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By James Rowland, Marcia Harris, Richard Mainiero, Michael Sapko

All explosive materials produce a cloud of reaction products, the most toxic of which is nitrogen dioxide (NO2). In the study reported here, 4.5-kg (10-lb) charges of blasting agent confined in either thin-wall 10-cm (4-in) diameter galvanized pipe or 10-cm (4-in) schedule 80 seamless steel pipe were detonated in a closed chamber. The detonation gases were analyzed for NO2, nitric oxide (NO), ammonia (NH3), hydrogen (H2), carbon monoxide (CO), carbon dioxide (CO2), nitrogen (N2), oxygen (O2), and methane (CH4). Data were evaluated to determine the kinetics of the oxidation of NO to NO2. Analysis revealed that the only mechanism for NO loss for the conditions existing in the chamber was the reaction 2NO + O2 6 2 NO2. The rate constant was 2.08 ?? 10-38 cm6 molecules-2 sec-1 for the rate equation -??d [NO]/dt = K ?? [NO]2 ?? [O2] for NO concentrations up to 100 ppm. The rate constant is in agreement with that recommended by Baulch, Drysdale, and Horne (1973).

Jan 1, 2006

By C. Anderson, Mike Michaelis

Ammonium Nitrate (AN) - based commercial explosives are non-ideal explosives. This is because the chemical and physical structure is heterogeneous on a distance scale comparable to, and in many cases larger than, the reaction zone in the detonating explosive. Such systems consist of inter-molecular fuel-oxidizer systems. Attempts have been made to minimize the heterogeneous nature (inter-molecular distances) of these explosives; emulsion systems are the latest examples of these commercialized AN-based explosives which balance cost, utility and performance. This latter factor (increased performance) is a direct result of increasing the contact between oxidizer and fuel.

Jan 1, 2003

By Lex L. Udy

Properties of an explosive which itiuence its performance on rock breakage are analyzed in relation to the rock: hardness and a discussion on the interaction of an explosive with the rock during the blasting process is given. Theoretical concepts regarding ideal and non-ideal detonation are reviewed to explain how the physical and chemical factors of an explosive influence the rate of energy release and its consequence on blasting performance. While a lower velocity of detonation indicates a slowed chemical reaction it does not necessarily mean a loss in energy from the explosive. High density ammonium nitrate (HDAN) can be used effectively in the formulation of modern industrial explosives to slow the energy release rate with its attendant decrease in detonation velocity. Examples of blasting performance using custom formulated explosives with HDAN are presented.

Jan 1, 1995

By Robert Hopler

The use of electrical fuzes is rapidly superseding the old cap and fuse method of firing blasts. It is therefore desirable that the details of this kind of blasting should be more generally understood

Jan 1, 2006

By Robert Morgan

The mind-set that only blasters and their helpers need training in explosives can result in risk to other employees working at mine or construction sites where blasting is conducted. Misfires are not always immediately obvious during postblast examinations performed by the certified blaster in charge; the presence of undetonated explosives may not appear until well within the muckpile as was the case in the photo, right. To avoid accidents involving misfires, follow safety procedures specified in mine safety regulations, and the ISEE Blaster’s Handbook that include the following:

Jan 1, 2004

By E. Contestabile, R. von Rosen, R. Guilbeault, R. Fouchard, P. Lightfoot

In August 1998, a truck loaded with 18 tons of blasting explosives, including over 13 tons of ANFO, left the road near Walden, Ontario. The crash caused a fire; approximately 30 minutes later a large detonation occurred, causing substantial damage to the roadway and local property. Although nobody was injured in the explosion, the consequences of a similar incident in a heavily populated area could have been catastrophic. Following the Walden incident, Transport Canada and Natural Resources Canada embarked on an extensive experimental program to determine the cause of the detonation. This paper describes part of that experimental program, designed to understand better the thermal decomposition of ANFO.

Jan 1, 2003

By Kwang-Tae Kim, Yong-Kun Choi, Jeong-Soo Chong, Yun-Jae Lee

An annex building at the former Agency for National Security Planning(NSP) complex located in downtown Seoul was demolished by progressive collapse method. This work was done as a part of efforts to restore the landscape of Namsan Mountain which lies in the Center of Seoul. The five-story reinforced concrete structure was razed in 5.5 seconds by the 29kg of high powered explosives which were placed in some 320 holes in the building with floor area of 2,577 m². The asbetos and all the other finishing materials in the building were removed before the demolition and the specially coated wrap minimized the spread of blasting dust. Seismic and air overpressure waves were monitored at 8 points, which were below safety limits and the continuous communication with neighborhood prevented any complaint.

