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By M. Kim, M. Ha

"The effect of red mud on the melting behavior of ferronickel slag was investigated by a laboratory-scale horizontal tube furnace. Melting and softening of slag samples fluxed with different amount of red mud was examined by in-situ visualization technique at temperature range from 1400 to 1550°C. FactSageTM 7.0 was used for the thermodynamic calculation of multi component system of ferronickel slag and red mud. Liquid phase area was extended to lower temperature by adding red mud indicating its suitability as a flux material. X-ray diffraction analysis confirmed the dependency of the phase changes on the red mud content. Microscopic observation by scanning electron microscope (SEM / EDX) clarified the phase transformations from olivine to spinel along with red mud additions.INTRODUCTION Ferronickel smelting by submerged arc furnace (SAF) is an energy intensive process performed at high temperature range 1500–1600°C. During the smelting process of saprolitic nickel laterite ore with a nickel content of 2.2–2.3 pct, a large quantity of ferronickel slag is being produced that account for 97 pct of ore charged. To achieve ferronickel grade of 15–20 pct Ni, electrical energy of 80 to 85 MW is used for the melting and reduction of nickel oxide (NiO) and iron oxide (FeO) in the ore (Rodd et al., 2010). Unreduced components, mostly MgO, SiO2 and partly FeO are removed from the furnace in a liquid slag form by a tapping operation. Due to the high melting temperature, forsterite (Mg2SiO4) based slag containing approximately 10 pct FeO requires typical process temperature of 1600°C. Flux in metallurgical process is a medium that decreases melting and operating temperatures while it increases fluidity of the liquid slags. Calcite and fluorite are examples of flux materials used for the ironmaking, steel refining and continuous casting process. Oxide systems based on CaO - CaF2 - SiO2 - Al2O3 - MgO cover most of the slag composition in ferrous metallurgy accordingly. Crucial operating factors for ironmaking and steelmaking slags are basicity (typically CaO/SiO2 ratio), viscosity and impurity levels. These are extensively controlled by the fluxes. General metallurgical fluxes such as limestone, dolomite and calcium fluoride are abundant in nature and supplied to steel mills at low prices. Meanwhile, in copper flash smelting process, silica is supplied with copper concentrate to remove iron oxide (FeO) generated from sulfide oxidation. FeO - SiO2 binary system formulates eutectic area at 25–38 pct of silica that has low melting temperature below 1205°C. Fayalitic system (Fe2SiO4) that has low viscosity (0.1 Pa·s) (Park et al., 2011) facilitates easy separation of slags from molten sulfide mattes. Recently, copper plants actively utilize recycled raw materials as a flux. Various recycled glasses are ground and fed to copper smelting process as a partial replacement of silica ore. Applying industrial wastes to smelting processes is advantageous since the operators can reduce the production cost remarkably. Not to mention the consumption of recycled materials can ultimately minimize the environmental risks and the waste management costs. The authors, therefore, investigated the reasonable waste materials that can be effectively used for ferronickel smelting process. Prerequisites for potential fluxing materials are non-recyclable property, low transportation cost and excellent performance as a flux."

Jan 1, 2017

By M. J. S. Innes

Abstract This paper is an account of an investigation made by the Dominion Observatory with a gravity meter and magnetometer over sulphide concentrations at East Sullivan, Val d'Or, Que., in June, 1947. The topographic relief over the area does not exceed 20 feet. The overburden varies from 0 co 50 feet. The west orebody had been outlined by extensive drilling. The average density contrast between the sulphide body and surrounding rocks is 0.5. Two hundred and sixty gravity and one hundred and ninety magnetic stations were observed. The results are shown on contour sketches. A derailed account is given of the methods employed to reduce the gravity observations. The survey shows that both gravimetric and magnetic methods are useful in delineating sulphide deposits under the conditions in which they occur at East Sullivan. The results indicate that the buried contact of the syenite intrusive southeast of the orebody could be traced with the gravimeter and chat the magnetometer was of little value for that purpose. Gravity anomalies due to the varying depths of overburden are negligible as compared to the magnitude of the total anomalies. Introduction The project was first suggested at a meeting of the Associate Committee on Geophysics of the National Research Council in September, 1946. At that time it was pointed out that the accuracy and speed of operation of the new gravity meters made them of special importance for geophysical prospecting and it was highly desirable to have an objective test of the performance of an instrument of this kind in delineating an orebody of known dimensions and density characteristics. Several years ago, a private company did some work with a gravimeter over the Amulet deposits, near Noranda. Unfortunately, the topography there is rather rugged, with hills and ravines exceeding 100 feet, so that the topographical effects rendered it impracticable to distinguish between anomalies due to the sulphides and those due to surface irregularities. An orebody of a typical nature, where the disturbing topographical corrections were not excessive, was therefore sought.

