Search Documents

By G. W. Jones, R. E. Kennedy

"INTRODUCTION Information relative to the ignition temperatures of acetylene and acetylene-air mixtures has become of particular interest recently due to a number of explosions that have occurred in 500-pound, double-rated, medium-pressure acetylene generators in shipyards on the West coast. Various suggestions have been made as to the causes of these explosions prominent among which has been that air finds its way into the acetylene generators during abnormal operation or that air remains in the carbide hopper of the generator following the purging and charging operations.This raises the question as to how and to what extent the presence of small percentages of air in acetylene affects the ease of ignition of such mixtures at the various operating pressures of the acetylene generators. The range of operating pressures in the 500-pound, double-rated generators involved in the explosions may vary from below atmospheric to 15 pounds gage.The present report gives the results of an investigation made to determine the effects of pressure on the ignition temperature of pure acetylene and of acetylene containing varying percentages of air:EXPERIMENTAL Apparatus A preliminary investigation showed that a heated quartz surface gave lower ignition temperatures than other material tested.A ""hot-spot"" method of ignition was found desirable in the case of the acetylene mixtures since the violence of the explosions was reduced by keeping most of the test mixtures at room temperature. Explosive violence was reduced further by using an ignition tube 17 mm. or less in diameter."

Mar 1, 1945

By J. C. White

A research study was conducted to devise a method for producing phosphoric acid directly from unbeneficiated Florida phosphate matrix. This research was performed as part of the Bureau of Mines, U.S. Department of the Interior, goals of improving minerals and metals recovery from domestic resources and of minimizing the environmental impact associated with mineral recovery operations. This report describes research in which unbeneficiated, dry, south-central Florida phosphate matrix was digested with sulfuric acid in a continuous-circuit, five-tank reactor to yield phosphoric acid and gypsum residue. Feed capacity of the reactor was 100 pounds (45 kg) of dry matrix per 24-hour day. When digestion was carried out at 185° F (85° C), acid filtration rates of up to 420 pounds of P20S per square foot per day were attained. Combined iron and aluminum impurities in the product filter acid were about 60 percent greater than values reported in commercially produced acid derived from concentrate. phosphate recovery was 87 to 90 percent of the phosphate contained in the as-mined matrix.

Jan 1, 1978

By F. D. DeVaney

An examination of the physical properties of manganese ores is being made at the Mississippi. Valley Station of the United States Bureau of Mines in cooperation with the Missouri School of Mines and Metallurgy, Rolla, Missouri. The object of the study is to find out how much these ores can be beneficiated by such processes as jigging, tabling, magnetic separation, and flotation. Some. of the results were given in an earlier report.4 Eighty samples obtained from various prospects and mines throughout the country have been examined; this is a very small part of those that should be examined before the work can be a definite factor in-the appraisal of manganese ores or the guide in beneficiation which the operators seek. The ore deposits are not expected to reach to great depths vertically, after the manner of copper and gold, but in lateral distribution their greater extent is notable. This applies particularly to the residual and replacement deposits of manganese.

Jan 1, 1929

By Hewitt Wilson

[ ]

Jan 1, 1927

By L. B. Berger

In this investigation, the ampoule type of carbon-monoxide (CO) detector which is manufactured under license of U. S. Patent 1,644,014 (October 4, 1927) was tested for sensitivity and reliability. This detector was devised primarily for examining the air of manholes and sewers for possible dangerous contamination with CO before workman enter those places, but dine to the simplicity of the device it may have a more general usage for examination of atmospheres which are known or suspected to be contaminated with CO. Some of the suggested uses are the examination of the air in garages, tunnels, mines, around blast furnaces, gas plants, and in the home.

Jan 1, 1930

By A. G. Starliper

Research was conducted by the Bureau of Mines to determine feasible roasting methods for the removal and the recovery of germanium, cadmium, and lead as enriched fractions from sphalerite concentrates. The two types of roasting processes studied were: (1) Batch, with a stationary bed, and (2) continuous, with a suspended bed, Results indicated that either method gave satisfactory metallurgical recoveries} but the continuous process is recommended because of inherent advantages. Final products were enriched fractions that could be treated by conventional methods for production of metallic germanium, cadmium, and lead. In the batch process, the concentrates were placed in a large tube furnace and heated at 1,080° C, an average of 3 hours. During the heating period, inert, reducing} or sulfur-laden gases were passed over the stationary charge to convey the sublimed metal sulfides from the hot portion of the tube to a lower temperature condensing zone at the end of the tube, where the metal sulfides were collected on baffles and recovered. In the batch and fluidizing roasting processes alike, the gases passed over or through the charge and served only as carriers for the sublimates and as suspension media in fluidization roasting. Since both processes depended on the volatilization, at relatively high vapor pressures, of the sulfides of germanium, cadmium, and lead, it was imperative that very little oxygen come in contact with the charge to alter the sulfide minerals. Germanium has a high affinity for oxygen, but in this instance it was buffered by being in solid solution in zinc sulfide.

