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By C. H. Fisher, M. L. Fein, A. Eisner, G. C. Sprunk, Loyal Clarke, H. H. Storch

"The large reserves of low-rank coals in the western United States are at a disadvantage in competing with the more mature but less plentiful eastern coals, which are nearer important markets and are more suitable for combustion and coke production. However, low-rank coals generally are amenable to hydrogenation, and the western coals might become an important source of liquid fuels and organic chemicals when petroleum is less plentiful.In view of these facts an the tremendous quantities available, further information on the western coals clearly desirable. The purpose of the work described in this paper was to study the hydrogenation characteristics of some of the low-rank western coals in discontinuous converters. The data obtained in this manner, which are inadequate for predicting the suitability of coals for large-scale continuous hydrogenation, were used as a basis for selecting samples for further study in the Bureau's experimental coal-hydrogenation plant (26, 35). 8/ Because of the general importance of the western coals and recently demonstrated relation between coal hydrogenation and petrograghy (14, 15, 16), the proportions of anthraxylon, (vitrain), translucent attritus, and opaque matter were determined. In some instances samples of anthraxylon were isolated and hydrogenated separately so that their properties might be compared with those of the entire coal. The samples studied include peat, brown coal, lignite, sub-bituminous coals, and low-rank bituminous coals."

Mar 1, 1940

In the spring of 1944 the Congress passed Public Law 290 (58 Stat. 190, 30 U. S. C. Sec. 321) "authorizing the construction and operation of demonstration plants to produce synthetic liquid fuels from coal, oil shales, agricultural and forestry products, and other substances, in order to aid the prosecution of the war, to conserve and increase the oil resources of the Nation, and for other purposes." Section 2 reads: "In order to carry out the :purpose of this act, the Secretary of the Interior is authorized- (a) to conduct laboratory research and development work, and, with pilot plants and semi-works plants, to make careful process engineering studies, along with structural engineering studies, in order to ascertain lowest investment and operating costs necessary to determine the best demonstration plant designs and conditions of operation;

Jan 1, 1948

By Vernon O. Markworth

This report contains the results of tests performed on three large diesel engines to determine their ability to meet selected criteria of the Mining Enforcement and Safety Administration Regulations for equipment used in gassy, non-coal mines. Study efforts were first directed toward determining the types of equipment expected to be used in underground oil shale mines. Three typical engines in the 800-1200 horsepower range were then selected for testing. Intake flame arresters, exhaust scrubbers, and water jacketed exhaust system were designed and built for each engine. During testing, each engine was evaluated for its gaseous emissions output, adequacy of the exhaust gas cooling system, ability to withstand internal explosions, and adequacy of the flame arresters. Surface temperatures of the engine and exhaust cooling system were determined under full load operation.

Jan 1, 1978

By David Schlain

"INTRODUCTION Electrolytic manganese is produced by electrolysis of a solution of manganese sulfate and ammonium sulfate in a diaphragm-type cell, metallic manganoese being deposited on the cathodes and sulfuric acid produced at the anodes. The spent electrolyte is used to leach fresh ore that has previously been subjected to a reducing roast; the resulting leach liquor is purified and returned to the cell.The leach liquor produced at the Bureau of Mines pilot plant 3/ at Boulder City, Nev., contains 135 to 140 grams of ammonium sulfate and 32 to 36 grams of manganese (as sulfate) per liter, and has a pH of about 2.5. After neutralization to a pH of 6.4 to 6.6 with ammonia and thickening, 0.10 to 0.15 gram of hydrogen sulfide per liter is added to the liquor to precipitate the heavy metals, and after 15 to 30 minutes the precipitate is filtered off. Residual sulfides and colloidal material are removed by ferric hydroxide formed by adding a small amount of ferrous sulfate to the solution at a pH of 6.5 to 7.0 and passing air through it. The solution is then filtered and clarified as a precoat filter. Finally, 0.1 gram of sulfur dioxide per liter is added, and the solution is electrolyzed in an anode-in-diaphragm cell. The spent electrolyte coming from the cell contains approximately 10 grams manganese, 135 grams ammonium sulfate, and 45 grams sulfuric acid per liter."

