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By Seth C. Schaefer

The Federal Bureau of Mines studied the Gibbs free energies of formation of chromous fluoride (CrF2), chromic fluoride (CrF3), and chromium (II,III) fluorides (CrF2.40 and CrF2.45) with high-temperature galvanic cells employing calcium fluoride doped with 1 mole-pct yttrium fluoride as the electrolyte. Free-energy changes were obtained from open-circuit potential measurements for the following cells: Cr, CrF2 // CaF2 // NiF2, Ni (a) NiO, NiF2 // CaF2 // CrF3 , Cr203 (b) CrF2 , CrF2.40 // CaF2 // NiF2, Ni (c) and CrF2 ?45 , CrF3 // CaF2 // NiF2, Ni (d) with the following overall reactions Cr(s) + NiF2 (s) = Ni(s) + CrF2 (s) (1) 3NiO(s) + 2CrF3 (s) = 3NiF2 (s) + Cr203 (s) (2) 5CrF2 (s) + NiF2 (s) = 5CrF2.4O (s) + Ni(s) (3) and 3.64CrF2.45 + NiF2 (s) = 3.64CrF3 (s) + Ni (s) . (4) These results were combined with the best available literature values of ?Gf° of NiF2, NiO, and Cr203 to deduce Gibbs free energies of formation for the chromium fluorides expressed as follows: ?Gf°(CrF2) = -179.31 + 24.33 X 10-3T ± 0.43 kcal-mole. (5) (858.1 - 964.9 K) ?Gf° (CrF3) _ -226.16 + 1.82 X 10-3T ± 0.79 kcal/mole (6) (880.8 - 957.8 K) ?Gf°(CrF2.40) _ -213.65 + 32.14 X 10-3T ± 0.44 kcal/mole (7) (0053.9 - 936.8 K) and ?Gf°(CrF2.45) _ -176.17 - 12.67 X 10-3T ± 0.80 kcal/mole (8) (875.1 - 937.6 K). Free energies and equilibrium fluorine pressures for three univariant and one bivariant equilibria are illustrated.

Jan 1, 1976

By M Boyd

The University of Wollongong was named University of the Year 2000, for its work in preparing students for the e-world. Computer facilitated learning is being introduced into subjects throughout the engineering course. First year mining engineering students are introduced to computers, e-communication, using the UniversityÆs web based information system, and web based subject delivery. Mining engineering students in the mid-years of the course use programming languages and numerical computation software such as MATLAB, while students in the final years use a range of commercially available professional engineering software such as TALPAC. Most of these subjects are offered as part of the UniversityÆs Learning Online program, co-ordinated by its Centre for Educational Development and Interactive Resources (CEDIR). Learning Online subjects are delivered using the Web Course Tools (WebCT) environment. WebCT allows all resources to be accessed through the web, allows email communication between lecturer and student, and allows discussion groups for the exchange of ideas. Students can submit their assignments through WebCT and receive immediate feedback. This paper describes how WebCT has been used to deliver a first year engineering computing subject, mid-year numerical computation subjects, a mining economics subject and mine planning subjects.

Jan 1, 2002

A maximum acceptable level of 2 mg/m3 of respirable coal mine dust in active mine workings was established, effective January 1, 1973, under the Federal Coal Mine Health and Safety Act of 1969. It is generally agreed that, as a result, coal mines in the United States are significantly less dusty than they were a decade ago. For example, operators of underground mining machines were exposed to between 3.9 and 6.5 mg/m3 of respirable coal mine dust during 1968-69; now they are exposed to between 1.3 and 1.8 mg/m3. Also, the incidence of underground sections cited for exceeding acceptable levels of respirable coal mine dust decreased during 1976-78, and the vast majority of all working sections are now in compliance. This improvement is very substantial by world standards. It must be regarded as a creditable accomplishment by the coal mine operators, federal agencies, and mine workers involved. Most of the improvement has been brought about by the use of existing technology to control, suppress, and collect respirable coal mine dust. Research and development by the Bureau of Mines has contributed significantly to the accomplishment by improving the methods for sampling, control, suppression, and collection.

