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By O. Bouaziz, O. Magnea, P. Cugy, E. F. Rauch

The experimental difficulty to perform Equal Channel Angular Extrusion (ECAE) of a bulk sample of hard material such as steel was overcome. The original method proposed in this paper consists in replacing the bulk sample by a stack of alternated hard metal (steel) and soft metal (aluminium) sheets. By applying this procedure to an Interstitial Free steel (IF steel), 2.7µm grain sized material was obtained after recrystallisation. Its mechanical properties (hardness, formability in shear, hardenability and faigue limit) were investigated and compared with the properties of the same IF steel with conventional grain sizes (12m and 25µm).

Jan 1, 2004

By Hasini Wijayaratne

Anode cover material, a mixture of crushed electrolyte and alumina, is a crucial part of an aluminium reduction cell because of its important role in maintaining overall heat balance. However, until recently little attention has been given to understanding or controlling its composition and quality. The thermal conductivity of anode cover material determines the extent of the heat loss from the top of the cell. This will change as a function of the granulometry and composition of the applied cover as well as over time as the cover material consolidates on top of the cell. The ability to measure or predict the thermal conductivity of fresh and ageing cover is an important tool for managing cell heat balance. Recent studies have shown that granulometry or more correctly, voidage is likely to be the predominant determinant of thermal conductivity of anode cover materials. We have developed equipment to measure the thermal conductivity of granular cover material and tested the relative importance of composition (ratio of alumina to crushed electrolyte) and granulometry/voidage on cover thermal conductivity. In general, our results confirm that granulometry is the dominating factor. Generally, high voidages contribute to lowering the thermal conductivity especially when particles are mostly fine. However the relationships between granulometry, voidage and thermal conductivity are complex due to the varying nature of heat transfer between particles. Aging of granular cover material occur during cell operation forming a consolidated crust due to exposure to heat and fumes over time. Structure and thermal behaviour of this consolidated crust is also important in understanding the overall properties of cover. This paper presents the outcomes of laboratory studies conducted in order to understand the thermochemical behaviour of anode cover material and in particular, the role of fines in anode covers mixtures.

Jan 1, 2011

By Stavros A. Argyropoulos, Radhakrishna Valiveti, Bernard Closset

"The use of microprocessors in metallurgy is currently increasing at a very fast rate. A large number of companies are offering systems ""off the shelf"" which are aimed at the data acquisition and process control market. There are two main drawbacks to these systems: first, they are usually quite expensive, and second, they are not completely compatible with the target metallurgical application. An alternative is to develop a microcomputer-based system "" in lab "".A dedicated microcomputer system has proved to be very useful in many metallurgical research applications(1,2)). However, in this system the analog input signals had to be transferred over long distances , and significant noise was introduced despite the use of shielded cables. In order to overcome this problem a network of low pass-filter s was designed and built. The usage of the abovementioned system brought the need to digitize the analog signals in-situ and transfer the digital signals, which are much less susceptible to noise over very long distances. This distinctly different design philosophy has become a reality with the evolution of microprocessor technology over the last few years. This design philosophy is utilized in this development."

Jan 1, 1984

By Christina Graf

A synthesis of colloidal gold shell particles with a silica core is described. Small gold nanoclusters were attached to the functionalized surface of colloidal silica particles. Reductive growth and coalescence of these clusters lead to the formation of a closed gold layer. By variation of the thickness of this gold layer and the radius of the shell it is possible to adjust the plasmon resonance of the gold shell particles over the whole visible and infrared region of the spectrum. The optical properties of the particles made are in good agreement with theoretical calculations for coreshell particles. Due to their low polydispersity these gold shell particles form in solution large crystals with submicron lattice constants. It is also possible to produce hollow gold shells by dissolution of the silica core. A new method to coat the silica core gold shell particles with an additional outer silica shell is also presented. This allows due to a reduction in the Van-der-Waals forces to make more permanent dried crystals and facilitates functionalization of the particles for use in various photonic applications.

