Search Documents

By Nickvinder Bhath, Johnson Matthey Plc, Jamie Baker, Daniel Kim, Jeff Lucht, Shijie Wang

"Precious metals (PM) in copper anode slimes are traditionally recovered by pyrometallurgical processes. Due to the compliance with increasingly stringent environmental regulations, it has made hydrometallurgical processing an attractive method for recovery of precious metals, including relatively inert metals such as gold and platinum group metals (PGMs). In this paper, a new method to recover PGM from complex and difficult feed streams is described. Using a proprietary Advanced Ion Exchange (AIX) adsorbent which has a high selectivity for PGMs over other metals and can achieve high PGM mass loadings with a series of incredible pilot test data plus the business case generated from the study results are also presented in the paper.INTRODUCTIONPrecious metals in copper anode slimes are traditional recovered by pyrometallurgical processes. Due to the compliance with increasingly stringent environmental regulations, it has made hydrometallurgical processing an attractive method for recovery of many metals, including relatively inert metals such as gold and platinum group metals (PGMs). Fully hydrometallurgical processes for extraction and recovery of gold and silver from copper anode slimes were employed in major copper refineries since 1995, which was first developed at Rio Tinto Kennecott Utah Copper.In Rio Tinto KUC process, the wet chlorination and gold solvent extraction were utilized to enable recovery of gold and silver as well as other metal compounds. The availability of water and the interaction and amenability of gold processing in water-based solution makes it possible that gold and silver are produced in only five days, compared with a traditional pyrometallurgical process that took 45 days. Most copper refineries are still following the tradition, but the use of hydrometallurgical technologies is increasing as the world demand for metals increases, energy utilization, and environmental viability."

Jan 1, 2016

By G. W. H. Norman

"The Indian Molybdenum deposit occurs in granite near the centre of Indian peninsula, Kewagama lake, in Preissac township, Abitibi county, Quebec, about 40 miles east of Noranda. Quartz veins containing molybdenite were discovered in the vicinity of the deposit in 1901 by J. F. E. Johnston of the Geological Survey of Canada. Innumerable trenches and a few pits were excavated during and prior to the first great war, but there was no production. During the second great war systematic drilling along a favourable zone disclosed by the earlier trenching outlined an orebody of 225,000 tons with a molybdenite content of 0.46 per cent.A 500 on mill was built in 1943, and 91,489 tons of ore underwent treatment, from which 699,568 lb . of molybdenite was recovered. The mill closed down early in 1944 when the wartime need for Canadian molybdenum production eased .GEOLOGYThe general geology in the vicinity of the deposit is shown in Fig. 1. The deposit lies at the north edge of a muscovite-biotite granite mass about 2 miles wide and several miles long. West of Kewagama lake this granite is cut by great swarms of quartz veins . The only other granite in the district known to contain similar swarms of quartz veins, and which similarly has become a source of mo!ybdenite, occurs 20 miles east in La Corne township. The non-molybdenite-bearing granites of the district are either more basic and contain frw dykes except aplite or are distinctly pegmatitic types and contain up to 50 per cent pegmatite dykes with molybdenite only here and there in small amount."

