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By A. Suzue, T. H. Okabe, Y. Taninouchi

Methods for the physical separation and enrichment of platinum group metals (PGMs) from autocatalyst scrap were studied in order to develop an environmentally friendly and efficient recycling process. In general, an autocatalyst has a honeycomb-structured ceramic substrate that is coated with a catalyst layer containing platinum (Pt), palladium (Pd), and rhodium (Rh). Therefore, physical separation of the PGM-containing catalyst layer directly from the ceramic substrate is favorable for upgrading the autocatalyst scrap. In this paper, the authors present a scrap-upgrade process consisting of electroless iron plating and magnetic separation techniques. Iron was plated on the surface of a catalyst sample used to represent an autocatalyst, which was then crushed and magnetically separated. The Pd in the catalyst sample was successfully extracted and concentrated in the magnetic powder. Under certain conditions, the process increased the Pd concentration by a factor of 4 and recovered 89% of the Pd in the autocatalyst sample.

Jan 1, 2014

By Terry McNulty

"Previous papers (McNulty 1998 and 2004) have dealt with the causes of successful and less successful achievement of design production rate by new processing plants in the minerals industry. Examination of many case histories has allowed the construction of curves or profiles that represent projects with similar characteristics that equate to differing degrees of care exercised during the project development phase. Simplistically, decreasing care is reflected by increasing risk and a heightened likelihood of poor technical and/or financial performance.This contribution provides an update, including recent case histories, and presents a modified Series 1A curve that includes the best 23 case histories, out of a total of 81 examined, or 28%. This is done to show that some very carefully developed and executed projects can ramp-up quickly and that owners of new projects should avoid being too pessimistic in projecting early cash flow if they are certain that they have done their homework. The role of metallurgical process development in the reduction of project risk is discussed and several financial analyses are presented that express the potential monetary value of a well-designed and professionally executed metallurgical program."

Jan 1, 2014

By Zhigao Xu, Ruan Chi, Zhenyue Zhang, Yaoyang Ruan, Zhengyan He

Thorium is frequently the main radioactive element in rare earth ores and is a resource that can potentially substitute for uranium. Thorium must be separated from rare earths in order to obtain products with low radioactivity. There are abundant resources of thorium in the rare earth ores in China, especially in Baiyunebo mixed ores. As an associated element coexisting in rare earth ores, thorium is, or can be, separated from rare earth concentrate, iron concentrate, as well as from waste water and slag to achieve recovery of thorium. The methods of separation include ion exchange resin, liquid-liquid extraction, and liquid-solid extraction. TBP extraction has been the main method applied to separate thorium by domestic and foreign scholars. This paper presents a comparison of different processes for the separation of thorium from rare earth ores, especially Baiyunebo mixed ores, single bastnaesite and monazite ore, and provides suggestions for the future recovery of thorium resources.

Jan 1, 2014

By J. P. Mogan, E. D. Dainty

Polynuclear aromatic hydrocarbon (PAH) levels were measured in underground mines in the vicinity of diesel vehicles equipped with several types of emission control hardware. In general, the emission control devices appeared to reduce PAH levels, but the companion mutagen study suggested that the reduction might not always be beneficial. All underground PAH concentrations were below the threshold at which a significant impact on health might be expected, but recent animal exposure studies have indicated that PAHs may not be the primary hazard from chronic diesel fume exposure.

