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By T. Nesane, S. S. Mnyakeni-Moleele, L. C. Murulana

The effectiveness of two synthesized ionic liquids, 1-(benzyloxy)-1-oxopropan-2-aminium 4-methylbenzenesulfonate (1-BOPAMS) and 4-(benzyloxy)-4-oxobutan-1-aminium 4-methylbenzenesulfonate (4-BOBAMS), were evaluated for mild steel corrosion inhibition in 1.0 M hydro-chloric acid solution, using electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), and gravimetric techniques. Organic moieties responsible for the adsorption process on mild steel surface were investigated using Fourier transform infrared spectroscopy (FTIR). Gravimetric analysis revealed that the inhibition efficiency of 1-BOPAMS and 4-BOBAMS increased with concentration, with maximum inhibition values of 90.32% and 97.91%, respectively, at the highest concentration of the inhibitors. Gibbs free energy (ΔG°ads) values indicated a strong interaction between the mild steel surface and the molecules of the ionic liquids, and that the adsorption process was spontaneous. These values also show that the inhibitive nature of ionic liquids against mild steel corrosion is caused by a mixedtype of adsorption film formed on the steel surface. The Langmuir adsorption isotherm was used to describe the adsorption of ionic liquid molecules onto the mild steel surface. Polarization curves showed that 1-BOPAMS and 4-BOBAMS have a similar effect on both the anodic and cathodic half-reactions, indicating that they prevent the dissolution of mild steel through both physical and chemical process. Nyquist plots were defined by incomplete semicircle capacitive loops, showing that the charge transfer mechanism controls the corrosion of mild steel in acidic solution.

Apr 1, 2021

By C. J. Lenz

The results of prospecting operations involving geological data and a large number of geochemical determinations of the metal content of soil samples are plotted and evaluated by computer. Anomalous areas are identified in each type of environment by selecting probability or population boundary values from frequency distributions. The anomalies are plotted to permit correlation with geographical or geological features. Ranking of prospecting targets is made using geographic pattern, geology, absolute value and metal ratios. Three short case histories are presented.

Jan 1, 2014

By G. B. Abaka-Wood, J. Addai-Mensah, W. Skinner

Recently, coal fly ash has become a potential candidate as a secondary resource of rare earth elements (REE). In this investigation, we studied the recovery of REE from fly ash from a commercial power plant. The specific aim was to assess the technical feasibility of recovering REE from the coal fly ash using conventional preconcentration methods, including gravity separation, magnetic separation, and froth flotation. The experimental results revealed that flotation achieved major gains in REE recovery and upgrading. However, during gravity and wet magnetic separation tests, the bulk of REE reported to the tailings. The results showed significant variations in the performance of the various beneficiation methods investigated. This study has confirmed that existing physical separation methods could be used to recover REE from coal fly ash prior to hydrometallurgical and pyrometallurgical processing, although some challenges persist.

Jan 2, 2022

By Z. Luo, W. Chen, Y. Zhao, Y. Fu, L. Dong

The gas-solid dense-phase fluidised bed includes a complex multiphase fluid-particle system; different complex exchanges significantly affect the stability of the fluidised bed. To elucidate the characteristics of fluidisation in a gas-solid dense-phase fluidised bed, this study used experimental performance tests to obtain the static density characteristics, and the attachment and flow characteristic of the dense medium. The results indicate that the bulk density of the dense medium increases first and then decreases with the increase of particle size. The airflow rate difference is used to quantify the wall attachment characteristics of dense medium and the average pressure gradient in the axial direction of the bed is approximately 20 Pa/mm under the fluidisation results. At the same settlement location, with the decrease of fluidisation number, the settlement velocity of large and small particles becomes slower, the boundaries of settlement displacement and location probability are gradually disrupted, and the falling velocity of particles with a radius of 20 mm is faster than that of materials with a radius of 15 mm. This work also established a theoretical basis for regulating the stability and separation characteristics of gas-solid dense-phase fluidised bed. Keywords: Fluidised bed, different size particles, fluidisation characteristics, flotation bubbles, settling motion

