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By G. W. Kenzy

Recently, in the United States, questions of possible deleterious synergistic health effects of the gaseous and particulate components in the diesel exhaust and mineral and coal dust have been the impetus for extensive research by several agencies. At the present time, diesel engines are tested and approved for use in gassy and non-gassy underground metal and non-metal mines under Parts 31, 32, and 36 of Title30 of the Code of Federal Regulations. Diesel-powered equipment for use in underground coal mines, though not explicitly addressed in the law, is administered under Parts 32 and 36 of Title 30, with Part 36 being applied in the case of equipment working inby the last open crosscut or in the return airways. Operation of diesel equipment in underground mines has the potential for serious health and safety hazards from the gases, vapors, and particulates in the exhaust. Therefore, various countries have rules and regulations for the safe deployment of diesel equipment. The applicable laws and regulations from several countries who have long experience with diesel-powered equipment in their mines are reviewed. Four major areas have been addressed: (1) testing and approval procedures of diesel engines, (2) ambient mine air quality specifications, (3) frequency of sampling and location of samples, and (4) air quality specifications in splits where diesel-powered equipment are operated. The review indicates that most regulations generally consider four possible hazards: (1) toxic components in the engine exhaust, (2) ignition of flammable atmospheres by the engine or electrical equipment, (3) fire hazards presented by the engine fuel oil and by combustible material that might come in contact with the equipment, and (4) mechanical hazards. There is a remarkable similarity in the laws with regard to engine design, testing and approval procedures. However, the aspects with regard to mine air quality and quantity are quite variable-- from a general statement to very specific standards for many different diesel exhaust constituents. However, the laws with regard to synergistic effects of diesel exhaust components and other mine air contaminants are an exception.

Jan 1, 1980

By S. M. S. Azghdi, K. Barani

The effect of microwave treatment on the surface roughness and wettability of chalcopyrite (CuFeS2 ) and on the chemical composition of its surface was studied. The microwave source was a conventional multimodal oven with frequency of 2.45 GHz and maximum power of 900 W. Pure chalcopyrite specimens and purified chalcopyrite concentrate were used in this study. Analysis using atomic force microscopy showed a decrease in the surface roughness of the chalcopyrite after microwave radiation. This decrease may be due to oxidation of the surface and formation of iron oxide. Moreover, the surface wettability of the chalcopyrite mineral increased with increasing duration of microwave radiation, which was in good agreement with the micro-flotation mass recovery results. The increased wettability of the surface may be attributed to the decreased surface roughness by microwave radiation. Analysis using scanning electron microscope/energy-dispersive X-ray spectroscopy indicate that after microwave radiation, the contents of sulfur and iron increased whereas that of copper decreased on the surface of the chalcopyrite, significantly changing the average atomic number of the chalcopyrite surface.

By K. N. Han

The kinetics of gold dissolution in iodide solutions with oxygen in an autoclave was investigated. The leaching process was described by a gas-liquid-solid heterogeneous reaction. The effects of stirring speed, temperature, oxygen partial pressure and lixiviant, concentrations on the overall leaching rate was investigated. It was found that the dissolution of gold could be represented by a heterogeneous chemical reaction. Under the conditions studied, the apparent activation energy ranged from 34.7 to 54.3 kJ/mol. Experimental findings were in good agreement with the kinetic model proposed.