Jan 1, 1949

By H. Sato, Y. Sato, T. Ooishi, K. Sakamoto

"Sumitomo Metal Mining Co., Ltd.(SMM)'s Niihama Nickel Refinery(NNR) produces high quality Nickel cathode, Cobaltcathode and other by-products using hydrometallurgical refining process called “MCLE”(Matte Chlorine Leach and Electro-Winning). In 2005,NNR started to use nickel and cobalt mixed sulfide (MS) produced by one of the SMM’s subsidiaries Coral Bay Nickel Corporation(CBNC)’s HPAL plant in Philippines, although its main and the only raw material until then was nickel matte. With start-up of the second HPAL plant at Taganito in 2013, NNR expanded its production capacity of nickel cathode from 41,000 to 65,000 tpa and finally achieved its target in 2015 by producing 65,980 tpa. SMM developed the technologies to improve poor reactivity of MS and installed new facilities to cope with increased Cobalt and Sulfur production at that time. This paper describes the technical approach to increase MS treatment with high efficiency.INTRODUCTIONThe Sumitomo Metal Mining Co., Ltd.(SMM)Niihama Nickel Refinery(NNR) produces Nickel cathode, Cobalt cathode and other by-products using Matte Chlorine Leach and Electro-Winning (MCLE) process technology. SMM uses nickel matte and nickel & cobalt mixed sulfide (MS) as raw materials for the MCLE process. Table 1 shows typical composition of these raw materials. Nickel matte had been only raw material until 2005, and with start-up of Coral Bay Nickel Corporation (CBNC) operation in the Republic of the Philippines, MS became major part of it. In 2009, when CBNC doubled its production capacity, NNR also expanded its plant capacity of electrolytic nickel from 36ktpa to 41ktpa, keeping an eye on the possibility of 65ktpa with oncoming SMM’s second HPAL in Philippines. Poor reactivity of MS was the prime concern at that time because our intention was to increase production with MS. Nickel extraction rate deteriorated with increasing usage ratio of MS in raw materials. To keep high nickel extraction rate under high ratio of MS, NNR developed a new leaching technology. Another concern arising from treatment of MS was Cobalt and Sulfur contents that are much more than those of nickel matte as shown in Table 1.NNR introduced new technology of solvent extraction process as to Co/Ni separation process in order to keep cost competitiveness instead of the conventional cobalt oxidation–neutralizing method. As to sulfur products, new sulfur productive facility was installed to improve the exposure to sulfur dust and the hot working conditions for workers. As a result of process development and installation of new facilities against the problem with MSusage,65 ktpa production was achieved in 2015."

Jan 1, 2017

By George H. Bodfish

This paper begins with a short history of air compressors, emphasizing their "roots" in the mining industry. It then describes the types of compressors available, including reciprocal, the various rotary positive-displacement compressors, and the centrifugal. The advantages and disadvantages of selecting a certain type of compressor over another are enumerated, considering customer requirements and operating costs, among other factors. Guidelines to operation and maintenance are discussed, including installation, monitoring and maintenance procedures. Finally, the paper addresses itself to future trends, with special attention being given to the system concept, the increasing use of rotary compressors, power consumption, reliability, packaging and noise attenuation.