Oct 1, 2003

By S. Caron, M. Bourassa, J. Châteauneuf, L. Tardif

"Since many years, the Yvan-Vézina gold plant custom mills and processes different ore types that show different behaviors. Because of this, cyanidation control is more complex than for a typical milling operation. In 1992, a Cyancor™ on-line « free cyanide » analyzer has been installed for monitoring and optimizing cyanidation. This implementation significantly reduced cyanide consumption for the overall cyanidation process. In order to further reduce cyanide costs, an automatic control strategy has been implemented to decrease fluctuations of« free cyanide » from their set points.This paper outlines the major steps of the project: process control audit, control strategy development, implementation and running-in period. Control strategy features include data filtering modules, adaptive PID algorithm and set points management modules are also presented. Finally, the strategy efficiency is illustrated with load-disturbance responses.IntroductionLocated in northwestern Quebec, the Yvan-Vézina plant has an average capacity of 1300 t/d using carbon-in-pulp technology. In 1991, the Yvan-Vézina gold plant was processing three types of ores (Beauchemin, Mouska and Silidor mines) and a pyrite concentrate (Beliveau mine). A cyanide reduction program was then undertaken to reduce « free cyanide» fluctuations <6>. To reach this objective, the optimum cyanide concentration was determined for each ore, a continuous monitoring method with the Cyancor™ on-line analyzer was developed and a tighter control of cyanide addition was applied. These modifications to the leaching practice significantly reduced cyanide consumption.After a while, it was observed that regulation of « free cyanide » concentrations could still be improved by the use of an automatic control strategy. Yvan-Vézina and CRM began collaborating in 1995 to develop and implement such a strategy. Results show that main disturbances of the circuit (e.g. ore mineralogy and pulp feed rate) can be significantly overcome in order to reduce their effects on the leaching operation."

Jan 1, 1998

By G. Shen, W. R. Tyson

In most fracture toughness test standards, such as ASTM E 1290 and BS 7448, crack-tip opening displacement (CTOD) is measured by using three-point bend (SE(B)) or compact (C(T)) samples with deep cracks. The loading mode and crack depth in these tests sometimes are different from that of pipelines. Pipelines usually have shallow defects and experience tensile loading when the supporting ground moves. As a result, the CTOD measured by these samples is lower than that of pipeline in tension. Recent researches suggest using single-edge-notch tension (SE(T)) samples to measure fracture toughness for pipelines. In the present study, shallow and deep SE(T) samples under fixed grip loading were analyzed by using the finite element technique. An equation to relate the CTOD to the area of the load/plastic crack mouth opening displacement (CMOD) is proposed. With this equation, the CTOD of a SE(T) sample can be evaluated by measuring the area under the load/plastic CMOD curve of a SE(T) sample.

Jan 1, 2005

By J. H. Sokolowski, R. I. MacKay

The level of Si and Cu in the 3xx series of alloys affects the volume fraction of the a-Al dendritic phase and the Al-Si eutectic phase. The volume fraction of these phases in turn affects the feeding conditions during solidification and ultimately the Area Fraction Porosity and Mean Pore Diameter measured in the as-cast structure. This work sets out to establish the relationship between the volume fraction of the a-Al dendritic phase and the Al-Si eutectic phase and the resulting porosity that forms on the Monotonic and High Cycle Fatigue properties. The alloys in question are the Al-9%Si-l %Cu and a Al-7%Si-4%Cu alloys which were cast into V8 performance engine block castings and then heat treated to achieve desired mechanical properties. The engine block castings provided the mechanical and metallographic test samples analyzed for this work.