Jan 1, 1998

By Carolina Bruecker, Axel Preusse

"The topic of ground movements in Germany has been studied extensively in the past, especially in the field of active mines. The active hard coal mines were finally shut down in 2018 in Germany and lignite mining is expected to take place only until 2038. The so-called long-term liabilities of the mine operators in Germany include, among other things, the long-term guarantee of stability and thus the monitoring of ground motion.So far, the economic use of underground mining in Germany was mainly the supply of raw materials. In the future, the underground storage of compressed air, methane, or hydrogen will play an important role in renewable energy supply and climate change. Therefore, underground storage space will become more important and spatial planning is essential to ensure availability of safe underground openings for the various options of environmentally friendly energy storage.However, this renewed usage of underground openings may also bring new and sometimes unknown challenges of geomechanical influence. On the one hand, the aftermath of hard coal and lignite mining will be an increasing challenge in mining subsidence engineering. On the other hand, new possibilities due to underground spatial planning may lead to subsidence and/or heaving of the upper surface.INTRODUCTIONBoth hard coal and lignite have a long tradition in Germany. The Prosper Haniel mine in the Ruhr area was closed at the end of 2018 after 150 years, which signalled the end of hard coal production in Germany. Lignite mining still takes place in the Central German, Lausitz, and Rhineland districts. However, lignite mining in Germany is expected to be phased out gradually by 2038 (MDR, 2019). With the closure of these mines, however, mining damage is not over. The long-term consequences of mining, which extend far beyond the closure of the mines, are associated with the liability and responsibility of the individual mining companies. The so-called eternity burdens on the mining company continue to apply. In the field of lignite production, the discontinuation of dewatering and the resulting possible elevations of the surface will be a relevant topic for the future of mine surveying. The same applies to the hard coal mines, which are partially flooded in Germany and therefore require extensive monitoring of soil movements in the future.The discontinuation of energy from hard coal and lignite calls for a change in the energy mix. With the renewable energy revolution in Germany, the focus is on a sustainable and environmentally compatible climate and energy policy based on renewable energies. Sustainable use of the subsoil, both natural and anthropogenically produced cavities, will play an essential role in the objectives of this policy. For example, disused mine cavities can be used to store electricity from renewable energy sources. (Umwelt Bundesamt, 2018) These functions will again cause classical ground movements such as subsidence and uplift, but will also bring new challenges for the mine surveyor. Challenges can be underground cavity exploration in inaccessible areas or legal aspects of underground competition."

Jan 1, 2019

By R. J. Lee

Asbestos analysis is conceptually simple. The objective, in most environmental analyses, is to determine the number of asbestos fibers per unit area or volume in a sample. The sample may be a consumer product, an ambient air sample, or a water sample. This determination is complicated by several factors: (1) sample collection and preparation, (2) counting techniques, and (3) operational definitions of asbestos in use. Three different definitions have been used in the study of environmental samples and are summarized in Table 1. The analytical procedure and detail required in the analysis vary with the definition of asbestos. Accordingly, this may be the only type of environmental analysis where the definition of a substance dictates the choice of analytical methods, and the rigor demanded of the analysis. Lead, arsenic, or beryllium are sub- stances having a constant definition and the method of analysis chosen depends on the concentration and precision required. However, the meaning of the term asbestos fiber is dependent on the eye of the beholder. Macroscopically, asbestos has certain physical properties that make it highly useful. Rockforming minerals do not display similar characteristics. Now, the question arises as to how three definitions of asbestos came into being. This is a result of two factors: (1) the definition of asbestos on any scale intrinsically involves the morphology or shape of the material, and (2) the advent of the transmission electron microscope permits detection of asbestos fibers and other mineral fragments in a size range where the physical properties of asbestos such as tensile strength, flexibility, or thermal resistance are difficult, if not impossible, to measure. There is a good deal of controversy about which definition is most appropriate for regulatory purposes because of a lack of appropriate health effects data (Cooper, 1978). Most differences of opinion center on the questions surrounding the following: 11 Morphology-Is a 3:l aspect ratio an appropriate medical or physical lower limit for the definition of an asbestos fiber? 2) Length-Are asbestos fibers shorter than some arbitrary length (5 pm) as hazardous as longer fibers? 3) Mineralogy-Is the mineralogical distinction between asbestos and nonasbestos minerals medically significant? While these questions are directly resolvable only with the biological and health effects data, ultimately such data reflects the ability of analytical procedures to fully characterize the materials used in health effects studies on animal models, and to monitor the exposure to particulates with different physical attributes in the workplace or community (Cooper, 1978). The following sections outline the analytical problems involved in distinguishing the asbestos and nonasbestos varieties of the same mineral; the analytical procedures available for identifying asbestos and measuring its concentration in environmental samples; the ability of these methods to distinguish asbestos fibers from nonasbestos particles; and their precision and reproducibility. Finally, we suggest some future directions in terms of definition and procedure that would greatly improve the quality of such analyses. ASBESTOS VS. NONASBESTOS Asbestos that is mined commercially belongs to two mineral families; amphibole and serpentine (Zoltai, 1978, Wylie, and Steel, 1978). The