Jan 1, 1978

By J. Dennett, M. Faris, M. Antonio, M. Collins, N. Tuffrey, R. Ellenwood, V. Reddy

"In January 2012, AngloGold Ashanti Córrego do Sítio Mineração, with assistance from Sherritt International Corporation, commissioned a new autoclave for pressure oxidation of refractory gold concentrate at the Córrego do Sítio operation in Brazil. Start-up of the plant occurred in a few weeks and enhanced gold recovery was realized almost immediately, with 94% gold extraction achieved in carbon in leach (CIL), compared to less than 70% without pressure oxidation. This paper describes start-up and commissioning of the plant and provides an overview of plant performance over the last five years.INTRODUCTION In 2008, AngloGold Ashanti purchased the former São Bento property from Eldorado Gold, which, along with AngloGold Ashanti’s existing Córrego do Sítio mine, was renamed AngloGold Ashanti Córrego do Sítio Mineração (AGA Mineração). Later that year, the Sherritt Technologies division of Sherritt International Corporation (Sherritt) was contacted to begin batch and continuous pilot plant tests to determine the amenability of the AGA Mineração refractory gold concentrates to the pressure oxidation process. Based on the results of the batch and pilot plant tests, AGA Mineração requested basic and detailed engineering studies to be conducted by Sherritt, eventually leading to commissioning of the plant in January 2012. AGA Mineração’s plant is located in southeastern Brazil in the state of Minas Gerais, near the city of Belo Horizonte. AGA Mineração`s Phase 1 mine plan covers three sites in the Laranjeiras, Carvoaria Velha and Cachorro Bravo ore bodies, and is designed to process 60,000 tonnes of refractory gold concentrate per year to produce 140,000 ounces of gold per year with an 11 year life of mine (AngloGold Annual Financial Statements, 2010). Recovery of gold at AGA Mineração is based on Sherritt`s pressure oxidation technology for refractory gold concentrates (Berezowsky et al., 1991; Collins et al., 2011a; Collins et al., 2011b). This process had previously been applied to the recovery of gold at the São Bento site (Carvalho et al., 1988; de Silva et al., 1989), in a plant that was operational between 1986 and 2007 (Silva et al., 2004)."

Jan 1, 2017

By S. H. Seyedein

A mathematical model was developed to study fluid flow and solidification in a single-roll casting system. Fluid flow coupled with energy equations were solved numerically using a finite volume method. A body-fitted coordinate transformation technique was adopted to handle the irregularly shaped domain. In order to couple the continuity and momentum equations, a SIMPLEC algorithm was used. A fixed-grid enthalpy method was considered to model the solidification in the system. The turbulence effect on flow field was modeled using a low-Re k-e model The model developed in this work was further run under various conditions to optimize the operating parameters of the process.

Jan 1, 2004

By F. Rashchi, A. Ghahreman, J. Moghaddam, S. Karimi

"In this work, the kinetics of ferric-ferrous redox reaction on a passivated sphalerite electrode is studied by the application of chronoamperometry method in 0.5 mol L-1 H2SO4 solution. The electrochemical behaviour of ferric and ferrous couple was investigated on two sphalerite minerals acquired from two different geological regions (Iran and Canada). The carbon paste electrode (CPE) of sphalerite was initially prepared and passivated in 0.5 mol L-1 H2SO4 solution and after reaching the steady-state condition, ferric and ferrous sulfate solution was added. The registered current density differences between the current density of the passivated electrode and that of the electrode in the iron salts added solution were interpreted for kinetics of ferric-ferrous reduction-oxidation reaction. The equilibrium potential for ferric-ferrous couple on sphalerites surface was about 500 mV vs. Ag/AgCl. The exchange current density (i0) for ferric-ferrous redox reactions on the sphalerite samples had the same magnitude of 10–6 A cm–2. The electrochemical impedance spectroscopy (EIS) measurements at 550 mV vs. Ag/AgCl illustrated that sphalerite oxidation was controlled by two charge transfer process in both of Fe-free and Fe-containing solutions. The charge transfer resistance remarkably decreased when Fe salts added to the 0.5 mol L-1 H2SO4 solution, owing to the ferric-ferrous redox reactions being the predominant reactions on sphalerite surface.INTRODUCTION Direct atmospheric leaching processes for sphalerite concentrates are performed by reduction of an oxidant (e.g. ferric ion and oxygen) and oxidation of sphalerite to zinc ions. Oxygen could be an oxidizing agent as well, but the concentration of oxygen is very low in the solution. The role of ferric ions is predominate in this oxidation (Babu, Sahu, & Pandey, 2002). The oxidation reaction for sphalerite in the presence of ferric in can be presented as follows (Lampinen, Laari, & Turunen, 2015):"

