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TiO2 and Ti/TiO2 thin films were deposited on a quartz substrate by laser ablation of Ti02 and Ti targets using Nd:YAG pulsed laser. After sulfurization of the Ti02 film in H2S or CS2 gas at 1273 K for 1 hour, the surface atomic structure was changed. Furthermore, the Ti/TiO2 film was successfully prepared by the subsequent ablation of Ti and TiO2 targets. The morphology and structure of the films were characterized by XRD, XPS and AFM analyses.

Jan 1, 2003

By Yutaka Yasuda

The particle dispersion phenomena in a turbulent gas jet of the flash smelting process has been investigated. The particle number density in a non- reacting jet was measured experimentally by taking photographs of the particles in flight and counting them using the image analysis. Numerical computations were also performed using a mathematical model for a turbulent particle laden gas jet The experimental particle number density data were then compared with the predicted results of the model. Good agreement was obtained between the experimental and predicted data. The effects of the parameters such as the injector design, particle loading and air flow rate are discussed. Optimization of the concentrate burner design can be achieved with the help of experimental and theoretical simulation as performed in this work.

Jan 1, 1994

By Richard B. Stein

Bechtel's BEMSIM computer program is a useful tool for solvent extraction-electrowinning plant design optimization. Its power (up to 90 stream components, 240 process streams, 180 process steps) has been applied to investigate floweheet configurations in order to perform basic engineering, sizing of plant equipment and to optimize performance of commercial-size copper plants. Flowsheet variations presented include series, parallel and series-parallel extraction stages, while heat balances simulate operations in summer and extreme winter conditions. The BEMSIM program has also been applied to nickel-cobalt, gold and manganese extraction.

Jan 1, 1993

By Tomas Astorga

APEC, the Asia Pacific Economic Cooperation is the forum of 18 economies, having a combined GDP of approximately 56% of the total world income, and over 45% of global trade. Its mining sector produces a large portion of the main minerals and metals in the world. In 1997, APEC economies produced 67% of world copper output, 55% of gold, and over 45% of other base metals. Mining in APEC captures more than 60% of the total mining investment in the world. Against this background, the Expert Group on Minerals and Energy Exploration and Development, in short GEMEED, was created in 1996, under the auspices of the APEC Energy Working Group. The sustainable development of mining activities is a main concern in APEC and GEMEED. Several programs related to the subject are actively being pursued by the Expert Group. Among them, it should be noticed the creation of an Environmental Cooperation Sub Group coordinated by Japan, whose main aim is to encourage proposals related to the environmental soundness of mining projects in the region. Also, it should be noted the existence of a Database Steering Committee whose focus is the development of an information network related to mining opportunities in the region GEMEED is a gathering of experts from all the APEC economies. As such, it represents a privileged forum to discuss policy issues related to mining. On this regard, the paper focuses on concrete actions taken by GEMEED to enhance the sustainability of the copper activity in the region.

Jan 1, 1999

Segregation roasting tests were carried out on Zaire cobalt oxide ores assaying about 2% Co and 3.5 to 6.5% Cu. The major parameters tested during the laboratory investigations were temperature, dosage and type of reducing agent, dosage and type of chloridizing agent, and particle size. Results showed that standard conditions suited to the segregation of copper ores, i.e. low temperature and low dosages of reducing and chloridizing agents, resulted in the segregation of copper only, while conditions suited to the segregation of lateritic nickel, i.e. higher temperature and increased dosages of reducing and chloridizing agents, led to a successful segregation of both copper and cobalt. Under the best conditions, 88% of the cobalt and 98% of the copper could be recovered in a concentrate assaying 32.5% Cu and 8.5% Co. Alternatives to process such a concentrate are briefly reviewed.