Oct 1, 1946

By D. D. Walker

Scheelite, the most abundant tungsten mineral in the Philipsburg region of Montana, is found in replacement deposits and along fissures and cracks in limestone at various distances from contacts with acidic igneous rocks. It also occurs at the limestone-igneous contacts, but typical garnet tactites are developed in only a few places in the region. The most favorable host rocks for scheelite mineralization are the Jefferson, Hasmark, and Madison limestones. Scheelite is exposed in float, outcrops, and surface and mine workings along a 2-mile-wide belt extending southwest from Lost Creek beyond Silver Lake, a distance of 15 miles or more. (See fig. 1.) Some scheelite is found in veins formerly mined for silver. Powellite and molybdenite occasionally are present with the scheelite. Hubnerite occurs in quartz veins in the Black Pine area 10 miles northwest of Philipsburg. These quartz veins occur in the quartzites of the Precambrian Spokane formation. Tungsten production in the region has come almost exclusively from scheelite deposits, both lode and placer. During a 6-year period beginning in 1943 a total of 142.0 tons of 63-percent W03 concentrate was produced by H & H Mines Co. In the early 1950's, the Trigger mine produced 4,000 tons of 1-percent W03 ore and the Tip Top 650 tons of 2.0-percent W03 ore and 2,906 tons of 2.2-percent ore. There has been sporadic production from some of the smaller properties in the area.

Jan 1, 1960

By F. F. Netzeband

This report relates to the sulfur industry of seven States--Arkansas, Kansas, Louisiana, Mississippi, Missouri, Oklahoma, and Texas--and is part of a national study of the sulfur industry by the Bureau of Mines. Markets as used 1n this report are divided into two components for individual analysis--(1) supplier markets which include regional Frasch and byproduct sulfur producers and (2) consumer markets which include processors and manufacturers requiring sulfur in their operations. The term sulfur as used in this report includes brimstone, native sulfur, elemental sulfur, or sulfur equivalents.

Jan 1, 1964

By Gordon Bath

During the summer of 1946, the Division of Geophysical Exploration of the U.S. Bureau of Mines established several primary magnetic base stations near important iron-producing districts in Minnesota, Michigan, and Wisconsin. Stations were located in groups of four to six in six separate base-station areas, and each position was marked with a concrete monument. Differences in magnetic intensity between stations in these areas, as well as the difference between each area and a magnetic datum at the magnetic observatory of the Coast and Geologic Survey at Cheltenham, Md., were measured with a modified Askania magnetometer. Measurements also were made with a Hotchkiss superdip to study the usefulness of the stations for the calibration of instruments of this type. The work was planned and supervised by F. W. Lee, chief of the Division of Geophysical Exploration, and Edward F. Fitzhugh, Jr., chief of the Minneapolis Division of the Bureau of Mines. Special mention is due Harold B. Ewoldt, Bureau of Mines engineer, for his assistance in the field work, especially in locating and establishing monuments. Special mention also is due Clyde L. Holmberg, of the Bureau of Mines, for the magnetic measurements made with the Hotchkiss superdip. Helpful suggestions were received in the field from H. L. James, of the U. S. Geological Survey. Acknowledgment is made of the cooperation of Stephen Royce, Irving E. Beckwith, Arthur Johnson, and Josiah Royce of Pickands, Mather & Co., and A. E. Matson, of Butler Bros. The U. S. Coast and Geodetic Survey furnished daily magnetograms from the Cheltenham Magnetic Observatory as well as calibration equipment and values of absolute magnetic intensity. Short-term forecasts of ionospheric conditions were obtained from the National Bureau of Standards.