Jan 1, 2017

By Robert J. Shank

This paper describes the Federal Government assistance available for northern mining development. The paper commences with a discussion of why the Federal Government should give assistance to northern mining development. It then uses a hypothetical case of a company which has a property it wants to develop to list the sectors within the . Federal Government that would have to be consulted in order to obtain federal financial assistance. The paper also outlines the type of information a company must be willing to provide the government in order to qualify for such assistance.

Jan 1, 1978

By Craig Faulkner

Discharge cones for large Semi Autogenous Grinding (SAG) and Autogenous Grinding (AG) mills are subjected to high wear as significant volumes of ground ore and slurry exit the mill. With the larger diameter mills of 32ft to 40ft in size becoming the norm, very high, concentrated wear is highlighting the limitations of conventional discharge cones and frequent changes are subsequently required. This paper outlines the advances made in the design of the Bullnose discharge cone. Superior wear materials to increase wear life over conventional rubber or chrome-moly steel discharge cones and the introduction of key design features to reduce reline times and improve fit and safety during installation, offer significant opportunities for the mill operator. Collated from multiple case studies, the wear data and reline history from 2004 to present clearly illustrate the way in which superior component longevity has reduced the frequency of relines over the life of the product to increase mill availability and effectively increase the tonnes milled in a period.

Jan 1, 2012

By M. Potesser

In the past, different furnace types have been developed for use within the copper industry, with two common anode furnace designs typically used in copper smelting plants worldwide: the tiltable reverberatory furnace (KPO) generally used for the secondary copper industry and the cylindrical or drum type anode furnace (TRO) for handling a liquid blister charge generated in primary copper production. The disadvantage of the KPO is its design related to the longer refining period, because of the low bath depth, however it provides good conditions in the melting period due to its large bath surface. On the other hand, small amounts of scrap charged into the TRO increase the melting and dissolution period, but it provides good conditions for the refining period. The newly-developed elliptical furnace concept (TRE) offers the advantages of each of these furnace types. The special design allows melting of the scrap more efficiently than in the KPO and refining the liquid copper more efficiently than the TRO. This paper shows a metallurgical comparison of the three furnace types in regard to the melting period by heat technological considerations (optimized arch design) and of the refining period done by CFD with concentration on current, recirculation and dwell time of the gas in the melt. The paper outlines the possibilities for a reduction of the tap-to-tap time and energy consumption as well as for an increase of the production capacity, which can be achieved by applying the TRE instead of the conventional furnace designs.

Jan 1, 2007

By M. Feinendegen, Ph. Siebert, C. Clauser, K. Willbrand, M. Ziegler

"Three institutes of RWTH Aachen University collaborate on laboratory tests and numerical simulations of hydraulically driven fractures in igneous rocks. The project´s target is to enhance the understanding of hydraulic induced fractures for deep geothermal energy exploration. Based on the idea of creating new discrete fractures in hot dry rock (HDR) reservoirs, the current project stage deals with this process on a laboratory scale. Especially for this purpose, a new testing facility has been developed and laboratory tests are performed to verify a hydraulic fracture propagation code based on the extended finite element method (XFEM). The testing facility enables us to initiate and propagate fractures in large samples of dense rock under triaxial confining pressures and to monitor the fracture propagation by extensive measurements. This contribution gives a short introduction to the project‘s background and mainly focusses on the test facility, the experimental procedure and exemplary results.INTRODUCTIONThe most efficient technique to increase the permeability of subsurface rock is to initiate and open fractures by applying hydraulic pressure from a packed borehole-section and to inject fluid into these fractures to propagate them. Since its first use in petro industries to enhance the production of wells in natural gas and oil reservoirs, the interest in targeted creation of hydraulic fractures has increased exponentially. As the key technology to the extraction of unconventional gas from shale, hydraulic fracturing (HF) became a major topic in a heated public debate. Based on the fact that a fracture tends to propagate in a direction perpendicular to the minimal principal stress, hydraulic fracturing has become an established tool for estimating geological stress states in almost any depth. Enhanced geothermal systems (EGS) in HDR reservoirs use engineered fractures as a heat exchanging system for a cycling fluid driving a power plant."