Jan 1, 1993

By John Wallace

"Monitoring compound semiconductor crystal growth using multifrequency eddy currents for sensing illustrates some of the extreme problems of measurement and interpretation that are not often seen in metallic systems. Using sensor arrays and scanning sensors have produced a qualitative and quantitative understanding of some of the high temperature electrical conductivity mechanisms in several compound systems. A detailed review of the CdTe/CdZnTe data is presented showing some of the complexity in the data as opposed to what is found in elemental semiconductors.HistoryThe most common goal in the use of eddy current measurement in crystal growth is to deter-mine the curvature of the liquid solid interface during growth to test if the heat transfer estimates of the thermal design were adequate for single crystal growth[l]. This aim could be met but represented only a small fraction of the data that was produced observing a growth cycle. A secondary consideration was what could be discovered in the recorded data about the growth and subsequent heat treatment as the boule cooled. This is usually a more difficult task because a crystal growth process is not a controlled experiment so much as a process that continually sees modification. Using a sensor arrays or a scanning loop has produced a qualitative and quantitative basis for understanding some of the high temperature electrical conductivity mechanisms. The implication of the these measurements of electrical conductivity variations are important in that they reflect the complex defect states that will occur on cooling and heat treatment following crystal growth. In contrast to the complex behavior of the conductivity of these compound semiconductors in the solid and liquid state we have the very well characterized system silicon to compare. Initially the interest on using eddy currents to monitor compound semiconductors came from G. Westphal at the Texas; Instruments Company in 1987 to monitor aspects of growth and compounding of GaAs. This was followed by work on solution growth of HgCdTe with D. Witter. The initial interest in the use of eddy cur-rents for monitoring CdTe crystal growth came from Prof. Wilcox at Clarkson University in the practical interest to determine and control the crystal interface curvature during vertical brigdeman growth. The first actual work was done by one of his former students. G. Neuge-bauer at the II-VI Corporation which was carried on by G. Rosen at Clarkson and R. Shetty at II-VI Corporation and with A. Socha at Johnson-Matthey Electronics. The work on CdTe extends over four years and yielded sufficient data to allow one to evaluate the utility of the information produced as compared to what could be obtained from monitoring an elemental semiconductor such as silicon."

Jan 1, 1997

By Shadia J. Ikhmayies

SnO2:F/CdS:In bilayers were produced by the spray pyrolysis technique on glass substrates. The structures were characterized by recording and investigating their transmittance curves, I-V plots, X-ray difractograms (XRD) and by observing their scanning electron microscope (SEM) images. From the I-V plots it was found that the SnO2:F forms an ohmic or quasi-ohmic contact with CdS:In. XRD patterns show the polycrystalline nature of the films and show that there is a small shift in the position of the (200) line of SnO2:F without the appearance of new peaks. The morphology of the structures are compared with those of SnO2:F alone and CdS:In alone on glass substrates.

Jan 1, 2009

By J. W. Dini

Introduction The mission of the Materials Fabrication Division (MFD) is to provide fabrication services and technology in support of all programs at Lawrence Livermore National Laboratory (LLNL). MFD involvement is called for when fabrication activity requires levels of expertise, technology, equipment, process development, hazardous processes, security, or scheduling that is typically not commercially available. Customers are encouraged to utilize private industry for fabrication activity requiring routine processing or for production applications. MFD is .a large diversified service organization including approximately 400 full time employees. The group provides a wide variety of processes including all common machining and fabrications operations, laser and water jet cutting, electrical discharge machining, lapping, electron beam and laser welding, vacuum brazing, heat treating, forming, electroplating and metal finishing, optical polishing and grinding, vacuum coating, vacuum engineering and a variety of plastics operations. These operations occupy more than 1,250,000 square feet of floor space. For more detail on the many fabrication related services available from MFD, see Reference 1.

Jan 1, 1992

By J. G. Reid

Nickel is second only to aluminium, of all non-ferrous metals, in energy required to convert the ore to metal. Nickel Laterite ores, which constitute the feed source for approximately 40% of world nickel production, are at a particular disadvantage because of the absence of sulphur, as an energy source, in the ore and because lateritic ores general 1 y are not amenable to beneficiation. The dramatic escalation of oil prices which commenced in 1973 and continued for a decade meant that Nickel Laterite refineries using oil as a primary energy source were placed at a distinct disadvantage relative to refineries utilizing nickel sulphide concentrate feeds. By the late 1970's the continuing large difference in oil and coal prices caused Greenvale to consider converting certain high oil consuming areas of the refinery to coal. These investigations confirmed that the areas of ore drying and power generation, which together consumed 50% of total Plant oil requirements, could be economically converted from oil to coal firing. Construction of the coal conversion facilities commenced in October 1980 and the first ore drying air heater came on line in August 1981. Construction was completed with the commissioning of the coal fired boiler in June 1982. This paper outlines the additions required to receive and utilize coal in ore drying and power generation and how the changeover was completed with minimal process disruption.