Jan 1, 1954

By J. Dubinski

Passive tomographic imaging is a technique that can be used for assessing seismic hazard in mines with high seismic activity induced by mining. The basic idea behind such an interpretation is the assumption that there is a relationship between high values of seismic velocity and high values of stresses in the rock mass. This relationship was confirmed both in laboratory an in situ measurements and constitutes the basis for rock-burst and seismic hazard evaluation. In the paper seismic tomographic images of seismic P wave velocity and seismic P wave velocity gradient have been presented to determine rock-burst hazard and locate high seismic activity zones in the area of coal panel 306 in Zabrze Bielszowice mine. The zones of high values of P-wave seismic velocity gradient have been found to correlate with the distribution of high energetic seismic events. Passive tomographic images were obtained using modern bent ray tracing tomography algorithm with regularization. Recent study give rise to observation that not only high values of P-wave seismic velocity is important in seismic hazard assessment as many strong seismic events are located in the areas of high values of velocity gradient. This recent observation permits to increase quality of passive tomographic imaging for detection of seismogenic zones and is presented in the paper. The advantage of passive tomography comparing to active tomography is that sources of seismic waves are generated by rock mass itself and costly controlled explosions are not necessary. Another practical limitation of active tomography is the size of study area which usually do not exceed 200 m by 200 m. This restriction does not appear in passive tomography where area of study is usually 2000 m by 2000 m and the tomographic images delineate velocity structure in locations where mining induced seismicity take place. Passive tomography method utilized in analysis of rock mass state in underground mines encounter some difficulties concerned with the numerical stability of optimization algorithms. In the presented approach to passive tomography problem numerical stability is obtained by special regularization method and by application of very stable numerical seismic ray-tracing algorithm.

Aug 1, 2013

By A. F. Beck

Abstract Canada has opened up a geological province in ?Western Canada which offers a new .stimulus to oil exploration geophysics. The problems of instrumental technique, interpretation, and logistics involved in the exploration of this new territory are presented in this paper and some of the efforts being undertaken to overcome them are discussed. The scope of this programme, its possible trend and extent, especially when viewed .against the background of the exploration effort in the United States, is touched upon. Introduction The science of earth physics was first applied to the search for oil on this continent some twenty-five years ago when torsion balance and refraction seismic methods were initiated in the Gulf Coast area of the United States. Since that time advances in the various branches of the science have been sporadic as new fields for their use opened up in the search for deep salt domes as well as less well-defined geological structures; in the application to well logging as part of the exploitation of petroleum; and in underwater surveys, aerial surveys, etc. In the present paper, attention has been concentrated only on the Western Canada plains area because of the recent remarkable growth of geophysics as an oil finding technique in this region. The other prospective oil areas of the West Coast and the Eastern Provinces of Canada are at present of minor importance, although they will undoubtedly receive increasing consideration in the future as accessibility to markets becomes a major factor and more improved geophysical and geological techniques are developed. A vast province in Canada, covering some 655,000 square miles of prospective oil territory (approximately one-half of the prospective oil area in the United States), has provided the new sphere of activity for geophysics (see Figures 1 and 2). Included in this area are immense inaccessible, uninhabited frozen regions which pose a new problem in logistics and operational techniques.

Jan 1, 1950

By Prodipto Ghosh

This paper is prepared as a review of existing and traditional methods related to electrical maintenance strategy. Its primary focus is to explore newer ideas and how they point the way to a more efficient and effective manner of electrical maintenance. This discussion is primarily related to large electrical distribution assets typical of heavy industry such as mining.

Aug 1, 2013

By E. G. Gaylord

THE material improvements which have been made in the practice of exploiting oil and gas reservoirs in the United States during recent years may be attributed largely to: (1) The necessity for drilling deeper wells at costs not much greater than was formerly expended on shallower wells. (2) The necessity for producing oil at a lower cost per barrel. (3) A growing recognition of the importance of the nature of production practice upon ultimate yield of oil and gas. The first two of these factors result, to a large extent, from the fact that a greater proportion of new development has been deeper development, and these wells have been drilled in the face of progressively lower per well allowables. In California, for instance, maximum allowables have declined from 400 barrels per day in March, 1938, to 156 barrels per day in September, 1940, and during this same period some 125 wells were drilled to the deeper 10,000-foot producing horizons discovered during this time. The third item listed above results from our increasing knowledge of the basic factors which influence the amount of recovery we may expect from reservoirs. In addition to the longer-range planning now being undertaken by the more prudent operators, State proration and conservation laws have focused attention upon the importance of methods conducive to obtaining progressively greater quantities of the hydrocarbons in place. In a paper of this length it will be possible to discuss only a few of the recent advances. An effort has been made to select the more important of these and to indicate, where possible, the factors which have made these advances possible.