Jan 1, 2015

By Fathi Habashi

Extraction by organic solvents is a chemical process in which metal species in the aqueous phase react with an organic reagent to form an organometallic com- plex, thus, the metal species leave the aqueous phase and enter the organic phase from which it can be stripped back in the aqueous phase to obtain a pure and a concentrated solution. The metal in the organic phase is not bound to carbon atoms as in organometallic compounds but to oxygen, nitrogen, sulphur, or hydrogen by a co-ordination (dative) bond (Habashi, 1999).Solvent extraction was used for the first time in hydrometallurgy in connec- tion with the special and urgent materials requirements of nuclear energy during World War II. A plant was constructed in the United States for the preparation of high-purity uranyl nitrate solution. In this plant, the yellow cake (a high-grade sodium or ammonium uranate) was dis- solved in HNO,, and uranium was selec- tively extracted by ether then stripped by water to give a concentrated solution of pure uranyl nitrate. This was gradually followed by developing methods for other high-priced metals such as plutonium, thorium, niobium, tantalum, zirconium, hafnium, boron, beryllium, and molybde num. The second step took place in the 1960s when solvent extraction was applied for the first time to extract a rela- tively cheap metal-copper. At present, solvent extraction technology is wide- spread, well accepted, and highly efficient. Solvent extraction had its origin in the discovery, by Christian Friedrich Bucholz (1770-1818) in 1805, that uranyl

Sep 1, 1999

By E. Tulcanaza

Mining companies normally establish exploration and research programs originated with actions in embryonic stage. At their early stages of development, these exploration and technological activities are subject to uncertainties that need, first, to be resolved, deciphered or, at least, mitigated for information reporting; and later, for valuation reporting. Under these circumstances, these exploration activities follow a sequence of development phases that range from exploration work to the profile, conceptual, and finally to basic engineering phases and construction. For information reporting, the International Template for Reporting of Exploration Results, Mineral Resources and Mineral Reserves integrates the minimum standards being adopted by the relevant professional bodies in Australia, Canada, South Africa, Chile, USA, UK, Ireland, and other European countries which set up the Committee for Mineral Reserves International Reporting Standards (CRIRSCO, www.crirsco.com). These standards are based on the progressive collection of relevant information to reduce present and future uncertainties over time under a context of transparency, materiality, and technical competence. For valuation reporting several procedures have been disclosed and applied. However, in the last decades financial instruments such as real options, decision analysis, and games theory have developed into a niche of great potential for mine valuation applications. The objective of this paper is to provide a summary of the information reporting standards prepared by the Chilean National Commission for the Qualification of Competent Persons in Mineral Resources and Mineral Reserves and show a procedure and an application of real options to the valuation of the sequential development phases of a mine asset from the exploration stage through up to full development.

Jan 1, 2007

By John I. Sharpe

Masses of pyritic copper and zinc ores are entrapped along the contact zone between two volcanic groups in the Matagami area. The upper limits of the sulphide concentrations tend to form concordant contacts against lava or cherty tuffite units of the younger group; the lower extremities tend to either follow transverse structures or merge with zones of dispersed sulphides. The sulphides are deformed and intruded by folded dykes. Close relations between metallization boundaries and volcanic lithology and stratigraphy, and a preliminary investigation of the fabrics and crystallization temperatures of the sulphide masses, suggest that the copper and zinc (but; not necessarily all the iron sulphides) were emplaced at h1gh temperatures during volcanism in near-surface lithological-stratigraphic traps. Introduction T HE Matagami area is centered 120 miles north of the Val d'Or and Noranda camps in north-western Quebec. For the present purpose, it is considered to comprise a 155-square-mile area in Isle-Dieu, Galinee and Daniel townships which encompasses the main sulphide masses. Airborne geophysical surveys within this area in 1956 led to the discovery of a large sulphide body -the.