Jan 1, 1961

By K. K. Kelley

"In an earlier consideration of the vapor pressure of iron 3/ it was found necessary to estimate the specific heat of gaseous iron to write satisfactory free-energy-of-vaporization equations for the several forms of iron. That the specific heat of gaseous iron will exceed greatly the classical value of Cp = 4.967 calories per gram-mole per degree is evident from even a cursory Lamination of its spectrum. The two lowest energy states are separated by only 416 cm-1, which is small enough so that the second state is effective, theoretically, at below room temperature. Such phenomena are by no means uncommon, but, while they have been recognized with substances that ordinarily are encountered as gases, classical gaseous specific--heat values still are used, often without question, for the vapors of metals and other elements that are solids under ordinary conditions. The following calculations for iron and copper gases are presented to illustrate the sort of deviations from classical values that are encountered with metal gases.The methods employed in calculating from spectroscopic data of thermodynamic quantities such as specific heat, entropy, and free energy have been described, in detail by Giauque 4/ and others. These will be briefly reviewed here. It is customary to separate the translational energy of a molecule from the rotational, vibrational, and electronic energies. In the case of monatomic gases, only translational and electronic Energies are involved. The classical expression for the specific heat of a mona¬tomic gas, Cp = 4.967, deals only with energy stored in the molecule as translational energy and consequently is valid only in temperature ranges in which no appreciable number of molecules undergoes a change in electronic state."

May 1, 1937

By W. A. Cole

As the mines get older and the active workings get Farther and farther away from the original mine openings, it becomes increasingly difficult and expensive to ventilate most coal-mines properly. At the same time, the avenues of escape for those employed underground have become so extended' as often to make it impossible for them to make their way out of the mine in the event of a fire, mine explosion, or other emergency. Where such Conditions exist, the only satisfactory solution is to make new ventilation and emergency-escape openings near the active mine workings. At most mines this would necessitate sinking shafts, which is often slow and expensive.

Jan 1, 1945

By John Nagy

Limited experiments in the laboratory with specimens of mine rock from a Virginia bituminous coal mine indicate that natural gas-air mixtures can be ignited by sparks generated by rubbing friction of sandstone against sand-stone, shale against sandstone, sandstone against (roof-bolt) steel, and shale against steel. Such sparks, generated during a roof fall, may have initiated a recent gas explosion in this Virginia mine, although this cannot be stated with certainty. No ignitions of gas were produced by sparks or heat generated by impact friction between mine rocks or steel, during tension breaks of roof bolts, or by pull tests of roof bolts through their washers and roof plate. However, this negative result of limited experiments does not preclude the possibility of gas being ignited by these conditions.

Jan 1, 1960

By Oliver C. Ralston, Foster Fraas

"INTRODUCTION The predominant characteristic of powdered mica is the thin -plate shape of the particulars, and the thinner the plates, the more enhanced is this characteristic. Consequently, it is frequently desirable to grade mica according to the thickness of the plates. Concerning the various possible methods for grading mica, very little has been published. There is also no information on the relative quantities of mica per given range of plate thickness. This paper presents a graphical method that shows how these quantities are distributed and how the different methods of grading compare.CUMULATIVE BULK DENSITYBulk density, which is an indirect measure of the plate thickness, was determined in a small cylindrical cup of 3.37 cubic centimeters volume. The mica was placed in the cup under a standard procedure. The densities thus measured checked these determined in a 273 cubic centi¬meter cup with less than a 2 percent error.In calculating cumulative densities it is important to know how they are averaged. In any grading operation the bulk density of a series of fractions is determined. Starting with the lowest density fraction, the cumulative percent under-density can be calculated through the various fractions. It is possible that quantity may be measured by volume or weight and that the averaging may be done by a number of methods. However, experimentally it has been shown that the quantity must be by volume and that the averaging must be arithmetic. This is illustrated in table 1, in which the calculated and actual bulk densities are listed."

