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By M. Krasowska, K. Malysa, M. Krzan

The paper presents fascinating, in our opinion, observations on mechanism and course of processes occurring during bubble collision with hydrophobic and hydrophilic solid surface. Hydrophobicity of particle surface is a necessary condition for the particle attachment to bubble. We have observed that even in the case of such hydrophobic solid surface as Teflon, the bubble attachment didn't occur at first collision. In distilled water the bubble bounced a few times without attachment. Influence of a-terpineol and n¬pentanol on bubble local and terminal velocity and the phenomena occurring during bubble collisions with hydrophobic and hydrophilic solid surfaces was studied. Bubble collisions with the solid surfaces were monitored and recorded using the high-speed (1182 frames per second) camera. It was found that in distilled water the velocity variations of the "approach-bounce" cycles were identical for Teflon and glass. Four distinct "approach-bounce" cycles were detected both at Teflon and glass surfaces. Moreover, the amplitude and frequency of the velocity variations were identical on collisions with the hydrophobic (polished) and hydrophilic surface. There was no immediate three phase contact formation, with the hydrophobic Teflon surface, what we found really astonishing. Roughness of Teflon surface seems to be important parameter, which affects probability of the bubble attachment as a result of a presence of micro-and/or nano-bubbles at the surface. It was detected that the presence of the micro-bubble affected attachment of the colliding bubble even in distilled water. Presence of a small amount of a-terpineol or n-pentanol affects dramatically the bubble velocity, but their role in mechanism of the bubble attachment needs further study.

Jan 1, 2004

By F. Sorensen

ABSTRACT Electricity production by the Electricity Supply Commission of South Africa (Eskom) is the most important beneficiation process for South African coal. As one of the world’s lowest cost producers, energy-intensive industries such as ferroalloys and aluminium were introduced. However the poor were neglected. The white paper on energy policy (Department of Minerals and Energy, 1998) sought to redress this. Also, chasing economic growth to generate jobs resulted in high electricity demand and interruptions. Lifespan estimates of South African coal reserves based upon peak theory vary widely. Approaching peak, coal production in the future will be more expensive and, thus, contribute to more expensive electricity, which could inhibit industrial development unless South Africans work smarter.

Jan 1, 2011

By H. Bouzahzah

Sulfidic tailings, subjected to atmospheric water and oxygen action, can generate acid mine drainage (AMD); which is the most important environmental problem facing the mining industry. AMD generating potential can be assessed by the static tests which consist of a screening method where the neutralization potential (NP) and the acid-generating potential (AP) of a given rock sample are determined. The AP and NP are determined separately in the different static test existing procedures which can be divided into two distinct classes: chemical and the mineralogical methods. For some chemical method, the AP is calculated on the basis of total sulfide sulfur content in the sample which may overestimate its AP if significant quantities of non-sulfide sulfur species are present (e.g. organic S in coals, some sulfate as gypsum, barite, etc.). However, the mineralogical method evaluates the AP by the sum of the individual sulfides participation on acid generation based on their concentration within the sample and can be more accurate than the chemical method. For AP calculation, the Paktunc (1999a) mineralogical static test takes into consideration all sulfide minerals occurring in the sample. However, it does not take into account the rates of acidity production of these sulfides submitted to weathering conditions. So, the present study focusses on the modification of Paktunc AP calculation by considering the acidity production rates of these minerals. To reach this objective, five base-metal sulfides (pyrite as reference, chalcopyrite, sphalerite, arsenopyrite, galena), diluted within quartz (25?75 wt.%) simulating mill tailings were subjected to a kinetic test to evaluate their AP. The results show that all the studied sulfides minerals generate acidity at different rates, so the Paktunc?s equation for AP calculation has been adapted accordingly.

