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By Douglas E. Wolfe, Jogender Singh, Robert Miller, Dong-Ming Zhu, Jeff Eldridge

This paper discusses microstructural changes produced by two novel approaches using electron beam physical vapor deposition (EB-PVD) in which periodic strain fields/microporosity was incorporated within the large columnar grains of Zr02- 8wt.%Y2O3 (8YSZ). The traditional columnar microstructure of partially stabilized zirconia has been slightly modified to produce a lower thermal conductive thermal barrier coating (TBC) by periodically interrupting the condensing vapor resulting in microstructural modifications with diffuse or sharp interfaces and morphological changes on the sub-micron scale without changing the composition of the TBC. These microstructural modifications resulted in a 20-30% reduction in the thermal conductivity, 28-56% increase in hemispherical reflectance, improved oxidation cyclic life (over 100%), and better strain tolerance as compared to standard ZrO2-8wt.%Y2O3 deposited on platinum-nickel-aluminide and CoNiCrA1Y bond-coated MAR-M-247 test samples. The TBC with tailored microstructures were examined by various techniques including scanning electron microscopy (SEM), x-ray diffraction (XRD), steady-state laser heat flux technique, and hemispherical reflectance.

Jan 1, 2004

By Kevin M. Ansdell, Irvine R. Annesley, Christine L. Mckechnie

The U-Th-REE mineralization at Fraser Lakes Zone B is hosted by granitic pegmatites and leucogranites, which lie along the deformed contact between Paleoproterozoic metasedimentary gneiss of the Wollaston Group and Archean orthogneiss, approximately 25 km from the southeastern edge of the Athabasca Basin. The pegmatites/leucogranites are subcordant to concordant with the regional foliation and are concentrated within a northeast-plunging antiformal fold nose, the study area, which lies west of Fraser Lakes. The mineralized pegmatites/leucogranites in the western part of the study area (Group A) are typically enriched in U (± Th) with Th/U ~1, and contain uraninite, thorite, zircon, and allanite. Those intruding the central part of the study area (Group B) are generally enriched in Th and LREE, with Th/U >2, and contain monazite, thorite (commonly U-enriched), and zircon. The pegmatites and leucogranites in Group A tend to be slightly enriched in SiO2 and depleted in TiO2 relative to those in Group B and are interpreted to represent more evolved crustal melts. Both groups are peraluminous and show varied chemistry. Partial melting (~850ºC and 9 kbar) of a metasedimentary rock-dominated source, entrainment of accessory minerals as xenocrysts, and assimilation-fractional crystallization processes combined to enrich the granitic pegmatites/leucogranites in U, Th, and REE elements. Transfer of melt from the source region to the crystallization sites was assisted by deformation within and along major structural zones, such as the folded Archean-Paleoproterozoic discontinuity. The character of mineralization and structural control in the study area is reminiscent of the alaskite-hosted deposits at Rössing, Namibia.

Jan 1, 2013

By C. Villaseca, F. Penna, R. Villarroel

Acid mist is the undesired result of copper electro-winning (EW) process, generating a contaminated and hazardous environment in the working areas, as well as promoting high corrosion conditions for structures and equipment in the EW tank-house due to the buoyancy of sulfuric acid in aerosol form. Likewise, organic entrainments that occasionally occur in this process contaminate the cathodes, as well as increasing the risk of fire. LateralVex® and LateralFlow® are technologies that effectively and efficiently solve these problems, without affecting the usual activities of the operators, thus presenting a significant distinction with respect to other technologies that seek to solve these problems. Minera Antucoya, an AMSA group company, which produces 80,000 tons of electrolytic Cu per year, decided to install both technologies for its EW tank-house, LateralVex® in commercial cells and LateralFlow® in scavenger cells to keep both the acid mist and the organic entrainments under control. This paper presents the effects of applying these technologies in Minera Antucoya’s electro-winning plant, the challenges addressed, the difficulties encountered, the problems and opportunities that their implementation involved, as well as the surprising results obtained at the time of measuring the acid mist— less than one hundred’s part of the Allowed Weighted Limit—in samples taken with the plant operating at maximum current capacity. Additionally, the paper includes some of the improvements identified during the period, more than 3 years, in which these technologies have been in operation in Minera Antucoya. INTRODUCTION Electrowinning is the most used electro-chemical process in the hydrometallurgical industry for the recovery of highly pure metallic copper as its final product, which is formed in previous stages in an aqueous medium that goes through a selective process using organic solvents to separate impurities and concentrate the metal in a sulfuric acid solution. In the last stage, this solution goes through a process in which high- density current at a low voltage is applied, so that the metal in the solution will deposit in solid state on a plate, usually a stainless-steel plate. This last process involves the generation of other sub-products due to the electro-chemical dissociation of the electrolyte’s components, or to the addition of chemical additives, or due to specific physical conditions or lack of controls during the operation.

