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By A. F. Neil, A. S. Bahaj, P. Watkins, P. M. Hyslop, C. E. Kirby, P. A. B. James

The results of initial work indicate that for 3 of the 5 quarry sands bioleaching reduces the iron oxide content to a commercially acceptable 0.035 wt% Fe20 3, although the time taken to achieve this is 14-22 days against a target leach time of 7 day. Subsequent work has identified strains of Aspergillus niger that are more efficient at producing the array of complexing agents for iron and is yielding excellent and rapid reductions in Fe levels. Potentially, bioleaching offers a more environmentally friendly and energy-efficient process for the removal of Fe from glass-making sands than conventional routes but the production of organic acids by fermentation must be achievable with low-cost substrates such as sugar-beet molasses and lactose permeates for bioleaching to offer a commercially viable alternative to treatment with hot mineral acids. Silica sands usually contain three groups of Fe minerals: iron oxyhydroxides, which comprise crystalline types such as goethite and limonite tending to occur as thin, discontinuous coatings and in cracks and crevices on the surface of the quartz; the assemblage of heavy trace minerals, which include ilmenite, rutile, leucoxene, chromite and haematite, commonly present at levels of 0.1 wt% or less as discrete grains or sometimes cemented to the quartz; and clay minerals cemented in pits on the surface of the quartz and in association with weathered, discrete feldspars. The response of the assemblage of iron minerals to short periods of exposure to hot inorganic acids is broadly related to which group they belong to, those that form coatings being accessible to acid and tending to react rapidly whereas the trace minerals are usually resistant and react very slowly, if at all, and the clays are probably digested. The note reports on a preliminary study of the use of microorganisms to develop an alternative clean technology that will give results comparable to those achievable with hot inorganic mineral acids but with more environmentally acceptable procedures. Various fungi and bacteria produce organic acids when grown in certain media. When these acids come into contact with Fe-stained sand grains the iron is removed as soluble complexes. Several strains of Aspergillus niger have been found to produce organic acids from sugar, predominantly citric, gluconic and oxalic acids, their relative yields depending on cultivation medium and conditions. Sand samples were prepared from five quarries in the UK: Levenseat, Lothian; Redhill, Surrey; King's Lynn, Norfolk; Chelford, Cheshire; and Oakamoor, Staffordshire; ranging in iron oxide content from 0.035 to 0.153 wt% Fe203

Jun 18, 1905

Two concentrates from Palabora, in South Africa, containing 0.056-0.068% undesirable Cu and 0.8 or 2.2% Ti, were chlorinated with air:chlorine ratios of 10:1, 15:1 and 20:1 at temperatures between 1 200 and 1 329 K. The resulting volatile chlorides were condensed and the solutions analysed for Cu, Fe and Ti. Recovery of Cu was less than 25% at low temperatures and short reaction times, but at 1 258 K almost all Cu was removed from the magnetite at all ratios of chlorine to air. At higher temperatures, the increased carrying over of iron as FeCl3 could be minimised by decreasing the partial pressure of chlorine. No titanium was detected in the volatile products and the percentage of Cu recovered was independent of Ti concentration in the concentrates, though as a function of Cl2 vol%, more Cu was recovered at 1 200 K from the low-Ti than from the high-Ti concentrate. In a fluidised-bed reactor, Cu recovery was 58-90% and iron carry-over less than 10 ppm

Jun 21, 1905

By Y. L. Ding, N. A. Warner

Cylindrical pellets made from graphite and chromite mixtures were reduced in high-carbon ferrochromium melts at 1 600-1 695 degrees C, under an atmosphere of almost pure CO. The reduction rate, as measured by gas evolution, increased with increasing melt temperature and graphite addition and with decreasing pellet diameter or height, although reductant particle size had a very limited effect on kinetics. At a pellet size, heat and mass transfer were significant in controlling the early stages of reduction of large pellets while at chromite grain size, gas diffusion was probably a rate-controlling step. The time required for dissolution of unfluxed pellets into the melts was significantly longer than that for reduction. This indicates that pellet dissolution may be the limiting factor in determining the operating parameters for a proposed new process to produce high-carbon ferrochromium using melt circulation

