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By L. M. Scovell

The Internet and its related technologies will radically change the way that mines manage and control their maintenance, repair, and operating supply chains. The Internet is creating new distribution channels and offers new technology platforms with significant advantages over more traditional methods. Mines will have to re-evaluate both the strategies and the tactics employed in these areas. Mines will use e-commerce to integrate their maintenance, repair, and operating supply chains. The integration will extend beyond traditional trading partners to a worldwide network of communities with similar interests and goals. The changes will transform the way mines operate, lower mining costs, and thereby increase their chances of success in an increasingly competitive environment.

Jan 1, 2000

By Masashige Makifuchi, Hiroki Kumakura, Kota Nagai, Takahiro Kikuchi

"A large amount of platinum group metals (PGM) are used in automobile catalyst. It is important to recover the metals from wasted catalyst. Nomura and Kageyama (2013) suggested recovery process that PGM oxides were absorbed to perovskite-type oxide based on LaScO3. In their process, the PGM in wasted catalyst as absorbed to the perovskite-type oxide as PGM oxide. It has potential to each element in the process if the perovskite-type oxide is selected properly. In this study, the PGM oxide absorption properties of various perovskite-type oxides are investigated to develop a new recovery and separation process. The various perovskite-type oxide were synthesized with metallic platinum, palladium, rhodium at high temperature in air atmosphere. And the PGM contents in the perovskite-type oxide after the experiment are determined by chemical analysis. Some of them have the properties to absorb specific PGM oxide selectively. In addition, in order to increase the amount of absorption of PGM oxide and composition of the perovskite-type oxide experimental temperature was investigated. Then it is also found that doping another specific element to the perovskite-type oxide is effective to increase the amount of absorption of PGM oxide. Then a new recovery process of PGM from wasted automobile catalyst, in which PGM can be separate to each element, was designed.INTRODUCTIONA large amount of Platinum (Pt), Palladium (Pd), and Rhodium (Rh) are used in automobile catalysis (Figure 1) (Platinum, 2013). Natural supplies for these metals are limited and PGM mining can detrimental environmental impact. Therefore, the recycling of PGMs from wasted automobile catalysis is very important. The Rose process (Figure 2) was developed as a process to recover PGM from wasted automobile catalysis. In this process, the automobile catalysis is first crushed mechanically, and then extracting agent, copper (Cu), and flux are melted at high temperature. The mixture separates into a metal phase, (Cu alloy containing PGM) and slag. The PGM is enriched by oxidizing. Cu to Cu oxide. The PGM are then recovered and separated to each element in a wet process. However, it is hard to dissolve the PGM with acid because they are chemically stable and strong oxidation agent such as aqua regia is used. Moreover, to separate the PGM to each individual element, a solvent extraction process is required."

