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By S. E. Khalafalla

The ability of potentiometric, gas-sensing electrodes to reliably monitor free gaseous molecules in solution has been recently demonstrated. A gas such as sulfur dioxide from a dilute sample solution diffuses through a hydrophobic, gas-permeable membrane to an internal filling solution. The latter solution contains a sufficiently large excess of sodium bisulfite, the concentration of which can be considered constant regardless of the quantity of sulfur dioxide entering by diffusion. The electrode response is essentially due to the liberated hydrogen ions from the bisulfite-sulfur dioxide equilibrium. This Bureau of Mines report describes a new technique used to detect the formation, and to estimate the stability constant, of gas-molecule and gas-ion complexes in solution, as part of an effort to minimize the undesirable environmental impacts associated with mining and mineral processing. Although the unknown activity coefficients of the neutral and ionic species in the external solution complicate the quantitation of results, methods to circumvent these difficulties are presented. The technique is based on the isometric shift of the Nernst diagram of ion-selective electrodes to higher concentrations relative to the standard aqueous calibration curve. The method is applied to detect and estimate the formation constant of a sulfitocitrate complex, and agrees well with an independently determined stability constant of the disulfitomercu-rate complex.

Jan 1, 1978

1.1 Bituminous-Coal and Lignite Dust. - Carboniferous material having a volatile ratio of 12 percent or more by weight and a fineness such that the material passes through a No. 20 sieve. 1.2 Active Underground Workings. - Underground places in which men are required to be or to pass through in the performance of normal mining operations for the production of coal. 1.3 Working Areas. - Underground areas where bituminous coal and lignite are mined, specifically: (a) Face. - The solid surface of the unbroken portion of the coalbed at the advancing end of the working place. (b) Face Area. - The working area inby the last open crosscut in an entry or a room, including the pillar being extracted or longwall being mined. (c) Room. - A place abutting an entry or airway where coal has been mined and extending from the entry or airway to a face. (d) Crosscut (Breakthrough). - Passageways or openings cut through a pillar to connect adjacent entries or rooms. 1.4 Entry. - Underground haulageways, travelways, and airways, except working areas as defined in section 1.3. (a) Active Entry. - An entry in which coal is being mined from a portion thereof or from connected sections. (b) Parallel Entry. - Usually an intake airway parallel to the haulageway. (c) Back Entry. - Usually a return airway parallel to the haulageway.

Jan 1, 1960

By Charles D. Martens

Raw non fuel minerals produced in the United States during 1981 had an estimated value of $25 billion, about the same as that of 1980. In terms of 1980 dollars. the value of minerals produced during 1981 was $23 billion.2 This chapter includes tables for 1980 that were not available for publication in the 1980 Minerals Yearbook, but does not include the corresponding tables for 1981. The underlying causes of the overall decline in U.S. nonfuel mine production during 1981 were varied, but the common factor was the worldwide recession. In some cases the decline was traced to foreign competition. For example, iron ore production was lower in part because of increased imports of steel products such as coiled steel sheet. Another problem experienced by the domestic mining industry was the continuing difficulty in attracting capital. This was due in part to the attractiveness of investments outside the mining industry, such as short-term, high-interest securities. Another reason was the importation of commodities from countries where overall costs were lower because of such factors as high ore grade, lower taxes, lower wages, government subsidies, and less stringent safety and environmental regulations.

Jan 1, 1982

By Rose L. Ballard

This chapter summarizes data on crude non fuel mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Included also are the tables that show the principal non fuel mineral commodities exported from and imported into the United States and that compare world and U.S. mineral production, The detailed data from which these tables were derived are contained in the individual commodity chapters of Volume I and in the State chapters of Volume II of this edition of the Minerals Yearbook. Although crude mineral production may be measured at any of several stages of extraction and processing the stage of measurement used in this chapter is what is normally termed "mine output." It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the output from auxiliary processing at or near the mines.