Jan 1, 1941

By T. T. Perles

This paper will review the state of the global vanadium industry and outline the implications for the market in the coming years. Global vanadium resources and reserves will be defined. Current production of vanadium will be quantified and examined in terms of production by country, sources of raw materials for production and cost implications of the production processes. Current consumption of vanadium by country and by application will be reviewed. Vanadium supply/demand balance in recent years and the resulting impact on global inventory levels will be discussed. Projections for changes in global production, consumption and resulting inventory changes for the vanadium market in the coming years will be made.

Jan 1, 2014

By S. Ghafarnejad Parto, Å. Rasmuson, A. Fredriksson, M. Mohammadi, K. M. Forsberg, J. Martinez De La Cruz

The present study aims at recovering rare earth elements (REE) in conjunction with the production of fertilizers from an apatite concentrate. Apatite is one of the REE rich minerals ending up in the tailings pond when Luossarvaara-Kiirunavaara AB (LKAB) in Sweden processes Malmberget’s iron ore deposit. Leaching with nitric acid, hydrochloric acid, and sulphuric acid respectively have been studied. The nitric acid route was chosen for further investigations and the optimum acid concentration for leaching of the REE were determined. The leached REE are recovered by solvent extraction using di-(2-ethylhexyl) phosphoric acid (D2EHPA) and 2-ethylhexylphosphonic acid-mono-2-ethylhexyl ester (EHEHPA).

Jan 1, 2014

By R. Chen, K. Xia

In deep mining activities, blasting induced compressive stress wave would be reflected as tensile wave at a free surface around the openings, which would facilitate the tensile failure of the deep rock since it is much weaker in tension than in compression. It is thus critical to understand the dynamic tensile failure of rocks subjected to static tension for deep rock engineering applications. A modified split Hopkinson pressure bar (SHPB) system is adopted to load Brazilian disc (BD) samples statically, and then exert dynamic load to the sample through stress wave generated by impact. The pulse shaper technique is used to generate a slowly rising stress wave and thus to facilitate the stress equilibrium of samples during each test. Five groups of Laurentian granite (with tensile strength of 12.8 MPa) BD samples under the pretension stress of 0 MPa, 2 MPa, 4 MPa, 8 MPa, and 10 MPa are tested under different loading rates. The result shows that the dynamic tensile strength of the rock decreases with the increase of pre-tension stress, which is easy to understand because pre-tension stress weakens the rock sample. It is also observed that under the same pre-tension stress, the dynamic tensile strength increases with the loading rate, revealing the so-called rate dependency that is common for engineering materials. Furthermore, it is found that the loading rate sensitivity of the rock increases with the increase of pre-tension stress. A qualitative explanation for this phenomenon is that more microcracks are generated and activated under higher pretension stress, resulting in a more viscous material. Based on the results, an empirical equation is proposed to fit the data and explain the dynamic tensile behaviour of rock under pre-tension stress. A physical model is used to simulate the dependency of the dynamic tensile strength of rock on the pre-tension stress and the loading rate, which is shown to be in good agreement with the experimental results.

Jan 1, 2015

By Murray W. Grabinsky

The in situ performance of Cemented Paste Backfill (CPB) systems can be monitored to improve understanding of the paste?s behaviour and therefore optimize the geomechanical design of the cemented paste backfill system (i.e., minimize binder content, minimize fill barricade complexity, maximize fill rate-of-rise during backfilling, and minimize cure time before resuming production blasting in proximity). However, undertaking such a monitoring program is inherently complex, because the rate-of-rise and accompanying self-weight induced stresses occur at a time rate that is similar to the rate of hydration and associated increase in the paste?s stiffness and strength. In addition, arching within the stope complicates the overall stress distribution. Therefore, to obtain a complete picture of the CPB?s response, it is necessary to measure several variables (3-D total pressures, water pressures and suctions, hydration rates, and blasting induced vibrations) at a given ?point?, and take all such measurements at many points throughout the fill mass as well as at barricade locations. The overall testing program can therefore be logistically difficult to implement and have an apparent high cost. However, if the program is successful, the benefits arising from improved mine design can significantly outweigh the seemingly high initial capital and labour costs of the monitoring program. A case study involving an instrumented paste fill in a tall and narrow Alimak stope is briefly outlined. Plans for a similar experiment in a large long-hole stope are then considered.

