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By Quinlan M. J, Ratcliffe J. S

Chemical kinetics is a dependent process which usually correlates the rate at which a reaction proceeds with the mechanism descriptive of the manner by which reactive particles interact. Given the latter, the object gen- erally is to find the reaction rate dependency in terms of an intensive property of the system - number of reactive particles present, and of the energetics of the system - usually temperature. Chemical kinetics depend on a dem- onstration that reaction considerations alone control the phenomenological process under study. For these rea- sons, chemical kinetics are usually involved in homogeneous gaseous systems. Even in liquid homogeneous sys- tems earliness or lateness of reactant mixing rather than chemical kinetics may be controlling. Considerations of transport phenomena are involved in heterogeneous systems and often control the observable rate:an additional problem in such systems is to apportion the rate due to mass transfer - usually a linear process - and that due to reaction which may be linear or non-linear. Experimentally, conditions are often chosen so that only one consideration controls but this becomes more difficult where solid phases are involved. Kinetic modelling involves considerations of chemical kinetics, transport phenomena, and factors attributable to the physical environment in which the process takes place. The latter two considerations may be quite different as between experiment and plant. The kinetic model may be a mathematical representation of a conceptual mech- anistic model of the reaction. Alternatively, it may be an empirical relationship resulting from, for example, some curve fitting procedure applied to experimental data. The latter approach may be necessary where the system is particularly complicated.

Jan 1, 1975

By Gooday PE, Brech GE

Ore reserve categories used by Pancontinental Mining fall into one of three fundamental groupings: Geological In Situ Reserves Mining Reserves Production Estimates The first of these describes the total reserve within stated parameters without implication as to its mineability. The second is that part of the Geological In Situ Reserve which is considered mineable under a specific mining plan. The third is the Mining Reserve adjusted with appropriate dilution and recovery factors and thus represents the best estimate of the tonnage and grade of production. This practical three category system mirrors the standard steps traditionally taken in ore reserve estimation and readily conveys the basis of the estimates. An important, but secondary classification can be added to qualify the level of confidence in these estimates using the terms: Proved (or Measured) Probable (or Indicated) Possible (or Inferred) These terms can be applied to any of the fundamental groupings, but it is generally implicit that the level of detail required to produce meaningful Mining Reserves or Production Estimates would require the basic Geological Reserve to be at a Proved or at least Probable level of confidence. The application of these classification systems by Pancontinental is illustrated by reference to the Paddington Gold Project. The methods of calculation are described including the use of geostatistics. Reconciliations of actual production with predictions from reserves are carried out monthly and annually. To date there has been an excellent correlation with Production Estimates, based on both manual and geostatistical calculations.

Jan 1, 1987

The paper, one of two papers on the Queensland Railways Brunswick Street tunnels presented at the VIII Australian Tunnelling conference, describes documentation, tendering and construction aspects.Tender documents were written to reduce the risk taken by the contractor. Details of tenders received are analysed and the changing industrial situation at that time described.Construction aspects covered include mobilisation, major equipment, tunnelling equipment and manning. Program and progress are reported including industrial relations and advance rates for Mitsui-Miike S-200 and S-65 roadheaders. Cycle times and performance in terms of cutting rate and pick wear are provided for the roadheaders.

Jan 1, 1993

Carbonate-hosted massive sulfide ores of the American cordillera compose a distinctive genetic class. Discordant fea-tures of occurrence together with measured high-temperatures of formation indicate their essential epigenetic character and close spatial association with centers of thermal activity during evolution of the cordillera. Their metallogenic character is complex from region to region: Cu-Zn-Pb-Ag, Pb-Zn-Ag, and Cu-Zn-Ag-Au represent extremes of composition and each may be identified with specific terranes of occurrence, notwithstand-ing an inferred common process of formation. Beyond the presence of a thermal center, other controls that may be identi-fied include apparent but obscure properties of primary perme-ability or chemistry of hosting strata, and secondary controls are imposed by stratigraphic differences in which permeability is strongly contrasted. Structures that act as channelways may be identified in some instances. Notwithstanding their intrinsic value, search for these ores is difficult and requires the solution of complex geochemical and three-dimensional geometric problems.