Jan 1, 1994

By K. Regl, J. Berneder

"AMAG investigated different aspects to improve the resistance against grain coarsening in aerospace alloys during recrystallization and was successful in finding several opportunities to minimize this effect. The studies show that one aspect to counteract grain coarsening is the chemical composition and subsequently all phases that are formed during homogenization. Starting with a fine grain (~ 50 µm) can lead to a final grain size of few mm. On the other hand with a coarse initial grain size (approximately 150 µm) and the right chemical composition the grain size can stay almost constant despite different deformation steps. Additional we investigated different sequences for the component production to eliminate the problem of grain coarsening as a coarse grain has a detrimental effect on product performance.INTRODUCTION In the aircraft industry, aluminium sheets are most commonly deformed in their soft state, followed by solution heat treatment and natural or artificial aging. If the preceding deformation is in a critical amount, during the recrystallization at solution heat treatment grain coarsening can occur. A subsequent deformation to this condition leads to an orange peel surface, which requires additional polishing. Next to this extra effort the coarse grain size produces a drop in the mechanical properties, often below specification limits. If there is no subsequent deformation, this effect is not visible and without destructive testing there is no possibility to detect the error. As mentioned before, this effect occurs during recrystallization, which is a process that is driven by the stored energy in the microstructure. The two most important aspects for an increase of the stored energy are the increase of the grain boundaries fraction (smaller grain size) and the increase of the dislocation density caused by deformation. The increase in dislocation density during the deformation arise from trapping of existing dislocations and from the generation of new dislocations. During recrystallization all grains are built completely new, so all dislocations are removed (Humphreys & Hatherly, 2004). There are three requirements for recrystallization:"

Jan 1, 2018

By Shae K. Kim

The aim of this study is to manufacture magnesium alloys with alkaline earth metal oxides (BeO, CaO, MgO or SrO) additions with the objectives of (1) ensuring safety during processing and applications by raising the ignition temperature and reducing oxidation, (2) protecting the environment by reducing or eliminating use of protective gases, (3) maintaining or improving elevated temperature properties with lower amount of Ca or Sr or rare earth metals when compared with conventionally developed high-temperature magnesium alloys, (4) developing cleaner strip casting and continuous casting processes without hot tearing and (5) obtaining all of these objectives without sacrificing mechanical properties or increasing the cost of magnesium alloys.

Jan 1, 2006

By Mark Stephenson, Paul Henharen

"The objective in the mineral processing of primary ores is to liberate and effectively recover each individual economically viable diamond with minimal reduction in its potential value.There are three distinctive phases in diamond processing:Feed PreparationWhere the diamonds are liberated and waste material finer than the economically selected cut-off size is rejected. In this section we will discuss the various techniques utilised worldwide to effect feed preparation.Primary ProcessingWhere the diamonds are recovered into a high grade concentrate suitable for the more expensive and selective final recovery process. In this section we will discuss the development of primary processing from jigs and pans to the more current techniques utilised worldwide.Final RecoveryWhere there is selective rejection of waste particles until only diamonds remain. The diamonds may then be acidised prior to packing and marketing.Within these distinct phases a variety of unit processes have been utilised and this paper will discuss their relative merits, limitations and suitability in respect to the various stages of diamond project development from prospecting through to production.Basic capital and operating costs are compared for the autogenous milling route developed in the CIS and the crushing and scrubbing route utilised in the west."

Jan 1, 1994

By Richard R. Klimpel

"This paper discusses the effect of water chemistry, reagent type, and other environmental factors on the performance of sulfide mineral size reduction and froth flotation processes. Two specific problems will be discussed: l.) the importance of appropriately utilizing the electrochemical window that is created in the grinding process to enhance sulfide mineral recovery by froth flotation; and 2) the impact of steel grinding media versus autogenous grinding on the efficiency of sulfide mineral flotation with varying thiol collectors and water sources.IntroductionThe mutual dependency between size reduction and mineral froth flotation is well recognized from the viewpoint of particle size and mineral liberation characteristics. The purpose of this paper is to discuss two less obvious industrial interactions between size reduction and froth flotation that have come up in the various plant optimization studies conducted by this author. These interactions are complex but appear to be important at the industrial level as plant throughput is directly affected, either positively or negatively by such interactions. Examples v.ill be given on how the method of grinding influences flotation and how different water sources influence the flotation behavior of electrochemically sensitive minerals. With each of these interactions, a number of fundamental research studies have shown previously that some effects can be measured under idealized and very small scale experiments. Such research studies will not be cataloged or exhaustingly reviewed in this paper. Whether these same types of effects can be measured in an industrial environment and are economically important is much less certain. This paper will present some rather unique experiences gained from larger scale test experiences which clearly indicate findings that plant operators should be aware of."