Jan 1, 1998

By S. Paul Singh

Rock is a heterogeneous medium, a fact often ignored during blast design. In reality, the rock mass characteristics have a controlling influence on the outcome of a blast. If the optimum blasting results are to be achieved over a range of rock mass conditions, it is prudent to understand the role played by the geological features of a rock mass in producing overbreak around the periphery of an excavation. The field work was performed in a drift located in a geologically dominant rock mass and also included observations and assessment of blast damage at several operating mines. The blast damage was estimated on the basis of the half cast factor. The effect of rock strength, rock quality designation, orientation , frequency and aperture of joints, number and thickness of layers and hydrogeological conditions on blast damage has been described.

Jan 1, 2000

By Thierry Bernard, Phillipe Cappello, Jean Marc Laboz

"The main reasons of the emergence of electronic detonators are linked to:-Local urban development close to mining operation sites-Environment regulations"

Jan 1, 1995

By Rennie Kaunda, David Streeter, John Kemeny

This paper describes a field/laboratory study that was conducted in cooperation with a mine in Arizona. The primary purpose of the study was to investigate the effect of blasting energy on the crushability and grindability of the post-blast rock fragments. The crushability and grindability of the rock fragments were evaluated through laboratory comminution tests. A secondary purpose of the study was to investigate different laboratory methods for estimating the comminution properties of the rock fragments. In particular, a number of standard rock mechanics tests were conducted and compared with the comminution test results. Finally, the study was used to evaluate new technologies for estimating insitu rock mass strength and for assessing post-blast fragmentation. To estimate in-situ rock mass strength, the specific energy of drilling (SE) was calculated during blast hole drilling utilizing a continuous drill monitoring system. Post-blast fragmentation was estimated using the Split image processing system. Results from the study support the idea that increases in blast energy can enhance crushing and grinding. Also, several simple rock mechanics tests were found to correlate well with the results from standard comminution tests, which could prove to be useful in practice.

Jan 1, 2003

By A J. Rorke, U Chhika

"A series of tests was carried out on a dry blend of PPAN and LAN prills (LANFO). The objective of thetests was to determine detonation stability and VOD performance compared to ANFO. Heave andfragmentation results in the field were also evaluated visually. A number of factors were behind for.mulating this blend. A lower cost is combined with higher in-hole energies, but at slower reactionrates and lower peak borehole pressures. The resultant effect is improved heave characteristics andlower energy losses caused by inefficient crushing of the rock immediately around the borehole.The test results indicate that IANFO is ideally suited to blasting in softer midburden and overburdenrock types often encountered in coal strip mines."

Jan 1, 1995

By Ann Barron

“Hurry up” is the latest battle cry at explosives companies struggling to stay in compliance with the ever-growing onslaught of government regulations. The pressure continues to mount on industry professionals who face stiff penalties if their companies fail to comply with the law. Such penalties can range from monetary fines and revocation of blasting permits and licenses, to increased liability for civil claims or even criminal charges.

Jan 1, 2006

By Bill Williamson, Doug Richmond, Kerri Kuntz, Gus Gilman, Larry Heywood

This was a description by the poet of what occurred over two centuries earlier to Hannibal’s troops as he passed through the Alps. Interestingly, the pass that many feel is the route that Hannibal chose, Col de la Traversette, is the sight of possibly the earliest avalanche mitigation known. Monastery records describe a tunnel built in 1470, near the top of the pass designed to protect pilgrims from the upper slopes. For the next several centuries, avoidance and reinforced structures were the primary tactics to defend from avalanches

Jan 1, 2009

By Peter Moser, Frank Chiapetta, Sacha Diaj, Florian Bauer

Good toe breakage and a flat working bench after blasting are important parameters to achieve a high productivity during material loading and reduce the necessity for secondary blasting. Good toe breakage requires a proper burden – side spacing design and a suitable sub-drilling. With unfavourable jointed rock mass conditions the use of horizontal bottom holes still can be found as common work practice even that this is associated to high risks.