Jun 19, 1905

By J. K. Brimacombe, F. D. Richardson

Studies have been made of interfacial turbulence occurring in reactions in which indium, zinc and cadmium, dissolved in amalgams, are oxidised into aqueous phases by ferric or mercurous ions. It has been found that this turbulence occurs when the concentrations of oxidising ions in the aqueous phase become sufficiently great. These concentrations are the same as those at which the mass-transfer coefficients in the aqueous phase increase sharply when both phases are stirred by gas bubbles rising through them. The effects of gas flow rate on the mass-transfer coefficients for zinc in mercury have been established, and the oxidation of pure mercury has been investigated. The relevance of the work to processes involving liquid metals is discussed

Dec 1, 1971

By M. A. Leosson, S. H. Bottrell, R. J. Newton

Sylvite at Boulby is mined 1 140 m beneath the sea and the mine suffers from the influx of water. This is of two kinds: persistent flows originating in the Sherwood Sandstone aquifer and entering the evaporite sequence through fractures in the intervening mudstone, and impersistent flows which are transient in nature and of uncertain origin. Water from the overlying sandstone has become enriched with NaCl and large amounts of KCl and some Mg and Br have been added by interaction with the evaporites. Waters from the transient flows are isotopically distinct from those in the Sherwood Sandstone, being enriched in H and O. They are also saturated with respect to halite and sylvite, but have higher K/Na than the persistent flows and are much more enriched in Mg and Br

Jun 18, 1905

By L. J. Barnes, R. O. Koch, J. H. Versteegh, C. J. N. Buisman, P. J. H. Scheeren

Several water treatment options have been studied and piloted. A process based on activity of sulphate reducing bacteria combines sulphate removal and heavy metal removal in one process step. The anaerobic bacteria reduce the sulphate to sulphide and consequently metal sulphides will precipitate. The final design for the commercial scale plant is described.

Jan 12, 1992

By R. M. Honey

An attempt is made to summarise the mining law of England, Wales and Scotland. Attention is also drawn to the recent privatisation of the electric power and gas industries and the intention of the present Government to follow suit as regards coal mining. The subject of mining law is discussed under the headings: minerals or rights that have been nationalised or are vested in the Crown; ownership (of land and mineral rights); special customs; tracing of owners; right of support (arising from mining); ancillary rights and easements; obtaining prospecting and mining rights; planning permission; statutory aids to obtaining rights; notes on the history, law and practices of petroleum (onshore and offshore), gas, coal, prescribed substances, gold and silver; electricity; safety, health and welfare; and technical information and boreholes. A correction in the subsequent issue amends errors on p.A75 and A82 and regrets the publication of misinformation on the availability of grants

May 1, 1991

By J. Ivon Graham, T. D. Jones

This paper presents methods in use in British coal-mines for the suppression of dust. While the effect of present-day treatment will not be apparent for several years, in pits in South Wales, concentrations as high as 50 gm./1,000 cu. ft. were some years ago fairly common in various operations at or near the coal-face, with an average concentration of 20 gm./1,000 cu. ft. Now the average concentration in what were previously dusty pits is probably not greater than 3 gm./1,000 cu. ft.Nevertheless, every effort must be made to improve conditions still further. In South Wales it is claimed that 99% of the coal-faces requiring treatment have been dealt with either by wet cutting, infusion, or hand-spraying. The extent of the treatment by these methods can be gauged by the fact that the total length of coal-faces now being treated by water infusion in Cardiff and Swansea areas is about 33,000 yds., by wet cutting 25,000 yds., and by hand-spraying nearly 14,000 yds. The influence of methods of mining upon dust production is only mentioned very briefly in this review, and there is no doubt that much more is to be learned concerning this aspect. It can be stated, however, that good mining practice is essential to prevent unnecessary dust production, and the problem of dust in mines will be solved only by the closest co-operation between mine managers, workmen, and scientists.

Jan 1, 1947

By S K. Das

An intensive investigation into modern roof support technology, including hy draulic and control systems, has been carried out against the perspective of global development and support behaviour on longwall faces across the Indian sub-continent. The wide ranging study examined various types and designs of modern supports used in seams of varying thickness and inclination where caving and stowing were practised. Consideration has been given to structural analysis, support resistance, the various forces acting over and on the powered supports and to support compatibility. The examination of the phy sical parameters has been allied to field experience and, together, have led to the formulation of standard designs for both the powered support structure and structural systems. A realistic mathematical model has been formulated for calculating the capacity of roof support requirements resulting from the actual behaviour of the immediate roof stratum. As a result of the work, it should be possible to readily select the most appropriate type of support sy stem for the conditions and longwall mining method that is to be employed.