Jan 1, 1980

By M Thierry Bernart

The software QUALITIR is a software developed by CNSIDCI, framework on five research and experimentation years. This conceived tool by specialists for professionals is a decision aided design tool concerning mining. It makes party the rare software regrouping the different themes approached by the profession namely, the general idea of blast design, blasting sequences, the fragmentation as well as the study of vibrations. Henceforth it is by the intermediary of such tools that performances in term of profitability, security or impact on the environment will be able to be realized.

Jan 1, 1997

By G. H. Lind

Research into the safe and economic extraction of underground coal pillars in the Witbank and Highveld coalfields of South Africa highlighted that future practices will have to consider pertinent risks associated with this least safe of all underground coal mining methods conducted in South Africa. To this end, a computer-based program called A-PEP (Analysis for Pillar Extraction Potential) was developed to assess three aspects of this mining practice, viz. risks associated with the physical attributes, operational risk attributes and economic attributes. This intelligent tool can thus be used when planning to conduct underground pillar extraction to ensure that all pertinent risk elements and legislative requirements are considered to conduct this mining method safely before a submission is made to the Department of Minerals and Energy. Keywords: operational risk management, mine planning, underground coal mining, pillar extraction.

Jan 1, 2003

By D. J. Bauer

Oxidation of mixed lanthanide solutions with ozone at pH 4.5 and at ambient temperature resulted in precipitation of 98 percent of the original cerium present. Corresponding cerium purity was increased from 50 to 98 percent. A second ozone oxidation-precipitation step produced cerium of 99.9 percent purity in high yield from the 98-percent-pure material. Alternately, ozonation at pH 6.5 and 85° C differentially precipitated cerium and rare-earth elements heavier than cerium and left 89 percent of the original lanthanum in solution at a purity of 95 percent. Subsequent recovery of cerium from the heavier rare-earth elements in the precipitate was accomplished by dissolving the precipitate in dilute mineral acid and reoxidizing the cerium with ozone at pH 4.5 and at ambient temperature. The filtrate contained an enriched praseodymium-neodymium-samarium-europium mixture that is amenable to separation by ion exchange or solvent extraction.

Jan 1, 1968

By Rozbeh Moghaddam, William D. Lawson, Priyantha W. Jayawickrama, Hoyoung Seo, James G. Surles

"This study provides calibration of resistance factors (?) for design of driven piles to implement Load and Resistance Factor Design (LRFD) for bridge foundations using Texas Cone Penetration (TCP) Test data. The basic research approach was to compile a database of published full-scale load tests including projects from the Texas Department of Transportation’s (TxDOT) historical archive and projects from neighboring state DOTs. Load test results from neighboring states were leveraged by performing new geotechnical borings with TCP tests at the project sites. The final dataset consisted of 30 load tests performed on precast square concrete piles, with pile widths ranging from 356 to 508 mm and penetration depths ranging from 5.2 to 25.5 m, driven in soils. Ultimate capacities for each load test were interpreted based on Davisson, 5%, and 10% settlement criteria. These measured ultimate capacities were compared against predicted capacities estimated from TCP blow count values (NTCP) and design charts following the procedures outlined in TxDOT’s Geotechnical Manual. From the comparisons, statistical parameters of the biases (??= measured capacity/predicted capacity) such as mean and coefficient of variation were obtained. Resistance factors (?) for LRFD were then determined using Monte-Carlo simulations for each ultimate capacity criteria with the target reliability indices of 2.33 and 3.00.INTRODUCTIONThe Texas Department of Transportation (TxDOT) has used the Texas Cone Penetration (TCP) test since its development in the 1940s. The TCP test is an in-situ penetration test to characterize the materials encountered during geotechnical exploration. Texas currently maintains over 53,000 bridges in the National Bridge Inventory (FHWA 2016), and most of these bridges plus other transportation infrastructure in Texas are supported by foundations designed using the TCP test and its associated foundation design method. The Oklahoma DOT adopted the TCP test and foundation design approach in the 1970s, so the foundations for most of the 23,000 bridges in Oklahoma’s inventory were also designed using the TCP method. With this significant body of experience, the TCP method has been viewed as a straightforward, relatively easy-touse foundation design method that consistently yields safe, serviceable, economical, and maintainable foundations. TxDOT’s deep foundation design method is documented in the TxDOT Geotechnical Manual (TxDOT 2012) and currently employs the allowable stress design (ASD) approach. However, the Federal Highway Administration (FHWA) has mandated that the states begin to implement the LRFD method in place of the older ASD approach (Densmore 2000). This paper presents resistance factors at ultimate limit state (ULS) for design of driven piles using the TCP test, resulting from efforts to be in compliance with the FHWA policy."