Jan 1, 1990

During late 1953 and early 1954, tests were carried out in Sydney metropolitan brickpits in order to determine if some improvement might not be effected in the personal shock, fly rock and possible ground displacement accompanying daily blasting occurrences in the numerous quarrying activities of the metropolitan area. As a result of this preliminary work (Reid, 1954), the Department of Mines decided to further investigate the problem with a view to placing this type of blasting on a sound economical and safe basis for both operator and nearby residents alike. To assist in the work, a Cambridge Universal vibrograph was acquired.Human safety was the first consideration followed by property damage to homes and factories in the extractive areas. Although most of the actual field work has been confined to the Sydney metropolitan area and in particular to the large clay-shale quarries, many cities and country towns have blasting problems associated with the extractive industries, engineering projects both above and below ground level, and in building excavations to which the results may apply.The following figures illustrate how much activity of this type is located around cities and towns:Sydney Metropolitan Area:

Jan 1, 1958

By Fiedler VA, Threadingham GM, Leckenby DF, Clarkson CJ

The Utah Development Company Research and Development Laboratory has embarked upon a programme of optimisation of the company's coal preparation plants. This goal is being accomplished in a three-fold manner - use of pilot plant equipment for optimisation and modelling of the various unit operations, evaluation or development of on-stream ash analysis for process control, and evaluation or development of alternative processes. In each of these areas, digital data acquisition- and at a later stage, process control feedback, is being extensively utilised, based largely upon the use of the HP85 and HP9915 desktop computers. A variety of input/output configurations such as HPIB, BCD, GPIO are used, and at times supplemented by microprocessors such as the Intel 80/05 to assist in data transfer. This paper will discuss a number of specific projects, especially in relation to the manner in which the variables are monitored, and the data later retrieved and analysed.

Jan 1, 1983

Investigation of standard tests used to establish the decrepitation rating of Western Australian iron ore showed scatter in results which could be reduced by textural type sampling. Testing of individual textural types resulted in separation.of a range of decrepitation behaviour patterns. No unique correlation was established between water content in goethite, or between any single mechanism and breakage in shock heating. The latter depends rather on several mechan- isms whose operation is controlled by the texture of the ore. Texture studies were used successfully to predict decrepitation behaviour which could be related to orebody structure for mine planning, and blending for sales or processing requirements.

Jan 1, 1973

By Bogie I, White P. J

Active geothermal systems occur widely in Sumatra and in the Taupo Volcanic Zone (TVZ) of New Zealand. There are also many occurrences of epithermal gold mineralisation in Sumatra, some of which are economic. Minor sub-economic occurrences of gold have been reported in the TVZ but none have yet been mined. There are both similarities and differences in the nature of the active geothermal systems and mineral deposits in Sumatra and New Zealand, which can be systematically related to the tectonic setting. The thicker crust and consequent predominance of silicic volcanism in New Zealand leads to hydrothermal. systems which are little eroded and with limited lateral outflows. The systems in Sumatra are of mixed character, with some of the characteristics of those in andesitic island arcs such as Java or the Philippines, eg a higher proportion of systems with identifiable acid magmatic volatiles, a greater potential for deep erosion and lateral outflows than in New Zealand; but modified by the more oblique component of subduction and thickened crust so that some are localised in volcano-tectonic depressions and consequently have high piezometric levels of primary hydrothermal fluid. The unusual occurrence of calcic zeolites in veins associated with gold mineralisation in Sumatra is thought to be indicative of "satellite" boiling zones along de-gassed hydrothermal outflows.

Jan 1, 1995

By Yagi Y

The double track railway tunnel, called the Second Shirasaka Tunnel is being constructed under the supervision of Japanese PTational Rail- ways (JNR) in the tertiary soft rock strata in order to speed up the railway transportation. This tunnel (L=1765m), located in a central part of Japan, is excavated by the machine (roadheader), while the adjoining First Shirasaka Tunnel (L=1296m), completed five years ago, was driven by the blasting, and NATM is adopted in both tunnels. The geological features in this region are Neogene Tertiary of Miocene sediments consisted of mudstone, the sandy mudstone and the alter- ation of these rocks, having a squeezing be- haviour. And the geological structure is as complicated as some anticline and syncline structures, large or small scale exist, and as a lot of faults are found. The machine excavation manner using road- header is adopted in this tunnel to minimize the effect of excavation because there is a possibility of the occurrence of landslide due to the tunnel excavation, and also because local inhabitants reside on the ground surface.