Jan 1, 1965

By Farzad Khodabakhshi, Adrian P. Gerlich

"Multi-pass friction stir processing (FSP) was performed to fabricate a new Al-Mg-Graphene nanocomposite. Microstructural developments and distribution of graphene were studied by using electron backscattering diffraction (EBSD) and transmission electron microscopy (TEM) analysis. In the stirred zone (SZ), grain structure was refined down to about 2 µm attributing to the operative dynamic restoration mechanisms and the locking effect of graphene phase. As a result, the yield strength of Al-Mg alloy was improved more than two times due to incorporation of graphene nano-sheets. Also, the indentation hardness resistance of nanocomposite was increased up to ~60%.INTRODUCTION Aluminum-matrix nanocomposites have garnered significant in recent years due to their superior performance and potential advantages for several industrial applications including the automotive and aerospace sectors. Among various reinforcing nano-materials, carbon-based structures featuring sp2 or sp3 hybridization bonds have been found to offer considerably improved physical and mechanical properties. Such carbon allotropes form at micro- and nano-scales including; graphite, carbon nano-tube (CNT), nano-fiber, and graphene. The potential of two-dimensional (2D) carbon materials was introduced in 2004, with the development of graphene as an alternate 2D allotropic form of the carbon structure with a honey-comb lattice at the atomic-scale. It has been shown that it is currently among the strongest materials ever tested with an intrinsic tensile strength of 130 GPa and Young’s modulus of 1000 GPa, and also offers unique thermal and electrical properties.To fabricate metal-matrix nanocomposites reinforced by graphene nano-sheets with typical metallurgical processing techniques, some attempts have been reported in the literature for various solid-state techniques including; hot rolling, mechanical alloying, and friction stir processing (FSP) of pre-cast plates or surface dispersed graphene oxides. The main challenge in those methods was to facilitate the considerable high temperature and pressure for attaining a uniform dispersion of the nano-sheets during the consolidation process. In most cases, significant difficulties have been reported in obtaining a uniform dispersion of graphene within the metal matrix. Among various techniques for production of metal-matrix nanocomposites, FSP has attracted significant attention as a method of surface modification since it was first reported by Mishra et al. In this process, a non-consumable rotating tool is plunged into the surface of material for the aim of microstructure modification. Extreme material plasticity is induced without melting as a result of friction between the tool and workpiece. Frictional heating and severe plastic deformation induced by the FSP process enables metal matrix nanocomposite fabrication by softening the base material and mechanical stirring to disperse the reinforcing nano-materials into the matrix."

Jan 1, 2017

By Donald L. Mordell

Introduction A very large part of the world's fuel resources are in solid form, as various grades of ?coal, but an increasing proportion of fuel demands on this Continent and else-where are having to be met by liquid fuels. Convenience and, in many cases, cost weigh heavily in favour of the liquid: fuels, and there are many fuel burning applications where the use of coal would be impractical, such as for automotive or air transport. By extrapolating the present trends one might conclude that, in future years in Canada and the United States, coal will be used only in a few power stations close to coal fields. If such a state of affairs should arise, it will obviously prove embarrassing to those accustomed to make their livelihood from the winning and marketing of coal, but it is perhaps not so obvious that it must also prove an embarrassment to the nation. The major reasons for this are two in number. Firstly, if present coal production is to be replaced by oil production, a large capital expenditure is necessary, which must inevitably be paid by the consumer; and secondly, in times of emergency, large amounts of oil fuels are required for military purposes which cannot be achieved with solid fuels. It is obviously unwise, therefore, to discontinue the use of coal for those non-military jobs that it can do. If we examine the major fuel markets we find that there are three: Domestic heating Steam generation Transport by air, sea, and land For domestic heating, the extreme convenience of oil, in spite of its greater cost, has captured much of the coal market.