May 1, 2008

By Stewart A. Ferguson

Location.-The property consists of eight claims (P-12339 to 12343, 12403 to 12405) in Robb township, adjoining Jamieson township on the west. A mocor road extends twenty-two miles northwest from Timmins to the mine. Acknowledgments.- The field work was done in 1940 and 1943, while the writer was employed by the Ontario Department of Mines. The Metals Reserve Company has made available information regarding the property through Messrs. W. R, Dunbar, of Hollinger Consolidated Gold Mines, and W. C. Ringsleben, of the Metals Control Board, Department of Munitions and Supply.

Jan 1, 1945

By G. Vibert Douglas

Introduction A preliminary paper dealing with the subject of ore-shoots was presented to this Society at its Annual Meeting last year (1). The present paper records the attempts which have been made during the interval to further this study. In reporting this work, I wish to state that I do not consider the investigation complete; many more experiments will have to be carried out, and more field data will have to be recorded, before the geologist can say with confidence an ore-shoot should start at this point and pitch in that direction. The aim of these experiments is to find some criteria which will serve the mining engineer and mining geologist concerned with ore-shoots in hydrothermal veins.

Jan 1, 1935

By K. N. Karparov

?Two highwall failures in a South African coal mine defied analysis by widely accepted limit equilibrium methods. ?The geological conditions were complex, with undulating coal-bearing strata overlying a karstic topography formed in underlying dolomite belonging to the Transvaal Supergroup. ?It was clear that the simplifying assumptions made by all limit equilibrium methods were inappropriate in the conditions.

May 1, 2007

By Paul E. Mather, Matthew J. M. Krane

Anode or fire refining is the final pyrometallurgical step in the production of copper anode. Part of this process purifies liquid copper by reducing its dissolved oxygen with a natural gas-steam mixture. Until now there have been no transient models of this process coupling the injected gas jet mass transport with its chemical reactions. A transient, 1D flow, chemical reaction model was made to estimate the time-dependent behavior of anode copper composition, soot formation, and the transient gas jet composition along its height. Model estimates were made for reduction rate, soot emission rate, and exergy loss and destruction distributions for two melt temperatures and a range of steam addition rates. It was found that increases to melt temperature and steam addition rate increased reduction rate and decreased soot emission, while having little effect on exergetic performance. Estimates for reduction histories were compared to industrial data. INTRODUCTION Anode/fire refining is the final pyrometallurgical step in the production of copper anodes; it is essential for removing dissolved gases which cause porosity in cast anodes. Despite its significance, the open literature appears devoid of any transient models of the entire process; furthermore, there are very little published process data with which to validate any models made. This dual dearth of modelling work and process data inhibits studies of the tradeoffs between process and performance changes, desirable for decreasing reduction time and soot formation as well as quantifying changes in the exergy losses and destructions of the process. This work introduces a reduced-order, transient model of reduction during fire refining, examines performance trends with operating conditions, and compares model estimates with industrial data. Overview of anode refining The purpose of anode refining is to produce liquid copper which can be cast with minimal gas porosity, which disrupts the downstream electrorefining process. Dissolved sulfur is removed first, then oxygen, by reactions with different injected gases. The removal of oxygen (the reduction step) is the subject of this proceeding and is effected by the bubbling of natural gas, typically mixed with steam, through the melt from tuyeres. A typical refining run reduces dissolved oxygen from 3000 ppm to 300 ppm in 2–3 hours (Schlesinger, King, Sole, & Davenport, 2011). The refined copper is then cast as anodes. Figure 1 shows a schematic of the furnace vessel.