Jan 1, 2016

By G. Graves, J. A. Walker

"Abstract - The Mount Fronsac North volcanogenic massive sulfide deposit is the most recently discovered massive sulfide body in the Bathurst Mining Camp. The deposit occurs within a sequence of intercalated fine-grained felsic tuff and sedimentary rocks (Little Falls member), at the top of the Nepisiguit Falls Formation. Aphyric to sparsely feldspar-phyric rhyolite and related volcanic rocks of the Flat Landing Brook Formation overlie the host sequence. The massive and semimassive parts of the deposit have a north-south strike length of 525 m and a dip of ~45°E; the deposit is continuous downdip for 600 m, and thickness varies from 2 to 20 m. The deposit contains an estimated geologic resource of 14 Mt of low-grade, semimassive (>60%) to locally massive sulfides, and includes a high-grade zone of 1.26 Mt grading 7.65% Zn, 2.18% Pb, 0.14% Cu, 40.3 g/t Ag, and 0.40 g/t Au. The semimassive to massive sulfide intersections occur in an envelope of quartz-sericite±chlorite schist, which is interpreted to be intensely deformed felsic tuff. This sequence has a maximum thickness of 140 m and contains significant (up to 50%) fine- to coarse-grained disseminated pyrite. The pyritic envelope has a strike length of 900 m and extends over 1000 m downdip. Massive sulfides are found throughout this alteration envelope, but more commonly occur at or near the upper contact. The significance of the discovery of this deposit is that it represents a near surface discovery of a large tonnage sulfide body in a mature mining camp, one in which the possibility of discovery of a new shallow deposit had been all but discounted. This opens the possibility for future discoveries in this part of the Bathurst Mining Camp. Sommaire - Le gîte de sulfures massifs volcanogènes du Mont Fronsac Nord est la découverte de sulfures massifs la plus récente dans le Camp Minier de Bathurst. Le gisement est situé dans une séquence de tufs felsiques à grains fins interlités de roches sédimentaires (membre de Little Falls, au sommet de la Formation de Nepisiguit Falls. La partie massive et la semimassive s’étendent du nord au sud sur 525 m et ont un pendage de ~45°E; le gisement est continu sur 600 m en angle de chute et son épaisseur varie de 2 à 20 m. Le gisement contient une ressource géologique évaluée à 14 Mt de sulfures semimassifs (>60%) localement massifs à basse teneur, incluant une zone à haute teneur de 1.26 Mt titrant 7.65% Zn, 2.18% Pb, 0.14% Cu, 40.3 g/t Ag, et 0.40 g/t Au. Les intersections de sulfures semimassifs à massifs se situent dans une enveloppe de schiste à quartz-sericite ± chlorite interprétée comme un tuf felsique intensément déformé. Cette séquence contient une quantité importante (jusqu’à 50%) de pyrite disséminée dont le grain varie de fin à grossier et son épaisseur maximale est de 140 m. L’enveloppe pyriteuse s’étend latéralement sur 900 m et a été tracée jusqu’à 1000 m en angle de chute. Des sulfures massifs sont trouvés partout à l’intérieur de cette enveloppe d’altération, mais ils sont plus fréquents près du contact supérieur. L’importance de cette découverte tient à ce qu’elle est un exemple d’un gisement à fort tonnage nouvellement découvert à une faible profondeur dans un camp minier mature, i.e., un camp ou l’on ne croyait plus qu’il était possible de trouver un gisement près de la surface. Ceci ouvre la porte à la possibilité d’autres découvertes dans cette partie du Camp Minier de Bathurst."

Jan 1, 2006

By Seungyeol Lee

Currently, a new construction method using a robotic system is widely spreading in construction sites. This study is related to the design of glazing robot?s teach pendant which can improve convenience of handling and hence improve the productivity through the efficient interaction between an operator and a robot while doing glazing works, e.g., curtain wall installing. The suitability of selection and arrangement of control switches was assessed according to mechanical motions of a glazing robot, and design guidelines for improving convenience and productivity were drawn up through questionnaires carried out by site operators. To verify the proposed design guidelines, working time comparison of the proposed teach pendant and the existing teach pendant was executed.

Aug 1, 2013

By A. Chieregato, C. G. Oñate Salazar, D. Martinelli, D. Peila, M. Barbero

This paper is aimed to confirm the possibility to excavate fractured rock masses by using EPB shields, even in presence of relevant water tables. This verification is based on laboratory test experiences carried out at TUSC laboratory of Politecnico di Torino, where the natural material is tested in order to verify the suitability of a certain conditioning technique in particular conditions. This is due to the fact that every case should be studied apart from existing studies on a certain rock type, as other factors such as fragmentation of the rock mass, natural water content and porosity of the rock can considerably influence the final result of the conditioning process. The most important aspects that allow to consider the conditioning of fractured rock masses as suitable are: possibility to create a plastic paste that can transmit the pressure at the front in a effective way; reduce the permeability of the spoil material in order to reduce the possibility of water leakage inside the chamber and eventually in the tunnel; verify the consistency of the conditioned material for the extraction through the screw conveyors and the belt conveyors. For this research an argillitic schistose rock mass, with some quartzitic and calcareous inclusions, has been studied by using different level of conditioning in order to verify the suitability of an eventual EPB excavation through this formation.

Jan 1, 2015

By M. R. Henzinger, G. Lenz, A. Gaich, Pötsch, W. Schubert, P. Wagner

"The better the information on the rock mass and its fracture system, the better is the basis for any rock mechanical decision that is required during the excavation process. While in conventional tunnelling free view to the tunnel face is available, possibilities are limited for mechanised tunnelling using a tunnel boring machine (TBM). An approach, already formulated in 2005, is used that produces digital photographs through openings in the cutting wheel of a TBM and merges them into a circular three-dimensional image. The 3D image is then used for geometric rock mass characterisation purposes including geological mapping, for example to measure spatial orientations or determine joint spacing. In the paper the basic concept is described together with first results from a pilot test.INTRODUCTIONA three-dimensional image unites digital photographs with spatial information on the objects/surfaces it shows. Since they combine geometric and visual information they are a straightforward source for geometric rock mass analysis and geological mapping. Their obvious benefits among others are: (i) they allow spatial measurements even in inaccessible regions, (ii) they provide objective and reproducible records of the rock mass conditions, and (iii) they increase working safety (Gaich et al. 2004).Pre-requisite for the generation of 3D images is the acquisition of at least two photographs from the region of interest. From the photographs the imaged object surfaces are reconstructed by means of image analysis using methods from photogrammetry (Slama, 1980) and computer vision (Hartley & Zisserman, 2001). See also Figure 1."