Jan 4, 1997

By John Craw

This paper has formulated the methods, both medical and engineering, for the control of pneumokoniosis in the haematite-mining industry in West Cumberland, but this is only part of a general service to improve the lot of the worker in these mines, to make him a better and happier workman, and to permit him to enjoy his work and leisure in comfort and good health. This organization has now been functioning for more than ten years and the results are indeed heartening, but it is only as a result of constant vigilance from the mining and medical point of view that such a plan can operate efficiently. The human element and its full understanding is by no means the least of the problems.

Jan 1, 1947

By NA NA

In the third of its features on the new owners of the British coal mining industry, Mining Technology reports on the newest company in the field, Midlands Mining.

Jan 2, 1997

By H. L. Paterson, R. R. Keays, M. J. Donaldson, D. J. Boyack, M. F. Smith, J. J. Gresham

"Albite-rich sedimentary rocks that contain abundant Fe sulphides occur in the lower portion of the ultramafic sequence at Kambalda and their broadly antipathetic relationship to most of the nickel orebodies is well documented. These sediments generally contain less than 0.1% Ni, but nickeliferous equivalents with 0.3 to >6% Ni occur locally in close spatial association with more typical volcanic peridotite-associated massive, matrix and disseminated ores. Nickeliferous sediments have been mined at several locations at Kambalda but, collectively, they constitute less than 2% of the total Kambalda nickel reserve. The nickeliferous sediments occur both on the ultramafic-footwall basalt contact and within the lower part of the ultramafic sequence, and are usually less than 5 m thick. They are commonly finely laminated rocks with a cherty appearance, composed essentially of layers of albite+quartz±amphibole, alternating with pyrrhotite+pentlandite±pyrite layers. Some contain a minor amount of carbon. The sediments are only of ore grade (> 1% Ni) immediately adjacent to massive Fe-Ni-Cu sulphides, which are interpreted as normal magmatic ores on the basis of geochemistry and the presence of distinctive ferrochromites. The nickel content of the sediments decreases to background levels (<0.1%) within about 20 m of the massive sulphides. In most locations the massive sulphides clearly have been emplaced tectonically within or adjacent to the sediments, which are commonly highly deformed. Typical nickeliferous sediments contain about 1% Ni, 0.1% Cu, 0.1% Zn, 400 ppb Pd, <0.2 ppb Ir and 10-200 ppb Au. They have lower Ni/Cu (average 10), higher S/Ni (average 6) and higher S/Se (average 11 200) than associated massive sulphides (average 40, 4.8 and 7400, respectively). The Pd/Ir ratio of the nickeliferous sediments (typically > 1000) contrasts markedly with that of associated massive sulphides (average ca 16).The high Pd/Ir values are similar to those which have been reported for hydrothermal Fe-Ni sulphides and barren sulphidic sediments of probable volcanic exhalative origin. They preclude a direct magmatic origin for the sulphides in the nickeliferous sediments, though S/Se and S isotope data indicate a magmatic source for the sulphur. The restriction of nickeliferous sediments to within about 20 m of normal magmatic sulphides and the lack of a widespread Ni dispersion halo suggest local redistribution of originally magmatic Ni. This probably occurred by diffusion and hydrothermal mobilization during deformation and amphibolite-facies metamorphism. Although not totally ruled out, a volcanic exhalative origin for the Ni seems unlikely."

Jan 1, 1984

By T R. Meng, C Wu

After carrying out a brief review of the existing safety assessment criteria for the spontaneous detonation of explosives in the mining of sulphide ore deposits in China, and giving a detailed description of the dynamic process and mechanism of the spontaneous detonation of explosives and the relative factors, the latest research results of three kinds of explosives reacting with a group of sulphide ores are presented, based on a reliable experimental method. Afterwards, a complete safety criterion for spontaneous detonation assessment, which depends on the hole temperature, the water solution Fe2+ and Fe3+ and the pH value, is established to determine (he safe charging time of explosives in variable conditions. The criterion is verified as correct by a large-scale field test.

Jan 10, 1996

By L. J. Barnes, R. O. Koch, J. H. Versteegh, P. J. H. Scheeren, F. J. Janssen

Following two years of laboratory research with bench scale reactors, a 9 m3 experimental process demonstration reactor was installed at Budelco's zinc refinery to treat their underlying groundwater. A 600-fold scale-up was successfully achieved. It has demonstrated that this anaerobic microbial process can remove a wide range of heavy metals and sulphate to the required levels. Extended operation of the demonstration unit has shown that the process is robust, can withstand wide variations in feed composition, rapidly recovers from operational upsets and is easy to start up and shut down. The metal sludge produced can be processed in a metal refinery to recover both metals and sulphur.