Jan 1, 1951

By N. A. Eilertsen

The Aroostook manganese-bearing deposits lie within a rectangle 30 miles wide and 70 miles long. Over 40 different deposits have been discovered in this area, but they have not been mined because the ores are difficult to treat. In 1949, the Maple Mountain area was selected for detailed investigation by the Bureau of Mines, because study by the State of Maine and the Federal Geological Survey indicated that it was the most promising in Aroostook County for developing a large tonnage of reserves. Investigation by the Bureau of Mines disclosed that all of the reported deposits of the central district were located on the limbs of a syncline underlying a pear-shaped area of 283 acres between the crests of Maple Mountain and Hovey Mountain. The ore area has been outlined by trenching and drilling along three sides of the perimeter, while the remaining side is defined by a fault. The area has a length of 6,300 feet and a maximum width of 3,100 feet. Diamond-drill holes have intersected the deposit as deep as 1,550 feet below surface, but additional deep drilling would be required to determine the intensity of folding or warping at depth. The Maple Mountain-Hovey Mountain deposit lies in the slates of Ordovician age and is classified into three zones, of which the upper, averaging about 57 feet thick, is designated manganiferous purple and red slate. The central zone, also averaging about 57 feet thick and containing the highest manganese content, is manganiferous, banded hematite. The lower zone is manganiferous, interbedded hematitic and green slate with an average width of about 33 feet. Manganese minerals occur with hematite in all three units. Trenching on the northwestern slope of Hovey Mountain uncovered other disconnected deposits of manganiferous rocks of earlier age than the ore of the syncline. The general strike of these deposits, which range from 15 feet to 75 feet in thickness, is southwest a length of 5,000 feet. They dip steeply southeast. The ore of the syncline is predominantly deep, hematitic red, inclining to red-dish black, fine-grained, dense, and thinly laminated. It is hard and siliceous. Hematite has, in places, been altered to magnetite. Because of the fine-grained texture of the ore, the manganese-mineral constituents are difficult to determine. Of the manganese silicates present, braunite is the most readily identified. Manganese carbonates and oxides are found also.

Jan 1, 1952

By R. A. Cattell

With the activities of the Petroleum and Natural Gas Division geared chiefly to problems directly connected with the war effort , the emphasis of the work under oil and gas development and production was to make engineering studies of selected reservoirs for the Petroleum Administration for War , to determine the extractable quantities of components in them, and to study the characteristics of these components for use in the manufacture of aviation gasoline and other products . The needs of the Petroleum Administration for War and the operators for specific data from gas - condensate fields were fulfilled , and , in addition , engineering data along lines of a forward - looking program of research on reservoir behavior were collected , which should be of great value in the postwar period . It is planned to publish many of these data as soon as conditions permit . The work of the Secondary Recovery Section had as its objectives in- . creasing the rate of production of crude petroleum and , which is more important , preventing the premature abandonment of wells in " stripper " and marginal According to the National Survey of Stripper Wells by the National Stripper Well Association in cooperation with the Interstate Oil Compact Commission , a total of 67,460 stripper wells was abandoned from January 1 , 1935 , to July 1 , 1942 , inclusive , with an estimated loss in proved reserves of approximately 216 million barrels . This survey also indicates that over 1.2 billion barrels of oil would be recovered by primary production from more than 290,000 stripper wells then in operation , and an additional 2.5 billion barrels of oil could be recovered from them by secondary production methods . The work of the Chemistry and Refining Section was oriented towards the optimum utilization of crude oils in the manufacture of aviation fuels for spark-ignition and jet - propulsion engines . The work involved intensive studies of superfractionation , hydrocarbon analysis , and the engine testing of fuels . Particular attention was given to the effect of sulfur compounds in the crude oils and in the fuels made from them . The research on thermodynamics is concerned with the experimental determination of precise and accurate values of the fundamental thermodynamic constants of pure hydrocarbons and related compounds . The data obtained in these investigations will be utilized for devising and improving chemical processes in which petroleum hydrocarbons are the raw materials . Without such data , much time and expensive material and equipment may be wasted in attempts to obtain reactions under conditions that the laws of thermodynamics rule out of consideration . Thermodynamic data are useful and required in the petroleum industry for calculations of heat balances in the design of furnaces , fractionating towers , and heat- transfer equipment . It is of utmost importance , also , to know the heat requirements of cracking and other chemical reactions so that heat may be supplied or dissipated in the proper proportions . These needs for thermodynamic data are being recognized more and more by petroleum -refining engineers . The responsibility for the production of helium for the Navy , the Army , other governmental agencies and non-Federal users is vested in the Bureau of Mines by an Act of Congress ( 50 Stat . 885 ; 50 U.S.c. 161-166 ) . The Helium Subdivision of the Petroleum and Natural Gas Division continued to meet all demands for helium .