Jan 1, 2015

By C. Mattich, Å. Holmström, L. Hedström

"The fluidized bed at Division Ministro Hales (DMH) division of Codelco in Calama, Chile is currently the largest operating roaster for partial roasting of arsenic rich copper concentrates. The roaster converts the Mina Ministro Hales (MMH) enargite rich (Cu3AsS4) copper concentrates into calcine with a low arsenic content that is suitable for mixing with other copper concentrates feeding a flash furnace. The plant sets a new standard for the processing of arsenic rich concentrates, both from the quality of the calcine as well as the environmental performances. The process technology and expertise are based on the solid practical experience of treating arsenic rich concentrates from both the Boliden smelter and Outotec.The partial roasting process is located next to the mine and concentrator and includes a sulphuric acid plant with auxiliary equipment. The produced calcine has an arsenic content significantly below target and the residual sulphur meets the requirement of the flash furnace. The plant operates with high efficiency cyclones resulting in a low amount of calcine passing to the hot electrostatic precipitator (HESP). The small flow of HESP calcine dust can be combined with the low arsenic calcine and still meet the flash furnace feed arsenic requirements.SO2 formed during roasting is converted into sulphuric acid, while volatized arsenic is recovered in the wet gas cleaning section of the acid plant along with a large proportion of antimony present in the MMH concentrate. Arsenic is stabilized as calcium arsenate and sent to disposal at a specially prepared site.The present production rate (September/October 2015) is close to or higher than the original maximum design capacity of the plant.INTRODUCTIONMineralogyThe mineralogy of an ore and concentrate is important, since there is a direct link between roasting performance and concentrate mineralogy. The MMH concentrate has a good combination of minerals that makes the roasting process efficient and flexible. The main minerals are pyrite, enargite and chalcocite (Figure 1). The inert content is about 15% and consists mainly of silicate and alumina based minerals. The lead content is very low and this is desirable, since the presence of even a small amount of lead will cause a substantial increase of sintering during roasting."

Jan 1, 2016

By Karl J. C. Harries

"2.1. INTRODUCTIONNo agreement can be perfect in the sense that it contemplates and provides for all eventualities. Mineral acquisition agreements are usually negotiated and drafted at a time when an orebody is no more than a gleam in a geologist’s eye, so it is hardly possible to provide for development and operation in other than the most general terms. However, an agreement that stops short of contemplating the possibility of an orebody and production is ill-advised. Accordingly, it is important to provide procedures to make decisions that will let the project proceed, even in the face of a fallingout between parties. Whether the parties are shareholders in a corporation or venturers in a contractual common undertaking like a joint venture, differences of opinion and disputes will occur. Unfortunately, more and more are ending up before the courts. Besides greed and the growing tendency in society to fight rather than talk, there are other factors that contribute to the increase of litigation. In some jurisdictions, agreements have tended to become complicated, often defying interpretation, even by a lawyer, and explorationists want their budgets to go into the ground as constructive work rather than into a lawyer’s pocket. All this has led to a growing tendency for corporations to take the attitude that the chances of finding a mine are, at best, marginal and there are lots of earlier agreements in the files to draw from, so why not prepare their own agreements? As discussed in the preceding chapter, this can be folly. All these factors can quickly have parties facing each other in court while a project sits idle. Added to this is the problem that, in some jurisdictions, lawyers may take cases on a contingency-fee basis, sometimes promoting the pursuit of a nebulous claim.When an orebody is discovered, someone will always want some, or more, for himself. There is a breed of “prospectors” who prospect for legal actions, on the somewhat sound grounds that a major corporation will buy off nuisance litigation, rather than incurring the cost and effort of attacking even a poorly founded claim in the courts. They may even find a winner. Besides, it is far more comfortable and relaxing to prospect for problems and legal niceties than to prospect for an orebody.1 In short, it is appropriate to consider briefly some of the factors relating to lawsuits and judgments. Although many of the comments are made in the context of the common law and the Canadian legal system, most of the concepts and suggestions are applicable to any legal system."