Jan 1, 2017

By Dave Minney

The South African mines health and safety regulations require that mine management establish a quality management system for rock support material. Quality control of resin capsules used as a support medium in South Africa is specified under SA National Standards No 1534. Experience has shown that this specification, while addressing the chemical and physical aspects of the products, but does not address the required performance criteria. In order to address this shortcoming, the industry has put a lot of emphasis on short encapsulation pull tests, performed insitu, in the underground workings of the mine. This is also fraught with many shortcomings, particularly as regards site availability, cost and repeatability of results. To try and address these issues, the Department of Mechanical and Aeronautical Engineering at Pretoria University were approached to develop equipment and machinery that could produce reliable, repeatable results in a laboratory environment which reasonably simulates installation practice underground. The test method is based on the ASTM F432-95 Strength Index test, but modified to use push test rather than pull tests. The paper describes development of the test method and the preliminary results and findings of the work.

Jan 1, 2007

By Andre Zingano

The objective of this paper is to compare the behaviors of different types of roof bolts: (1) One-Step Bolt (OSB), (2) Fully grouted Bolt (RB), (3) Combination Bolt (CB), and (4) Torque tension Bolt (TB). Two dimensional numerical models were built for both bolted and unbolted roofs. The geological sequence and rock properties used in the numerical models represent the typical roof condition for Pittsburgh coal seam. Using the unbolted roof as a base case, a comparison is conducted by monitoring the roof vertical displacement at the center of the entry and at the bolt positions, the axial force in the roof bolts, and stress distribution in the bolted area. The grout/rock interface is assumed to be perfect. The estimated roof displacements showed that the differences among the four types of roof bolts are small. The major differences are in the shear stress at the grout/rock contact and in the shear stress along the immediate roof bedding interface as well as in the bolt axial stress. There is less axial stress for the OSB compared to RB and CB as the diameter of the OSB is much bigger and the contact area between grout and rock is twice as large as for RB and CB. The higher strength of the OSB contributes to keep the bedding planes in the roof closed.

Jan 1, 2007

By K. S. Gritton

The Bureau of Mines investigated the feasibility of numerlcally modeling the sorption of cobalt, a vulnerable strategic and critical metal, from spent copper leach solutions in a multiple-compartment ion-exchange (MCIX) column. Equilibrium resin loadings, cobalt-sorption kinetics, and resin-fluidization characteristics were determined in simple laboratory tests, and a numerical model was developed to predict cobalt extraction and the MCIX-column resin inventory based upon the test results. The model was implemented on a microcomputer to approximate the solution to the set of differential equations that govern model performance. Results compared very well with data from 12 pilot-scale MCIX-column experiments. The average difference between predicted and actual cobalt extractions was 3.2 pct; the maximum difference was 9.3 pet. The actual and predicted resin inventories differed by an average of 5.8 pet, and the maximum difference was 12.0 pct.