Jan 1, 1986

By Danforth R. Hale

The pressure of military use of quartz resonators led to efforts to Grow high, grade quartz crystals in Germany and in Great Britain during 19)3-25, and was responsible for a series of U.S.A. Signal Corps contracts beginning in 1946 with the Clevite Corporation (as the former Brush Development Company), Bell Telephone Laboratories, Antich College, and others. The technique of growing crystals from the melt, such as KI, NaBr, was already commercially inuse Quartz could not be so grown, since its utility depends on the form stable below 573°C, and, even if it could be grown from an extraordinarily viscous melt, the higher form passing through this transition becomes twinned. Again, several crystals were being grown commercially from water solutions; quartz, however, is listed in the common literature as being insoluble in water. Fused quartz, or vitreous silica, was chosen as raw mater¬ial by the European experimenters because of its thermodynamically lesser stability than quartz, and various alkaline solutions were tried for the purpose of enhancing the solubility.

Jan 1, 1964

By John S. Anderson

The need for fuels and minerals in this country is estimated to double, triple, or even quadruple by the end of the present century. Even assuming more recycling of scrap metals and some priority allocation of energy, as has been done, for instance in war time, the projected increase in the nation's population and ever-increasing wants of that population will require vastly more minerals than are now being produced. Since mineral ores are being mined at lower grades, and since all minerals, including fuels, are having to be mined from deeper deposits, the amount of surface land to be disturbed will, inevitably, be increased. We cannot depend on foreign sources to supply all the extra requirements, since the non-U.S. population is increasing, in most cases, faster than our own. Furthermore, starting from a lower base, their mineral needs may accelerate more rapidly than ours. Restrictions on exports may be applied in foreign countries, if it appears that remaining reserves are not sufficient to fill the national needs. In vice; of the opposition which the mineral industry is receiving, as has been well described at these sessions and elsewhere, what can we, as mineral producers, anticipate as regards our ability to continue to operate, to sway nothing of expanding production? Although not minimizing the problems involved, it seems obvious that, except under emergency conditions, the country cannot tolerate a reduction in the available

Jan 1, 1971

By P. K. Sharma

The acidophilic and chemolithotrophic Thiobacillus ferrooxidans bacteria grown in the presence of soluble ferrous ions and solid substrates (sulfur, pyrite and chalcopyrite) as their energy source have been used in the investigations. The cell surfaces are characterised by zeta-potential, contact angle, FT-IR and FT-Raman studies. The adsorption isotherms of the cells on pyrite and chalcopyrite indicate that the adsorption begins on pyrite at a much lower equilibrium cell population than on chalcopyrite. The isotherms tend to level off at a cell adsorption density corresponding to a horizontal monolayer coverage when the geometrical dimensions of the cells are considered. In the presence of cells, the xanthate flotation of pyrite completely depressed, whereas chalcopyrite flotation is unaffected. The results suggest that chalcopyrite can be selectively floated from pyrite, also at a neutral pH region, in the presence of T. ferrooxidans cells.