Aug 1, 2013

By L. E. Djingheuzian

IN 1953, Lewis (1) published an article which brought forth a great amount of discussion by grinding engineers. In his contribution to discussion the present writer (2) suggested that, for the most efficient performance of a ball mill, there must be a .definite relationship between Cn, per cent critical speed, and V p, per cent mill volume occupied by the ball charge. Later, he ( 3) was able to publish some grinding data from Wright-Hargreaves milly which appeared to bear out this contention. It is with this view to establishing a fundamental relationship between Cn and Vp that the idea of this Forum was conceived. Accordingly, a questionnaire was prepared and copies of it were mailed to over eighty Canadian mill operators. This questionnaire did not include a question on dilution on the assumption that each mill operator was using the most efficient dilution for his operation, nor was a question on efficiency of classification included since it was thought that the inclusion of efficiency of dassification in the questionnaire at this preliminary stage might render the forum discussion,. while everybody was trying to find his bearings, too unwieldy. However, it is evident that, as discussions develop, this forum will have to define a uniform method for establishing most efficient classification in grinding circuits

Jan 1, 1957

By G. R. Webber

CHEMICAL AN AL YSIS by x-ray emission spectrometry has become increasingly important during the past few years. The method is analogous to optical spectrography ?with x-rays being used instead of light and should not be confused with methods of x-ray diffraction used? for identification of minerals and chemical compounds. X-ray emission spectrometry has many advantages for both qualitative and quantitative analysis. Its optimum concentration range is higher than that of the optical spectrograph, and the group of elements which can be detected is not identical to that which can be detected by the optical spectrograph. Elements which can be detected by the x-ray spectrometer are those elements from magnesium (atomic number 12) to uranium (atomic number 92) in the periodic table. The lightest elements in this range have low sensitivities and more specialized equipment is necessary for their detection than for the heavier elements. A large number of applications of x-ray analysis have been directed toward the analysis of ores, metallurgical products, and related materials (see References at end of paper). A more complete bibliography is presented in the Norelco Reporter, Vol. 3, 1956, pp. 37-39. The periodicals Analytical Chemistry and Applied Spectroscopy are a good source of current articles and references.

Jan 1, 1957

By L. C. Stevens

The particular purpose of this paper is to direct attention to the development of underground conveying as applied to methods of working coal in the mines of Alberta. Historical A retrospective view of coal mining discloses a continuous effort, on the part of those interested, to substitute mechanical contrivances for hand labour. A patent for a coal-cutting machine was granted to Michael Menzies in 1761, at which time much of the transportation of coal underground was accomplished by means of sledges. Early forms of cutting machines attempted to duplicate the action of a miner's pick, and one hundred years lacer than Menzies? patent we still find this class of machine, driven by water power or compressed air, in use to a limited extent. A coal-cutter using the principle of a circular saw and worked by hand was exhibited in London in 1851, and from these crude beginnings the machines of today have been evolved. Transportation of coal underground has similarly been subject to considerable improvement. The above mentioned Michael Menzies took out a patent in 1750 covering the use of a self-acting incline plane, which is probably the earliest record of any system devised to lighten the load of the crammer or car-pusher of those days. In the year 1868 the Gillot & Copley machine was patented, this being a compressed-air-driven disc coal-cutter which proved highly successful. The chain cutters were a natural development from this type, and for a number of reasons they have been even more successful in the majority of cases.