Jan 1, 2009

By Bob Turnbull

The International Society of Explosives Engineers (ISEE), at its 1995 annual conference, established a Seismograph Standards Working Group to develop performance standards for blast vibration seismographs. This group was transformed into the Blast Vibration and Seismograph Section in 1997 with 5 working committees one of which was the Seismograph Standards Committee. Standards are essential to ensure that vibration records from different seismographs would report the same vibration levels within a stated tolerance. In 2000, the ISEE through the work of the Blast Vibration and Seismograph Section published the “Performance Specifications for Blasting Seismographs.” This document is available on the ISEE web site at www.isee.org/sections/blast.htm.

Jan 1, 2007

By Pharis E. Williams

The ability to predict the performance of an explosive relies upon having a Reaction Rate Law and knowing its functional dependence upon various parameters of the explosive. In particular, emulsion explosives have a matrix cell size and may be sensitized with glass or plastic microballoons. The cell size dependence should. be very nearly the spherical grain burning dependence upon web that appears in the reaction rate laws for ball gun powder. The dependence of the reaction rate law upon the parameters of the sensitizing microballoons has been explored using hydrocode analysis of the pressure field produced by the collapse of a microballoon. This pressure field provides an increase in pressure in the vicinity of the microballoon which, in turn, increases the rate of reaction within this field and provides the energy release that must be achieved in order to have a steady state detonation for use as a blasting agent. Hydrocode analysis allows the determination of an approximate functional form for the reaction rate law which shows the dependence upon the size, type, and quantity of microballoons. This presentation includes the theoretical background and the determined functional form of the reaction rate law.

Jan 1, 1995

By S. J. Dillingham

As we enter the new century and close out the old, it has become standard procedure for most blasters to complete a blasting log or shot report following a blast. However, how can you be sure these completed blasting logs are worth the paper or electronic space they occupy.3 Is the recorded data accurate and meaningful? Will the blasting logs stand up under investigation? This paper will attempt to define the purpose of a blasting log, illustrate common mistakes, discuss potential problems, and indicate steps that a company or individual blaster can take to improve and protect against costly errors. The end result will be a reminder of the importance of accurate documentation following a blast that must be given the same individual effort as went into the blasting itself. This paper will also attempt to achieve a proactive training resource to improve the use of blasting logs. A completed blasting log is, quite possibly, the only witness to the overall credibility of the work of the responsible blaster. The log may remain perpetually silent, only to end up in a file that is moved progressively with time to various levels of long-term storage. But, will this silent witness be ready to speak out should a concern arise from the blasting ? Will the blasting log communicate with authority and credibility, or will it be ridiculed by investigation and silenced in shame with costly adverse results for the blaster and company? It is not enough to simply complete a blasting log. The information it contains must be accurate enough to stand the test of time and arduous scrutiny. Unfortunately, most blasters and their associated blasting companies do not realize the status of the silent witness until it is too late.

Jan 1, 2000

By Jack Elorenta

We often hear that, "Blasting was an art, but now blasting is now a science". 'Scientific' blasting implies that we have quantified and reproducible measurements of the feedstock and product of the blasting process. However, the industry's reluctance to adopt two key technologies, drill monitoring and optical size analyzers, sheds doubt on the claims of scientific blasting.

Jan 1, 2003

By Randy Wheeler

The importance of having full wave form information for recorded blast events cannot be overstated. Knowing the peak particle velocity and the frequency at the peak are the tip of the iceberg. This presentation will focus primarily on using the FFT (fast Fourier transform) for detailed frequency analysis. Employing linear superposition to evaluate timing effects on amplitude and frequency will be discussed.

Jan 1, 2005

By Wes Bender

Considering the current interest in Global Positioning System (GPS) usage, it might be timely to look at a more efficient means of utilizing these instruments. The GPS system currently utilizes 28 satellites (4 are spares) circling the earth in an inclined orbit. Normally at least six satellites are within your area of reception at any given time. The satellites broadcast an extremely accurate time signal and an almanac containing all the satellites’ orbital data. This information is updated regularly as the satellites circle the earth. Your GPS receiver, once it has picked up one satellite’s broadcast, can then determine which other satellites should be available for plotting.

Jan 1, 2002