Jan 1, 2006

By Y. Mudryk, D. Paudyal, K. A. Gschneidner, V. K. Pecharsky, M. Khan

"Rare earth intermetallic compounds are utilized commercially as magnetic and battery materials, electron gun electrodes, etc. Several of these intermetallics will be briefly discussed. There are many other rare earth intermetallic compounds which are not utilized industrially but have unusual properties which are of fundamental interest and may have future technological applications. Several of these materials are discussed as well.INTRODUCTIONTens of thousands of rare earth intermetallic compounds exist, but physical properties (primarily their magnetic behaviors), other than their crystal structures have been measured for only a small percentage of these materials. Among these are the commercially important compounds: Nd2Fe14B, and the SmCo5 – Sm2Co17 family – well known high strength permanent magnets; (Tb0.3Dy0.7)Fe2, Terfenol-D, a giant magnetostrictive material; LaNi5Hx a critical component of the rechargeable Ni metal hydride batteries; and LaB6 an electron emitter. There are, however, many other intermetallic compounds which are not utilized industrially, but none-the-less, exhibit interesting, and sometimes, exotic physical properties which are of fundamental interest and may have some future technological significance. These include: the giant magnetocaloric effect compounds Gd5Si2Ge2 and La(Fe13-xSix)Hy; the RCu and RAg families of ductile intermetallics; the mixed intra-lanthanide (R,R')Al2 compounds in which magnetic transitions disappear and reappear as one R is substituted for by R'; and GdNi which exhibits large dilations along two crystallographic directions and a larger contraction in the third direction at the Curie temperature resulting in zero volume change as GdNi orders magnetically via a second order phase transition.COMMERCIALLY IMPORTANT INTERMETALLICSNdFeB Permanent MagnetsThe Nd2Fe14B permanent magnets were discovered in 1984 independently in the USA and Japan. It is a ferromagnet and with proper heat treatment and processing Nd2Fe14B is the strongest near room temperature permanent magnetic material known today. This intermetallic compound is utilized as a permanent magnet in many applications, such as electric motors (e.g. the modern automobile contains up to 35 electric motors), spindles for computer hard disc drives, microphones and speaker magnets for cell phones and other audio equipment, direct drive wind turbines, actuators, and Magnetic Resonance Imaging (MRI) units. There are two kinds of NdFeB permanent magnets – bonded and sintered. The bonded magnets have a lower magnetic strength than the sintered magnet. The highest strength magnets are obtained by small substitutions of Dy (up to a maximum of 10%) for Nd, because Dy can significantly increase the coercivity and thus the energy product (a measure of the magnetic strength or hardness). The bonded magnets account for about 12% of the NdFeB market (~82 metric kt per year, containing ~20 kt/a of Nd). The NdFeB permanent magnet market is growing at a rate of about 15% per year. (Burzo & Kirchmayr, 1989; Kobayashi & Hirosawa, 2001; Coey, 2011)."

Jan 1, 2012

By T. Miura, Y. Mori, H. Aoki

In a flash smelting furnace, easily combustible concentrate particles excessively oxidized and melt. The excessively oxidized molten particles then collide with less oxidized solid ones to create uniform oxidized molten particles. This collision phenomenon plays a very important role in achieving high smelting performance. The authors developed a mathematical model describing above combustion phenomena. This model incorporated fluid flow, heat and mass transfer, chemical reactions and collisions of concentrate particles. Both gas flow and particle motion were calculated using the Eulerian method. Copper concentrate was assumed to consist of chalcopyrite(CuFeS2). Considered in the concentrate reactions were the decomposition of CuFeS2, and the oxidation of the resulting sulfur(S) and pyrrhotite(FeS) to produce magnetite(Fe30 4) and sulfur dioxide(S02). Moreover a reaction due to concentrate particle collisions, in which Fe304 in the excessively oxidized molten particle reacts with FeS in the less oxidized particle, was also considered. The particle collisions were assumed to occur according to a collision probability rule obtained by computational experiments. Particle growth in diameter was described as a change in the volume fractions of particle phases. When applied to a commercial flash smelting furnace, this model reproduced the particle growth and component transfer as observed in the actual furnace.