Jun 1, 1949

By W. F. Watts

In 1980 the Bureau of Mines developed the Mine Inspection Data Analysis System (MIDAS). MIDAS is a computerized, industrial hygiene data base capable of statistically analyzing environmental data collected in coal and noncoal mines and mills by Mine Safety and Health Administration (MSHA) inspectors or mine operators. The objectives of this report are to describe the current contents of MIDAS, to report analyses of coal and noncoal mine respirable dust samples collected by MSHA inspectors and to evaluate the proposed change in the metal and nonmetal respirable dust standard from a formula based upon the percentage of quartz identified in the sample to 100 µg/m3 of respirable quartz. Based on samples collected by MSHA inspectors, changing the noncoal respirable dust standard would result in 4 pct fewer samples with dust concentrations exceeding the standard. Analysis of respirable coal dust data collected by MSHA inspectors showed that mines with longwall plows or shears had the highest geometric mean concentrations (1.64 and 1.29 mg/m3, respectively). Mine operations using continuous rippers out-numbered longwall mine operations about 10 to 1 and had a geometric mean concentration of 0.66 mg/m3.

Jan 1, 1987

By H. R. Appell

The Bureau of Mines studied the conversion of a variety of cellulosic wastes, for example, sawdust, bovine manure, sewage sludge, urban refuse (free of metal and ceramics), etc., to heavy oils. The objective of the investigation was to determine the scope of the reaction and elucidate the chemistry involved. The reactions took place in the presence of synthesis gas and water or carbon monoxide and water under conditions of elevated temperatures and pressures. Waste conversions above 90 pct, often near 99 pct, with oil yields in the range of 40 to 60 pct, were obtained in the temperature range of 250° to 425° C and pressure range of 1,500 to 4,000 psig. Because mild conditions were sought, most of the experiments were conducted at temperatures of 250° to 350° C and pressures of 1,500 to 3,000 psig. In general, lower viscosity products were obtained at higher reaction temperatures. Conversions and oil yields were significantly increased by operating in the presence of a high-boiling oil; either anthracene oil or oil recycled from the process was satisfactory. Synthesis gas containing 50 pct carbon monoxide gave satisfactory results as a replacement for carbon monoxide. Cobalt molybdate on alumina catalyst, used with sodium carbonate, gave a product of lower viscosity and lower oxygen content than sodium carbonate used as the sole catalyst. The waste-to-oil process has been successfully investigated in continuous flow equipment as well as in batch autoclaves.

Jan 1, 1975

By J. E. Shelton

This presentation covers the results of laboratory studies conducted by the Bureau of Mines Mineral Dressing Section, Northwest Electrodevelopment Laboratory, Albany, Oreg., on alluvial sands from Dismal Swamp, Bear Valley, and Cascade, Idaho. The search for radioactive minerals has led to the reexamination of alluvial deposits; in the process of this reappraisal the frequent presence of minerals bearing columbium and/or tantalum was toted. Because of increased demand for these metals by the defense industries and because these industries depend upon foreign sources for their supply the domestic alluvial black sands are being considered, as a possible domestic source. However, utilization of these alluvial deposits depends upon development of methods of concentrating these valuable minerals. The primary objective of the test work was the study of the effect of attrition scrubbing, sizing, magnetic, electrostatic, and gravity separa¬tion as methods for concentrating and recovering the columbium and tantalum-bearing minerals, samarskite, euxenite, ilmenorutile, and columbite.