Jan 1, 2003

By A. M. S. Hussein, B. E. Rogers

Progressively more stringent emission limits and advances in regulations and enforcement have made air compliance more difficult for metallurgical facilities. This has historically required improved collection and treatment of stack sources. Fugitive emission reductions are now increasingly required to achieve compliance. Typically small in magnitude, fugitive emissions have a disproportionate impact on ground level concentrations, can be visible to the public and can influence workplace health and safety. Moreover, these emissions are complex, as they are spread over multiple sources, distance and time and are affected by various activities and conditions. As such it is difficult to find, define and monitor these emissions and their impacts. This difficulty translates to the design of emission reduction measures and operational requirements. This paper presents an overview or ‘heuristic’ of fugitive emissions management for compliance in existing operations. This includes aspects such as the impact of regulations on project scope, approaches to developing a comprehensive emission inventory, considerations for solution development and the plant’s role in sustaining compliance once achieved. Case studies are presented to demonstrate how portions of this approach have been applied.

Jan 1, 2015

By Hrayr Agnerian

The fair market value of an exploration property is determined by its potential to host a mineral deposit. This potential is gauged by the results of previous exploration, exploration stage, meaningful past expenditures and remaining targets that are not yet tested. Values of exploration properties can be viewed as distinct points in a three-dimensional space defined by orthogonal axes, namely: Exploration Stage (x-axis); Cumulative Expenditures (y-axis); and Property Value (z-axis). In general, these values are estimated by applying activity factors on previous exploration expenditures, e.g. an activity factor of 100% for an active property with good potential and a factor of 50% for an active property but past expenditures have not upgraded the property. At certain periods, a market factor may also be applied to reflect the activity of mineral property acquisitions. For properties that do not exhibit any exploration potential, only nominal values are applied.

Jan 1, 1996

By R. Matusewicz

The key drivers for the copper smelting industry are a complex mix of economic and "human" factors which combine to drive technology in new directions and can provide a strong indication of future industry trends. Recent examples have been the drive to achieve increased scale of production and resultant cost efficiencies by using a single furnace high intensity smelting vessel, and the broad acceptance of Top Submerged Lancing (TSL) technology for this duty. The development and adoption of continuous converting processes to counter the increased pressures faced by the Peirce Smith converting process is another example of the need for innovation. This paper discusses the merits of the continuous converting process, describes how the Ausmelt TSL batch converting process has been adapted to the new Ausmelt Continuous Copper Converting (C3) process in response to these industry trends and examines the Ausmelt continuous converting flowsheet options available to the end user.

Jan 1, 2007

By Y. Kashiwaya, J. Yagi, P. R. Austin

The problems of global environment and resources have become important issues in recent years, and the iron and steelmaking industry is requested to decrease energy consumption and carbon dioxide emission. The improvement of efficiency of ironmaking system is one of the countermeasures for these problems because more than a half of total energy input to the integrated steelwork is input to the ironmaking system. Various approaches to improve the blast furnace process have been made. The authors examined their performances through mathematical simulations of blast furnace operation, and confirmed the improvement of blast furnace efficiency under some operating conditions. The ironmaking system consists of various processes, and the materials and the energy are transported among these processes. Thus it is necessary to evaluate the efficiency of the novel operation of blast furnace based on the ironmaking system. In this study, the balances of material and energy on ironmaking system that consists of blast furnace, coke oven, sintering and hot stove processes were analyzed. The operation status of each process in the system was adjusted according to the results of the operation simulation of the blast furnace under novel operating conditions. The analysis clarified the effect of the blast furnace operation on the energy balance and CO2 emission of the ironmaking system.

Jan 1, 2015

By G. A. Vissac

METHODS of coal preparation have been greatly developed and improved during the past few years. Under the pressing competition from substitutes that have been displacing coal as a source of heat or power, the coal industry has been able, in many cases, not only to hold its own but to regain much of the lost ground, by offering better products of a higher value. The purpose of this paper is to present, in a brief and simple form, the principles of the latest methods and machinery used in coal preparation, in order to enable the coal operator t0 select methods and equipment capable of solving his own problems in the most efficient and economical way. The paper will deal, in the main, .with coal cleaning. It must be emphasized, however, that a complete coal preparation study covers many other operations, such as handling, screening, de-dusting, dust-proofing, and ash-conditioning. Handling Coal From the producing face to the railway car, coal must be handled with great care, t0 prevent degradation, because the coarser sizes are not only easier to clean than fines but, for our markets, they are often the more valuable. Generally speaking, such care is less important or is unnecessary in the Old Country, where conditions are different. The best way to minimize breakage is to avoid gravity methods in coal transportation. All chutes in a preparation plant should be shaken mechanically, and cleaning processes requiring large surge bins must be avoided. De-Dusting De-dusting of coal is accomplished by the use of vibrating screens, fans, or classifiers, or by a combination of these. Fines below 1/32-in. (or coarser than this, with some coals) can very seldom be cleaned efficiently. Common practice is to discard them immediately, if the moisture content of the coal allows this to be done. Otherwise, they are liable to give unnecessary trouble, either in the form of dust or sludge, which are difficult to collect or to settle. Flotation is the only process which will effectively clean fines.