Jan 1, 1996

By Dale A. Sketchley

"Abstract - Large differences in gold content between rock fragments or small volumes of unbroken rock, commonly referred to as the nugget effect, are related to sample and subsample weights, crushing and pulverizing sizes, and density, shape and size distribution of gold grains. Gy’s sampling theory, which relates gold grain characteristics to sample weight, fragment size, and error, provides a method of estimating a sampling constant that quantifies deposit characteristics that contribute to the nugget effect.Sampling control tests provide methods for determining the sampling constant. Sampling control charts, comprising nomographs that relate sample weight, error and particle size, use the sampling constant to optimize sample weights and comminution sizes, and to minimize the variability introduced by incorrect or inadequate sampling and sub-sampling procedures. The sampling constant is useful in classifying ores into arbitrary categories according to expected sampling difficulties. Spatial variations in the sampling constant can be used to aid in defining ore types for modeling geological domains, which should have unique sampling protocols. Examples that illustrate the relationship between the sampling constant and expected sampling problems, and the spatial variation of the sampling constant, are given for various deposits. Case histories of sampling programs are presented.Quality control procedures consist of monitoring sample contamination amd accuracy and precision of analytical results. Accuracy, precision and contamination are monitored by including standards, duplicates and blanks into batches of samples being analyzed. Analytical results of standards and blanks are plotted on a batch-and-time basis with control lines at plus or minus two/three standard deviations as confidence limits of the accepted round-robin value. Examples are given that illustrate a laboratory system in statistical control and the various types of problems encountered when interpreting quality control data. These include sample transcription errors, degradation, contamination, sampling errors, detection limit problems, instrumental drift, lack of statistical control, laboratory bias, procedural problems and data tampering.Where bias is negligible, precision, as a function of concentration, can be obtained from duplicates using the Thompson-Howarth precision algorithm, which also allows calculation of the practical detection limit. Examples are given that illustrate variations in precision, with grain size, for different types of duplicates, as well as mineralogical changes and sampling errors."

Jan 1, 1998

By Richard W. Herzer

Introduction Thermal methods have been predominant in the metallurgy of the base-metals ever since the foundation of the industry thousands of years ago. Development in hydrometallurgy has been confined largely to the past six or seven decades. It was at first necessarily slow, then for a number of years rapid progress was made. At present, the uncertain state of the metal industry has curtailed research on the subject; however, in the next few years one may assuredly look forward to an ever increasing use of wet processes. Leaching methods have attained the dominant position in the case of certain metals, notably zinc. For others, they have made no headway at all. Copper presents a situation all its own. Due to the varied nature of its ores and to the large number of localities in which it is mined, a great number of processes have been developed, each suitable in its own particular field. In the case of this metal, therefore, it is more difficult to arrive at definite conclusions. It is the purpose of this paper, first, to review the outstanding developments of base-metal hydrometallurgy, and, secondly, to consider possible Canadian applications of some of the processes in use. The discussion will be confined to the three metals, zinc, lead, and copper, with particular reference to the last mentioned. Zinc General Note At present, zinc is produced by two principal processes, the older retort process and the electrolytic process. The latter is a development of the last twenty years and, judging by its present progress, bids fair eventually to supplant older methods in a large proportion of cases. It is certain, at least, that in the erection of a new plant, a hydrometallurgical process would be given the most serious consideration