Jan 1, 2019

By L. E. Djingheuzian

"IntroductionDURING the past two decades an enormous amount of empirical data has been accumulating on grinding. These data have been obtained by mill operators on grinding ores with a diversity of characteristics, and generally they have been published. However, whenever an operator, who has started milling on a new ore, has tried to find a case in literature which would exactly fit his particular grinding problem, he has failed. Evidently, something fundamental has been lacking in all these empirical data, and, as a consequence, each new operator has had to undertake his own experimenting, get the best results he can, maybe publish these results, and let it go at that. This, in the writer's opinion, has been• due to the fact that even the ablest and most inquisitive millman has been forced to look on grinding as an art, and so, except very rarely, has not been able to find the time to stop and think; if he did so, it was rather in a philosophic way, that grinding is a fundamental process, a process that takes place in river beds, on the sea shore, etc.Nevertheless, when all the data so far published are correlated and examined as a whole, one is struck with the advances that have been made in grinding. The writer (7) had made such a study in 1949, and, when the correlation was completed, it showed that there was nothing heterogeneous about the accumulated data and that when brought together they were in harmony with each other. The writer's conclusion was that, if grinding criteria were defined and were expressed in such a way as to make integration of any data into basic formulae possible, grinding would be established as a mathematically exact science, and grinding worries of the harassed mill operator would be at an end!The first attempts to rationalize comminution were made by Rittinger and Kick. However, their theories led to endless disputes which did not accomplish much, except possibly clearing the path for subsequent investigators."

Jan 1, 1952

By Raj K. Rajamani, Nikhil Dhawan

"Agglomeration has become common pre-treatment step to improve heap leach percolation thereby recovery, the fundamental understanding of the agglomeration process for crushed ores is still lacking. Agglomeration is required for ores which either contain excessive amounts of clay or an excessive quantity of fines generated during mining and crushing. Numerous experiments have been carried out in laboratory scale batch drums using different ores. It has been found out that experimental agglomerate size distributions exhibit self-preserving spectra. The self-preserving/ similarity distribution of the agglomerates is found to be independent of operating conditions and is uniquely determined by the size enlargement mechanism. An empirical model based on the absolute difference between moisture applied and optimum moisture was developed. This model uses self-preserving spectra in the form of a Rosin-Rammler distribution function to predict size distribution at different operating conditions. The empirical model was considerably easier to work with plant scale agglomeration drums. Also, a test known as dip test is developed which improves fundamental understanding of the agglomerate formation and growth mechanisms. This test also provides the progeny size distribution of each agglomerate size. The progeny size distribution was analyzed with a model that partitions the particles into a host and guest category. The ensuing partition coefficient identifies the behaviour of a particle as a host for other particles or a guest layering on other particles. This concept helps in identifying the type of agglomerate that would result for a specific feed size distribution. INTRODUCTIONHeap leaching is one of the hydrometallurgical processes that have served as a green and economically viable process for the treatment of low grade complex ores of copper, uranium, nickel, silver and gold (Dhawan et al., 2013). Heap leaching appears to be a favorable candidate for the least energy consuming process for low grade ores. In heap leach operations nowadays a pretreatment step known as crushed ore agglomeration has been implemented (Dhawan et al., 2013). A bed of agglomerates improves the uniform percolation of solution through the heaps of ore. Therefore, it was possible to treat wastes and mill tailings via agglomeration and heap leaching. Agglomeration pretreatment is required for ores which either contain excessive amounts of clay or an excessive quantity of fines generated during mining and crushing (Bouffard, 2005; Dhawan et al., 2013).While agglomeration has become common practice pretreatment step in heap leach operations, the fundamental understanding of the crushed ore agglomeration process is still lacking. The author reviewed publications up to 2012 on the crushed ore agglomeration process and did not come up with modeling studies on the topic (Dhawan et al., 2013). Some of the possible reasons can be the stochastic nature of the process, experimental difficulties, and lack of instrumentation for fundamental studies."