Jan 1, 1988

By Martín Reyes

Iron concentration by ion flotation techniques, from sulfate solutions in presence of zinc was studied in a laboratory flotation column by continuous mode using a synthesized sand shell plate sparger, an anionic collector, promoters, and surfactant propylenglicol 400. Effects of experimental parameters, such as the concentration of reagent: potassium amyl xanthate and dithiophosphate, superficial gas velocity, and superficial liquid velocity were studied in terms of the recovery and enrichment of Fe (III). The results show that the iron elimination from the solution in the presence and absence of zinc (II) are of 59 % and 72 % respectively. The flotation efficiencies decrease with an increase of the concentration of xanthate and air flow rate. The best recovery was achieved, at Jg 0.1 cm/s, Jl 0.72 cm/s and a mixture of xanthate and dithiophosphate as promoter. It was also demonstrated that it is possible to selectively separate and concentrate iron (III) from solutions containing zinc. The behavior of iron ion flotation in a flotation column is reported in this research as a gas hold up, superficial gas velocity, bubble size and superficial bubbles area flux function. The results show that the extraction of aqueous ions of metal iron by ion flotation is strongly affected by: [C], Jg (cm/s), eg (%), Db (mm), Jl (cm/s), y Sb (s-1).

Jan 1, 2009

By Józef Czernecki

The Polish copper concentrates are characterised by low content of sulphur and iron. At KGHM Polska Miedz S.A. two copper production technologies are in use. The shaft furnace process is used at the Legnica Copper Smelter and the Glogów I Copper Smelter. A single-stage direct to blister Outokumpu flash smelting process is used at the- Glogów II Copper Smelter. Melting copper concentrates in the shaft furnaces is carried out in a reducing atmosphere and the product obtained is a matte. Instead, a result of melting copper concentrates by an oxidising flash process blister copper of a quality similar to that of converter copper is obtained. The annual copper production at KGHM Polska Miedz S.A. exceeds 450,000 tons. Another important metal is silver produced from slimes from copper electrolysis (about 1000 t/y). Moreover, such metals as Pb, Ni, Se, As, Au and other precious metals, including Pt and Pd, are recovered from various semiproducts. This paper presents technological flow sheet of the copper production in plants using the shaft furnaces and in another plant in which a single-state flash process is applied. Characteristics of products, methods of their utilisation, main parameters of particular technological operations, and advantages and shortcomings of the solution applied are presented. There are also discussed: the natural environment protection as well as directions of the KGHM Polska Miedz S.A. plants modernisation.

Jan 1, 1999

By Richard Hollis

The Mount Isa copper smelter was expanded in 1998 to a capacity of over 250000 t/y anode copper. This tonnage will be produced from a single stream consisting of an Isasmelt smelting furnace, and four Peirce-Smith converters - one of which was installed as part of the expansion project. During the course of the expansion project Mount Isa Mines Limited (MIM) signed an agreement with WMC Fertilizers Ltd (WMCF) to supply sulphur containing smelter gases over the fence to a new sulphuric acid plant to be built by WMCF. This will result in a further increase in copper production by reducing the time when smelting is curtailed by Air Quality Control restrictions. As well as the need to modify the primary gas system to connect to the acid plant, the hoods and crossover ducts and their support structures on the original three converters required replacement, and secondary ventilation was also needed to improve converter aisle hygiene. Each of these areas was addressed by the project. Preliminary ideas for carrying out the modifications were found to have a serious impact on converter aisle operations, and would have led to a production loss of over 50000 tonnes of copper. Following benchmarking in other copper smelters, a suitable construction plan was developed and carried out to minimise this loss. This paper describes the methodology and construction plan adopted.