Jan 1, 1987

Types of structure found in 'Jest Australian beach sands are described. Their recognition by geostatistical methods follows nth a discussion of the effectiveness of sampling patterns. Examples of structures are given, and an account of their effect on valuation procedures.

Jan 1, 1977

With the progress of modern mining engineering, one of the features of which is the mining from greater depths and the hoisting of greatly increased loads, it becomes a matter of increasing importance that the engineer should be able to determinewith some degree of precision the character of the strains on the hauling rope. But a wire rope is a complex structure; it is made up of spirally-twisted strands, which in turn are composed of spirally-twisted wires, and it is not particularly easy to say exactly what happens when this "doubly-twisted structure is wound round a drum or over a pulley.. The difficulty has been generally evaded in ordinary practice by the simple device of adopting a large factor of safety for the rope-usually from 8 to 10-a factor which experience has shown is sufficiently large to cover the bending strains set "up when the rope is passed over pulleys of the sizes commonly considered appropriate.When, however, we add the stress due to the bending of the rope to the stress produced by" the direct pull, we find that the actual factor of safety is usually more nearly 4 than 10, and frequently the bending stresses in the rope are so large compared with the simple tensile stresses that their neglect may easily lead to disastrous results when dealing with problems a little out of the common run. Common Empirical Rules.-It is always "recognized that the bending of a wire rope round too small a pulley is likely to do the rope serious injury, but as it is desirable in ordinary winding operations to reduce the inertia of the moving parts to a minimum...

Jan 1, 1907

The coal basins that formed near the margin of Permian Australia were comparable in size with the Appalachian coalfields and with the European fields between Wales and Poland. They formed on the foreland side of a growing orogen in a system of linked transform basins formed by transtension on strike-slip faults. They were terminated and compressed when the Gympie volcanic arc was accreted to the orogen. Another huge system of Permian coal basins extending far inland from the Permian coast was also terminated when the Gympie Terrane was Accreted.

Jan 1, 1987

By Mortimer RR

The Weipa bauxite mining operation on the west coast of Cape York currently mines lb million tonnes of crude ore per year from the Andoom and Weipa mines. Andoom ore is trucked up to 4 km to a rail load station and hauled 20 km by train to the Beneficiation Plant. Weipa ore is trucked up to 7 km to the Beneficiation Plant. Increasing haul lengths and production requirements have led to a progression of larger two axle rear dump trucks and currently he intrcducticn of 145-tonne, three axle L t Dm dump trucks. bith the introduction of the Andoom a operation in 1972, the decision was made to use a railway system to haul crude ore from Andoom to Weipa. This system has proved to be successful from both an economical and operational view point. Due to the successful combination of a truck and rail haulage operation in Andoom, future :evelopment of orebodies requiring increased haul distances and increased production tonnages will probably result in extension r>f the railway system to compliment the trucking operation from the mine face.

Jan 1, 1978

The phosphatic overburden of Christmas Island is a lateritic soil and consists dominantly of crandallite and millisite. These minerals are polymorphs of general formula, (Na,K)x Ca2-x (Al, Fe)6 (PO4)4 (OH)10-x (2+x) H2O. Iron occurs only in millisite. Both minerals exhibit similar thermal transformations, dehydroxylating near 600¦C and recrystallizing above 800¦C. Dehydroxylation results in crystal structure collapse but retention of crystal morphology. Ggethite, boehmite and apatite are minor constituents of some-of the phosphatic Soils.

Jan 1, 1971

By D Obeng, D Alexander

Over the past five years, commodity prices have been high and the focus of many plants has been æthe more metal the better, at whatever costÆ. In the recent economic crisis, the focus has shifted more to reducing the cost of production and operating at higher efficiency. Since 2002, JKTech has partnered with the Century mine in north-west Queensland to transfer technology and understanding through the good, bad and ugly economic environments, using methodology and techniques arising from research at the Julius Kruttschnitt Mineral Research Centre (JKMRC) and other research institutions around the world as part of the AMIRA International P9 Project. The JKTech studies were concentrated around the primary zinc circuit. During this period, Century expanded the primary zinc regrind capacity, installed additional scavenging capacity, installed and commissioned a Jameson cell for concentrate cleaning in the carbon preflotation circuit, and installed additional primary grinding capacity. Flotation circuit models were developed for each of the survey campaigns and enabled opportunities for further improvement to be identified, implemented and tested in the subsequent campaign.

