dissolution-reprecipitation step to form rutile. Raman spectroscopy shows that the 18O is incorporated in the rutile during the recrystallisation. Throughout the alteration process the original morphology of the ilmenite is preserved although the product is highly porous. The rutile inherits crystallographic information from the parent ilmenite, resulting in a triply-twinned rutile microstructure.

Jan 1, 2008

By Sandenbergh RF

The debate on the mechanism of adsorption of gold and silver di-cyanide onto activated carbon could be divided into two schools of thought. On the one hand, it has been proposed that the combined effects of electrostatic and chemical interaction between the activated carbon surface and adsorbing gold di-cyanide anion results in the adsorption of the latter. On the other hand the `ion-pair' adsorption reaction mechanism has been vigorously advocated as the dominant mechanism responsible for the adsorption of gold di-cyanide onto activated carbon. It is maintained that gold is adsorbed onto the carbon surface as the neutral ion-pair [M"+][Au(CN)z ]". Adsorption is viewed as the result of mainly the chemical interaction while electrostatic interactions are neglected. The validity of the `ion-pair' adsorption mechanism may be challenged on a number of counts. However, the alternative mechanism (based on aqueous surface chemistry principles) has not gained general acceptance yet, because it has not been applied widely enough to explain the different adsorption phenomena associated with gold di-cyanide on activated carbon. In the present study the case in favour of an adsorption mechanism based on general aqueous surface chemistry principles is presented. A model framework is developed for the adsorption reaction mechanism of gold di-cyanide onto activated carbon which incorporates the effects of chemical and electrostatic interactions between the dissolved species, the aqueous solution and the carbon surface. This model is then employed to explain a wide variety of reported adsorption phenomena for gold di-cyanide on activated carbon, such as the effects of pH, the adsorption of different metal cyano complexes, ionic strength, and type and concentration of cations in solution. In addition the effects of cyanide and dissolved oxygen concentration were investigated. No ready explanation, in terms of aqueous surface chemistry principles, is yet available for the switch in adsorption behaviour that agrees with ion exchange to ion-pair adsorption with increasing ionic strength.

Jan 1, 1997

By J Chßvez, J Rosa del Castillo, J Rui

Environmental Impact Assessment (EIA) and Feasibility Studies (FS) were carried out to evaluate the potential use of treated acid mine drainage (AMD) occurring at the Kingsmill Tunnel in the Central Andes of Peru. The 11 km long tunnel drains the underground works of the Morococha Mining District and discharges about 1.25 m3/sec of AMD directly into the Yauli River in the Amazon Basin. The communities living downstream cannot use the Yauli River water due to its low pH and elevated concentrations of metals (eg Cu, Zn, Fe, Mn, As, Cd) and sulfate. Studies carried out for this project included technical feasibility, EIA, economic viability and social impact assessment phases. During the æTechnical FeasibilityÆ phase, the treated AMD was produced by simulating a high density sludge (HDS) lime neutralisation/ precipitation process and was evaluated for various potential uses. Mining companies located in Morococha, in particular Centromin Peru SA, and the Water Works Company of the City of Lima (Sedapal) collaborated with Golder Associates during the studies. The Canadian International Development Agency (CIDA) provided the financial assistance. The results of the physical, chemical, biological and toxicological analyses demonstrated that the AMD could be sufficiently treated to be potentially used to supplement the drinking water supply of Lima, and for agricultural (eg irrigation and livestock) and recreational purposes. Process design and scale-up parameters were also determined for implementation of the full-scale treatment facility at the site. The use of the treated AMD as a drinking water supplement would be economically feasible.

Jan 1, 2003

By B, R E. Browner, H R. Watling

A number of hydrometallurgical treatment methods are being developed to extract copper from chalcopyrite flotation concentrate including microbial leaching and ferric sulfate leaching. However, chalcopyrite is difficult to process efficiently by hydrometallurgical methods as it exhibits slow reaction kinetics. Comparative leaching tests do not always satisfactorily explain or predict observed copper recovery, acid consumption, or differential leaching of minerals. This is especially true when reactive gangue constituents are present. The aim of this study was to determine how the leaching regime (microbial versus ferric sulfate) affects both the extraction of copper and residue mineralogy. Chalcopyrite flotation concentrate was leached at 30¦C and 65¦C using a pure culture of Acidithiobacillus ferrooxidans and a mixed consortium of thermophiles, respectively. In addition, the concentrate was leached at the same temperatures using 0.1 M ferric sulfate. Microbial leaching of chalcopyrite extracted more copper than ferric sulfate oxidation of chalcopyrite at 30¦C, demonstrating that the microbes promoted the solubilisation of copper at this temperature. This result was confirmed by leach solution analyses and residue analysis using quantitative X-ray diffraction (QXRD). More chalcopyrite was oxidized with ferric sulfate at 65¦C than at 30¦C (as expected). QXRD confirmed that pyrite reacted during ferric sulfate leaching at 65¦C but was relatively unreactive during lower temperature leaching. The high ferric ion concentration in the ferric sulfate leach at 65¦C led to significant precipitation of jarosite. This phase was only detected in small amounts at 30¦C in both the microbial and ferric leached residues. Sulfur also precipitated in the ferric leaching at 65¦C whereas no sulfur was detected in the microbial leached residue. Quartz was a relatively unreactive mineral phase regardless of the leaching medium and temperature. QXRD analysis indicated the residue mineralogy differed with different leaching regime.

Jan 1, 2004