Jan 1, 2019

By P. E. Auger, J. E. Gill

"The zinc deposits to be described are in Lemieux township a few miles south of the Tabletop mountains, in the central part of Gaspe peninsula, Quebec. Although they have not been worked, they constitute a potential source of zinc and lead and structurally are of considerable interest.GENERAL CHARACTER OF THE OCCURRENCEThe deposits are in sharp-walled quartz-carbonate veins and breccia zones carrying locally, and in varying amounts, sphalerite, galena, pyrite, marcasite, chalcopyrite, and specularite. Those so far investigated strike generally north-south, have steep dips, and cut through sediments of Lower Devonian age, mostly calcareous argillites or siltstones. Wall-rock alteration is negligible.BROADER STRUCTURAL FEATURESThe principal known occurrences are in the south-central part of a dome structure measuring 6 by 5 miles. The argillaceous sediments are overlain, on the flanks of the dome, by sandstones and lavas. These have been stripped from the central part of the dome, revealing the veins in the argillites beneath. The veins formed after the volcanics, but the fractures and breccia zones in which the deposits formed are confined mainly to the argillite series, presumably because of the greater strength of the lavas.The argillite series is cut by dykes, sills, and small stocks of diorite and acidic 'porphyries' that are older than the veins.THE FEDERAL HILL AREAThe distribution of known veins is shown in Fig. 1. The characteristic features of the veins are well illustrated by the Federal Hill area shown in Figs. 2, 3, and 4, and described below."

Jan 1, 1954

By Yugo Mitani, Tatsuya Kato, Chiharu Tokoro, Abdullah Al Mamun

Acid mine drainage (AMD), which is a major source of mining pollution, often contains ferric and/or ferrous ions together with several toxic elements. The ferric and ferrous ions in AMD precipitate in several mineralogical forms after neutralization, and the ferric/ferrous precipitates become the main component of the sludge generated after AMD treatment. The precipitates are also good absorbents for several toxic elements. To avoid generation of voluminous sludges and the re-dissolution of toxic elements from the sludge, it is very important to generate well-draining and efficiently adsorbing sludges by controlling the mineralogical form of the ferric/ferrous precipitates. Green rust, which is ferric and ferrous hydroxide, is a double layer hydroxide which is able to sorb several toxic elements. The green rust transforms to goethite or lepidocrocite by rapid oxidation, whereas it transforms to magnetite at ambient temperature by slow oxidation. The magnetite is also good absorbent especially for toxic cations and it makes a compact sludge due to its magnetic properties. We investigated the magnetite generation process at ambient temperature in detail. The magnetite generation process can be divided into three steps; (i) oxidation of Fe(II), (ii) Fe(II) surface complexation to Fe(III) hydroxide, and (iii) crystallization of magnetite. More magnetite can form when the oxidation rate is slower than the crystallization rate, and optimum conditions for its formation are at pH 9.5 with mild agitation. Ferrihydrite is the most common precipitate and it is able to sorb many different toxic elements. However, it drains badly and its solid/liquid separation properties are poor. We investigated the removal mechanism of several toxic elements by co-precipitation with ferrihydrite. We confirmed that the removal mechanism by co-precipitation partly involved surface precipitation when the initial ratio of toxic elements to ferric ion was high, although the main mechanism was always surface complexation. When surface precipitation occurred, highly efficient toxic element removal with ferrihydrite could be achieved.