Jan 1, 1999

By J. B. Zachwieja

Cationic reagents have been utilized in mineral processing since the mid 1930's and are based upon fatty nitrogen derivatives. The initial commercial development was centered around a flotation collector capable of separating potassium chloride from sodium chloride - potash flotation. The first commercial sale for Akzo, known then as Amour and Company, was realized in the summer of 1940 to a potash producer in Carlsbad, New Mexico for the flotation of potash. The success of the potash flotation collector led to the development of other cationic mineral processing reagents. Flotation collectors for iron ore, phosphate, calcium carbonate, silica sand, feldspar, and other silicates materialized into a large commercial business. Another area that realized commercial success was the development and use of anticaking/antidusting reagents for hygroscopic salts, fertilizer mixes, and granular fertilizers. A more recent development has found use in the trona industry as a defoamer and crystal growth modifier during the crystallization of sodium carbonate liquors. A review of cationic reagent chemistry and applications will be given and the potential for new application areas will be explored.

Jan 1, 1994

By R. J. Gochin, G. D. Schena

Mineral processing options and technical innovations should be financially assessed. Indeed technical feasibility alone does not offer an adequate process selection criterion. An appraisal by the use of engineering economics principles leads to a more efficient evaluation and selection of feasible mineral processing solutions. Financial consequences of different options synthesised by profitability indices allow better decision making. Selected examples derived from real world problems are used to illustrate the potential of engineering-economics methods applied to mineral processing.

Jan 1, 1995

By Frank E. Kottlowski

Widespread high-calcium (HC) limestones in New Mexico and adjoining areas, are low in magnesium, but some units include shale interbeds that would be deleterious for usage in sulfur removal. In southwest New Mexico, southeast Arizona, and adjoining parts of Mexico, limestones in the thick Mississippian Escabrosa, Pennsylvanian-Permian Horquilla, and Cretaceous U-Bar units are HC as are strata in the Mississippian Lake Valley, Pennsylvanian formations, Permian Hueco, and parts of the Permian Capitan Limestone of south-central and southeast New Mexico and west Texas. In north-central and central New Mexico, many limestones in the Pennsylvanian Madera Formation are HC as are some of the Cenozoic travertines. In northwest New Mexico, where the present-day mine-mouth coal- fired power plants occur, there are no HC limestones, but to the north in southwest Colorado some beds of the Mississippian Leadville Limestone and Pennsylvanian Hermosa Formations are HC. HC limestones considered contain at least 95 percent calcium carbonate and less than 3 to 5 percent magnesium carbonate. Limits for other impurities are alumina, 1 percent; silica, 2 percent; sulfur 0.05 percent; phosphorous, 0.02 percent; and iron oxide, about 1 percent. Chemical and physical requirements differ slightly depending upon the ultimate use.

Jan 1, 1995

By Michael J. Martinson

A powerful methane explosion in the mid-shaft pump station of a main service and ventilation shaft killed several persons on the station; more workers were killed when a mancage travelling down the shaft fell to the shaft bottom under a pile of broken concrete slabs from a brattice wall destroyed by the explosion venting into the shaft and a tangled mass of twisted steelwork from the equipped compartment. The newly-commissioned shaft serves a recent extension of an established mine on the Orange Free State (OFS) goldfield in South Africa. After outlining the circumstances in which the paper was written, and reviewing the nature and extent of the methane hazard in OFS mines, the paper describes the physical layout of the shaft and summarises evidence given by witnesses at the official inquiry concerning events prior to the explosion. No attempt is made to apportion blame for the incident.