Jan 1, 2007

By K. Barbetti, J. Avraamides

"The processing of gold ores with high silver contents can provide operational challenges, such as high cyanide consumption, retardation of gold leaching and competition during adsorption stages of carbon-in-pulp/leach/column (CIP/CIL/CIC) circuits. In particular, the silver, which is about 1.5% of the value of gold, competes with gold during carbon adsorption due to its higher concentration in many Ag-Au ores, potentially leading to gold solution losses. Fresh and partially fouled (barren and regenerated) activated carbons were evaluated at various Ag:Au ratios and total metal concentrations with regard to the adsorption kinetics and equilibrium loadings. Conventional Freundlich isotherms were found to be highly inaccurate for predicting equilibrium loadings in the competitive adsorption environment. An integrated model, which incorporates competitive adsorption kinetics with a modified competitive adsorption isotherm model has been developed and validated using plant and laboratory data. The model performance and some of its salient features will be discussed.INTRODUCTIONThe processing of gold ores with high silver contents can present a range of operational challenges, such as high cyanide consumption, retardation of gold leaching and competition in carbon adsorption circuits. Silver is often present at significantly higher concentrations than gold in many gold-silver ores and competes with gold in carbon adsorption circuits, limiting the gold loading rate and capacity, resulting in gold solution losses and reduced gold recovery.Curtin University’s Gold Technology Group has evaluated fresh and partially fouled (barren and regenerated) activated carbons at various Ag:Au ratios and total metal concentrations to determine the adsorption kinetics and equilibrium loadings for gold and silver. Conventional Freundlich isotherms were found to be highly inaccurate for predicting equilibrium loadings in the presence of both gold and silver.An integrated model, which incorporates competitive adsorption kinetics with a modified competitive adsorption isotherm model has been developed and validated using plant and laboratory data. This paper describes the model performance and some of its salient features."

Jan 1, 2016

By C. R. Hocott

"IntroductionRESEARCH in petroleum production consists primarily in investigations related to the drilling for and recovery of oil. As an organized activity of individual oil companies, production research is now 30 to 35 years old, and the petroleum industry may point with justifiable pride to the achievements of this third of a •century. Emphasis on research has grown through the years until at the present time many of the larger companies operating in the United States •have well-organized production research staffs.In addition to the efforts of the oil companies, significant research and development in petroleum production technology have been performed by oilfield service companies and others. Valuable contributions have been made through fundamental research carried on by the U. S. Bureau of Mines and by various colleges and universities, both in their own programmes and in programmes sponsored by industry, such as those of the American Petroleum Institute. However, the total effort of these groups is small when compared to the sum of the effort devoted to research by the individual .oil companies. In contrast to some industries which conduct the major portion of their research through co-operative, sponsored research at universities or research institutions, research by the petroleum industry is done predominantly by individual company research staffs. These industrial research groups have usually been organized in such a way as to provide liaison and co-ordination with operating technical staffs. In this way, the research groups are kept aware of the major problems confronting the operating departments and, correspondingly, the operating technical people •are able to keep informed on research activity and progress. This type of close contact generally results in prompt testing of research developments in actual operations."

Jan 1, 1953

By J. U. MacEwan

Introduction The equilibrium between copper, zinc, and chlorine may be considered as the simultaneous equilibrium of the two separate chemical reactions of formation of the stable chlorides of copper and zinc at the temperature of the reaction i.e., l440°K. (1,167°C., 2,133°?F.)§ [Zn(g) +Ciz(g) ZnCl2z(g). ... (1) ] [2Cu(l)+Cbi&apos;g) Cu2Cl2(l 1 ....... (21 ] Subtracting, [Zn(g) +Cu2(Clz(l i ZnClz(g) +2Cu!l) ... . (3) ] If this reaction is carried out with a copper-zinc alloy at some constant temperature above the melting point of brass, and at a total pressure of one atmosphere, the equilibrium concentrations obtained will depend on the free energy decrease .of the reaction as written in (3) and on the activities of the various components in. the reaction mixture. If the equilibrium is examined from the point of view of the phase rule, it is a three-component system, and if it exists in two phases (liquid and gas) it will have three degrees of freedom. If the restrictions of constant temperature and pressure are imposed, the degrees of freedom are reduced to one. This means that, in a two-phase system under these conditions, each different alloy phase will be associated with a gas phase of constant composition.