Jan 1, 1999

By Alex Moyano

At present, the Codelco Norte smelter processes in the Teniente Converter and the Flash smelting Furnace 1,420,000 t/y of its Chuquicamata concentrate with an arsenic content of up to 1.5%. In a near future Codelco-Chile is considering different processing options for a new projected concentrates from the Alejandro Hales mine (former Mansa Mina mine with an arsenic content of up to 6%). The main option is the possibility to process 3,000 t/d of mixing concentrates from the Alejandro Hales and the Chuquicamata mines, in the Teniente Converter. The main feature of this smelting unit will be high volatilization of arsenic when processing high arsenic-bearing concentrates. The CN smelter staff carried out a technical feasibility study to evaluate the processing of high arsenic-bearing concentrates directly in the Teniente Converter, thus the low arsenic-bearing concentrates can be processed in the FSF. Accordingly, laboratory scale tests were carried out at the Tohoku University facilities. The lab-scale results allowed an industrial scale test at the Codelco Norte smelter to smelt 2,300 tpd of high arsenic-bearing concentrates in the TC and evaluate the metallurgical impact in the smelting, converting and refining areas of the smelter. The main industrial-scale result confirmed the stabilization of the arsenic content at 0.5% in the 70% Cu produced white metal at the test condition.

Jan 1, 2006

By T. S. Piwonka

Modeling the solidification of shaped castings has progressed beyond the initial problem of determining the correct heat and fluid flow relationships which describe the solidifying castings. Today the challenge is to describe second order effects which determine the ultimate quality of the casting. The challenges to the modeling community posed by the needs of today's foundries for models that work are discussed, with some examples of current modeling problems.

Jan 1, 1992

By Derek J. Fray

The need for on-line sensors is outlined and it is demonstrated that the control of many processes is prevented by the availability of these devices. The use of solid electrolytes is described for the sensing of elements in molten pyrometallurgical phases. In the cases where there is no suitable electrolyte, the addition of a second phase of a compound containing both the element to be measured and the element whose ion is mobile in the electrolyte can be used. For the measurement of high concentrations of an element a method based on current measurement is proposed.

Jan 1, 1994

By Yun Guo, Min-Min Lin, Bing Xie, Hong-Yi Li

The extraction of vanadium from vanadium-containing APV-precipitated wastewater by W/O microemulsion system was studied. In the N263/n-heptane/isoamyl alcohol/NaCl microemulsion system, N263 played double functions of cationic surfactant and extractant to form microemulsion in n-heptane, and isoamyl alcohol was added in the microemulsion as a cosurfactant. The extraction of vanadium by W/O microemulsion systems effectively accelerated the extraction and improved the extractatability because of the enormous increase in the micro-interfacial surface area. Due to ion association with extractant, vanadium was extracted into the microemulsion phase. The influence of different parameters on the extraction ratio (E%) were investigated, including the volume ratio of aqueous phase to microemulsion, surfactant concentration, pH value of the feed solutions, cosurfactant concentration, extraction time as well as temperature. In optimum conditions, the extraction ratio (E%) can reach 97.2%.

Mar 1, 2018

By Malti Goel

"Ferrous and non-ferrous metals industries are source of both direct and indirect greenhouse gas (GHG) emissions. Metal industry accounted for 29.7% of the total GHG emitted from the Indian industry sector in 2007. Aluminum is second largest contributor after steel. Indian Aluminum industry has been growing and is adopting several effective measures for better efficiencies through process change and waste utilization. Improvement in the energy efficiency can form the basis of monitoring reduction in emissions. Under the National Action Plan on Climate Change 2008, National Mission for Enhanced Energy Efficiency (NMEEE) aims to upscale the efforts to unlock the market for energy efficiency improvement on a public private partnership (PPP) basis. For a transition to low carbon economy industry is undertaking voluntary measures through scientific and technological innovations both in upstream and downstream sectors. In this paper an attempt is made to overview recent developments in Indian Aluminum industry as well as summarize scientific & technological challenges and prospects.IntroductionAluminum plays a vital role in industrial development. It is a substitute for different type of materials ranging from wood to copper and steel. The aluminum industry has high energy consumption and high contribution to greenhouse gases from carbon dioxide and perfluorocarbons (PFCs) emissions. It is estimated that CO2 equivalent burden of aluminum industry is about 1% of total anthropogenic emissions. The anticipated world growth rate is 3.5% for aluminum demand. Through measures to reduce both direct and indirect CO2 emissions, electricity consumption was reduced from 25 kWh / kg of Aluminum in 1998 to 15 kWh / kg of Aluminum produced in 2008. It is targeted to further reduce it to 10.8 kWh. Aluminum industry is also responsible to about 60% of all PFC emissions. The PFC emissions are harmful to environment, accumulate in surrounding vegetation and contaminate. Efforts to reduce PFC emissions from aluminum industry started early and reduced to 0.5-1 kg / tonne in 1990 [1] from 12-15 kg / tonne in 1940. Since 1990s to 2000 it further reduced to 0.2 -0.4 kg / tonne as seen in Fig. 1. The Global Aluminum Sustainable Development Initiative (GADSI), targets perfluorocarbon (PFC) specific emissions reduction of 80% for 2010 relative to 1990."