Jan 1, 1986

By William J. Campbell

The purpose of this investigation by the Federal Bureau of Mines was to design and construct a fluorescent X-ray spectrograph for dynamic rate studies of selective oxidation in molten metals and to establish basic principles for interpretation of data obtained by this method. An X-ray spectrograph was constructed in which the sample holder is a resistance wound furnace; it was operated up to 800° C. in oxidizing atmospheres. No difficulties were experienced with the cooling or heating systems nor with the protective layer of mica around the X-ray tube window, even though the oxidizing surface of the metal is only 0.5 inch from the X-ray tube window, Means are provided for heating under controlled atmospheres for selected time? temperature cycles.

Jan 1, 1961

By Kihong Park

A hygroscopicity tandem differential mobility analyzer (HTDMA) technique is used to determine size-effect of nanoparticles (NaCl, (NH4)2 SO4, KCl, NH4NO3, MgCl2,CaCl2) on their hygro­scopic properties (deliquescence relative humidity (DRH) and hygroscopic growth factor (GF)). The HTDMA system uses a combination of two nano DMAs and two regular DMAs to measure particle size change in a wide dynamic particle size range. Particles are subsequently analyzed with a transmission electron microscopy to investigate the potential effect of particle structure or morphology on the hygroscopic properties. We found that structural properties of NaCl and (NH4)2SO4 particles also play an important role in determination of the DRH and GF and are more pronounced at smaller diameters. Data show that the DRH of NaCl nanoparticles increased from *75% up to *83% RH at 8 nm and that their GF decreased with decreasing size. The extent to which the GF of NaCl nanoparticles decreased with decreasing size was greater than theoretically predicted with the Kelvin correction. The GF of furnace-generated NaCl nano­particles that have pores and aggregate shape was found to be smaller than that of atomizer-generated particles that are close to perfectly cubic. For the case of atomizer-generated (NH4)2SO4 nanoparticles, we observed no signi?cant size-effect on their DRH, and the measured GF agreed well with predicted values using the Kelvin correction. For furnace-generated (NH4)2SO4 nanoparticles, a gradual growth at moder­ate RH without noticeable deliquescence behavior occurred. Their TEM images showed that contrary to atomizer-generated (NH4)2SO4 nanoparticles the fur­nace-generated (NH4)2SO4 nanoparticles are not perfectly spherical and are often aggregates having pores and holes, which may favor holding residual water even in the dried condition. For atomizer-generated KCl, MgCl2, and CaCl2 nanoparticles, we observed no signi?cant size-effects on their DRH and GF for the mobility size as small as 20 nm.

Jan 1, 2008

By W. J. Fene, H. B. Humphrey, J. J. Forbes

"INTRODUCTION Loss of life from coal-mine explosions in the United States in 1949 was the lowest in any year since before 1870. Although fatality reports from coal nines before 1910 were incomplete,' the explosion fatalities from single disasters or individual States exceeded the 1949 total in each year as far back as 1870, when the records become fragmentary. Since 1890, the only other year in which fewer than 35 were killed was 1946, with a total of 32. Figure 1 shows the total yearly fatalities from explosions in all coal mines and those in anthracite mines alone since 1870. The fatalities in bituminous coal mines were not completely reported before 1910, but enough reports were issued by major coal-producing States to compile reasonably representative figures back to 1885. Any corrections would be additions to these totals.The reason for the moderate total of 46 explosion fatalities in 1948 and the low total of 8 killed in 1949 is thought to be the serious and careful attention devoted to elimination of coal-mine explosion hazards after the disastrous explosions in 1947. The standards now being observed generally with respect to ventilation, rock-dusting, and inspections for gas are better than those found earlier in even the mines having the best reputations for safety. Exceptions are still numerous, but they are fewer, month by month, because of the pressure of Federal and State inspections and a changing conception of the hazards that should not be permitted underground. The prevailing precautions have not eliminated all ignitions of gas or dust, but they have limited propagation to small explosions and have prevented serious loss of life.The number of ignitions (14) reported for the year was less than the average (24) for the 5 years 1944-48 and only half the average for the fiscal years 1929-44. Another favorable factor is that Bureau of Mines representatives were probably in closer contact with both small and large mines in nearly all coal-mining districts. Inspectors now assigned to individual districts are better able to keep informed on the happenings and the progress of safety in their districts. In 1948, one-fourth of the explosions were in mines that employed fewer than 10 men; this condition was duplicated in 1949."