Jan 1, 1951

By Fred Horne

1N THIS PAPER, the writer proposes to limit his comments to few generalized phases of the subject, based on his personal experience in the midwestern United &apos;States and in one section .of the Coal Branch in Western Alberta. The following statistics are submitted to show the importance that strip mining has assumed in the coal mining industry of the United States. In 1914, 1,281,000 tons of strip coal were produced, amounting to 0.3 per cent of the total production. In 1948, the total was 13~,505,000 tons, representing 23.3 per cent. In 1949, the percentage figure dropped slightly and this can be partially accounted for by the labour disturbances prevalent throughout the year. In 1914, there were 48 power shovels and draglines being used in the stripping of coal; in 1949 there were 3,712, not to mention other types of coal stripping equipment such as bulldozers, tractors and scrapers, rotary excavators, and stackers. At the bituminous coal mines in Western Canada, strip mining was introduced only a few years ago, two of the major reasons for its development being the need for increased production during the war and post-war years and the need to hold the line on increasing production costs, but even in these few years the percentage of strip production has in-creased to such an extent that some mines that, five or six years ago, were producing all their tonnage from underground operations are today obtaining up to 80 per cent of their total output from strip mines.

Jan 1, 1951

By G. Zeng

Although the solubility of oxygen in zinc electrolyte is less than 9 mg/L, the effect on deposit stability and zinc-dust consumption can be significant. Sodium sulfite is used to deoxygenate the electrolyte. The effect of the sodium-sulfite concentration on cobalt removal is investigated. The results show the reduction of sulfite to elemental sulfur that adhered to the zinc dust surface forming a passivating layer, and small amounts of sodium sulfite have no effect on cobalt removal. The optimum amount of sodium sulfite is 100 mg/L. It is an important consideration in purification circuits to use sodium sulfite as an additive to cobalt cementation.

Jan 1, 2005

In this study, flotation of fine galena, chalcopyrite and pyrite was performed after grinding with different extent of oxidation-reduction condition adjusted by grinding media. Sodium dithionite and iron ions were added in mill to simulate pulp potentials and iron oxidation species produced by grinding media, respectively. The types and quantities of the metal oxidation species on mineral surfaces were determined by EDTA extractions, while the surface electrical properties of minerals and interaction of different types of metal oxidation species were studied by zeta potential measurements. It was found that the nature and concentration of the absorbed metal oxidation species were dependent on oxidation atmosphere controlled by the iron amount of grinding media. These species interacted with each other and had an important role in determining flotation of fine galena and chalcopyrite as well as activation of fine pyrite by lead and copper.

Jan 1, 2006

By Ajit K. Sinha

"Abstract - Electromagnetic surveys were conducted over the Yava sandstone-hosted lead deposit in Nova Scotia to evaluate the usefulness of such surveys for detecting and mapping sedimentary­ hosted metallic ore deposits. Both transient and multifrequency systems were used for that purpose. The deposit consists of three zones of disseminated galena which also contain minor amounts of pyrite and sphalerite filling the interstices of the sandstone grains. Each zone overlies a basement depression and is separated from the adjacent zone by an intervening basement high. A conductive shale layer underlies the galena-rich sandstone formation at all three zones.Because the concentration of galena (3% to 4% ) and other sulfides is too low to affect the resistivity of the sandstone formations for detection by ground electromagnetic (EM) methods, the strategy for our survey was to look for areas of basement depressions and the presence of conductive shale in those depressions by EM depth soundings. The presence of the galena-rich sandstone formations could be inferred because of the close association of these two features with the deposits in the Yava area. Both transient and multifrequency EM systems were successful in mapping the basement depressions and detecting conductive shale at the three known mineralized zones. The technique, therefore, seems to offer good prospects for mapping similar stratabound sedimentary-hosted sulfide deposits."