Jan 1, 2016

By I. H. Warren, Forward F. A

The reduction of aqueous slurries of uranyl carbonate at elevated temperature with compressed hydrogen m the presence of metal catalysts and certain organic promoters has been shown. to yield uranium dioxide. The reduction takes place in a sequence of steps. The purity and sintering properties of the dioxide make it of interest as a starting material for fuel element production. Simple control can be exercised over the surface area and oxygen/uranium ratio of the product during reduction. URANIUM dioxide for fueling atomic power reactors 1s conventionally produced as a powder by simultaneously decomposing and reducing ammonium diuranate with hydrogen in a furnace at high temperature. Fuel elements are then generally made from this powder by compacting and sintering ( 1). In order that elements approaching theoretical density may be obtained,

Jan 1, 1961

By Marcel Vallee, Fernand Dubuc

"The St-Honoré carbonatite complex, located 8 miles north of Chicoutimi, Quebec, was discovered in September 1967 as abnormal radioactivity was detected in the course of SOQUEM's aerial surveys. The complex, covered by a shallow layer of Trenton limestone, has been explored by aeromagnetic, ground gravimetric and magnetic surveys, and 12,013 feet of diamond drilling. Its age, from potassium-argon dating, is 650 million years. The carbonatite is approximately kidney-shaped and has a surface area of 6 square miles, 20 per cent of which is explored. It shows a central core of coarse-grained massive dolomitic carbonatite and an outer ring of foliated dolomitic carbonatite.The exploration work to date has resulted in the discovery, in the foliated carbonatite, of an incompletely drilled niobium (columbium) zone of pyrochlore-bearing carbonatite, at least 1,000 by 800 feet in size. This zone contains 5,000 tons per vertical foot grading 0.86 per cent Nb205 or at least 15,000 tons per vertical foot grading 0.66 per cent Nb205 or 45,000 tons grading 0.48 per cent Nb20s. The pyrochlore contains an average of 64 per cent Nb,Os. The central core contains a zone of rare-earth-bearing carbonatite (as monazite), grading up to 4.5 per cent rare-earth oxide, 3,500 ppm zinc and 290 ppm molybdenum. Stocks of nepheline syenite and magnetite diorite accompany the carbonatite. The total analysis and trace-element contents of typical rocks are presented."

Jan 1, 1970

By W. E. MacDonald

This paper relates the story of 100 years of mining in the Harbour Seam at the Princess Colliery, Sydney Mines, Nova Scotia. Several interesting anecdotes are included along with the discussion of the evolution of coal mining methods in the area. Finally, some of the recently introduced equipment at Princess Colliery is described, and prospects for the future of the industry are outlined.

Jan 1, 1968

By V. E. Dawson

Brake testing of large mining trucks was initiated in British. Columbia in 1969 following an accident involving the failure of the service brakes of a l00-ton electric-drive truck. Some selected results of the 1976 brake test program are presented and discussed ?in this paper . The tests were conducted on end- dump trucks having load capacities ranging from 85 to 235 tons. All tests were made with the vehicles fully loaded operating on downhill grades varying from 8 to 10 %. Stopping distances were measured from initial speeds varying between 10 and 39 mph. The results are adequate, in most cases, to determine the "ultimate" capabilities of the service brakes of varying models and sizes of haulage trucks operating in British Columbia mines.

Jan 1, 1977

By John Plecash

This paper comprises a general outline of all of the developments, including the history, geology, mining, milling, power and transportation installations, at the gold mining operation of La Luz Mines Limited and the copper mining operation of its wholly-owned subsidiary, Rosita Mines Limited, both located in north-central Nicaragua. The low-grade, gold-bearing ore-bodies of La Luz Mines, contained in highly fractured and folded Lower Cretaceous sedimentary rocks, were from 1909 to 1928, mined and treated by primitive methods by the La Luz and Los Angeles Mining Company. The abandoned property was acquired by La Luz Mines Limited in 1936, and was equipped with modern machinery and put into production in 1939. Between 1939 and 1948, the daily rate of production was in-creased from 300 tons per day to 2,-000 ton per day. The ore reserves available for open-pit mining were depleted in 1954. Since then, the entire production has come from under-ground operations.