Jan 1, 1930

By S. k. Kim, H. B. Trinh, R. R. Srivastava

"Spent auto-catalyst is a promising secondary resource of platinum group metals (PGMs), which are being extensively used in automobiles catalytic converters to control the hazardous gaseous emissions (CO, NOx and hydrocarbons). Several pyro or hydrometallurgical routes has been employed to recover PGMs from such spent materials but there is no proper process for recovering the other constituents metals. Therefore, it causes the loss of other major constituents like, Al and Mg along with rare earth metal Ce. In the present study, we investigate the dissolution of Al and Mg using sodium hydroxide (NaOH) roasting followed by a sulfuric acid (H2SO4) leaching; thereby concentrating the PGMs and Ce in leached residues. The effect of roasting temperature, time and amount of NaOH were varied. Subsequently, the dissolution behavior of metals in H2SO4 as a function of acid concentration was investigated from the roasted samples. At an optimal condition for roasting at 600°C with 1:1 NaOH-to-catalyst ratio and 60 min duration, the maximum of Al and Mg were dissolved in 1 M H2SO4 solution at ambient temperature (~25°C). Thus obtained leached residues containing enriched PGMs and Ce content can be treated separately for the recovery of these high-value metals.INTRODUCTION Spent auto-catalyst has been considered as a potential resource for recovering the platinum group metals (PGMs) (Jha et al., 2013). The commonly used auto-catalyst is made of cordierite (2MgO.2Al2O3.5SiO2) in which the chloro complexes of PGMs are impregnated onto the surfaces of porous washcoat of alumina substrate (Aberasturi et al., 2011). The average concentration of PGMs in ore are 2-4 g/ton for Pt, 7-2 g/ton for Pd and 0.2-0.5 g/ton for Rh, whereas, an individual catalytic converter weighing about 1 - 2 kg contains on average 1.56 g Pt, 0.62 g Pd and 0.156 g Rh (Upadhyay et al., 2013). Moreover, recovery of PGMs from spent auto-catalyst offers other advantages like, simple process, low cost and less pollution, as compared to recovery from primary resources (Dong et al., 2015).Therefore, technologies to recover PGMs from spent auto-catalyst has become attractive in the recent past and their recycling contribution has been accounted for 35% Pt, 26% Pd and 36% Rh of the quantity consumed in the production of auto-catalysts (Johnson Matthey, 2016)."

Jan 1, 2017

By R. C. Tait

The gold at Giant Yellowknife is intimately associated with a complex mixture of sulphides, including pyrite, arsenopyrite, stibnite, and a wide variety of antimony sulpho-salts. Direct cyanidation has never been feasible. Recovery is almost entirely dependent upon flotation, roasting of flotation concentrate, and cyanidation of calcine. In November 1958, an Edwards-type roaster and an early prototype, two stage Fluosolids roaster, were replaced by a large two-stage Fluosolids roaster of improved design. The new roaster was started at "safe" medium temperatures, but early in 1959, temperatures in both stages were gradually and deliberately lowered to determine whether continuous autogenous roasting could be maintained under exacting low temperature conditions necessary for good extraction. Operation is smooth and continuous with first and second stage temperatures controlled at 925° and 875°F respectively. Plant cyanide ex-traction compares very favourably with extraction from low

Jan 1, 1961

By M. Bryson, S. Broom-Fendley, A. E. Brady, W. Dawes, G. Beer, N. Sehlotho, S. Al-Ali, F. Wall

The Songwe Hill Rare Earth Element (REE) Project in Malawi is a near surface carbonatite-hosted deposit with synchysite and apatite as the key REE bearing minerals. A strong focus has been placed on understanding the REE mineralogy of the Songwe Hill carbonatite as REE mineralogical characterization is a crucial component at all steps, ranging from exploration to production, in the development of REE deposits. Extensive mineralogical work has been completed at Camborne School of Mines (CSM), Natural History Museum (NHM) London, British Geological Survey (BGS), Nottingham, Aberystwyth University, Wales, Mintek, South Africa, and SGS Inc. Canada (SGS). The following analytical techniques were used: scanning electron microscopy (SEM), electron microprobe analysis (EMPA), laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), and QEMSCAN®. The detailed studies have demonstrated that while synchysite is light-REE enriched as expected, apatite, abundant in all stages of carbonatite emplacement at Songwe, is anomalously enriched in mid- to heavy-REE relative to apatite in other carbonatite deposits. The distribution of REE within synchysite and apatite at Songwe has had important implications for the direction of the metallurgical work with respect to the behaviour of light and heavy REE through the flotation and hydrometallurgical stages of the flow sheet.

Jan 1, 2014

By X. Q. Jiang, D. L. Chen, A. Macwan

Magnesium alloy, being the lightest structural material, is a key candidate for the weight reduction of vehicles in automotive and aerospace industries; however, its poor corrosion resistance and difficulty in deformation are limiting factors. Recently, Al/Mg/Al tri-layered clad sheets have been considered as a promising alternative to improve corrosion resistance and formability of magnesium alloys. The aim of this study was to evaluate the tensile properties and deformation behavior of Al/Mg/Al tri-layer clad sheets at different temperatures and strain rates. Yield strength (YS), ultimate tensile strength (UTS), and elongation were observed to increase with increasing strain rate. With increasing temperature from -40°C to 180°C, YS and UTS decreased and ductility increased. The strain hardening exponent evaluated via three equations of Hollomon, Swift, and Afrin et al. showed a similar increase with increasing strain rate and decreasing temperature. The fractographic analysis showed partial debonding of clad interface especially at higher strain rates and lower temperatures.