Jan 1, 1987

Although cyclones have been around in their current form since the early-1890s, there have been some exciting new developments, which have extended their efficiency/operation. These developments have taken place with both dense medium and classification cyclones. The more noteworthy developments are:Inlet designInlet design is the determining factor in classification cyclone capacity and efficiency. The recently developed ribbon inlet with patented pressure bulge has not only resulted in unbelievable increases in capacity, but also in efficiency. Sharpness of separation corresponding to an alpha value of greater than four has been achieved! Secondary offtakeOne of the factors leading to reduced cyclone efficiency is the presence of coarse particles in the cyclone overflow. The secondary offtake has been developed specifically to scavenge these particles from the cyclone overflow with great success. Water injectorThe other major factor resulting in reduced cyclone efficiency is the presence of misplaced fine particles in the cyclone underflow. The water injector, which has been around for many years in various forms, can reduce this short circuit fraction by up to 50 per cent. 3-in-1 cycloneThe 3-in-1 cyclone combines the inlet design, secondary off take and water injector into a single unit resulting in the most efficient classification cyclone available in the market. The RejectorTMIron ore has a high yield to underflow and traditional dense medium cyclones have always been spigot constrained. The Rejector TM is an exciting new development whereby the spigot capacity has been increased substantially. The application of the Rejector TM will result in fewer/smaller cyclones being required for a given duty resulting in efficiency gains and reductions in both operating and maintenance costs.

Jan 1, 2002

The common theme of these four objectives is declaration. Declaration tells the compiler that an entity exists and also provides the name and nature of the entity. Since everything you create has to be declared, you must know how to declare correctly and be able to make appropriate use of all the declaration tools available to you. This objective recognizes the importance of declaration by requiring you to know everything about Java declarations Write code that declares, constructs, and initializes arrays of any base type using any of the permitted forms both for declaration and for initialization. This objective addresses your understanding of all aspects of arrays. Arrays are the simplest possible data collection and are supported by all modern programming languages. However, Java?s arrays are different from those in other languages, especially C and C++, because they are actually exotic objects. This objective recognizes the importance of being able to make use of all the functionality of arrays. You will be expected to know how to declare, construct, and initialize arrays.

May 1, 2011

By S. Gorzalczynski

The recent trend in underground mine developments is “bigger is better.” This is most certainly evident in the mine shaft and conveyances that operate within its compartments. Today, there are several new installations requiring mine cages that can transport up to 170 passengers. The technology in mine hoisting is advancing to address a combination of higher capacity requirements, deeper hoisting depths and faster winding rates, however, some areas of the hoist plant have not changed in the past 50 years. The most notable of these areas is the shaft compartment guide string and the conveyance mounted safety arrest mechanism. The technology in use today for the protection of passengers in a shaft conveyance from a hoist rope severance incident remains conceptually unchanged from Elisha Otis’ design of 1850. The actual retardation components, the safety dogs, have taken on several forms since Elisha’s invention with the last major design change occurring in the late 1940s. The arrest of a free falling shaft conveyance requires that the shaft guides withstand the energy imparted on them by the safety dogs. There are some very real limitations presented by the use of wood for this application. The new hoisting era will most certainly continue to demand larger capacity equipment, but also an increased awareness toward safety

Jan 1, 2002

By H. Saridikmen, C. S. Kucukkaragoz

In the present study, the measurement of sulphur distribution ratios between the slag and metal phases encountered in the ferromanganese smelting has been carried out at 0.83 atm of partial pressure of CO at 1773 K by using classical gas-slag-metal equilibrium quenching technique as a function of composition. The distribution results were employed in calculating the sulphide capacities of SiO2-Al2O3-CaO-MgO-MnO slags in equilibrium with the Mn-Fe-Si-Csatd.-S metal phase. It is shown that the sulphur transfer from metal to slag phase increases with increasing the basicity of the slag. As expected, the sulphur distribution ratio decreases by increasing the silica content of the slag system. The effect of metal composition on the sulphide capacities of the slag as well as on the sulphur distribution ratios between the slag and metal phases have been discussed. Emprical relationships were developed to express the sulphur distribution ratios and sulphide capacities of the above slag system.