Jan 1, 1963

By Jerry C. Tien, Yingjiazi Cao

"Coal spontaneous combustion (SponCom) is a natural phenomenon in underground operations, which can either happen naturally or be triggered by human activities. For underground operations, espe-cially in coal, SponCom can happen frequently as a result of air leakage, although its incubation period may vary depends on types of coal and surrounding environment, resulting in uncertainty in control. In China, most of the underground coal operations now use longwall mining method because of its superior safety, high productivity and efficiency. With an increased popularity, there is also an increasing necessity to study spontaneous combustion, its occurrence and management. There have been many theoretical analysis and experimental studies over the past half century hoping to understand the occurrence of coal combustion and its control measures to better understand the occurrence and to design controlling measures to limit the dam-age it causes. In this paper, research on coal spontaneous combustion fundamentals from these three aspects will be reviewed, gaps highlighted and possible directions for future studies. INTRODUCTION The history of anthropic development is the history of human's energy utilization progress. From the first usage of fire, people have been continuingly seeking energy resources on earth. Coal, as an abundant, economic and convenient source of fuel quickly became indispensable and made significant contribution to economic growth worldwide. With technology and societal development, people are becoming more and more coal-dependent, but at the same time, problems of fossil fuel combustion came into sight. In global coal mining industry, spontaneous combustion has now presented one of the most challenging safety issues, it is also believed that it has contributed significantly toward the climate change. It is essential that more effort be invested to examine the cause of SponCom and its control measures. Coal SponCom is a complex process, with both physical and chemical inter-actions among various interrelated factors such as local airflow distribution, ventilation pressure, methane emissions (if any), and physical surroundings underground. With the advent of powerful computers, simulation techniques and af-fordable modelling packages in recent years, significant advances have been made in understanding sponta-neous combustion. But because of the complex nature of combustion and varying underground conditions, there are still areas that need further examining. This paper will focus on illustrating the current research of coal spontaneous combustion and addressing research gaps and future study areas."

Jan 1, 2019

By D. B. Dreisinger, M. Rasouli

"Developing technology to address the environmental hazards associated with selenium in mine-impacted waters has been a serious challenge. Ion exchange (IX) has been identified as a potential treatment technology. This paper begins with a review on selenium adsorption with commercially-available basic anionic exchangers (BAS). It then looks at the use of resins for selenium removal via modification with the addition of -O, -N, or -S-containing chelating ligands and chelating polymeric ion exchangers pre-loaded with immobilized metal cations. The synthesis of chelating exchangers requires a final product with a highly stable metal in the ligand-metal complex. The nature, oxidation state, size, and affinity of the metal for the target oxyanions and the size, degree of protonation and space configuration of the oxyanion are among critical factors affecting the oxyanion uptake. There is a limited number of studies on the critical parameters affecting the selenium affinity for chelating exchangers. Such a study could fill in the gaps of our understanding of selenium-metal-chelating ligand interactions and assist in developing a new ion exchanger. In addition to commercial IX resins, layered double hydroxide materials (LDH) have received attention for oxyanion removal from waste water. The adsorption capacity of the LDHs are affected by the crystallinity of LDH, the nature of metal components, the ratio of metals, charge and type of anion, and the space between the layers. In particular, the Friedel phase (FP), a member of the LDH family, showed high adsorption capacity for selenate removal from synthetic solution. A study is currently underway at the University of British Columbia to investigate the effect of different synthesis methods and aging on the suitability of FP for selenium removal from mine waste water."

Jan 1, 2017

By Howard W. Tipper, Richard B. Campbell

"The Quesnel Trough is underlain by a thick sequence of mainly Upper Triassic and Lower Jurassic volcanic-clastic and sedimentary rocks that lie between the highly deformed Proterozoic and Paleozoic rocks in the Omineca Geanticline to the east and the Upper Paleozoic Cache Creek Group in the Pinchi Geanticline to the west. Broad areas of the Trough between Kamloops and Williams Lake are covered by Eocene volcanics and sediments and by Miocene-Pliocene plateau lava. Granitic intrusions were apparently mainly confined to two major episodes; one about 200 m.y. ago (coeval with the Guichon batholith) and one about 100 m.y. ago. In addition, the region includes small granitic and syenitic intrusions, some porphyritic, that may be all or partly still younger. Exposures in the region are generally small and scattered, obscured by widespread, not necessarily thick glacial deposits. This, together with the extensive Tertiary cover, makes prospecting difficult. The part of the Quesnel Trough discussed here is the direct northwest-ward extension of the copper-rich Kamloops-Merritt-Princeton region. It contains the Boss Mountain molybdenum mine, related to a breccia zone induced in a batholith of the oldest group by a younger intrusion, and the Cariboo Bell copper deposit in Lower Jurassic volcanic-elastic rocks and syenitic intrusions. The Gibraltar deposit, in a 200-m.y. intrusion, is within the Pinchi Geanticline close to the margin of the Trough. Molybdenum prospects are mainly restricted within or near the 100-m.y. granitic rocks. Copper prospects, on the other hand, are most prominent in the volcanic-elastic rocks and in the 200-m.y.-old granitic rocks, although they can also be spatially related to younger intrusions. Copper thus has a wide potential distribution.The writers believe that the region is deserving of careful and comprehensive exploration by directly applying the knowledge and techniques developed in the important producing areas to the south. All of the major pre-Tertiary geological elements seem to have potential for mineral deposits; none should be ignored. A thorough knowledge of the thickness and distribution of the Tertiary rocks and the development of geophysical methods to ""see through"" them is of particular importance."