Jan 1, 2015

By P. Kostuik

"Recent interest in the pipeline transport of solid mate-als has been sparked by the idea that, in an inflationary onomy, pipeline costs are more stable than the costs of any other transport systems. Pipelines have proved over 1e years to be dependable, records indicate that main-•nance and operating costs are comparatively low, and 1eir amenability to automation is of considerable im->rtance.The concept of hydraulic hoisting of solids from under-round, or cross-country hydraulic transportation of con-~ntrates and ores, is currently of prime interest to the ining industry. In general, this paper deals with a preliminary investi-ation of energy losses incurred while transporting a rela-vely heavy, crushed mine product, namely magnetite, oth vertically and horizontally. The basis and validity of everal equations derived by other experimenters to com-ute these losses is discussed. A theoretical analysis of ydraulic hoi:,,ting is made, and, based upon test results, calculation of horsepower requirements for hoisting an re under a given set of conditions is presented. Results indicate that:n vertical transport, the friction head losses are identical to those of clear water, and the total energy requirement for hydraulic hoisting then becomes a function of height of lift, concentration and specific gravity of the solids being hoisted. .-In horizontal transport, friction head losses can be calculated with reasonable accuracy using Bonning-ton's correlation curve. Losses computed utilizing Durand's correlation (K = 85) result in estimates which are too low by 10 to 30 per cent, an<l those calculated using Newitt's correlation (K = 1,100, K = 66) give friction loss values which are too high by 10 to 30 per cent . . -The theoretical horsepower (RMS-hp.) required for hoisting hydraulically is approximately half of that required for conventional double-drum skip hoisting."

Jan 1, 1966

By R. B. Hyde

"Severe drilling conditions and difficult mud problems are briefly out-lined as the major cost items in all production operations. The chief problems discussed are abnormal pressures, high temperature, trouble-some shales, and low rates of penetration. These problems have been eliminated or greatly reduced in many areas by• the proper application of recently developed drilling mud products and techniques. These severe problems and their solutions are discussed generally: the application of high-density weighting materials to overcome abnormal pressures; surfactant muds with sodium polyacrylate as a solution for deep and high-temperature drilling; shale control muds and new dispersants for severe shale problems; and low-solids emulsions and •extreme-pressure lubricants for greatly improved rates of penetration."

Jan 1, 1959

By Harold Hopkins

THE Wright-Hargreaves mine is one of a group of seven mines long active in the Kirkland Lake district, Ontario. Detailed geological reports and maps covering the area have been published by the Ontario Department of Mines (1,3)t. Though all these mines work several productive veins there is one vein which is common to all and is known as the North Vein of the camp?not that it is the most northerly vein mined, but it is the more northerly of the two major veins of the camp. At the Wright-Hargreaves mine there are in all ten important producing veins, and most of them have a N.60°-65°E. strike and in general a steep southerly dip. It is a common belief that most of these veins lie along faults but it will be shown that whilst this is true of some of them it is not true of all, and also that a vein may lie in a fault along part of its course and elsewhere fill a fracture in line with the fault, this being a consequence of rotational movements that took place during faulting. The paper describes the history of faulting at this mine in particular, makes observations on the principal pre-ore fault, and describes the method used in solving the movements on the post-ore faults. Other details of geology are not discussed except to mention here that our main veins lie almost entirely in the syenite porphyry stock except on lower levels close to the east boundary of the property, where the North vein leaves the porphyry to enter the greywacke.