Sep 1, 1942

By Harold J. Bennett

This report deals with the processing and marketing of iron and steal scrap in the intermountain States of Arizona, Colorado, New Mexico, Utah, and Wyoming and the northwestern Plains States of Nebraska, North Dakota, and South Dakota. The quantity and quality of iron and steel scrap consumed in both the steel mills and iron foundries in these States in 1964 were decided by (1) the type of facilities used to produce an end product; (2) the availability of a dependable source of iron and steel scrap at competitive prices; and (3) the, ratio of the cost of iron in iron ore to iron in scrap. In recent years the quantity of scrap used per ton of steel ingot produced has decreased. The major individual. consumers of iron and steel scrap were the steel mills in Arizona, Colorado, and Utah, foundries in Utah and Arizona, and copper leaching, operations in Arizona, New Mexico, and Utah. About 2 million tons of iron and steel scrap was used by the iron and steel industry in 1964. Although there has been a decline in the amount of scrap used per ton of steel ingot produced because of changes in steelmaking methods, there has been a slight increase in the overall quantity of scrap used because of the increase in ingot production. It is estimated that the scrap consumption in the steel industry will increase by 19 percent by 1980. In addition to the scrap consumed by the steel industry, 273,000 tons of ferrous scrap were used by copper-leaching operations. Thirty-one percent of the ferrous scrap used by the steel industry in 1964 was purchased from dealers and other sources. The CF&I Steel Corp. (formerly The Colorado Fuel and Iron Corp.) at Pueblo, Colo., complemented its blast- and open-hearth-furnace operations with basic-oxygen converters in 1962. The basic-oxygen and open-hearth furnaces were charged with 30 and 90 percent scrap, respectively. Future use of the open-hearths would probably be used to supplement ingot production requirements. Because it was more economical to use less scrap and a high molten-metal charge, the United States Steel Corp. at Geneva, Utah, which uses the open-hearth process to make steel, charges the furnaces with 25 to 35 percent scrap. The Allison Steel Manufacturing Co. at Tempe, Ariz., uses a 100 percent scrap charge in its electric furnace. Although it was estimated that there were 327,000 tons of various grades of motor vehicle scrap generated in 1963, no estimates were made concerning the total quantity and grade of scrap available in the area. Most of the scrap used in the steelmaking industry originated within the area. It was advantageous to sell scrap generated in eastern Nebraska, North Dakota, and South Dakota to markets in the Midwest because of freight costs.

Jan 1, 1967

By C. G. Kirkland

An apparatus for determining trace impurities in Grade-A helium by mass spectrometer methods was designed and built by the Federal Bureau of Mines. Grade-A is the designation for helium commercially produced by the Bureau. Its nominal purity is 99.995 percent. The device, following a suggestion by Deaton, concentrates the impurities in the helium by freezing them out in a coil-and-trap assembly cooled by liquid helium. A known volume of helium is passed through the trap, the concentration ratio determined, and samples of the concentrated impurities are analyzed by mass spectrometer methods. The apparatus has been in service for approximately 20 months and has satisfactorily met all requirements. Over 200 analyses were made of helium contained in conventional cylinders, obtained from the Amarillo, Exell, Otis, and Navajo Helium Plants, during the 6-month period ending March I, 1959. Total impurity concentrations, in parts per million, were as follows: Amarillo, 19.1; Exell, 17.1; Otis, 11.3; and Navajo, 6.6. Neon and nitrogen were the major impurities. Complete data are shown in table 4 in the body of this report.

Jan 1, 1960

By W. W. Weller

Heat-capacity measurements of sodium dimolybdate (Na2Mo207) and sodium ditungstate (Na2W207) were conducted over the temperature range from 51° to 298° K. The entropies of the two compounds at 298.15° K were calculated from the heat-capacity values and were used, in conjunction with other entropy data, to evaluate the entropies of formation of the compounds from their constituent elements and oxides.