Jan 1, 2020

By K. C. Naidoo

There are two main types of densifying cyclones currently available in the market, namely polyeurethane (PU) and ceramic. The PU densifying cyclones are currently used throughout the Grootegeluk complex and coal beneficiation in general. It has been identified that PU densifiers wear relatively fast depending on the operating pressure and need to be replaced frequently as a result. The motivation for this paper is to achieve an increase in the densifying cyclone lifetime through less wear and an increase in efficiency resulting in the ability to build higher relative densities (RD) more quickly. This will allow for a reduction in downtimes due to replacing densifying cyclones as well as building RD and a reduction in the operating costs associated with replacing worn densifying cyclones. Some of the major findings of the study indicated that the ceramic cyclone theoretically undergoes less wear than the PU cyclone, but since wear is application-specific and was evaluated, the wear on the polyurethane cyclone was found to be minimal. The RD differential is higher on the PU cyclones than the ceramic cyclones, showing that the PU cyclones perform better in a densifying application. This is the first test conducted on this application and type of cyclones. It should therefore be noted that having the PU cyclone significantly outperform the ceramic cyclone was not expected, due to the only change being the material of construction. This is an indication to take the material of construction into account when selecting cyclones as it can have a significant impact on the cyclone performance in specific applications. Keywords: Ceramic, cyclone, densifying, density, dense medium, polyurethane, wear

Jan 1, 2020

By L. Prosch

"The word 'sustainability' has gotten such a work out lately that the whole concept is in danger of floating away on a sea of inoffensiveness" Michael Pollon. It is estimated that approximately 65% of the roughly 130 million carats of diamonds mined globally per annum originate in Africa and has an annual value of US$ 8.4 billion', Many of these mines are located in remote areas of the continent where the directly affected project community's income is often well below the poverty line. Often associated with these communities are occurrences of localized over exploitation of natural resources, environmental destruction and the abundance of social ills.

Jan 1, 2010

By K. G. Lomberg

The density used to covert volume to tons is critical in determining the real in-situ tonnage of Mineral Resources. However, the methods used to determine density and the use of different technical terms are seen to be inconsistent throughout the industry. Probably the best discussion addressing the determination of density was presented by Lipton (2001). This paper does not try to replicate this excellent work, but rather to review current industry practice and present a comparison of the approach to density in public reporting. Some of the technical terms used in reporting and the common methods applied are also discussed.

Sep 1, 2021

By C. Karageorgos, J. Sakala, A. Prinsloo, B. Ngambi

The sulphide flotation circuit at First Quantum Minerals’ Kansanshi mine in Zambia produced over 100,000 t of copper in 2019. For this circuit, mineralogical analysis has shown that the majority of the copper lost is hosted in fine liberated chalcopyrite, which is a paramagnetic mineral. The objective of this work was therefore to improve fine chalcopyrite recovery in the sulphide flotation circuit at Kansanshi, using a magnetic conditioning technology to agglomerate fine paramagnetic minerals. This theoretically increases the probability of attachment during collision and therefore improves recovery. A four-month paired ‘t’ test plant trial was carried out and comprised of consecutive ON-OFF periods with and without magnetic conditioning in the rougher flotation bank of the sulphide circuit. The experimental design involved assessment of recovery by size based on daily and weekly composite samples of feed and tails, sized using both wet-screening and cyclosizer. Both the daily plant data and the sized samples showed an increase in Cu recovery with magnetic conditioning ON. A 0.56% copper recovery improvement was measured with magnetic conditioning at a 99.4% confidence level. Keywords: Flotation, fine mineral, chalcopyrite, magnetic aggregation

Jan 1, 2020

By H. J. E. Hamel

Some aspects of the deformation behaviour and temperature rise during instantaneous compression loading of high purity aluminium By H. J. E. HAMEL The influence of deformation speed on the deformation behaviour of high purity aluminium was investigated. By varying the initial height-to-diameter ratio a considerable influence on the deformation behaviour could be noticed. Lubrication of the specimen end faces was found to have an influence on the flow behaviour and on the roughness of the specimen interface at pressing platens. The results of temperature measurements during deformation agree with work-hardening behaviour of the specimens. Flow curves calculated with the measured temperature rises do not agree with results obtained at lower strains by other workers. The possible reasons are discussed.

By k. Lebecki, S. Trzcionka

The prototype and test results of the instrument for quick determination of incombustible content in deposited dust as a protection against coal dust explosion propagation are presented. Presently existing methods do not permit to obtain quick information about incombustible content, needed for the proper protection of workings. As the operating principle for the e instrument the dependence of reflection of infrared radiation intensity on incombustible content in the sample is chosen. The construction is based on the modern electronics. The measurement will be done at the sampling site. The range of the instrument is 0-100% of incombustible, direct reading, autonomous supply, weight no more than 0.5 kg, and is intrinsically safe according to EN Standards. During the Conference the instrument will be commercialized.