Jan 1, 2007

By Patrick J. Hannigan, Geir Veslegard, Frank Rausche, Rozbeh B. Moghaddam

A common type of deep foundation used in Norway to support bridge structures is the drilled pipe piles (piles) filled with concrete reinforcement after installation. The standard installation practice is the use of down-hole hammers. Complex geology and difficult subsoil conditions in Norway causes a high variability of soil and rock layers which in turn make for differences between actual subsurface conditions and those expected from geotechnical exploratory borings. This situation is strongly noted when the foundations are not fully socketed, and the rock layer is sloped. In this particular case, special testing procedures are required to assess the drilled pile base material and evaluate the rock-socket to ensure full contact between the foundation base and the rock surface. The local standard practice to verify the latter condition, consists of coring and visually evaluating the material recovered at the bottom of the drilled pile. This paper presents a case where the coring and visual inspection were not possible and alternatively the geological material encountered at the base of the deep foundations was evaluated using force-displacement measurements. Two 1016-mm (40in) diameter open-end drilled piles identified as P02-04 and P02-05 were tested and evaluated using in-situ force-displacement data prior to filling the piles with concrete. Test results showed an average displacement of 7mm (0.28in) corresponding to 35MPa (5.1ksi) stress level for P02-04, and 7.2mm (0.28in) corresponding to a stress level of 38MPa (5.5ksi). Based on testing results, both drilled piles were within the established material assessment criterion presented by the local authorities. INTRODUCTION This paper presents a case study in Norway where the material encountered at the base of an open- end drilled pipe pile (pile) was evaluated using force-displacement data. In the deep foundation industry in Norway, it is a common practice to install piles to support transportation structures. Once the piles reach the embedment elevation, and the pile base is assessed, these are filled with concrete. In projects where sloping rock is the supporting layer, and all nominal loads are supported by the pile base resistance, assessing the material encountered at the pile base to ensure full contact with the rock becomes critical. The local practice to make this assessment consists of the use of weighted tape, coring, or inspection cameras. However, similar to any other testing and evaluation methods, these come with their own limitations. The variability associated with the use of the weighted tape, accessibility for the coring equipment to complete a coring process, or the conditions at the foundation base such as murky water or thick drilling fluids could significantly impact the photo or video quality taken at the pile base. In such conditions, it is important to consider alternate testing methods to evaluate the material at the foundation base.

Jan 1, 2018

By José L. M. Clemente, John R. Davie

"Abstract An extensive pre-production static and dynamic pile load testing program was conducted for a coal-fired power plant. The static load testing program included axial compression, uplift (tension), and lateral load tests. Three types of piles were tested: Monotube, closed-end pipe, and step-tapered. The load tests were used to (a) determine pile driveability characteristics for each pile, (b) verify pile load response behavior, and (c) provide data to support the selection of a cost-effective piled-foundation system for the plant. A recent publication (Clemente and Lewis, 2013) describes the compression load testing program, the interpretation of instrumentation measurement results, and pile selection criteria. This manuscript describes site subsurface and groundwater conditions and installation of probe piles for testing, focuses on the uplift and lateral load testing program, and provides a comparative interpretation of the load test results.INTRODUCTIONThe pre-production probe pile load testing program described here was conducted for a 202-megawatt, coal-fired power and steam generating (cogeneration) facility. A schematic layout of the main plant (power block area) is shown in Figure 1, which also includes the locations of clusters of preproduction probe piles and boreholes drilled near these clusters.The load testing program included 24 pre-production probe piles driven throughout the power block area. The probe piles were driven at locations T-1 through T-8, shown in Figure 1. Three types of piles were driven at each location: Monotube pile; closed end, straight shaft pipe pile; and step-tapered pile. At each location, the three piles were driven in a row with the pipe pile at the center, and the center-tocenter spacing between piles was equal to about 1.5 m (> 3.5 pile diameters for the largest pile). No pile cap was used to connect the three piles, and the three piles driven at locations T-1 through T-8 will be referred to as pile clusters. A complete suite of static load testing (compression, tension, and lateral) was performed on each individual pile at Cluster T-2 and on the step-tapered piles only at Cluster T-8, shown in Figure 1.Clemente and Lewis (2013) provide details of the compression load testing program, the interpretation of instrumentation measurement results, and pile selection criteria. This manuscript focuses on the uplift (tension) and lateral load testing program. A brief summary of the site geology and existing subsurface and groundwater conditions in the vicinity of the test pile clusters is presented, with emphasis on T-2 and T-8. Probe pile driving results at T-2 and T-8 are also presented. Descriptions of the static uplift and lateral load test program at T-2 and T-8 are given along with a comparative evaluation of the load test results."