Jan 1, 1970

By K. Prajapati, P. Hes

Transmission of vibration to the operator from percussive vibrating tools is increasingly of concern in industrial and mining applications. Prolonged exposure to high levels of vibration transmitted via the hand causes disorders known as hand-arm vibration syndrome (HAVS). The vascular component of HAVS is called vibration white finger (VWF) and has a debilitating effect on the hand. Vibration at frequencies below 1250 Hz, a tight hand-grip force and cold environments are reported to increase the likelihood of developing VWF. A vibration damping handle design with patents pending that addresses some of the causes of VWF has been developed and retrofits onto jackleg pneumatic rock drills. The handle is decoupled from the drill while maintaining jackleg twist-grip controls on the hand-grip using a combination of sealed self adjusting hydraulic pistons and compliant materials in series, and a new air control valve. The ergonomics of the hand-grip was also modified by the addition of a polyurethane sleeve with a diameter of 50 mm. The new hand-grip reduces direct cold metal contact and minimizes grip force. Measurement of vibration as the quantity acceleration was made in accordance with international standard ISO 5349. Overall vibration damping in all axes of 50% to 63% was attained at frequencies below 1250 Hz. The dimensions of the damping handle are comparable and its weight is only 100 g heavier than a standard handle.

Jan 1, 2001

By E. Fritz

This paper reviews the history, developments and 10 milestones of the oxygen steelmaking processes, with a special focus on conventional autothermic converters, high-speed converters with a blowing rate up to 5 m3n/t min and allothermic converters with coal addition, post combustion and the possibility to increase the scrap rate up to 50%. Related operating results are introduced. A new process route, which is based on hot metal and chromium ore, is outlined. The cost advantage for the production of 304 stainless steel grade is higher than 100 USS/t. The synthesis of EAF and oxygen converter steelmaking, a comparison of decarburization rates, refining combustion burners for optimized oxygen-management in EAF and an example for a large advanced EAF are outlined. Possibilities of flexible steelmaking and the growth and outlook of worldwide oxygen steelmaking are described.

Jan 1, 2004

By X. -G. Chen, K. Liu

Nowadays, great interests are rising on aluminum alloys for the applications at elevated temperature, driven by the automotive and aerospace industries requiring high strength, light weight and low cost engineering materials. As one of the most promising candidates, Al-Mn-Mg 3004 alloys is found to possess considerably high mechanical properties and creep resistance at elevated temperature resulted from the precipitation of a large number of thermally stable dispersoids during heat treatment. In present work, the effect of Fe contents on the evolution of microstructure as well as high temperature properties of Al-Mn-Mg 3004 alloys has been investigated. Results show that the dominant intermetallic changes from a-Al(MnFe)Si at 0.1 wt.% Fe to Al6(MnFe) at both 0.3 wt. % and 0.6 wt. % Fe. In the Fe range of 0.1 to 0.6 wt.% studied, a significant improvement on mechanical properties at elevated temperature has been observed due to the precipitation of dispersoids, and the best combination of compression strength and creep resistance at 300°C is obtained in the alloy with an intermediate Fe content (0.3 wt.%) with finest size and highest volume fraction of a-Al(MnFe)Si dispersoids. The superior properties obtained at 300°C makes 3004 alloys more promising for high temperature applications. The relationship between the Fe content and the precipitation of stable dispersoids as well as the materials properties has been discussed.