Jan 1, 1952

By S. Bantubani, I. Mc Dougall, S. Arjun, H. Joubert, R. Hansraj

The requirements determining the design of the Söderberg electrode columns used in base metal applications are different to those of other industries. There is a strong trend to position the contact shoes above the furnace roof in order to reduce the risk of water leakages directly onto the furnace bath. Tenova Pyromet has adapted its proven electrode column design for application on base metal electric furnaces based on these requirements. The design modifications implemented as well as considerations regarding the overall electrode-roof-furnace arrangement are discussed. Equally important is the management of the Söderberg electrodes to prevent over or under baking. Tenova Pyromet has developed the AutoFurn™ furnace controller to not only optimise furnace operations, but to improve electrode management. An overview of the electrode management control philosophy implemented by AutoFurn™ is provided, focusing on intelligent electrode regulation, slipping and baking. INTRODUCTION Tenova Pyromet has developed an electrode system for use in base metal furnaces, which builds on the experience that Tenova has gained during the past 30 years with electrodes in the ferroalloy and base metals industries. In base metals applications, an important safety consideration is the minimization of water within the furnace and on the furnace roof. In addition, direct contact between copper equipment such as contact shoes and pressure rings and the contents of the furnace is discouraged. In a 3 phase AC furnace, three electrode columns transfer the electrical energy to the furnace bath. Both Söderberg and prebaked carbon or UHP graphite electrodes are in use in base metal furnaces. In each column, the electrode is held in position by a hydraulic slipping and regulating device, a pressure ring and contact shoes. The electrodes can operate in a submerged-arc or brush-arc configuration, where the electrode is immersed in the slag or a short distance above the slag (Mc Dougall 2013). The electrode equipment is divided into an upper and a lower electrode assembly. The self-baking Söderberg electrode is made from lengths of steel casings that are added to the top of the electrode column and welded into place. Carbon electrode paste is added to the inside of these casings and is baked to form a solid tip in the region of the contact shoes. The working platform that surrounds the area where new electrode casings are added, is electrically isolated from the building and each electrode is isolated from the others to ensure the safety of the personnel who perform the electrode casing additions.

Jan 1, 2019

"The successful commissioning and ramp up of the Albion Process™ at the GPM Gold Project relied on the successful scaling up of the process from batch and continuous pilot plant campaigns (Voigt et al., 2015). Critical information about reaction kinetics and residence time, grind size and pulp density were determined at the laboratory scale and successfully applied to the commercial scale. A limitation of small scale testwork, is that some parameters cannot be measured reliably and scaling up is a function of the physical size of the equipment which isn’t possible to test with laboratory scale equipment. Oxygen mass transfer rate is one such parameter since this is a complex interaction of many factors including slurry temperature, solution and slurry chemistry, slurry viscosity, agitator type, dimensions and power, oxygen bubble residence time, oxygen purity, tank geometry and oxygen injection technique. Oxygen generation represents an important operating cost for the Albion Process™. Pivotal to the Albion Process™ operating economically at atmospheric pressure is the capability to efficiently transfer oxygen while utilising as much oxygen injected to the process as possible. To respond to this Glencore Technology developed the HyperSpargeTM supersonic gas injector. This paper compares the HyperSparge™ against other sparging techniques to quantify the benefits of oxygen injection via a supersonic gas jet on scale up of the oxygen mass transfer system. The paper then examines plant survey data from the GPM Gold Project to demonstrate the very high oxygen utilisation that can be achieved with a correctly designed oxygen mass transfer system.INTRODUCTION One of the main challenges in chemical reactor design is the scale-up of processes from the laboratory to industrial scale. Processes which cannot be faithfully simulated with an experiment at the laboratory scale face challenges due to the physical dimensions and complexity of full scale operation. One example of this is the design of oxygen mass transfer systems in atmospheric oxidative leaching circuits such as the Albion Process™. A number of constraints associated with the use of laboratory scale equipment to design full scale circuits are involved in gas mass transfer processes in agitated slurries such as the Albion Process. Chiefly, typical laboratory and pilot size equipment lacks the required volume to provide useful design data without relying on empirical correlations: the specific agitator power input is artificially high, the bubble residence time in the vessel is artificially low, the oxygen partial pressure at the base of the vessel is artificially low and the oxygen delivery method may differ significantly to the industrial process. Further, the dynamic nature of the process introduces additional impacts on gas mass transfer, including the presence of solids, recycle streams and minor elements, plus the variances within the reality of a process plant such as disruptions or variance of feed quality."