Jan 1, 1937

By J. J. Jonas

The categories of interpass time encountered in hot rolling are characterized. These are shown to fall into three broad categories: short (in rod rolling); intermediate (in strip processing); and long (in plate schedules). The effects of interpass time on recrystallization and carbonitride precipitation are described, and particularly on the interaction between these two mechanisms. The interactions, in turn, determine the final microstructure produced as well as the mechanical properties.

Jan 1, 2005

By K. G. Chipman

THE discussion on Dr. Chipman's paper, Mapping by the Topographical Survey, centred mainly on the urgent need for aerial photographic reconnaissance of unmapped portions of the country as an initial phase in the provision of suitable topographical maps for use as a guide in geological mapping, prospecting, exploration, and development work in the areas concerned. This, ir was pointed out, would necessitate an expansion of the topographical work of the Bureau of Topography to keep pace with the photographid work and to meet the demand for maps for use by geologists of the Bureau of Geology and others. A resolution requesting Institute Council to make representations to the proper authorities, urging that aerial photography and topographic map-ping be greatly expanded to meet the pressing needs of the situation, was moved by DR. W. F. JAMES and seconded by MR. L. G. SMITH, and carried unanimously. The full text of the resolution appeared on page 221 of the May BULLETIN. Others who spoke in support of the resolution were MESSRS. E. S. MOORE, L. B. ROCHESTER, F. D. SHEPHERD, and W. J. WRIGHT. Dr. Hansen then presented his paper, Mapping by the Geological Survey, discussion on which is summarized below. MR. FRANK EBBUTT(l) spoke of the very valuable service the Geological Survey bas rendered the mineral industry, and indeed the whole nation, in its century of existence, despite the very inadequate financial support it has received. Now, more than ever before, a strong and expanded Geological Survey is essential if the Industry is to continue to prosper. Our known ore reserves are being depleted very rapidly, and we are finding no new orebodies to take their place. As an aid in prospecting and exploration, and also in the development of orebodies when they have been found, we must have geological maps of the vast sections of the country which at present are unmapped or inadequately mapped. The Institute should make every endeavour to have the Geological Survey strengthened so that such maps may be made available as soon as possible.

Jan 1, 1944

By Paul J. Beck

The impact of mining development on the environment can be minimized through comp careful construction and accurate monitoring. Key to meeting these objectives is t information at all stages of design, development, operation and decommissioning. This paper will describe cost-effective means of gathering and managing reliable fiel groundwater flow and surface water regime within and surrounding the mine site, as localized contaminant plumes associated with mine operations, and monitoring ground quality. Recent research has led to the development of inexpensive, easy to install syst sampling/monitoring from different zones within a single borehole. Advances in elect developed small diameter probes and pumps for measuring water levels and taking wat continuous monitoring stations in remote areas can be colldeacttaeldo gaguetrosm aatnidc adlolwyn luosaidnegd from a central facility using telemetry systems powered by direct, battery or solar radio frequency, landline or cellular telephones, and satellite. Two case studies will illustrate the use of datalolgagregres sacnadl et eblaesmient rwyi dien mao nitoring sc and the use of multilevel samplers for managing a contaminant plume.

May 1, 2004

By P. D. S. St. Pierre

IN REGENT YEARS, blast furnace operators have found it necessary to improve their technology in order to handle increasingly low-grade feed and yet satisfy the demands for greater tonnages of metal. Studies have been made covering several aspects of the problem, and in this connection the slags produced in the iron-making process have been critically examined with a view to discovering the slag with the optimum properties for a given operation. A good slag should combine, as far as possible, the properties listed in Table I. Unfortunately, some of these desirable properties are incompatible. For example, the advantage of the small ?bulk of a low-flux slag is offset by its low desulphurization potential and high viscosity. Similarly, a very fluid slag increases refractory wear. It will be seen, then, that a balance must he struck between these conflicting requirements. In the .present paper only the melting relationships of blast furnace slag ?compositions will be considered in detail. In interpreting the data herein presented, the optimum property requirements listed in Table 1 must strictly be borne in mind. It should also be noted that the discussion presented here always relates to calcined fluxes, since this facilitates reference to the final slag composition. Thus, in making calculations pertaining to the ?burdening of the furnace, due allowance should ?be made for the fact that the fluxes are added as carbonates.