Jan 1, 2016

By Jan Rosenkranz, Anders Sand, Lisa Malm, Nils-Johan Bolin

Within flotation technology the general trend is towards very large cells. Scale-up is usually done by postulating geometrical similarity, which implies keeping the aspect ratio constant when increasing cell volume. Consequently, the design of flotation circuits typically involves several cells of identical geometry within a bank. Using a few standard sizes in a flotation plant simplifies design, manufacturing and maintenance of the cells, but does not necessarily guarantee optimal performance and selectivity of the flotation process. Geometry parameters for a given cell volume that influence flotation cell performance include cell height, which causes changes in the hydrostatic pressure and suspension hydrodynamics, and also influences the travel distance of particle-bubble agglomerates as well as the homogeneity of the mixing. Also the thickness of the froth layer depends on the aspect ratio of the cell. The objective of this work is to gain a better understanding of material distribution and properties within a flotation cell and, based on this information, elucidate how alterations of the cell geometry can influence separation efficiency. For this purpose systematic measurements and analyses of the spatial distribution of the different phases within a 160 m3 flotation cell have been carried out with a particular focus on an industrial, low-grade copper ore beneficiation process. The concepts for sampling at different vertical and lateral positions of the flotation cell are introduced. The results from the experimental work give an understanding of internal material distribution within flotation cells. Based on the measured phase distribution and concentrations as well as particle properties at various positions within the cell, the implications for an optimized scaling and design of individual flotation cells within a flotation circuit are discussed.

Jan 1, 2016

By Tom Brady

A major focus of ground control research presently being conducted by the Spokane Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) is to incorporate data on weak rock masses into existing design relationships, with an emphasis on updating the span design curve for manned entries and the overbreak curve for longhole entries. Both curves were originally developed at the University of British Columbia, Vancouver, BC. The original database has been augmented by information from mines throughout the United States, Canada, Australia, and Europe. The common factor in all these mines is the presence of a weak back and/or walls. In most cases, the ore zone is the weakest rock unit and must be stabilized so that the mineral-bearing rock can be extracted safety. The current NIOSH research attempts to provide rock mechanics tools to assist a mine operator in making economic decisions that will also ensure a safe working environment. This paper documents the North American database.

May 1, 2006

By G. Dodbiba, A. Otsuki, T. Fujita, J. Ponou, A. Shibayama

"The different types of nano to submicron particles, which are well-dispersed nano particles, coagulated nano particles or settled submicron particles, have been measured by the interactive force apparatus (IFA). The information is very useful for mineral processing treatment. The IFA can measure the particle size distribution in low to high concentration of particles in liquids and non-light transparent liquids. Here, mainly the emulsion and bubble size measurements are described.Emulsion (w/o type) is prepared with oil and water mixture. The nano to micro emulsion particle size is usually measured by light scattering method. The particle size distribution of emulsion of light oil measured by IFA agreed well with the one by the dynamic light scattering (DLS) method. The water size distribution in emulsions of gasoline is difficult for the small reflection index and C heavy oil is difficult for the black color by DLS method. The IFA can measure both emulsions.There are many methods to measure fine air bubbles, however, the finer nano size measurement apparatuses are DLS method and IFA. A “ghost” peak appeared in the large particle micron meter size in DLS method. The mean diameter in IFA is similar with DLS for the nano meter size. INTRODUCTIONParticle size distribution measurement of nano to submicron particle, emulsion and bubble size distribution are very useful for ultrafine particle separation and characterization of fine particles by the necessity of recent fine minerals separation (For example, Li et al.2016, Mikhlin et al.2016, Wang et al.2013). As for the size measurement of solid particles in liquids, three different types of nano to submicron particles, that are well-dispersed nano particles, coagulated nano particles or settled submicron particles, have been measured by the interactive force apparatus (IFA). The particle size distributions are compared with the one of dried particles measured by TEM or SEM. The well-dispersed nano particle size distribution by IFA is influenced by the nano size surfactant micelles and becomes smaller, when compared with the TEM result. The size distribution of nano size of magnetite particles in water is influenced by the isoelectric point and the mean diameter of coagulation becomes larger. The particle coagulation in diluted suspension is about 2nm smaller when compared with the higher concentration. The submicron nickel particle size distribution is well agreed the result by SEM. The coagulation effect is small in the submicron size of nickel powder in water (Fujita et al., 2013). In this paper, the emulsion and bubble size measurements are mainly described."

Jan 1, 2016

Superconductivity, New Mexico and Mining? ? High Temperature Superconducting cables made from ?nickel tape? ? Testing on U.S. power grid ? 25 year time horizon Purpose Create awareness about the successful application of energy management systems at a Northern Ontario mine site.

May 1, 2008