Jan 1, 1934

By Rodrigo Madariaga, Tracy T. Morris

The practice of stripping copper starter sheets from titanium blanks to be used in a conventional electrolytic tankhouse has been around since the advent of Electrometallurgy. Historically it has been done manually, utilizing many people to produce in some cases thousands of starter sheets per day. Some other conventional tankhouses have successfully converted to using mechanical means to strip starter sheets or have made the switch to permanent cathodes and although robotics have been around for quite some time they have not been used to strip starter sheets until recently. The Amarillo Copper Refinery began using robotics to strip several years ago and the details to how this came about and how the robots work will be described. INTRODUCTION ASARCO LLC (Asarco) was organized in 1899 as the American Smelting and Refining Company. Originally a consolidation of several lead-silver smelting companies, it evolved over the years into an integrated producer of primary non-ferrous metals, including copper, lead and zinc and associated co- products (Marcosson, 1949). Grupo México, S.A.B. de C.V acquired Asarco in 1999. Today, Asarco is a vertically integrated producer of primary refined copper and associated co-products such as gold, silver, molybdenum, selenium and tellurium. Asarco operates three open-pit mines and mills and two solvent extraction-electrowinning (SX-EW) plants all in Arizona plus a copper smelter in Arizona and a copper refinery in Texas. Figure 1 illustrates how the copper metal comes out of the ground at the mine and ends up as a refined product at the refinery The copper refinery in Texas is known as the Amarillo Copper Refinery (ACR) and is located in Amarillo, Texas. It was built in 1975 to replace 3 other aging refineries and was designed to produce 550,000 tons (500,000 MT) of refined copper per year using conventional starter sheet technology. At the time it was commissioned it was the largest tankhouse in the world at just under 1/2 miles long under one roof.

Jan 1, 2019

By R. Roufail

Mineral liberation is accomplished by comminution and is the first step towards achieving successful downstream processes such as flotation or leaching. In metal mining, one of the most effective comminution methods that is used to grind particles below 10 microns is stirred milling. In this paper the study of particle breakage mode vs. mill operating parameters is addressed. Stirred mills' grinding action is mainly attrition, but operation can be manipulated to include breakage by compression or impact loading. Macro and micro analysis of particle breakage and grinding mechanisms are correlated. Macro analyses convey information that relates grinding mechanism to particle size and shape. It is speculated that the breakage mechanism in the horizontal stirred mills is massive fracture for the coarsest particles and attrition (abrasion) close to the grinding limit where the size reduction ratio approaches 1.0. For micro analysis, the particle breakage mode has a direct impact on fracture type either transgranular or intergranular. Intergranular particle breakage leads to higher mineral liberation compared to transgranular breakage. Similar minerals would have more homogeneous properties that convey a stronger bond compared to dissimilar, heterogeneous mineral bonds. Transgranular fracture requires higher energy than inter granular fracture; trans granular fracture toughness of pure single phase mineral is about 10-14 % higher than the intergranular fracture toughness. This communication presents the results of an investigation to assess how operating conditions can affect trans- vs. inter-granular breakage.

Jan 1, 2009

By H. Dundar, C. Dzomeku

An extensive testwork was performed around the HPGR plant at GoldFields Ghana Limited Tarkwa Gold Mine. The HPGR was used to prepare the feed for heap leaching. The circuit was configured in such a way that the edge material from the HPGR discharge was recycled for further crushing while the product from the centre reported to the heap leach section. The set-up of the Polysius HPGR provided an opportunity to study the effect of different design and operating variables. This paper will discuss the results from the tests performed to assess the effect of rolls’ speed and applied pressure on the capacity and the grinding efficiency of the HPGR. Applying different pressure values appeared to have an influence on the amount of edge material recycled.