Jan 1, 1993

By D. M. Xue, T. B. Li

"With the increase of human engineering activities, global climate change and active plate tectonics movement, the giant landslide frequently occurred in southwest China, which caused huge property and human losses. Besides, the potential landslides pose severely threaten to the construction and operation of airports, railways, highways and power stations etc. In order to provide accurate guidance for the landslide investigation, stability analysis and mitigation, the giant landslide is redefined according to landslide volume, depth of slip surface, complexity of landslide mechanisms, and degree of landslide mitigation difficulty, and classified with the typological classification approach based on the twofold attributes of landslide behavior including formation mechanisms and reactivation features. Finally, the threefold particularity of the giant landslide is also summarized, which enables a more effective landslide mitigation design.INTRODUCTIONWith the increase of anthropogenic activities, global climate change and active plate tectonics movement such as continual uplifting of Qinghai-Tibet plateau and strong earthquakes, the occurrence of giant landslides was in ascending trend in southwest China (Huang, 2009), which caused serious destruction, and greatly endangers such engineering construction from safety, time and economic aspects as airports, railways, highways, power stations, etc. Giant landslides have huge scale, complex formation/reactivation mechanisms and mechanical behavior. They may not be identified during the hazard investigation, but may be firstly initiated or reactivated due to the following engineering activities, heavy rainfall or strong earthquakes. Consequently, the landslide mitigation is inevitable and costly. However, it is difficult to control the deformation of giant landslide with lack of a correct understanding of genetic mechanisms (Marui, 2012; Zhang, 2000) and the excessive large sliding forces of the slide blocks calculated by the conventional limit equilibrium method. For instance, the failure of anchored pile wall for the No.102 giant ancient landslide (Zhu et al., 2012) and stabilization measures for the Sidi Rached viaduct landslide(Guemache et al., 2011); four rows of piles had not prevented the occurrence of the No.12 landslide in a high fill slope in the Panzhihua airport (Li et al., 2012)."

Jan 1, 2015

By Philippe V. Scheers

Polycrystalline gold, glassy carbon and gold-activated glassy carbon electrodes were compared for the production of hydrogen peroxide by the cathodic reduction of dissolved oxygen. Gold was deposited on glassy carbon by sputtering with a sputter coater and by electrodeposition from a diluted KAuCl4 solution using short potential steps. The sputtered gold particles were not adherent enough, but there were no adhesion problems with the electrodeposited gold particles. The gold coverage of the glassy carbon surface could be varied by applying a different number of potential steps. The overpotential for the electroreduction of oxygen to hydrogen peroxide decreases with increasing gold coverage of the glassy carbon surface, and for gold coverages exceeding about 16 %, the overpotential is close to that observed on polycrystalline gold.