Jan 1, 1956

By F. R. Joubin

MR. CHAIRMAN, Members of the C.I.M., and Friends -particularly friends, because I am not entirely a stranger in your city. I was last here some five years ago and it has given me a great deal of pleasure this evening to be able to say "Hello" again to those I had met at that time, when Bourlamaque and V al d'Or were very busy centres of intensive and successful gold exploration. My remarks this evening have to .do with Canada's Place in the Atomic Age. They will be of a general nature but I hope to tell you ?enough to whet your appetite so that you may be provoked into per-.suing the subject further. Now, atomic developments have become quite commonplace. Words like radioactivity, reactors, nuclear fission, and so on are known to everyone, even the youngsters. I re-member two or three years ago one of my office boys came to me and said "Mr. Joubin, I would like a raise." I gave the request a few seconds of serious thought and finally said "Alright, Jimmy, we'll give you a raise." However, he made no effort to leave, so after a -couple of seconds more I said, "Is there something else ?" and he said "Yes, Mr. Joubin, could you make that raise 'radioactive' to the first .of the year ?"

Jan 1, 1958

By B. B. Meadows

"The Minto-Chipman Strip Mining Reclamation Project was initiated to re-vegetate the spoil piles remaining from strip mining operations.All available information was studied by the team responsible, and areas being reclaimed in the U. S. were visited, Methods applicable to the N. B. Project were noted for future use.We have both surface and underground mining operations in New Brunswick, Both deface the natural landscape and reclamation varies in difficulty, Surface operation disturbances are the most difficult to correct.Some of the surface mining is carried out next to two main highways and the results are definite eyesores, With this in mind, it was decided to landscape the spoil ground next to the highways and plant “as is"" the ground remote from the public view.The landscaping entailed various degrees of bulldozing from complete levelling to contouring, smoothing and topping, Bulldozing is, of course, the most expensive part of any reclamation project.There are two phases to the planting program; experimental and operational--experimental both prior and, later, in conjunction with the operational planting.Initially in the experimental project, the pH and composition of the spoil was determined using a grid sampling system. Soil samples were tested in a laboratory at the University of New Brunswick."

Jan 1, 1970

By P. A. Riveros

The literature on the arsenic disposal practices of the metallurgical industry and the long term stability of the disposed arsenic compounds were reviewed from a Canadian perspective. The review was complemented with visits to selected operating metallurgical sites to obtain information on their specific arsenic disposal practices and the behaviour of their impounded residues. The arsenic disposal procedure currently favoured by the industry involves the formation of an insoluble ferric arsenate compound which is allowed to sediment at the bottom of tailings or residue ponds. It has been shown recently that this poorly formed crystalline compound is similar to ?arsenical ferrihydrite? which is ferrihydrite containing strongly adsorbed arsenate anions. Despite concerns about its long term stability on thermodynamic grounds, arsenical ferrihydrite appears to be stable for many years in the proper environment which includes a slightly acidic pH and oxidizing conditions. A high Fe/As ratio and the presence of heavy metals appear to increase the stability of arsenical ferrihydrite. High temperature operations, such as those encountered in the autoclave treatment of refractory gold ores, are conducive to the formation of scorodite, FeAsO42H2O, and/or a series of ferric arseno-hydroxy-sulphate compounds depending on the solution composition. Scorodite has several advantages over arsenical ferrihydrite as a disposal compound including a lower iron demand, a higher density and a greater thermodynamic stability. New procedures have been developed to generate scorodite at ambient pressure. These procedures would offer significant reductions in capital cost because of the elimination of the need for autoclaves. Lime precipitation which was widely used in the past is being abandoned as a result of strong evidence showing that calcium arsenate compounds decompose slowly in contact with atmospheric CO2 to form calcium carbonate and soluble arsenic acid. In all cases, the long term stability of the disposed arsenic compounds depends on a number of factors including disposal site characteristics, particle crystallinity and size distribution, the presence of complexing agents and the effect of bacterial activity.

May 1, 2002