Jan 1, 2011

By R. W. Lawrence

A method by which it is possible at an oxidation potential below 680 mV SHE to achieve quantitative conversion of sulphide sulphur to elemental sulphur instead of sulphate in a biological leach of chalcopyrite and bornite has been investigated. The process chemistry, biological phenomena and process flowsheet options are discussed. Several copper concentrates have been evaluated and have been found to be amenable to th process. Results to study the progression of chalcopyrite decomposition during the leach are presented and mineralogical factors affecting the requirement for silver addition are discussed. A chloride addition method for improving silver recovery is described. The results of a small scale continuous leach test have demonstrated that continuous operation can be carried out with high copper extraction and stoichiometric conversion of sulphide sulphur to elemental sulphur.

Jan 1, 1985

By Onuralp Yücel, Mehmet Bugdayc, Murat Alkan

"In this study, iron based alloys (Fe-Mo, Fe-Cr-Ni, etc.) were produced by using aluminothermic methods starting from Mill Scales obtained continuous casting processes. Mill scales are an oxidised layer of steel alloys containing iron oxide, which includes + 2, + 3 values, on the surface of slabs and billets occurring during annealing in heating furnace at integrated iron and steel milling plant, and continuous casting unit. In the metallothermic experiments, different ratios of starting mixtures and addition of the oxide powders (Alz03, Si02, CaO, MgO) were examined, and their effects on the metal recovery and alloy compositions were carried out. The samples were characterized by using chemical analysis (AAS), XRD, XRF and SEM/EDS techniques.IntroductionSelf Propagating High Temperature Synthesis process (SHS) has many favour compared to the furnace applications, such as low energy requirement, low cost, very short processing time and simple operation, [l, 2]. In a SHS process, the ignition starts the combustion and propagates throughout the reactant mixture yielding the desired product. However, the disadvantages of the process such as inhomogeneous or unreacted products due to undesirable reaction rates needs to be overcome by changing some parameters such as ignition temperature, particle size, additive, atmosphere etc. [3, 4]. Mill scale is a layer of iron oxide which forms on ferrous materials cooling after being processed in hot rolling or continuous casting plants. Mill scale contains iron (II) and iron (III) oxides, which result in a 70% total iron content in oxide form. Not being able to reuse this material will prevent the raw material entering the production plant from being fully utilized [5]. This study aimed to produce Fe-based alloys via SHS (Self Propagating High Temperature Synthesis) metallurgy which is attractive process technique regarding fast and low-cost production ability of cast alloys by using high metallic iron content by reducing continuous casting mill scale."

Jan 1, 2013

By C. Leticia Hernández, P. Martín Reyes, D. Iván Alejandrox Reyes, L. Miguel Pérez, T. Julio Cesar Juárez, G. Mizraim Uriel Flores, T. Raúl Moreno, R. Aislinn Michelle Teja

This study shows the characterization of tailings from the mining district of Coscotitlán, State of Hidalgo, Mexico. Chemical analysis by Spectroscopy of atomic absorption (AAS) allowed to quantify the concentration of Fe, Mn, Zn, and Pb as the most abundant elements in the mineral sample; in addition to the presence of Sn, Te, Bi, Ni, Co, and Cd. The presence of precious metals as the Ag (64 g ton−1) and Au (0.65 g ton−1) were identified. The greater distribution of Ag was detected in particles with diameter of 74 lm. Species as pyrite (FeS2), galena (PbS) and hematite (Fe2O3) were observed in a matrix of quartz (SiO2) by Polarized Optical Microscopy (POM), these species were also identified by X-ray Diffraction (XRD). Both the elemental and mineralogical composition of tailings was corroborated by the technique Scanning Electron Microscopy - Energy Dispersive Microanalysis (SEM-EDS).

Mar 1, 2018