Jul 1, 1950

By A. C. Watts, C. A. Allen

In the No. 3 Sunnyside mine of the Utah Fuel Co. a disastrous fire started on the afternoon of August 17 , 1920 , the effects of which are still present in the mine . On account of the extent of the fire , the expense involved in reopening the mine and the opportunities afforded for determining the effects of depleted air , a description of it is worthy of record . This paper is a summary of a more complete report , prepared by the writers , which will be published by the U. S. Bureau of Mines .

Feb 1, 1922

By Robert A. Bruce

A motion transducer based on coherent mixing of laser light backscattered from rough surfaces is evaluated in terms of sensitivity, bandwidth and range. Tests made with a prototype composed of a 4-mw HeNe laser, a silicon avalanche photodiode, and a 15-cm aperture telescope demonstrate that remote measurements with reasonable bandwidth and accuracy are feasible at distances up to 100 meters.

Jan 1, 1977

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

B 5 Typical Input - Ouput The input data and the printed output for case 8 of the simulations (Section A.4) are shown in the following. The branch, level, node, miner and hoist numbers mentioned in the input and output refer to the corresponding numbers in Figures A-3, A-4 and A -5, The plotted ouput, already shown in Figures A,11 and A-12 is not repeated. The input data shown does not include the following simulation parameters: DTIME = 0, 05 FTIME = 130 JPLT(K) = 1 for K = 1, 2, 3 0 for other K TPLSTR = 0.0 TPLST P = 130

Jan 1, 1976

By Launa G. Mallett, Kathleen M. Kowalski, Michael J. Brnich

The characteristics of leaders under the duress of an emergency are important in the development of emergency planning, training, and in the management of an actual emergency. Knowledge of human behavior is an important component in the formation of emergency strategies. The U.S. Bureau of Mines analyzed the leadership behavior in three underground mine fire escapes. The subjects described their escapes during open-ended interviews. Data were coded according to: (1) evidence of leadership behavior, (2) evidence of lack of leadership behavior, and (3) characteristics of the individual in each group who led the subjects out of the mines. This paper discusses the profile of six individual leadership characteristics which emerged from the data.

By LB. Berger

"INTRODUCTION The use of gasoline engines as the motive power for lift trucks, tractors, and other types of mobile equipment operated in enclosed spaces, such as industrial plants and warehouses, may create a hazard because of the carbon monoxide present in the exhaust gases of the engines; gasoline-powered equipment should not be used in mines or tunnels. Because the equipment is mobile, local ventilation usually is impracticable, and general ventilation of the spaces is nec-essary to dilute and remove the carbon monoxide. To estimate the rate of ventilation required in such situations, information is necessary on the concentration of carbon monoxide in the exhaust gas and the rate at which exhaust gas is produced under given operating conditions. The purpose of this paper is to present data that may be used in making estimates of ventilation requirements.COMPOSITION OF GASOLINE-ENGINE EXHAUST GASThe exhaust gas of a gasoline engine consists mainly of carbon dioxide, carbon monoxide, hydrogen, oxygen, and unburned hydrocarbons (usually reported as methane), together with the nitrogen present as a residue from the air sup-plied for combustion. 3/ The exhaust also contains water vapor resulting from combustion of the hydrogen of the fuel. The water-vapor content is not included in exhaust-gas analyses calculated on a ""dry"" basis and is not involved in the estimation of ventilation requirements."

Jun 1, 1947

By R. L. Grant, R. W. Van Dolah, N. E. Hanna

An experimental investigation was conducted to assay the relation between natural gas concentration and ignitibility of the gallery atmosphere . Both the gas concentration representing maximum ignitibility and the relationship between certain properties of the explosives and their incendivity are discussed . The data show that variation in the natural gas content in the gallery can have a highly significant effect on ignitibility of the gallery atmosphere ; maximum ignitibility of the atmosphere by permissible explosives occurs with approximately 8.1 percent natural gas . The study also shows that incendivity of a permissible explosive cannot be determined only by its detonation velocity , oxygen balance , or ballistic mortar strength . However , for similar type explosives , trends observed indicate that their incendivity increases with detonation velocity or bulk strength . Additionally , for underoxidized explosives studied here , the more negative the oxygen balance the less incendive was the explosive within a class defined by salt content .