Jan 1, 1989

By Chee S. Theng

As the 2017 president of the Society for Mining, Metallurgy & Exploration Inc., I am pleased to present the 2017 issue of the Transactions of the Society for Mining, Metallurgy & Exploration Inc., Vol. 342. A significant portion of the contribution that we make as a professional society is the publication of professional and technical papers that accelerate the advancement of scientific knowledge and enable the transfer of technology. Communication within the mining community is the key to a successful society. This technology exchange continues a tradition that dates back to the 1871 meeting of 22 mining engineers in Wilkes-Barre, PA, that resulted in the founding of the American Institute of Mining, Metallurgical and Petroleum Engineers (AIME). Those individuals envisioned that these transaction volumes “would form a most valuable and greatly needed addition to our professional literature.” This volume fulfills that pledge. The 2017 Transactions contains some of the most interesting research and insights from the past year and features an international slate of authors spanning industry, academia and government. Papers include the latest findings from the U.S. National Institute for Occupational Safety and Health (NIOSH), a special review article on Heap Leach Modeling, and articles from two Special Issues on Rare Earths. The 2017 Transactions consists of a total of 54 technical papers, encompassing all 21 papers published in 2017 in the Technical Papers Section of Mining Engineering (Vol. 69) and all 24 papers published in 2017 in Minerals & Metallurgical Processing (Vol. 34). Additionally, this volume contains 9 papers that are being published for the first time in this issue. The papers presented in this volume were written by some of the most distinguished professionals in the industry worldwide. All of the technical papers were peer-reviewed. The process of review and publication requires much hard work by authors, reviewers and our Publications staff. As the 2017 president of SME and on behalf of all our members, I would like to extend our gratitude to all whose volunteer efforts contributed to the publication of this volume.

Jan 1, 2017

By John McMorran

An open pit mine design system should have the characteristics of being flexible, versatile, and simple. All of these characteristics are necessary for producing a dynamic mine design. In other words, a design that can be improved, updated, and implemented. Flexibility is an important characteristic due to changing times. For example, the effects of a changing economy, increased knowledge of the mineral deposit, or improvements in mining technology can result in a considerable, if not a complete change in the long range mining plans. Since the short range mining plans are based on the long range mining plans, they will-also be effected. Also, it is very important to validate the information used in the design or the design itself. This means the system should have the flexibility of being able, not only to detect, but to correct errors. Versatility is another important characteristic of a mine design system due to the wide range of situations that may appear. First, a design system must be able to handle both long and short term planning. This is necessary because of the variability in the definition of a time range. Second, a design system must be able to handle different types of deposits. Special emphasis must be placed on this issue, because many deposits, if not the majority, do not fit predefined categories such as bedded, massive, or roll-front, etc . . . Furthermore, the true test of the versatility of a design system is not only the ability to create an ultimate design but also to schedule sequences for this design. Thus, the versatility of being capable to design with a variety of time ranges, variety of deposit types, and scheduling are all important characteristics of the design system.

Jan 1, 1982

By Bernard Scheiner

A number of wells were drilled at two phosphogypsum stacks, one at P-21 owned by IMC and the other at Agrico's South Pierce Stack. Each well was sampled, and composites representing 5-ft increments were leached with synthetic rainwater to determine the extent of metal and nonmetal migration. To simulate what was occurring in the stack, composite samples were placed in a column, so that the column represented the stack in miniature form. Leaching experiments showed that both metals and nonmetals moved down the column when water was added to the top of the column. Data obtained from P-21 showed that with time the concentration of metals and nonmetals reached equilibrium values. The concentration of Ca, SO4, F, Si, and PO4 were -600 ppm,~1,500 ppm, 32 ppm, 14 ppm, and 22 ppm, respectively. Column leaching of South Pierce material, representing 0 to 55 ft of stack, showed that after 355 in. of water, the stack was near equilibrium values down to the 33-ft level. With continued addition of water, the portion of the stack at equilibrium would continue to increase and eventually reach the values observed for P-21. The test showed that the sulfate concentration of the effluent from the stack would never reach the USEPA standard value of 250 ppm. During the leaching test, it was determined that the permeability of the phosphogypsum in the columns was 0.000103 cm/sec. This number was used in the modeling. The data obtained from the leaching experiments cast some doubt on the practice of entombment now being practiced for closure of phosphogypsum stacks. The data clearly shows that with time, the amount of material leaching from the stack is low in concentration, with only the calcium and sulfate at higher levels. When a stack is closed at an existing operating plant, allowing rainwater to fall on the stack and capturing the solution in the existing pond system would eliminate the need for covering the stack, since with time the closed stack would continue to leach and at some point reach the equilibrium values of the P-21 stack. Entombment means that the leachable material in the stack will always be there and will require monitoring forever. Allowing rainwater to decontaminate the stack may be the best environmental solution to the problem.