Jan 1, 1955

By Albert L. Toenges

The Deep River coal field is in Chatham, Lee, and Moore Counties, N. C. The coal-bearing part of the basin is about 35 miles long and 5 to 10 miles wide. Sanford, the county seat of Lee County, is the largest town in the area, with a population of 10,000. Four railroads provide transportation to the area, and four United States highways and improved county roads provide easy access to the field. The Carolina mine at Farmville is the only operating mine in the field. The mine was opened in 1921 by two rock slopes driven from the surface to the Cumnock bed. Mining operations continued intermittently until 1945 and then stopped. In the fall of 1947 the mine was reopened by the newly organized Raleigh Mining Corp.

Jan 1, 1952

By H. William Zeller

The U.S. Bureau of Mines evaluated the effects of two iron-based fuel additives on diesel particulate matter (DPM) emissions. The 5.6-L, six-cylinder test engine is typical of engines used in underground mines. One additive, ferrous picrate, did not measurably affect exhaust emissions. This report is mainly about a ferrocene-based additive that reduced DPM between 4 and 45 pet., depending on engine operating conditions. The report concludes that the DPM reductions were caused by the catalytic oxidation properties of a ferric oxide coating that developed inside the engine's combustion chamber. The ferric oxide coating also decreased gas-phase hydrocarbons and O2, but it increased CO2 and NOx, The increase in NOx, of about 12 pet, is considered the only adverse effect of the ferrocene-based fuel additive. The results suggest that the effectiveness of ferrocene was partially offset by increased sulfates because of the high-sulfur fuel used. Recommendations for continuing fuel additive research are presented.

Jan 1, 2010

By S. E. Burton

The White Rock area of the Boiling Springs manganese-iron deposits comprises about 3,200 acres of land in Monroe Township, Cumberland County, Pa. (See fig. 1.) This property was brought to the: attention of the Bureau of Mines by Pennsylvania Geological Survey Bulletin 128, entitled "Manganese Ores of Pennsylvania" by R. M. Foose. It was examined by an engineer of the Bureau of Mines in August 1942 and was further investigated by the Bureau by churn drilling and underground development during the period December 1942 to February 1944. Beneficiation tests were made on samples of the ore. This report describes the work done during the investigation and presents the results obtained.

Jan 1, 1949

By George Watkin Evans

The United States Geological Survey has estimated 1 that the State of Washington contains 11,412,000,000 tons of bituminous coal and 52,442,000,000 tons of subbituminous coal, in beds more than 14 inches thick. As the present rate of production is about 4,000,000 tons a year, Washington apparently contains coal enough to supply Pacific coast markets for many years. The character of the coal beds of Washington renders the production of clean coal very difficult, and a considerable proportion of the output is washed before it is marketed. In 1915 Washington ranked fifth among the States in the amount of coal washed, though only twentieth in total output. In that year 37.9 per cent of the coal produced in the State was treated in surface cleaning plants.

Jan 1, 1924

By R. L. Marek

The number of Persons fatally injured in the petroleum industry in California in 1930 was 50, a decrease of 20.6 per cent from 1929, when 63 men accidentally lost their lives. The decrease in the number of fatalities for 1930 has caused the first downward trend in the fatality curve of the California petroleum industry since 1927 and is coincident with a period of little active development in new fields, the shutting in of many wells, and reduced activity in the older fields of the State. That a direct relationship exists between the number of accidental deaths and the rapidity of new field development is particularly emphasized by the fact that in 1929, a year of intensive field development in California, 48 men were killed in the drilling and producing division, whereas in 1930, a year of less development work, only 25 men were killed in this division. The figures for the average number of drilling and producing wells in 1930 decreased appreciably from comparable figures for 1929 and a greater percentage of producing wells were shut-in in 1930 than in 1929.