Jan 1, 1963

This report summarizes the results of several field tests conducted by Collins for the Bureau of Mines under contract SO122076 and contract H0232056. The field projects represent a part of Collins continuing effort on a broad study of coal mine communications. These experiments analyze the propagation characteristics of radio signals in a working coal mine environment. The intent of the program is to provide basic propagation loss characteristics by which we may evaluate various approaches to an integrated mine communications system. The goal of such a system is to satisfy both operational and emergency communications needs in the mine. Field testing was conducted during the last week of November 1972, at a coal mine operated by Inland Steel Company, near Sesser, Ill, and in the Robena No. 1 Mine, Waynesburg, Pa, on 12 March 1974. The tests included uhf propagation losses and noise (200 MHz to 1 GHz) in the Sesser, I11 mine location and vlf propagation loss and noise (1 to 200 kHz) in both of the above locations. The basic experimental parameters were frequency, polarization, antenna type/orientation, and distance. The following reports treat the various aspects of the test programs in detail. Since different antenna configurations were used in the two mines, each report contains its own experimental predictions drawn from its corresponding test activities. A test equipment list and block diagrams of typical experimental setups for the tests of section 2 are contained in appendix A.

Jan 1, 1974

By S. P. Kinney, A. C. Fieldner, S. H. Katz

"1 Introduction The regrettable death of James S. Cunningham, Foreman Miner, attached to Bureau of Mines Rescue Car No. 2, while wearing a half-hour type oxygen breathing apparatus in a gasoline storage tank at Trinidad, Colorado, raised the question as to the possibility of gasoline vapors permeating the rubberized fabric of the breathing bags of such apparatus.It is known that most gases and especially certain organic vapors permeate rubber, by solution or a similar process. The rubber becomes saturated with the gas and if a concentration of gas is maintained on one side of the rubber sheet it slowly gives off gas from the other side. It of course takes some time for the gas to diffuse through the rubber and the length of time before it reaches the other side is proportional to the thickness of the rubber. The amount of gas that passes through per unit of area in unit time increases with the concentration of gas and also varies with the structure and composition of the rubber.It has been suggested that the gasoline vapor could not have penetrated into the interior of an oxygen breathing bag because the pressure is greater on the inside, but this is not true as the process of permeation by solution in the rubber is affected only by the difference in the partial pressures of gasoline vapor on the inside and outside of the bag. The positive oxygen pressure on the inside can only prevent the entrance of gasoline vapor through measurable holes, and has no effect on permeation by diffusion through the rubber."

Dec 1, 1919

By Everett A. Sondreal

Material and energy balances for stockpiled lignite were calculated by computer simulation techniques to determine the occurrence of spontaneous heating. Data on properties of lignite which affect spontaneous heating were required. In some cases, best values from reported data were utilized; in other cases, new data were developed. These include specific studies on the rate and conditions that influence oxidation, heat of oxidation, heat of wetting, specific heat, thermal conductivity, and permeability of stockpiles to air. These data are presented and discussed in detail for possible application to other studies. Results of computer simulations confirm past field experience on the storage of lignite containing as-mined moisture, and predict a greater risk of heat occurrence in stockpiles of dried lignite where experience is lacking. Successful storage was predicted for dried lignite of 20 pct moisture content, if it were cooled after drying and compacted to an interparticle void fraction of 9 pct (bulk density of 67 lb/cu ft) compared to 10 pet void fraction (72 lb/cu ft) for as-mined lignite.