Jan 1, 1963

By A. M. Cummings

During August 1943, the Bureau of Mines undertook sampling and measuring of the Kennedy zinc tailing pile near Hazel Green, Lafayette County, south-western Wisconsin, as part of a general investigation of this lead-and zinc-producing area at a time when it was extremely important to increase the production of metals for the Nation's War program. The tailing pile was the residue from old jigging plants that treated ore from the Kennedy mine, one of the oldest and. largest mines in the district. Because retreatment of tailing by modern milling methods was proving economically successful at other sites in the southwestern Wisconsin field, the Bureau?s investigation was designed to assist the potential operators in evaluating the feasibility of a retreatment operation at this site. The study involved measurement of the tailing pile and sampling by means of auger to determine the average metal content within the narrowest possible limits. A total of 46 auger holes ranging in depths up to 40 feet and aggregating 886.5 feet of bore were drilled in the tailing pile, and weighted samples from each hole were analyzed and averaged to determine the zinc and iron content of the tailing.

Jan 1, 1949

By Jami M. Girard

INTRODUCTION Slope stability accidents are one of the leading causes of fatalities at U.S. surface mining operations. The Spokane Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) is currently conducting research to reduce the fatalities associated with slope failures and other unexpected failures of ground. The purpose of this paper is to introduce various warning signs of slope instability so operators are better able to recognize hazards. The most common slope monitoring equipment and practical methods of installation are discussed as well as the limitations of these systems. CONSEQUENCES OF SLOPE FAILURES Unexpected movement of ground causes the potential to endanger lives, demolish equipment, or destroy property. Between 1995 and 2001 (2nd quarter), 34 fatalities were caused by ground instability. This accounts for approximately 15% of all surface mine fatalities (Figure 1). These figures include fatalities classified by the Mine Safety and Health Administration (MSHA) as “fall of face or highwall,” “powered haulage,” “equipment,” and other MSHA accident categories, where the primary cause of the accident was unanticipated movement of the ground. This includes fatalities resulting from bench and highwall failures, rock falls, waste dump and stockpile failures, and the collapse of unknown underground workings. [ ]

By Powell. Alfred R.

"An investigation has been made of the applicability to a variety of coals, other than those from Illinois, of the Powell and Parr method of analysis for the forms of sulphur in coal.A complete study was made of the sulphur in the following coals:- Upper Freeport, Pa.; Pittsburgh seam, Pa.; Pocahontas No. 3, W, Va..; Letcher Co., Ky.; Morgan Co., Tenn.; and Cherokee Co., Kan.The method of analysis gave excellent results when applied to these coals. In the determination of pyrite, the iron-sulphur ratio checked in every case with the theoretical. After the extraction of the pyrite and sulphates, the remaining sulphur was proved to be organic in nature.This work indicated that sulphur exists in coal in three typical forms: - pyrite or marcasite, sulphates, and organic sulphur. A study of the changes which these forms undergo during coking has been made on a variety of coals, and the following five classes of reactions established.First. Complete decomposition of the pyrite and marcasite to ferrous sulphide, pyrrhotite, and hydrogen sulphide. This reaction begins at 300°C., is complete at 600 °C., and generally reaches its maximum between 400 and 500°C."