Jan 1, 1931

By R. L. Marek

The number of persons fatally injured in the petroleum industry in California in 1930 was 50, a decrease of 20.6 per cent from 1929, when 63 men accidentally lost their lives. The decrease in the number of fatalities for 1930 has caused the first downward trend in the fatality curve of the California petroleum industry since 1927 and is coincident with a period of little active development in new fields, the shutting in of many wells, and reduced activity in the older fields of the State. That a direct relationship exists between the number of accidental deaths and the rapidity of new field development is particularly emphasized by the fact that in 1929, a year of intensive field development in California, 48 men were killed in the drilling and producing division, whereas in 1930, a year of less development work, only 25 men were killed in this division. The figures for the average number of drilling and producing wells in 1930 decreased appreciably from, comparable figures for 1929 and a greater percentage of producing wells were shut-in in 1930 than in 1929.

Jan 1, 1931

By Peter C. Wood

This report describes research directed toward the preparation of chemical oxygen (02) sources which exhibited improved 02 storage and reaction characteristics when compared to potassium superoxide (KO2). The initial focus of the research was the preparation of calcium superoxide (Ca(02)2) by the disproportionation of calcium peroxide diperoxyhydrate. The Ca(02)2) was characterized by chemical, thermal, and x-ray analyses. Several methods for scaling up the Ca(02)2 synthesis process were studied. Next, the reactivity of Ca(02)2 toward humidified carbon dioxide (C02) was evaluated and was compare o that of K02 under flow-test conditions approximating those existing in portable breathing apparatus. The reactivities of mixtures of K02 and Ca(02)2 or lithium peroxide towards humidified CO2 were also studied. Finally, an analysis of two commercial, K02-based, self-contained self-rescuers was conducted to determine the potential weight and volume savings which would be possible if Ca(02)2 or a mixture of K02 and Ca(02)2 were used as a replacement for K02.

Jan 1, 1983

By F. Chen, L. J. Gaydos, L. M. Demers, D. C. Kuhn, S. C. Sun

"In this report, we demonstrate that NF-KB, a ubiquitous transcription factor, plays an essential role in silica-induced inflammatory mediator production in the mouse macrophage cell line RAW 264.7. Compared to the effect of lipopolysaccharide (LPS), silica mediated a stronger activation of NF-KB p50/p50 homodimer at early phase of poststimulation. Furthermore, activation of NF-xB by silica and LPS appears to be mediated by different signal transduction pathways. Both silica and LPS increased mRNA expression in these cells for cyclooxygenase II, inducible nitric oxide synthase, tumor necrosis factor-a and interleukin- I a. This expression was attenuated along with the inhibition of NF-KB activation. It is well documented that exposure of alveolar macrophages to silica can initiate excessive production of inflammatory mediators and cytokines from several early response genes (1-3). At the DNA level, a common structural characteristic of these genes is the presence of one to five NF-lCB binding sequences (KB) in the 5'-flanking region (4-6). In resting cells, NF-KB is retained in the cytoplasm in an inactive form by binding to inhibitory protein known as hcBcx, hcB~. p 105 (precursor of p50) and p 100 (precursor of p52) (7-9). Upon cellular stimulation, these inhibitory proteins are proteolytically degraded or processed by certain proteases, which allows the liberated NF-KB to translocate into the nucleus as an activated form to initiate or regulate early response gene transcription by binding to its consensus element (GGGRNNYYCC)(7).In this report, we demonstrate that silica can efficiently induce NF-lCB activation in RAW 264.7 cells, and that silica displays different characteristic from LPS in the activation of NF-KB, both with respect to NF-KB subtype composition and the signal transduction pathway that leads to the activation of NF-KB. In addition, abrogation of NF-KB activation by inhibiting the protease can dramatically reduce the mRNA expression of cyclooxygenase II, inducible nitric oxide synthase, tumor necrosis factor-ex (TNF-o.) and interleukin-lex (IL-lex). These findings strongly suggest that NF-KB plays an essential role in silica-induced inflammatory mediator production in the monocyte/ macrophage cells."

Dec 1, 1996