Jan 1, 2009

Land is of extreme importance to citizens of Papua New Guinea and is fundamental to most of their customs and values. Because of this, matters to do with land cannot easily be separated from other matters to do with the community. Good relation-ships with landowners and the community surrounding a development are, indispensable ingredients that -must flavour and colour the entire ;operati on .

Jan 1, 1994

The large rotary blast hole drills for hole sizes of 250 to 375 mm in diameter have been utilized by large open pit metal and coal mines for production drilling all over the world. The design of such rotary drills is in most cases about two decades old and it has not been done much in order to apply a modern technology on rotary drilling. The most modern large rotary drill, Tamrock RI 10, consists of an advantageous rotary head with a squirrel cage AC motor controlled by a frequency converter, a beneficial mast structure with a possibility for inclined drilling, hydraulic driven, independent crawlers, and a modern ergonomic cabin to provide a comfortable working condition for the oper- ator. Several automatic features are available as options. The rig has been designed to be operated by one man only. With this modern rig the produc- tion rate can be increased and production cost kept on a low level.

Jan 1, 1989

Magnetic separation using particle rotation in a continuously rotating magnetic field offers very low to insignificant non-magnetic particle entrapment, and precise magnetic fractions. The precision of rotating magnetic field separations makes the method ideal for dry laboratory magnetic analysis work, where conventional laboratory magnetic separators can give misleading or uncertain data. The very low entrapment characteristics make the method ideal for entrapment-critical separations within the diamond exploration industry or in gold recovery. A single wet rotating magnetic field (RMF) unit is able to achieve a cleaner separation (at similar or better recovery rates) than a three-stage separation using conventional wet drum separators. The RMF separator is able to work effectively at particle sizes below 50 ¦m, and RMF separation could, at least in theory, be used down to single domain particle sizes. Rotating magnetic field (RMF) separation is carried out by magnetically spinning the particles at frequencies up to 300 Hz. The particle rotation itself may be used to roll the particles out of the separator. At angular velocities of 100 Hz, magnetic flocs are unable to form, and any entrapped particles are energetically expelled. In an RMF separator, the outer drum can be stationary while the inner magnet rotor rotates, allowing, for example, the injection of cleaning water underneath the separating magnetics to help remove small suspended non-magnetic particles.

Jan 1, 2000

By Hyslop W

It is shown that coke has a major influence on the pattern of operation and on the aerodynamics of the blast furnace and that the physical and chemical characteristics of coke, at each stage in the furnace, determine its ability to satisfy requirements for iron production and coke economy. Analysis of coke sampled from operating furnaces is compared with furnace behaviour. The available data suggests the importance of segregation, strength, size change and chemical degradation of coke on furnace performance. Correlations are presented for coke breakdown ratio as a function of coke rate and hearth diameter which shows that breakdown increases with hearth diameter and with decreasing coke rate. It is also shown that the Micum tests do not reflect the coke strength in a predictable way and that solution reactions appear to play an important role in giving rise to a pitting effect on the cell walls of the coke with the resultant deterioration in coke properties. The catalytic effect of activating substances, such as alkalis, is noted and results are presented which show the effect of carbon solution on the coke strength. The importance of coke in the stack and in the bosh is discussed and flooding results are presented for BSC furnaces which show the probable driving limits for the furnaces considered. It is also shown that coke sampled from different tuyeres in a furnace gives quite different flooding limits. Other applications of the coke test work at BSC are also noted and the relevant objectives listed.

Jan 1, 1975

By Nott M. C

The oxidation of xanthate collectors to xanthate/dixanthogen results in a higher hydrophobicity of sulphide minerals surfaces due to the action of dixanthogen. This higher hydrophobicity can be proved on a fundamental level by examining the st

Jan 1, 1994