Jan 1, 2017

By V. G. Papangelakis, T. Clark, G. Kolliopoulos

Sustainability of the hydrometallurgical industry requires the development of processes for effective water recovery; if process water is recovered and recycled, fresh water intakes will be reduced. Forward osmosis (FO) is an innovative membrane process that promises to recover water from industrial process aqueous streams or seawater with less energy input compared to reverse osmosis (RO) and evaporation; the energy efficiency relies on the spontaneity of the process (no energy input required). The driving force of the process is the osmotic pressure gradient between a dilute feed solution (process water) and a concentrated draw solution. The draw solution is an engineered aqueous solution that contains a highly soluble chemical reagent that is able to osmotically "draw" only water from the dilute stream, through a semi-permeable membrane, leaving behind a small volume of concentrated brine. The draw solute is separated and recovered for reuse, leaving behind water. The main energy requirements of the FO process arise from the separation and the regeneration of the solute chemicals from the diluted draw solution. This work focuses on the evaluation of aqueous carbonated trimethylamine (TMAH:HCO3) as the draw solution and reports recent findings on the separation efficiency of TMA and CO2 from the solution.

Jan 1, 2015

By A. Navarra, C. Arrancibia, R. Yañez, C. Acuña, F. Valenzuela

"Discrete event simulation (DES) is a suitable framework to evaluate and optimize the dynamics of sulphide smelters. In particular, iron-nickel-copper-cobalt sulphides undergo continual oxidation within a roasting or smelting operation, followed by batch oxidation within the converting operation, thus producing iron-free Bessemer matte (or blister copper, in the case of copper smelters); this semi-finished product undergoes further processing to produce nickel, copper and cobalt products, and to recover precious metals. The juncture between continuous smelting and batch converting is often an appropriate focus for the earliest phases of DES development, since it is typically a major bottleneck within nickel and copper smelters; later phases may include increasing levels of detail for auxiliary unit operations, as well as plant logistics. Moreover, DES can support matte-slag chemistry, including Gibbs free energy balances to determine the iron speciation within the slag. DES is therefore capable of linking the fundamentals of oxidation reactions to the intricacies of plant dynamics.INTRODUCTION Discrete event simulation (DES) is gaining acceptance within the extractive metallurgy community, as a technique that quantifies the system-wide performance of metallurgical plants under conditions of uncertainty (Wheeler & McGinty, 2015). In particular, over 90% of smelters that process nickel-copper-cobalt sulphides and copper sulphides exhibit similar semi-continuous dynamics (Crundwell et al., 2011b; Schlesinger et al., 2011b), in which the converting aisle produces batches of material that are sent for further processing (Figure 1). Thus the tools and practices that are developed for a specific sulphide smelter are often relevant to numerous other smelters.The juncture between continuous smelting and batch converting has long been a focus for discrete event simulation (Welgama et al., 1996). Nonetheless, the broad acceptance of DES in nonferrous smelters has been hindered by interdisciplinary barriers that divide industrial and metallurgical engineers (Navarra et al., 2016; Noorossana et al., 2012); this divide has been less severe in steel plants (Hollocks, 2006). In recent years, DES has been used in copper smelters to analyze crane-and-ladle motions (Coursol et al., 2009a), reverts production and consumption (Noorossana et al., 2012), and innovative control systems (Herrera et al., 2016); additionally, DES models have accounted for shutdowns and random breakdowns to provide realistic assessments of copper smelter capacities, thus guiding equipment upgrades (Campbell et al., 2013; Coursol et al., 2009a). All of these studies feature a Peirce-Smith converting aisle similar to Figure 1 that, under normal operations, constrain the smelter throughput, and are thus a bottleneck (Campbell et al., 2013; Navarra et al., 2016)."

Jan 1, 2017