Jan 1, 2014

By Gang Chen

This paper explores the possibility of using short-term time-dependent plate loading tests to estimate the elastic and viscoelastic parameters of the weak floor strata typically associated with coal seams in Illinois. Plate loading tests with incremental loads, similar to incremental creep experiments, were conducted until the floor failure occurred. For each increment, the load was held constant for a period ranging from 1-4 hours until a constant deformation rate was achieved. The deformation-time data were analyzed for viscoelastic parameters of weak floor strata assuming its behavior to be adequately represented by the standard Burgers model. The analysis required development of mathematical equations for the time-dependent deformation of the standard Burgers material under a three- dimensional state of stress. Time-dependent pillar settlement data at one mine were also analyzed for elastic and viscoelastic parameters of the weak floor strata using the developed equations. These parameters were compared with similar parameters estimated from plate loading tests.

Jan 1, 1990

By P. Bermingham

A new approach to load testing of high capacity piles is presented. The method is mobile, inexpensive, repeatable and non-destructive allowing for multiple pile testing at a single site. A reaction mass is placed over a pressure chamber situated atop the pile to be tested. The test method is significant in that it can produce linearly increasing forces of high magnitude (over 5.0 MN) with durations of up to 80 milliseconds. This represents pulse durations an order of magnitude longer than achieved using a drop hammer. The accelerations the pile undergoes are less than one g, (conventional dynamic methods = 50 to 100 g). These effects combine to produce pile behaviour no longer dominated by the action of stress wave, instead the pile is under high levels of stress through its length during the force input. This is representative of the situation when static loads are applied, thus the method may be considered quasi-static. Further advances introduced with this method are that pile deflection and transmitted force are measured directly by means of a laser beam and load cell. This allows accurate correlation of event load displacement histories without the error associated with zero shift (acceleration integration) or non-homogeneous materials (strain measurement). The load displacement histories emulate those obtained for static load testing.

Jan 1, 1989

By Sidney Speil

In the study of clays and related minerals, the analytical techniques commonly employed in mineral analysis are not always applicable. The X-ray examination of a clay sample usually will show the major constituents, but often minor· clay impurities will not be detected because of line broadening and the similarity of the main lines of clay· mineral diffraction patterns, The petrographic analysis of clay minerals with clay particles as small as a few microns is usually difficult. With still smaller particles, a gross effect often is noted in which a mixture of several constituents gives the appearance of a single constituent with the mean optical-characteristics of the mixture. 3/ The electron microscope has recently been used to study clay particle shapes of various aluminosilicates. 4/ However, this method has not yet been sufficiently explored. The Chemical method in which a mineralogical analysis is calculated from the oxide chemical analysis has been discussed by Wilson 5/ and others, and many of the shortcomings have been pointed out. It should also be recognized that the variable alkali and alkaline earth content of bentonites makes it inaccurate to assign these basic elements arbitrarily to feldspar or mica in any clay that contains appreciable bentonite.

Jul 1, 1944

By Michael Stuart Parsons

The haulage cycle is the sequence which a haulage vehicle must first arrive at the loading area, then turn around and reverse into position. Once it is loaded, the vehicle leaves and travels to the unloading area, where again it must turn around and back up to unload. The cycle is repeated over and over again. The Vector Neutral truck is a rubbertired, self-propelled hauling vehicle designed such that it eliminates the requirement to turn around and back-up to either load or unload. Vector Neutral Truck Cycle: 1.) Travel from the load station to the dump station. 2.) Stop and dump load. 3.) Travel from the dump station to the load station. 4.) Stop and load. The Advantage is in the Difference: 1.) Shorter distance traveled. 2.) Fewer brake and steering actuations. 3.) Easier to automate. 4.) Easier to adapt for remote control operation.

May 1, 2003