Jan 1, 1974

By S. P. Kinney, A. C. Fieldner, S. H. Katz

"The regrettable death of James S. Cunningham, Foreman Miner, attached to Bureau of Mines Rescue Car No. 2, while wearing a half-hour type oxygen breathing apparatus in a gasoline storage tank at Trinidad, Colorado, raised the question as to the possibility of gasoline vapors permeating the rubberized fabric of the breathing bags of such apparatus.It is known that most gases and especially certain organic vapors permeate rubber, by solution or a similar process. The rubber becomes saturated with the gas and if a concentration of gas is maintained on one side of the rubber sheet it slowly gives off gas from the other side. It of course takes some time for the gas to diffuse through the rubber and the length of time before it reaches the other side is proportional to the thickness of the rubber. The amount of gas that passes through per unit of area in unit time increases with the concentration of gas and also varies with the structure and composition of the rubber.It has been suggested that the gasoline vapor could not have penetrated into the interior of an oxygen breathing bag because the pressure is greater on the inside, but this is not true as the process of permeation by solution in the rub¬ber is affected only by the difference in the partial pressures of gasoline vapor on the inside and outside of the bag. The positive oxygen pressure on the inside can only prevent the entrance of gasoline vapor through measurable holes, and has no effect on permeation by diffusion through the rubber.A sample of gasoline was obtained from the tank in which Cunningham met his death. Examination by Dr. E. W. Dean of the Petroleum Division of the Bureau of Mines gave the following results.This shows the gasoline to be heavy and typical of the gasolines sold throughout Colorado for motor fuel A. Salvus half hour oxygen apparatus was arranged with the breathing bag only in a gas tight box in which the space was kept saturated with the vapor of this gasoline. The main part of the apparatus was outside the box. Oxygen from the apparatus was breathed by a man in the usual manner. Gas samples were taken from the box at intervals to determine the concentration of gasoline vapor, also samples of the oxygen breathed were taken from a side tube in the mouthpiece. The room temperature was 75°F. The concentration of gasoline vapor in the box at the beginning of the test was 4.3%. The man breathing from the apparatus thought he detected gasoline in his oxygen in two minutes after starting the test. Analysis of the inspired oxygen at this time showed 0.03% gasoline vapor. The same man remained on the apparatus for 18 1/2 minutes without suffering any ill effects. His place vas then taken by another man who wore the apparatus until the oxygen was exhausted without noticing more than a trace of gasoline at any time. At the end of the test the inspired oxygen contained 0.07% gasoline vapor. The total time of test was 38 minutes."

Dec 1, 1919

By Raymond M. Kacmar

This report presents the Bureau of Mines research on the hardware reliability prediction for two Bureau monitoring projects. The basic concepts of reliability predictions are introduced along with the reliability models and assumptions used for this particular evaluation. The results of the reliability predictions are for ground-fixed and naval-sheltered environments.

Jan 1, 1986

By Walter T. Ackley

[The geophone has occupied a prominent position as a mine signalling device since its first introduction. The Bureau has carried out tests at different times with a view to improving the early geophones. The following paper describes briefly the adaption of the vacuum-tube audio frequency Amplifier to a new form of geophone. It is not intended to convey the idea that the results described are sufficient to warrant the drawing of definite conclusions as to the practicability of the electrical geophone, but the data and tests liven herein are made public because of their possible use to the industry and as a result of inquiries received as to the feasibility of such adaptions and modifications of the early geophones. Because of the limited time available to the authors, only one geophone with its auxiliary amplifier was constructed. As is well known, two geophones are necessary in order to determine the direction of a sound. Although the principles upon which the electrical geophone operates appear to be fundamentally correct, it is not possible to state whether two such devices 'rill function as efficiently, (as regards determining direction of sound) as the present geophone. In order to operate efficiently as a direction finder, the amplifiers of the electrical geophone must each amplify with exactly the same degree of magnitude. By proper design and adjustment this can probably be accomplished without greatly complicating the design. inasmuch as audio frequency amplification is used, no tuning; is necessary as is the case with tuned radio-frequency circuits. The same filament and plate batteries can be used to operate the amplifiers and by the use of dry cell tubes, requiring shall filament and plate currents, it if believed that a compact, portable and practical instrument can be evolved. Further investigations of the electrical geophone should be conducted to determine the points outlined in this preliminary report.]

Jan 1, 1924

By Lisa Steiner, Robin Burgess-Limerick

Working with or near underground coal mining equipment is hazardous because of the multiple sources of energy and adverse environmental conditions. Of the 4169 injuries reported to Coal Services during the three years to June 2005,447 were associated with continuous miners, 232 with LHD (load-haul- dump) vehicles, 140 with shuttle cars, and 140 with personnel transport - a total of 959, or 23% of all injuries reported during the period. An analysis of the injury narratives accompanying these injury claims highlights a number of opportunities for controlling injury risks. Using the frequency of reported injuries for the prioritisation of risk control strategies has limitations because of the tendency to underestimate the importance of relatively uncommon but potentially high consequence events. Injury reports also underestimate the contribution of risk factors such as whole body vibration, which have a long-term cumulative contribution to an elevated risk of injury. However, taking these limitations into consideration, the results of the injury narrative analysis suggests the following hazards as the highest priority for elimination or control: • handling continuous miner cable • strain while bolting • slipping off continuous miner platform • inadvertent or incorrect operation of bolting controls, and operation of controls while a person is in a position of danger • hitting potholes or other roadway abnormality • collisions while driving underground vehicles