Jan 1, 2003

By D. F. Malan, J. C. Esterhuyse

In this study we explore the use of a novel numerical modelling approach to study the effect of pillar reinforcement on pillar stability. Case studies in the literature indicate that tendons, strapping of the pillars, and shotcrete or thin spray-on liners are commonly used to reinforce pillars. No clear methodology exists to select the type of support or to design the capacity of the support required, however. This has led to ongoing collapses in some mines in spite of heavy support being used to reinforce unstable pillars. A limit equilibrium model with confinement on the edge of the pillar was used to simulate the interaction of the support with the failing pillar. The model correctly predicts that an increase in confinement will lead to a decrease in the extent of pillar failure. As the displacement discontinuity boundary element method allows for the efficient solution of largescale bord-and-pillar layouts, the effect of pillar confinement can now be studied on a mine-wide scale. Accurate calibration of the limit equilibrium model is, however, required before this method can be used for the design of effective pillar support.

May 3, 2023

By A. Galibois, A. Dubé, H. Monette, J. L. Collins

"The start of mining operations often raises serious financial problems. In marginal cases promoters frequently demand financial aid from governments.In the past, the financial assistance has taken the form of gifts, procurement contracts, etc., but aid in such form has been severely criticized. A new formula has been developed to provide a more equitable distribution of the revenues accruing to the government and to private capital.The benefits to these two parties have been evaluated in an hypothetical case and compared in terms of internal rates of return on their investment, their shares of the undiscounted cash flows and their primary profits.The method based on the non-zero sum game theory provides a means for suggesting the lowest feasible annual production and the optimal sum contributed by the government in the form of outright gift, equity capital and convertible bonds. Other financial hypotheses can also be optimized by the computerized analysis."

Jan 1, 2014

The relationships between backfill-transportation parameters (solids concentration, velocity, and pipe diameter) and the wear rate of backfill-transportation pipelines is well understood. However, the degree of wear experienced by a pipeline depends not only on the transportation parameters, but also on the characteristics of the solids making up the backfill, i.e. the particle-size distribution, hardness, shape, and sharpness of the particles. Therefore, unless data corresponding to the specific wear rate of the solids are available, the determination of the wear rate for pipes transporting an uncharacterized backfill is largely guesswork. This paper describes an evaluation of particle characteristics with special reference to particle sharpness so that pipe wear rates can be correlated with solids of different size distributions and sharpnesses.

Jan 1, 1993

By T. Steyn, M. Fofana

"One of the most important performance indicators of a dense medium cyclone (DMC) circuit is the Tromp curve, and by extension the separation density and Ecart Probable (Ep) values. The densimetric profiles of DMC product streams have been traditionally acquired using heavy liquid sinkfloat analysis, which has certain disadvantages, such as the associated safety and health risks. More recently, non-toxic media such as lithium hetero-polytungstates (LST) have been used, with the desired densities being achieved by maintaining the solutions at specific temperatures. However, the high costs of these liquids can be prohibitive. The long turnaround time of the sink-float analysis is a further disadvantage for timeous interventions to the operating set-points of the DMC process.The RhoVol technology can generate the density distribution of a batch of particles in a rapid, accurate, repeatable, and safe manner. Additional data of interest, such as particle size and shape, are also measured and reported on a per-particle basis. Furthermore, samples can be sorted into discrete sorting bins based on any of the measured parameters of the particle, making further analyses of the material possible.This technology has applications across all commodities that use the DMC, particularly in the size fractions –25 +8 mm and –8 +3 mm. To date, laboratory results have proved very encouraging – separation densities are within 5% of traditional sink-float results, and the technology is being introduced to diamond DMC plants. IntroductionDense medium separation is a commonly applied beneficiation technique for the density separation of valuable products from crushed ores. The industrial applications of dense medium separation have been summarized and reviewed by various authors (Scott and Napier-Munn, 2000; Bosman, 2014; Napier- Munn, 2018). Dense medium cyclones (DMCs) are widely used in the coal and diamond industries to produce clean coal or to preconcentrate kimberlitic ores, respectively. Cyclone performance (separation density monitoring) techniques are varied. In the mineral industry. Density tracer tests (Napier- Munn, 1985, 2014; Davis, Wood, and Lyman, 1985) without mineral material, are widely used, although their accuracy in predicting operating cut-points becomes limited once mineral material is introduced. More recently, radio frequency tracers have been also used for the determination of cyclone efficiency (Partition Enterprises, 2017)."