Jan 1, 1940

By Claudio Acuña, Sergio Romo, Gerardo Fuentes

The leaching kinetics of a zinc concentrate in autoclave reactors were studied. A sample of concentrate from Bolivia, with typical mineralogical characteristics of the Andes region, was used. A concentrate containing 49% zinc and 145 ppm of silver from Minera Viacha was characterized chemically and mineralogically (atomic absorption, X-ray diffraction, and SEM microscopy) and tested in bench scale reactors. Two types of autoclave batch reactors were used at 40 bars of oxygen pressure and three levels of temperature (150°C, 200°C and 250°C). The solid to solution leaching ratio was 1:10 (10% sulphuric acid concentration). The effect of the particle size of the concentrate on the leaching kinetics was studied (P80: 145 and 45 µm). Iron from the leaching solution was removed by precipitation by increasing the pH in order to generate a clean solution for zinc electrowinning. The zinc solution was used to evaluate the feasibility of cathode production at the laboratory scale. Zinc extractions with higher liberation (P80 = 45 µm) reached up to 98%. Ground concentrate with finer sizes resulted in agglomeration and the use of dispersing agents did not improve slurry mixing. The leaching solution contained 55 g/L zinc and 7 g/L iron; it was purified by precipitating iron. The precipitation was evaluated using sodium hydroxide and ammonium hydroxide. In the first case, a colloidal suspension of ferric salts was formed while in the second case, different iron compounds were precipitated. The precipitate obtained with ammonium hydroxide had better filtering properties. Electrowinning was carried out using two types of cathodes (stainless steel and aluminium) and solutions purified with ammonium hydroxide. Zinc cathodes formed on stainless steel presented a better physical quality than those formed on aluminium.

Jan 1, 2015

By C. Butcher

Numerical simulations of straight tube hydroforming of a dual phase steel were performed using both upper and lower bound constitutive models for porous ductile materials. The Gurson model is based upon an upper bound approximation to the material behavior and thus overestimates formability. Conversely, a lower bound solution to Gurson&apos;s unit cell geometry was developed by Sun and Wang to provide a conservative estimate of formability. The effect of a compressive axial load (end-feed) on damage development and tube formability is investigated. The resulting upper and lower bound models successfully captured the experimentally determined burst pressure, formability and failure location.

Jan 1, 2010

By David Scott, Denis V. Lachance, Daniel Marcotie

"LocationThe Heath Steele mine is located 50 km northwest of Miramichi, New Brunswick.Brief DescriptionHeath Steele is a 2700 t/d, copper-lead-zinc operation which employs conventional crushing, grinding, and differential flotation.HistoryThe Heath Steele mine is located in northeastern New Brunswick approximately 50 km northwest of the city of Miramichi and 65 km southwest of Bathurst. The massive sulphides containing ore values in zinc, lead, copper and silver were discovered in 1953 as a result of a joint venture between the American Metal Company and the International Nickel Company of Canada. The discovery was named after Mr. Heath Steele, manager of exploration for Amco at the time of the discovery.Mill production began in February 1957; however, the mine was forced to shutdown in 1958 due to depressed metal prices and metallurgical problems. It was re-opened in 1962 and milling operations resumed at 725 t/d until 1968 when the milling capacity was boosted to 1450 t/d and then to 2700 t/d in 1969.OreThe main ore zones are massive sulphides with very fine mineral grain. The chalcopyrite, galena and marmatitesphalerite occurrences are finely disseminated.Liberation is accomplished by grinding to 68% to 72% <400 mesh. Average mill feed assays are 0.8% to 1.2% copper, 1.8% to 2.5% lead, and 5.5% to 6.5% zinc, with 60 to 75 g/t silver."