Mar 1, 1920

By R. Hogg, E. Kaya

"The presence of agglomerated particles in airborne dust in coal mines has been confirmed by SEM examination of static samples collected on substrates. In addition, the effect of agglomerated particles on the performance of cascade impactors and cyclone-type personal samplers has been studied. Simple procedures have been developed for evaluating the extent of agglomeration in air-borne dust by comparing the observed size-selectivity of the sampling devices with that expected under idealized conditions. Applications of these techniques in the laboratory and in underground mines are discussed.INTRODUCTIONAirborne dust is invariably present in mine atmospheres. Particle size is a primary factor in determining the behavior of the dust, its effects on miners' health and the effectiveness of dust control measures. Obviously, agglomeration of the dust particles can have important effects on: ""natural"" dust removal processes such as settling• the use of water sprays etc., for dust control• pulmonary deposition characteristicsIn addition, the presence of agglomerates could influence the effective toxicity of the dust. For example, ultrafine particles are often thought to be relatively unimportant in the development of respiratory ailments because of their low deposition efficiency. However, the latter could be substantially increased if such particles were present in larger agglomerates. It is by no means obvious that there should be significant agglomeration of the airborne dust in a mine atmosphere. In fact, calculations based on the classical coagulation theories indicate that, at the kinds of dust concentrations that exist even in what would be regarded as “very dusty"" atmospheres, the coagulation half-time* .should be of the order of weeks or even months. On this basis, agglomeration would be expected to be essentially negligible. On the other hand, laboratory experiments (Polat et al., 1991) have revealed very extensive agglomeration in the airborne dust released during the crushing of individual coal and mineral particles. It is postulated that such agglomeration occurs immediately at the point of dust generation. In other words, many of the fine fragments produced on fracture are never completely separated from their neighbors."

Mar 1, 1992

By E. C. Lane

The motor gasoline that is being marketed in the United States this winter (1928-29) is slightly more volatile than that gold a year ago. This characteristic is shown by a slight lowering of the distillation temperatures, particularly at the average initial and 20 per cent boiling points. Daring the past mine and a half years the Bureau of Mines has made semi annual surreys of the gasoline marketed in the United States; the Survey just completed is the nineteenth in the series. The 12 cities in which samples have been collected were chosen as representative of the more important marketing territories, as it was obviously impracticable to obtain a sample of every gasoline sold in the entire country.

Jan 1, 1929

By G. W. Jones, R. E. Kennedy

A simple , quick, and relatively accurate device is needed for determining the presence of very small concentrations of organic halide gases in various atmospheres . Such a device would enable safety engineers , health officials , and others to discover quickly the presence of these gases in a suspected atmosphere and thus be able to apply protective measures promptly. This detector should prove useful in detecting leakage of halide gases from refrigerating and air - conditioning systems and in determining the presence of halide solvents in the atmosphere of dry - cleaning and degreasing establishments where organic halide solvents are used . Virtually all poison war gases are halide compounds . Because of the high toxicity of these gases , even in very low concentrations , a detector having the proper sensitivity should be useful in civilian defense for determining when atmospheres are relatively free of poison gases .

Apr 1, 1943

By A. W. Kbair, L. D. Gehl

"INTRODUCTION The rock-bit interaction during the cutting process in underground mines has been a matter of great concern to mining operators, researchers and manufacturers, particularly after the passage of strict environmental laws. Coal cutting bears directly on airborne coal dust generation and rock cutting generates frictional sparks which may cause face ignitions, jeopardizing the productivity, safety and economy of the industry. It is imperative to investigate into the factors which have influence on bit we.ar. Hurt and Evans (1981) concluded that the point attack bits have greater ignition potential than the conventional wedge shaped bits, and also worn bits were more responsible for ignition than the new bits. The results of a study (Khair et al., 1992) suggested that after 7% weight loss, the bit should be replaced. The polycrystalline compact diamond (PDC) tipped bits are reported to be cost effective in a study done by USBM (Twin Cities Research Center), and it was stated that the PDC tipped drill bits had 80 to 100 times longer life than the ordinary tungsten carbide (WC) tipped bits.This paper presents the results of the experiments which were conducted utilizing a coal cutting simulator at the laboratory of the Department of Mining Engineering, West Virginia University, USA. The description of the machine and the experimental set-up have been described elsewhere (Khair et al., 1989; Gehi & Khair, 1994), and therefore, will not be discussed here. The rock types which were used in experimen~ are Tennessee sandstone, Berea sandstone and Indiana limestone. The operating parameters include (1) drum speed, (2) water spray pressure and (3) bit type. Besides studying the wear characteristics influenced by the above mentioned variables, the effect of these parameters on the required cutting force, specific energy consumption, acoustic emissions rate and rise in temperature of the bit were also studied. A preliminary study was also done to compare we.ar characteristics of the WC bits with those of the poly-crystalline compact diamond tipped bits."

Dec 1, 1995