Oct 1, 2003

By Andrew Artzer, Michael Moats, Jack Bender

Antimony and bismuth in copper electrorefining electrolytes can cause cathode contamination, leading to the careful control of their concentrations. This study examined the laboratory scale removal of bismuth and antimony from an electrorefining electrolyte using a solvent extraction mini-pilot plant. The ability of a proprietary phosphonic acid ester extractant (REX-2) in a commercial diluent was studied in a simulated commercial setting. Antimony and bismuth were both extracted effectively from the electrolyte (72% Bi and 70% Sb removed) and Bi was effectively stripped (92% Bi recovered) with 400 g/L sulfuric acid. A final strip solution was obtained from the SX circuit containing 0.36 g/L Bi, 0.043 g/L Sb, 1.3 g/L Cu, and 0.18 g/L As. Unfortunately, most of the extracted Sb remained in the organic phase. Following the pilot study, experiments were performed to examine the precipitation of bismuth from the aqueous strip phase and the removal of antimony loaded on to REX-2. INTRODUCTION For many years, antimony and bismuth have been some of the most problematic impurities in copper electrorefining (ER) (Bardwell & Lapee, 1933). Along with surface roughening, high concentrations of Sb and Bi can contaminate the copper cathode and precipitate at the copper grain boundaries. This drastically reduces the drawing ability of the metal (Bender & Emmerich, 2016). For these reasons, it is necessary to control Sb and Bi concentration in the cathode, which is done by controlling their concentration in the electrolyte. Conventionally, Sb and Bi concentrations are controlled by maintaining a proper As/(Sb+Bi) molar ratio in the anode and arsenic concentration in the electrolyte. Antimony and bismuth are removed during electrolyte purification using liberators (electrowinning cells) and/or ion exchange. Liberators treat an electrolyte bleed stream from the ER circuit and electrodeposit increasingly impure copper as the copper concentration of the solution decreases. Traditionally, first stage liberators reduce the copper concentration from ~45 g/L to ~15 g/L and produce saleable copper. Second stage liberators decrease the copper concentration to ~8 g/L (Biswas & Davenport, 1980) which results in contaminated cathode that is returned to anode production (Biswas & Davenport, 1980; Wang, 2004). Further electrolyte purification is not always required but third stage liberators can be used to reduce copper concentration below 2 g/L which results in significant removal of As, Sb and Bi and very impure deposits which are recycled to a smelter or used for As production. However, liberators do not have very high energy efficiency (Acharya, 2014; Ando & Tsuchida, 1997) and below 0.5 g/L copper, highly toxic arsine gas may form (Biswas & Davenport, 1980).

Jan 1, 2019

By Guichao Wang, Geoffrey M. Evans, Graeme J. Jameson

"In this paper we present a new method for studying the detachment of particles from bubbles in a rotating turbulent eddy. The eddy is formed in a wall cavity in a two-dimensional water tunnel with transparent walls. When water flows through the tunnel, a vortical flow field develops in the cavity. The properties of the eddy can be modulated by changing the free-stream velocity of the water in the tunnel. Bubbles are pre-loaded with one or more particles in a fluidized bed flotation device located beneath the vortex cavity. Loaded bubbles are released one at a time into the cavity, and the motion of the bubbleparticle aggregate is studied using a high-speed video camera. The diameters of the particles and the bubbles, and the number of particles initially attached to the bubble, can be varied. The trajectories taken by the bubbles are quite complicated. In some cases, the bubble moves to the centre of the eddy, and particles rotate around its axis. If the rotational speed is sufficient, particles may detach due to centrifugal force. However, other modes were observed, including inertial detachment due to rapid changes in direction of the surface of the bubble, because of changes in trajectory of the bubble as a whole, or because of pulsations and oscillations of the bubble surface. Clusters of bubbles held together by particles were seen to form and reform. In the traditional explanation for the detachment of particles in flotation cells, it is assumed that particles detach from bubbles rotating in an eddy due to centrifugal force (Schulze, 1977). Although the conditions assumed in Schulze's theory may exist, it is only one of a range of phenomena that can lead to the detachment of particles from bubbles in a turbulent vortex.INTRODUCTIONThe recovery of particles by flotation methods is dependent on the particle size. The recovery in the existing flotation machines reaches a peak for particle size, typically in the range of 20 to 100 µm. This size range varies as a function of the particle’s properties (type and composites). For coarser particles, the recovery drops very quickly (Gaudin, Groh & Henderson, 1931; Jowett, 1980). If the upper size limit can be increased for flotation, dramatic savings in the grinding energy can be achieved."

Jan 1, 2016