Jan 1, 2015

By C. H. G. Bushell, G. Brown, C. J. Krauss

1N FLOTATION, copper sulphate is used universally for the activation of sphalerite and marmatite and, to some extent, for the activation of other minerals. The copper activated surface readily adsorbs standard collectors such as the xanthates and dialkyl dithiophosphates whereas untreated zir~ sulphide does not. With the host of reagents available, making a mineral float is seldom difficult. The problem is to achieve selective flotation. In zinc flotation, the great value of copper sulphate results from its ability to activate zinc sulphide preferentially to gangue minerals. At the Sullivan Concentrator of The Consolidated Mining and Smelting Company of Canada Limited, the most abundant gangue mineral in the lead-zinc ore is pyrrhotite, and the zinc mineral is marmatite of somewhat variable zinc to iron ratio. For this Cominco study, selectivity between marmatite and pyrrhotite was therefore the most interesting aspect of copper sulphate activation.

Jan 1, 1961

By G. H. Blackwell, A. J. Sinclair

"The main components of a ""PC” -based mineral inventory system are described in a sequence common to many real reserve/ resource estimation projects and in the practical context of problems and decision-making typically encountered in such studies. Some components are designed particuarly to improve the geostatistical instructional capability of the package. An important part of this approach involves the use of widely available software for data manipulation and evaluation in the design of a mineral inventory study progressing to mine design and feasibility. A variety of more or- less fixed routines written in high level languages provide acceptable computational speeds on a personal computer. These critical segments are linked by simple, short, compiled Basic programs easily adjustable to various data configurations and needs. IntroductionGeostatistical mineral inventory estimation has progressed greatly since its slow dissemination during the 1960s. The mining industry generally has accepted the benefits of the technique, notably the quantification of grade and geology, an indication of error in grade estimation, and of the mined volume / grade variance relationship (Clark, 1979, Isaacs and Srivastava, 1989).Acceptance has been slowed, first by complexities of geostatistical theory and second by a bewildering variety of computer systems and applications programs. Continuing improvements in education will facilitate a better understanding of the underlying theory.The purpose of this paper is to describe, in a practical context, the development of a geostatistical-based approach to reserve/resource estimation. The approach integrates various existing commercial software packages with a wide selection of programs developed by the authors for personal computers which estimate mineral inventories and educate users in the techniques applied; that is, the QMIN system.It is hoped that the approach presented here will convince mining and geological engineers concerned with resource estimation, of the soundness of geostatistical methods and its broad potential to their problems."

Jan 1, 1992

By Ahmad Ghahremaninezhad, Rebecca Radzinski

Arsenic is a highly toxic compound that is naturally found in the environment and is released through the processing of sulphide minerals. Arsenate (As5+) is less toxic than arsenite (As3+) and is soluble in water but can form insoluble precipitates when metal ions are present. The arsenic removal processes used in industry assume that arsenic is in its pentavalent state. Hydrogen peroxide can be employed to oxidize arsenite; however, it is expensive. It has been shown that activated carbon can be used to catalyze the oxidation of arsenite with oxygen as the only consumed reagent at ambient conditions with an efficiency of 99% in less than 24 hours. The mechanism which oxidizes arsenite is not yet understood; however, this study shows that a strong oxidizing agent is formed in-situ. The species and amount of oxidant formed were determined via iodimetric titration and electrochemical methods. The production of oxidant was optimized by comparing the amount of oxidant formed in-situ to the relative amount of arsenite oxidized.

Jan 1, 2015

By F. Vasilikou

Commercial deployment of Carbon Capture Utilization and Storage (CCUS) requires field testing of a scale that can stress the geologic reservoirs. One such reservoir of interest consists of unminable coal seams that exhibit favorable characteristics and depositional environments and lower pressure and temperature than other, deeper, reservoirs. Such conditions can reduce compression costs while utilizing the action of adsorption that offers a more effective carbon dioxide (CO2) bonding than free storage or solution. To ensure the success of such tests, a number of parameters should be accurately determined, such as the seam geometry and stratigraphy, coal porosity and permeability parameters as well as optimum injection conditions. In essence the CO2 injection model should be calibrated for the reservoir characteristics using all available data. History matching calibrations are based on gas and water production from existing wells prior to injection. This paper will present reservoir models that were developed for a pilot--scale 907 tonnes (1000 tons) CO2 injection test that was performed in 2009 through one legacy coalbed methane production well in Russell County, Virginia, USA. The model incorporates a number of individual coal seams about 0.3 m (1ft) in thickness located at depths ranging from 300 to 700 m (1,000 to 2,200 feet). Model calibration was performed through history matching to prior production data, and subsequently the model was utilized to develop different injection scenarios. The developed model was used after injection to calculate CO2 plume distribution patterns that were monitored at the injection test. The paper will present model data and assumptions with a special emphasis on the effect of hydraulic fractures and the skin factor to the coalbed methane (CBM) production model.

Aug 1, 2013