Feb 1, 2019

The Department of Mineral Resources of Thailand is organising, on behalf of the Government of Thailand and the International Tin Council, the Second Technical Conference on Tin. The Conference will be held at Sala Santitham, Bangkok from 18th to 22nd November, 1969. Papers will be grouped under three main headings: (i) Geology and prospecting; (ii) Mining and ore dressing; (iii) Miscellaneous, e.g. stimulating production, metallurgy, estimation of reserves etc. Pre-prints of papers will be circulated. A field trip to Southern Thailand has been arranged for 25th November to 2nd December, 1969. Details of the Conference and the field trip can be obtained from Mr. W. Fox, International Tin Council, Haymarket House, 28 Haymarket, London, S.W.l, England.

By P. N. Harris

The Colloquium on 'Recent Mining and Metallurgical Developments in the Orange Free State' was held at the Civic Centre in Welkom on the 4th and 5th May, 1983. The Chairman of the Orange Free StatejKlerksdorp Branch of the Institute and Acting General Manager of Unisel Gold Mining Company, Mr D. A. Parfitt, opened the proceedings, and Professor A. N. Brown gave the welcoming address. Mechanization of mining The South African Institute of Mining and Metallurgy is to hold a one-day colloquium on 'Developments in the Mechanization of Mining Operations' during September 1984. Surfac,e mining and quarrying The Second International Surface Mining and Quarrying Symposium is being organized by The Institution of Mining and Metallurgy in association with the Institute of Quarrying.

Jan 1, 1983

By L. M. Falcon

Cassiterite is considered to be the only economically significant tin mineral in the earth's crust. In its purest form, cassiterite contains 76 per cent tin. The mineral is hard and heavy but also extremely brittle. and is therefore ideally suited to gravity recovery techniques. Cassiterite deposits can be categorized into two main types, i.e. alluvial or 'soft' rock deposits, and 'hard' rock deposits. The former are relatively simple to upgrade owing to their relatively coarse nature and their high degree of liberation. Hard-rock deposits, on the other hand, require considerably more sophisticated gravity methods to achieve the required degree of beneficiation. Various types of gravity recovery devices, both old and new, are described, and their respective roles in the flowsheets used are illustrated.

Jan 1, 1982

By K. C. Sole

The International Solvent Extraction Conference takes place every three years, under the auspices of the international Solvent Extraction Committee. ISEC '96 held in Melbourne, Australia, in March 1996, was attended by delegates from 34 countries. South Africa was well represented, with delegates from Amplats, De Beers, Mintek, Western Platinum Refinery, and independent consultant Phillip Lloyd (who represents South Africa on the International Committee). The theme of this year's conference was 'Value Adding through Solvent Extraction'. Five plenary lectures were presented. Dr E. Blass of Germany gave the opening presentation entitled 'Solvent extraction-a historical review', which traced evidence for the use of solvent extraction (SX) from the time of the ancient Egyptians, through the Middle Ages and Renaissance, to the Industrial Revolution.

Jan 1, 1996

The 96th Annual General Meeting of The South African Institute of Mining and Metallurgy was held in the Gold Room of the Transvaal Automobile Club in Johannesburg on Wednesday, 11th August, 1993. OBITUARIES The President announced the deaths of the following members of the Institute during the past year. Life Fellow E.F. Laschinger. Other Members R.K. Boright, J.S. Jacobi, R.D. Power, J.H. Cannon, C.J. du Plooy, L.B. Mcrae, C.P. Rossouw, A.L. Sillars, A.W. Heugh, R.K. Briggs, P.J. Stark, and C.S. Stott. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, all rose and observed a moment of silence.

Jan 1, 1993

By M. Steyn

The coordination compound tetrakis(1,3-diphenyl-1,3-propanediona to)zirconium(IV), [Zr(DBM)4], (DBM = dibenzoyl methane/1,3- diphenyl-1,3-propanedionol) was synthesized and characterized by single-crystal X-ray diffraction. [Zr(DBM)4] crystallizes in the monoclinic space group P21/c (a = 24.769(4) Å, b = 10.216(5) Å, c = 19.314(4) Å, and = 101.541(5)°). The coordination geometry around the zirconium atom, formed by the eight O-donating atoms of the four -diketonates, is found to be a near-perfect square antiprism. Crystal packing is stabilized by C?H... interactions throughout the crystal lattice. This structure is a noteworthy example of the application of ambient condition synthesis of zirconium compounds in N,N'-dimethylformamide (DMF) as reaction and crystallization solvent, highlighting the possibilities of aerobic condition metal purification through chelation.

Jan 1, 2014