Jan 12, 1992

By J. H. E. Jeffes, K. T. Jacob

Solid oxide galvanic cells, of the type: Pt,Ni-NiO | Solid electrolyte | O(metal),Cermet,Pt, were used to measure the activity coefficient of oxygen in liquid Cu at 1 100 and 1 300°C and in Pb at 1 100°C. Similar cells were used to study the activity coefficient of oxygen in the whole range of Cu + Pb alloys at 1 100°C and in Pb-rich alloys at 900 and 750°C. The results obtained are discussed in terms of proposed solution models. An equation based on the formation of 'species' of the form M(2)O in solutions of oxygen in binary alloys is shown to fit the experimental data

Dec 1, 1971

The mineralogical composition of the ore was determined and the mineral phases with which nickel is associated were identified. The ore was prepared by grinding to -420 micrometres and classification into granulometric fractions. Prior to the main series of experiments the effect of agitation rate on nickel recovery was investigated. The influence of sulphuric acid concentration, temperature and particle size on the kinetics of nickel extraction was then studied, both quantitatively and qualitatively, over fixed value intervals. Application of the initial rate method enabled determination both of the order of reaction with respect to sulphuric acid concentration and the activation energy for the dissolution of nickel. The results indicate that a physical mechanism can be ruled out as the rate-determining step in the extraction of nickel from the ore and that a chemical mechanism is more likely

Dec 1, 1991

By Haldane J. S.

(Paper presented at the Institution of Mining Engineers' general meeting held in London on 8th June 1916.) It was shown in the last Supplement to the Registrar-General's Reports, in connection with the census of 1901, that the general death-rate among colliers was considerably lower than in the great majority of occupations but that there is an exception to this in the case of colliers above the age of 55. Examination of the statistics finds that the excessive death-rate among old colliers is to a large extent only apparent, and that the real excess of bronchitis from which they have suffered has greatly diminished. It is concluded: (1) that good ventilation is of considerable importance to the health and continued working efficiency of miners, as well as to their safety from accidents; and (2) that there is no real statistical evidence of harm resulting from the inhalation of coal-dust or shale-dust in the quantities ordinarily breathed by miners, and a strong presumption that the dust they breathe protects them against serious dangers from bacilli that are removed from the lungs by the dust-clearing cell mechanisms

Dec 1, 1916

By R. Winand, P. Harlet

he cathodes produced are of electrorefined grade; metallographic structure and surface roughness are controlled to a depth of 1.3 cm (single-side deposits); silver levels in the cathode are regulated by the presence in solution of Cl- and Br- ions; organics must be used at very low concentrations (around 0.1 mg/l with a consumption of about 0.01 mg/l/hr). The required concentrations of additives were established according to a well-defined strategy based on the consumption of organics at the cathode by a mass transfer limited-process.

Jan 4, 1992

By D. J. Allan, W. R. Wilson

For conventional aerospace aluminium alloys of the 2000 (copper) and 7000 (zinc, magnesium) series the recycling of process scrap from both metal suppliers and aircraft manufacturers is a well-established, worldwide industry. The recent introduction of a new family of alloys that incorporates lithium has posed a new challenge to the recycling industry owing to the high cost of lithium, its high reactivity to the atmosphere and to refractories and its absence from the specifications of all other registered alloys. Various process options for recycling have been identified, but vacuum distillation has been selected as the most cost-effective and technically feasible solution. Experimental work established that the separation of Li from AI-Li scrap is feasible and an industrial process has been designed. The economics of Li recovery are very sensitive to the AI-Li content of the feed material. Owing to the design of aerospace vehicle manufacturing plants it is expected that the swarf will be mixed with other alloys. A method of enriching this feed has been developed that is based on the control of swarf morphology by thermal and mechanical treatments as a precursor to eddy-current separation. After eddy-current separation and vacuum distillation small proportions of Li are retained in the AI residue. The effects of this on the properties of conventional AI-Si shape-casting alloys were investigated and safe threshold levels have been established.

Jan 4, 1993

By J. Temporal

An introduction to the conference material in this issue is given together with the issue contents list, closing remarks by its chairman Dr. J. Temporal, the list of contributors and their companies, and the information that the 26th Sir Julius Wernher memorial lecture had had to be presented by the lecturer's wife, M. Biggart, in his absence due to site problems on the Storebaelt project

Jun 16, 1905