Jan 1, 1999

By Richard W. Hornung, Steven Samuels

A great amount of work in recent years has been devoted to refining older survivorship models, e.g. life tables, and developing newer ones, e.g. Cox regression. In this paper, these models are applied to data from an epidemiological study of uranium miners in four western states conducted by the U.S. Public Health Service. One of the principal problems addressed in this paper concerns the appropriateness of using cumulative dose as the measure of radiation exposure. An alternative is considered that incorporates dose rate into the model. This procedure does not implicity assume that equal cumulative doses produce the same lung cancer mortality, but instead considers the amount of time in which each miner's dose was accumulated. Results of the statistical analysis indicate that dose rate is a significant factor at higher cumulative dose levels, with lower dose rate apparently more damaging than higher dose rate. The shape of the dose response curve is curvilinear at higher dose levels. No interaction was found between smoking and radiation exposure on a multiplicative or relative scale.

Jan 1, 1981

By Jr. Wilkinson

In today's work environment a tremendous amount of data is required to provide the regulatory agencies justification to issue a mining permit. The demands for data, specifically environmental characterization data, grow and the mine plans must address the issues raised by the interpretation of that data. Computers and computer software can provide operators and consultants with the tools necessary to assimilate, digest and interpret these seemingly unmanageable data sets. This paper presents some examples of how Mincom's MineScape software can be applied to the task of developing coal mine permits in an electronic format.

Jan 1, 1996

By Y. Ye, J. D. Miller

Certain bituminous coals are known to contain appreciable quantities of natural fossil or subfossil resin. Such resinous coals are found in the western US, particularly the Wasatch Plateau coalfield of UT. Some of the seams in this field contain an average of 5% resin. This fossil resin has been recovered by gravity and/or flotation processes since 1929. Resin concentrates thus produced are of low quality and are usually refined by solvent extraction. The purified resins are of commercial importance in the adhesive, coating, rubber. and ink industries, etc. An improved flotation technique has been developed which involves ozone conditioning to selectively float resin from high-volatile bituminous coal. With this flotation process, a concentrate product which contains 95%

Jan 1, 1990

By F. M. Doyle, Jun Li, Milton E. Wadsworth, E. Peters

The Raman spectroscopic technique was used to study electrochernically oxidized pyrite in-situ. It was found that Raman-active sulfur oxidation products could be detected after a proper potential was applied to the pyrite electrode for a threshold period of time. There existed a minimum potential below which sulfur could not be observed. However, when the applied potential exceeded a certain limit, the intensity of the sulfur spectra decreased. The minimum potential at which sulfur could be observed changed with solution pH. For both acid (pH 2.7) and weak alkaline (pH 9.2) solutions, the minimum potential was 0.8 V/SCE, whereas for neutral (pH 6.5) solutions the value was 0.4 V/SCE. In strong alkaline solutions (pH 12.5) surface sulfur oxidation products could not be detected at any potential.

Jan 1, 1993

By R. Y. Wan

Newmont Gold has advantageously used the capabilities of mineral oxidizing bacteria to develop a process for the pretreatment of low-grade sulfidic and carbonaceous-sulfidic refractory gold ores. The biooxidation process results in the oxidation of the sulfidic minerals with increased exposure of gold for subsequent gold recovery. The biooxidized carbonaceous-sulfidic ores cannot be heap leached with cyanide because of the preg-robbing characteristics of the carbonaceous matter in the ores. Therefore, an alternative heapleach process using ammonium thiosulfate was developed to extract gold from these preg-robbing bioaxidized ores. The ammonium thiosulfate leach process was successfully applied in both laboratory and pilot plant tests. Satisfactory test results were achieved, encouraging the continuation of process development.

Jan 1, 1997