Jan 1, 2000

By E. Laatio, W. McKay

"History of Tara Mines Ltd.Tara Exploration and Development Company Ltd. was formed in Canada by Irishmen in 1953. The discovery of an orebody approximately six miles from the historically famous Hill of Tara in County Meath was a wild dream . Nevertheless this dream became a reality. Tara Mines Ltd. was formed, and the mine developed some 35 miles northwest of the City of Dublin in the Irish Republic.Tara&apos;s original drilling program indicated a zinc-lead orebody of approximately 60 million tonnes grading at 10.1% Zn and 2.6% Pb. The terms of the mining lease stipulated that the Irish government would acquire 25% equity interest in the operation. The mine was thus owned 75% by Tara Exploration and Development Company Ltd. of which the principal shareholders were Noranda and Northgate, together with 25% being held by the Irish government. The mine was purchased in March 1986 by Outokumpu Oy, a Finnish mining and metallurgical company, and together with the 25% government stake are the current owners. Outokumpu Analysis on Tara Mines Ltd.Upon ownership Outokumpu carried out a comprehensive analysis on the operation and came to the following conclusions :1. Tara had a good orebody;2. Tara had a skilled, capable, stable workforce;3. Tara&apos;s concentrator and processing equipment was adequate to meet requirements;4. Tara&apos;s mobile equipment fleet was too old and too numerousin numbers; and5. Tara had too many employees, both staff and hourly paid .With ore reserves of approximately 50 million tonnes and at a planned extraction rate of 2.6 million tonnes it meant that the mine had a lifespan of approximately 20 years. To be a viable operation into the future, the mine had to become more efficient. Operating costs and manpower levels had to be dramatically reduced."

Jan 1, 1989

By T. W. Wlodek

"AbstractThe results of research into the fatigue properties of SAE 1080 carbon steel and nickel-chromium-molylbdenum steel for mining drill rods are analysed and described in detail.The effect of water corrosion on the fatigue strength of drill rods of these two steels in the as-rolled condition has ,been investigated and the beneficial influence of shot-peening on their dry and water-corrosion fatigue strengths determined by employing the method developed previously (1).Eight S-N curves for as-rolled and shot-peened mining drill rods under both dry and water corrosion conditions have been derived and their shape and relative position are discussed. The main features relating to field performance of the drill rods are analysed.Purpose of Research and Outline of ProgrammeDRILLING holes in rock and ore by means of drill rods attached to a pneumatic drill is a basic procedure required in mining operations. Detonation of explosives placed in these holes is at present the only practical method of breaking down the rock and ore.A drilling rod is supported by its bit end in the drilled rock. Its shank end, fixed in the drilling machine, transmits impact energy to the cutting edges of the bit. On the field performance of the drill rod depend a number of basic mining operations such as sinking, drifting, and stoping. The drill rod is there-fore regarded as one of the most important tools used in the mining industry."

Jan 1, 1952

By Pravin Mathur

"Praxair&apos;s CoJet® technology was introduced in 1997 to effectively inject chemical energy in electric arc furnaces. Coherent jets were invented as a revolutionary means of injecting oxygen and other gases into the EAF and into converters. Today, steel makers have widely accepted this concept in over 70 EAFs worldwide. Indeed, the whole industry has shifted to this new standard for chemical energy input in EAFs. CoJet® technology has also been implemented successfully in BOF converters.This paper will review the principles of coherent jets as applied to steelmaking. The key learnings garnered from several furnaces are also reviewed. In addition, while the CoJet® program has been widely accepted worldwide, based on steady feedback received from customers and the market place, several programs are underway in development and commercialization. These enhancements and new applications of CoJet® technology are also overviewed in the paper."

Jan 1, 2004

By Habib Zughbi, Paul Zulli

"A key step towards sustainability in iron and steelmaking is to optimise the use of raw materials and energy consumption, and consequently minimise CO2 emissions. Models based on a Process Integration (PI) approach play a key role in evaluating various scenarios and the impact of introducing changes in raw materials and operational conditions on the overall energy consumption and CO2 emissions. BlueScope uses a PI based comprehensive model for its Port Kembla Steelworks (PKSW), called the Integrated Steelworks Energy and Emissions Model (ISEEM). ISEEM is tightly coupled to the configuration of PKSW. It is based on mass and energy balances as well as thermodynamic relationships. ISEEM is a steady-state model and is used to predict overall and detailed unit-by-unit energy consumptions and CO2 emissions. It is also used for plant-based scenario modelling. This paper investigates the impact of major changes to PKSW configuration, including the shutting down of a blast furnace and cokemaking battery, on the energy consumption and CO2 emissions of the plant. It discusses some of the issues involved in updating the model and some identified opportunities."

Jan 1, 2015