Jan 1, 2012

By D. J. Charlton

"IntroductionMaintenance is a business, which to be successful, requires good management, systems and reporting. The prime objective of the maintenance management group, be they large or small, must be to anticipate and prevent interruptions in operations by keeping equipment in good mechanical condition. This objective should be carried out at minimum cost consistent with maximum productiveness.The objective of this chapter is to give an insight into the various aspects of maintenance management that must be considered to effectively and efficiently operate a mill complex. The degree to which the maintenance sub-systems are developed in an operating mill will be determined by the size of the mill and the needs of the operation.The criterion of the management system used is that the system serve the operation and not vice versa. The systems presented should be considered as tools and, as with all tools, they must be sharpened and replaced as the need arises or as more effective tools become available.To understand what is involved in maintenance management, it is worthwhile to consider a systems approach to analyzing management problems. This approach was developed by J.A.B. Rae while reviewing maintenance management systems for Cominco Ltd.A very simple system involving managing results and objectives is shown diagrammatically in Figure 1.The systems approach to organizational development involves four basic elements: an objective, a result, an activity and feedback. In the analysis, the activity element is broken down into individual actions that people could be held responsible for. If we introduce the action of operating into the diagram of Figure l, we arrive diagrammatically in Figure 2."

Jan 1, 1989

By Nelson Lawrence

An Electrical Risk Management/Inspection Program has been designed specifically for the mining sector in order to provide electrical code expertise and systemic gaps in electrical systems. Goals include improved safety and productivity, reduced injuries and help to enable businesses to better comply with the electrical codes and regulations that govern them. The Electrical Risk Management/Inspection Program is now recognized by some of the world?s largest mining organizations. Since June, 2001 these electrical safety advisory services have been available to underground and surface mine sites throughout Ontario and are now offered throughout Canada and around the globe. This program is also currently being applied to review new electrical installations for mine construction projects thus improving the safety and reliability of mine site electrical systems.

May 1, 2006

By D. Ferrand, C. Villeneuve, N. Bensalah

"La conciliation entre l’expansion de l’industrie minière et les exigences du développement durable représente un grand défi. Face aux différentes controverses touchant cette industrie, la dernière décennie a été marquée par une plus grande mobilisation de l’ensemble des parties prenantes. Cependant, plusieurs carences persistent en matière d’opérationnalisation du concept de développement durable. Ce défi met en cause la responsabilité partagée entre les parties prenantes. Il exige le renforcement des responsabilités gouvernementales et l’instrumentalisation de bonnes pratiques de responsabilité sociale des entreprises. En aval, s’impose la gestion intégrée de l’usage des produits miniers et la promotion de l’innovation et de la recherche.ABSTRACT Conciliation between expansion of the mining industry and sustainable development requirements represents a great challenge. With regards to the various controversies touching this industry, the last decade was marked by a great mobilisation phase of all stakeholders. However, there are still many shortcomings regarding operationalization of the sustainable development concept. This challenge involves shared responsibility between the stakeholders. It requires strengthening government accountability and instrumentalization of good corporate social responsibility practices. Further down the chain, the use of mining products and the promotion of innovation and research must be achieved through integrated management."

Jan 1, 2015

By A. Gillis

"In order to obtain the equipment necessary to automate the equipment it was decided that the Department of Mines and Milltronics would jointly survey the circuit. This survey involved a metallurgical study by the Department of Mines and Milltronics took sound recordings during manual operation, checking in circuit bottle necks and determining the number of sensors that could be applied.The conveyer is driven by 2 PIV drives, each has a variable speed of 3/ 1. The cross conveyer that feeds directly into the rod mill feed chute will contain an automatic sampler and will eliminate the necessity of stopping the belt feeders to take samples. At present, hourly samples are taken from this point and the circuit is upset and cycling results.The Adequate scale is very close to the rod mill to totalize and thereby give a continuous indication and the second purpose is to take a signal from it and control the solution addition to the rod mill.A pneumatic positioner was obtained and put on the scale which produces a 3 tp 15 psi signal which is proportional to the actual tonnage going across the scale. This signal was fed to a bias loader which was mounted on the control panel. From there the operator can set the amount of solution that is wanted by the rod mill. No matter what the feed rate is, the signal coming from the bias loader will follow it automatically. This in turn goes to the pneumatic solution valve (1 ½” ) and the solution goes in with the feed to the rod mill. This is only part of the solution required for dilution since the rest of it is used as a force jet for the feed to the rod mill."

Jan 1, 1965

"Cobalt refining at Vale Canada (previously known as Inco) has been associated with Ni production. Because certain compounds of both metals carry risks for adverse health endpoints by inhalation exposure, it is critical to understand the aerosol concentrations of specific substances and the metallurgical processes through which they enter the air. Vale Canada has therefore decided to describe the histories of its Ni-related operations and to report industrial hygiene measurements when available. This paper describes electrolytic Co operations carried out at Port Colborne, Ontario (1954–1966), and provides aerosol measurements (1995–2008) for current Co electrowinning operations.RÉSUMÉ L’affinage du cobalt chez Vale Canada (anciennement Inco) a été associé à la production de nickel. Puisque certains composés de ces deux métaux comportent des risques d’effets néfastes pour la santé par exposition à l’inhalation, il est essentiel de comprendre les concentrations en aérosol des substances spécifiques ainsi que les procédés métallurgiques par lesquels ils entrent dans l’air. Vale Canada a donc décidé de décrire les historiques de ses opérations liées au nickel et de divulguer les mesures d’hygiène industrielle lorsqu’elles sont disponibles. Le présent article décrit les opérations électrolytiques effectuées sur le Co à Port Colborne, Ontario (1954–1966), et fournit des mesures de la teneur en aérosol (1995–2008) pour l’extraction électrolytique actuelle du Co."

Jan 1, 2015

By A. Fawceit, B. C. Dyer

"The basis of the tomographic velocity imaging technique is briefly described and an application of the method to detect and image a cross-section through a chromite pod is presented. Using the chromite application as an example, the relative costs of tomographic data acquisition and processing are compared with those of diamond drilling to obtain similar resolution. A number of different tomographic survey configurations and the potential role of the method in surface and underground exploration are discussed.IntroductionThe technique of seismic tomography has been most widely applied in oil industry exploration, nuclear waste disposal, civil engineering site investigations and in the assessment of the condition of mass concrete structures. Although model studies had indicated that tomography would be a useful tool in mineral exploration, relatively few applications have been reported.Essentially the method relies on the determination of the speed with which sound travels through a region within a cross-section of the earth or large body. The speed of sound is determined by the physical characteristics of the medium through which it is passing. In geophysics the speed of sound is generally referred to as the seismic velocity. Due to variations in the formations of different rocks the seismic velocity will vary and so can be used to map geological boundaries"

Jan 1, 1994

By Marcel Vallée

"Abstract-In recent years, several unsavory events in international mineral exploration, as well as several widely publicized project difficulties and failures have occurred. The report Setting New Standards has "raised the bar" and proclaimed a "commitment to continuous improvement... and change." We need to evolve from our "generally accepted" practices to more effective quality assurance policies, guidelines and standards. Several steps will be required to support the work of the "qualified persons" now wholly entrusted with technical and professional matters:• adopt a mineral development model and objectives appropriate to orient the selection of workmethods and verification procedures suitable to increase the profitability of these activities;• review the definitions and implications of the terms practice, guideline and standard;• review three quality assurance systems with emphasis on commitment of company management and complementary emphasis on systematic quality policies, plans and manuals (ISO 9000), continuous improvement through "profound knowledge" (Deming, 1986), and self-appraisal of continuous improvement and client satisfaction using the Qualimeter Guide (Québec Society for Quality);• determine, from the objectives of the mineral development model proposed and the problems often encountered, the requirements of resource/reserve estimation and the production feasibility study. To regain investors’ confidence and improve the returns from mineral development activities, an explicit commitment to quality by the board of directors and the management of every company is required.A number of mining companies have gained ISO 9002 certification for their operations but exploration companies should start by developing and implementing quality assurance guidelines and standards based on the ISO 9001 pattern, without achieving actual ISO certification in the short term. Both professional associations and industry organizations must be involved in the process of developing the required quality and continuous improvement guidelines and standards."

Jan 1, 1998